{"id":71122,"date":"2017-03-30T06:30:28","date_gmt":"2017-03-29T22:30:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=71122"},"modified":"2017-03-27T22:38:55","modified_gmt":"2017-03-27T14:38:55","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e2%88%a3%e9%9d%9e%e5%9d%87%e7%9b%b8%e8%87%ad%e6%b0%a7%e5%82%ac%e5%8c%96%e5%89%82%e5%b0%86%e4%bd%95%e5%8e%bb%e4%bd%95%e4%bb%8e%ef%bc%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=71122","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\u2223\u975e\u5747\u76f8\u81ed\u6c27\u50ac\u5316\u5242\u5c06\u4f55\u53bb\u4f55\u4ece\uff1f"},"content":{"rendered":"

\u975e\u5747\u76f8\u81ed\u6c27\u6c27\u5316\u6280\u672f\u5177\u6709\u5bf9\u6709\u673a\u6c61\u67d3\u7269\u6c27\u5316\u5f7b\u5e95\u3001\u7a33\u5b9a\u6027\u597d\u3001\u50ac\u5316\u5242\u53ef\u518d\u751f\u91cd\u590d\u4f7f\u7528\u7b49\u4f18\u70b9\uff0c\u8fd1\u5e74\u6765\u6210\u4e3a\u6c34\u5904\u7406\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u81ed\u6c27\u6c27\u5316\u6280\u672f\u5e94\u7528\u4e8e\u6c34\u5904\u7406\u5df2\u6709100\u591a\u5e74\u5386\u53f2\uff0c\u4f46\u662f\u76f4\u5230\u73b0\u5728\u7531\u4e8e\u7f3a\u4e4f\u5bf9\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u53cd\u5e94\u8fc7\u7a0b\u673a\u7406\u7684\u7406\u89e3\uff0c\u7279\u522b\u662f\u7f3a\u4e4f\u5bf9\u50ac\u5316\u5242\u6d3b\u6027\u53ca\u5176\u5931\u6d3b\u7684\u7406\u89e3\uff0c\u50ac\u5316\u81ed\u6c27\u8f83\u5c11\u5e94\u7528\u5728\u5de5\u7a0b\u4e2d[1]<\/sup>\u3002\u56e0\u6b64\uff0c\u76ee\u524d\u50ac\u5316\u81ed\u6c27\u9886\u57df\u52aa\u529b\u7684\u4e3b\u8981\u65b9\u5411\u8fd8\u662f\u901a\u8fc7\u7406\u8bba\u7814\u7a76\u63a8\u52a8\u6280\u672f\u5e94\u7528\u3002<\/p>\n

\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u6027\u80fd\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u50ac\u5316\u5242\u53ca\u5176\u8868\u9762\u6027\u8d28\uff0c\u4f46\u5176\u53cd\u5e94\u8fc7\u7a0b\u53ca\u673a\u5236\u590d\u6742\u3002\u4e3a\u6df1\u5165\u4e86\u89e3\u975e\u5747\u76f8\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u53cd\u5e94\u673a\u5236\uff0c\u5c06\u7740\u91cd\u4ecb\u7ecd\u4ee5\u4e0b\u4e09\u4e2a\u65b9\u9762\uff1a\u975e\u5747\u76f8\u50ac\u5316\u81ed\u6c27\u53cd\u5e94\u673a\u7406\u3001\u50ac\u5316\u5242\u8868\u9762\u7f9f\u57fa\u57fa\u56e2\u53cd\u5e94\u673a\u7406\u4ee5\u53ca\u6539\u6027\u50ac\u5316\u5242\u50ac\u5316\u81ed\u6c27\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u2160. \u975e\u5747\u76f8\u50ac\u5316\u81ed\u6c27\u53cd\u5e94\u673a\u7406<\/strong><\/span><\/p>\n

\u975e\u5747\u76f8\u50ac\u5316\u81ed\u6c27\u5316\u53cd\u5e94\u4e2d\u50ac\u5316\u5242\u4e3b\u8981\u6709\u56db\u79cd\u7c7b\u578b\uff1a\uff081\uff09\u91d1\u5c5e\u6c27\u5316\u7269\u578b\u50ac\u5316\u5242[2]<\/sup>\uff1b\uff082\uff09\u8d1f\u8f7d\u578b\u50ac\u5316\u5242[3]<\/sup>\uff1b\uff083\uff09\u77ff\u7269\u578b\u6216\u6539\u6027\u77ff\u7269\u578b[4]<\/sup>\uff1b\uff084\uff09\u6d3b\u6027\u70ad\u578b\u50ac\u5316\u5242[5]<\/sup>\u3002\u5c3d\u7ba1\u5728\u975e\u5747\u76f8\u81ed\u6c27\u50ac\u5316\u6c27\u5316\u9886\u57df\u5df2\u8fdb\u884c\u4e86\u8f83\u591a\u7814\u7a76\uff0c\u4f46\u5bf9\u4e8e\u5177\u4f53\u7684\u50ac\u5316\u53cd\u5e94\u673a\u7406\u5e76\u672a\u5e76\u672a\u7edf\u4e00\u3002\u76ee\u524d\u63d0\u51fa\u4e86\u591a\u79cd\u53cd\u5e94\u673a\u7406\uff0c\u4e3b\u8981\u6709: \u81ea\u7531\u57fa\u7406\u8bba\u3001\u6c27\u7a7a\u4f4d\u7406\u8bba\u3001\u8868\u9762\u539f\u5b50\u6c27\u7406\u8bba\u3001\u8868\u9762\u7edc\u5408\u7269\u7406\u8bba\u548c\u81ed\u6c27\u76f4\u63a5\u6c27\u5316\u7406\u8bba\u3002<\/p>\n

\u00a01.1 \u81ea\u7531\u57fa\u7406\u8bba<\/strong><\/p>\n

\"\"\u56fe\uff11 \u81ed\u6c27\u5206\u5b50\u5206\u89e3\u4ea7\u751f\u7f9f\u57fa\u81ea\u7531\u57fa\u7684\u673a\u7406[1]<\/sup><\/p>\n

\u5982\u56fe1\u6240\u793a\uff0c\u81ea\u7531\u57fa\u673a\u7406\u4e3b\u8981\u5728\u7279\u6b8a\u50ac\u5316\u5242\u8868\u9762\u4e0a\uff0c\u5c06\u81ed\u6c27\u5206\u89e3\u4e3a\u6c27\u5316\u80fd\u529b\u66f4\u5f3a\u7684\u7f9f\u57fa\u81ea\u7531\u57fa\u00b7OH\u3002Bulanin\u7b49[6]<\/sup>\u63d0\u51fa\u4e86O3<\/sub>\u5438\u9644\u5728\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u4ea7\u751f\u81ea\u7531\u57fa\u7684\u673a\u7406\u5982\u4e0b\uff1a
\n \u7b2c\u4e00\u6b65\uff1a
\n \"\"\u81ed\u6c27\u4e0e\u2261Me-OH\uff08Me\u6307\u91d1\u5c5e\u5143\u7d20\uff09\u4f5c\u7528\u4ea7\u751f\u4e86O2<\/sub>-\u00b7\u548cHO2<\/sub>\u00b7\uff0c\u5e76\u5f15\u53d1\u4e86\u4e00\u7cfb\u5217\u7684\u81ea\u7531\u57fa\u53cd\u5e94\u3002
\n \u7b2c\u4e8c\u6b65\uff1a
\n \"\"\u7b2c\u4e09\u6b65\uff1a
\n \"\"\u7b2c\u56db\u6b65\uff1a
\n \"\"O3<\/sub>\u5728n\u578b\u6c27\u5316\u7269\u8868\u9762\u5438\u9644\u4f1a\u4ea7\u751f\u8868\u9762\u7ed3\u5408\u6c27\u539f\u5b50\uff0cO3<\/sub>\u4e0ep\u578b\u6c27\u5316\u7269\u8868\u9762\u4f5c\u7528\u4f1a\u4f7fO3<\/sub>\u5206\u89e3\uff0c\u6700\u7ec8\u751f\u6210\u7f9f\u57fa\u81ea\u7531\u57fa\u00b7OH\u3002<\/p>\n

1.2 \u6c27\u7a7a\u4f4d\u7406\u8bba<\/strong><\/p>\n

\u6c27\u7a7a\u4f4d\u7406\u8bba\u5c5e\u4e8e\u81ea\u7531\u57fa\u7406\u8bba\u4e2d\u7684\u7279\u4f8b\u3002\u6c27\u5316\u7269\u7684\u8868\u9762\u5e38\u5b58\u5728\u5927\u91cf\u7684\u6676\u683c\u7f3a\u9677\uff0c\u8fd9\u4e9b\u7f3a\u9677\u5bf9\u50ac\u5316\u5242\u4e0a\u81ed\u6c27\u7684\u5206\u89e3\u9014\u5f84\u4ea7\u751f\u4e86\u5f88\u5927\u7684\u5f71\u54cd\u3002\u4ee5NiFe2<\/sub>O4<\/sub>\u4e3a\u4f8b[7]<\/sup>\uff0c\u5176\u53cd\u5e94\u673a\u7406\u5982\u4e0b\uff1a
\n \u7b2c\u4e00\u6b65\uff1a
\n \"\"\u7b2c\u4e8c\u6b65\uff1a
\n \"\"\u7b2c\u4e09\u6b65\uff1a
\n \"\"\u7b2c\u56db\u6b65\uff1a
\n \"\"\u7b2c\u4e94\u6b65\uff1a
\n \"\"
\n NiFe2<\/sub>O4<\/sub>\u50ac\u5316\u81ed\u6c27\u964d\u89e3DBP\u65f6\u9075\u5faa\u81ea\u7531\u57fa\u53cd\u5e94\uff0c\u4f46\u4e0e\u4e00\u822c\u7f9f\u57fa\u81ea\u7531\u57fa\u751f\u6210\u673a\u7406\u6709\u6240\u4e0d\u540c\uff0c\u94c1\u79bb\u5b50\u6ca1\u6709\u8d77\u5173\u952e\u4f5c\u7528\uff0c\u800c\u662fNi3+<\/sup>\/Ni2+<\/sup>\u548cO2-<\/sup>\/O2<\/sub>\u4e4b\u95f4\u76f8\u4e92\u8f6c\u6362\u7684\u5e73\u8861\u53cd\u5e94\u4fc3\u8fdb\u4e86\u7f9f\u57fa\u81ea\u7531\u57fa\u7684\u751f\u6210\u3002\u53cd\u5e94\u7684\u6d3b\u6027\u4f4d\u70b9\u4e3aNi2+<\/sup>\uff0c\u6676\u683c\u6c27\u5931\u53bb\u7535\u5b50\u88ab\u6c27\u5316\u6210\u6c27\u6c14\uff0c\u539f\u6676\u683c\u6c27\u4f4d\u7f6e\u5f62\u6210\u4e86\u7a7a\u7a74\uff0c\u5728\u5bcc\u6c27\u72b6\u6001\u4e0b\u7a7a\u7a74\u5bfc\u7535\u8fc5\u901f\u8fd8\u539f\u6210\u6676\u683c\u6c27\uff0c\u4ece\u800c\u786e\u4fdd\u4e86\u6c27\u7684\u8fde\u7eed\u4f9b\u5e94\u53ca\u50ac\u5316\u6d3b\u6027\u3002\u5982\u56fe2\u6240\u793a\u6676\u683c\u6c27\u4e0e\u6c27\u7a7a\u4f4d\u7684\u5faa\u73af\u8f6c\u53d8\u8fc7\u7a0b\u662f\u6574\u4e2a\u53cd\u5e94\u7684\u5173\u952e\u6b65\u9aa4\u3002<\/p>\n

\"\"\u56fe\uff12\u3000\u6c27\u7a7a\u4f4d\u7406\u8bba\u4ea7\u751f\u7f9f\u57fa\u81ea\u7531\u57fa\u7684\u673a\u7406[1]<\/sup><\/p>\n

1.3 \u8868\u9762\u6c27\u539f\u5b50\uff08*O\uff09\u7406\u8bba<\/strong><\/p>\n

\u975e\u5747\u76f8\u53cd\u5e94\u4e2d\uff0c\u5927\u90e8\u5206\u6587\u732e\u4e2d\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u8fc7\u7a0b\u7684\u9ad8\u6548\u90fd\u662f\u57fa\u4e8e\u7f9f\u57fa\u81ea\u7531\u57fa\u7406\u8bba\u3002\u7136\u800c\uff0c\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660e\u50ac\u5316\u81ed\u6c27\u8fc7\u7a0b\u4e0d\u4ec5\u5b58\u5728\u7f9f\u57fa\u81ea\u7531\u57fa\u7406\u8bba\uff0c\u8fd8\u5b58\u5728\u8868\u9762\u6c27\u539f\u5b50\u7406\u8bba\u3002\u5982\u88681\u6240\u793a\uff0c*O\u7684\u6c27\u5316\u80fd\u529b\u4ecb\u4e8e\u00b7OH\u548cO3<\/sub>\u4e4b\u95f4\uff0c\u5177\u6709\u6bd4\u81ed\u6c27\u66f4\u5f3a\u7684\u6c27\u5316\u80fd\u529b\u3002<\/p>\n

\u88681 \u90e8\u5206\u6c27\u5316\u5242\u7684\u6c27\u5316\u80fd\u529b\u6bd4\u8f83[1]<\/sup><\/p>\n

\"\"\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 a <\/sup>\u4ee5Cl2<\/sub>\u6c27\u5316\u80fd\u529b\u4e3a\u57fa\u51c6\u3002<\/p>\n

\u8868\u9762\u6c27\u539f\u5b50\u673a\u7406\u5982\u56fe3\u6240\u793a\u3002\u4ee5PdO\/CeO2<\/sub>\u4e3a\u4f8b[8]<\/sup>\uff0c\u81ed\u6c27\u5438\u9644\u5728PdO\u8868\u9762\uff0c\u5206\u89e3\u4e3a*<\/sup>O\uff0c\u8868\u9762\u7684\u8fc7\u6c27\u5316\u7269*<\/sup>O2<\/sub>\u548c\u6c27\u6c14\u3002\u5176\u5177\u4f53\u53cd\u5e94\u8fc7\u7a0b\u5982\u4e0b\uff1a
\n \u7b2c\u4e00\u6b65\uff1a
\n \"\"\u7b2c\u4e8c\u6b65\uff1a
\n \"\"\u7b2c\u4e09\u6b65\uff1a
\n \"\"\u7b2c\u56db\u6b65\uff1a<\/p>\n

\"\"
\n \"\"\u56fe\uff13\u3000\u81ed\u6c27\u5206\u5b50\u5206\u89e3\u4ea7\u751f\u8868\u9762\u6c27\u539f\u5b50\u81ea\u7531\u57fa\u7684\u673a\u7406[1]<\/sup><\/p>\n

\u8868\u9762\u6c27\u539f\u5b50\u4e5f\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u4e2d\u95f4\u4ea7\u7269\uff0c\u8fdb\u800c\u8f6c\u5316\u4e3a*<\/sup>O\u548c\u00b7OH\uff0c\u4e8c\u8005\u534f\u540c\u6709\u6548\u964d\u89e3\u6709\u673a\u7269[9]<\/sup>\u3002<\/p>\n

1.4 \u7edc\u5408\u7269\u7406\u8bba<\/strong><\/p>\n

\u5bf9\u4e8e\u975e\u5747\u76f8\u50ac\u5316\u5242\uff0c\u7edc\u5408\u7269\u7406\u8bba\u7c7b\u4f3c\u4e8e\u5747\u76f8\u91d1\u5c5e\u79bb\u5b50\u50ac\u5316\u81ed\u6c27\u53cd\u5e94\u673a\u7406\uff1a\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u5177\u6709\u7a7a\u7684d\u8f68\u9053\uff0c\u540c\u65f6\u5927\u591a\u6570\u6709\u673a\u6c61\u67d3\u7269\u5177\u6709\u4e0d\u9971\u548c\u952e\u3001\u82b3\u73af\u7b49\u7535\u5b50\u4e91\u5bc6\u5ea6\u5f88\u5927\u7684\u5b98\u80fd\u56e2\uff0c\u4e24\u8005\u4e4b\u95f4\u5bb9\u6613\u5f62\u6210\u91d1\u5c5e\u6709\u673a\u914d\u5408\u7269\u3002\u4ee5CuO\/CeO2<\/sub>\u50ac\u5316\u81ed\u6c27\u964d\u89e3\u8349\u9178\u4e3a\u4f8b[10]<\/sup>:
\n \u7b2c\u4e00\u6b65\uff1a
\n \"\"\u7b2c\u4e8c\u6b65\uff1a
\n \"\"\u7b2c\u4e09\u6b65\uff1a
\n \"\"\u7b2c\u56db\u6b65\uff1a
\n \"\"\u81ed\u6c27\u5c06\u50ac\u5316\u5242\u8868\u9762\u5b58\u5728\u7684Cu\uff08\u2160\uff09\u6c27\u5316\u6210\u66f4\u5bb9\u6613\u5f62\u6210Cu\uff08\u2161\uff09\u2043\u8349\u9178\u7edc\u5408\u7269\u7684\u65b0\u578bCu\uff08\u2161\uff09\u3002\u7136\u540e\u81ed\u6c27\u6781\u6709\u53ef\u80fd\u5c06\u65b0\u578bCu\uff08\u2161\uff09\u8fdb\u4e00\u6b65\u6c27\u5316\u6210\u9ad8\u4ef7\u6001\u7684Cu\uff08\u2162\uff09\u7edc\u5408\u7269\uff0c\u800cCu\uff08\u2162\uff09\u7edc\u5408\u7269\u5f88\u4e0d\u7a33\u5b9a\uff0c\u914d\u4f53\u5206\u5b50\u5185\u7535\u5b50\u8f6c\u79fb\u5f62\u6210\u66f4\u52a0\u7a33\u5b9a\u7684Cu\uff08\u2161\uff09\uff0c\u751f\u6210\u8fd8\u539f\u6027\u5f88\u5f3a\u7684\u8349\u9178\u81ea\u7531\u57fa\u3002\u7531\u4e8e\u8349\u9178\u81ea\u7531\u57fa\u8fd8\u539f\u6027\u5f88\u5f3a\uff0c\u6709\u5f88\u9ad8\u7684\u53cd\u5e94\u901f\u7387\uff0c\u80fd\u4e0e\u5206\u5b50\u6c27\u53cd\u5e94\u88ab\u964d\u89e3\u3002<\/p>\n

1.5 \u81ed\u6c27\u76f4\u63a5\u6c27\u5316\u7406\u8bba<\/strong><\/p>\n

\u81ed\u6c27\u672c\u8eab\u4e5f\u662f\u4e00\u79cd\u5f3a\u6c27\u5316\u5242\uff0c\u53ef\u4ee5\u76f4\u63a5\u5c06\u6709\u673a\u6c61\u67d3\u7269\u6c27\u5316\u964d\u89e3\u3002<\/p>\n

\u2161.\u50ac\u5316\u5242\u8868\u9762\u7f9f\u57fa\u57fa\u56e2\u53cd\u5e94\u673a\u7406<\/strong><\/span><\/p>\n

\u81ed\u6c27\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u5206\u89e3\u662f\u50ac\u5316\u5242\u6d3b\u6027\u7684\u4e00\u4e2a\u51b3\u5b9a\u6027\u56e0\u7d20\u3002\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u4e00\u822c\u4e3a\u5176\u8868\u9762\u78b1\u6027\u542b\u6c27\u57fa\u56e2\uff0c\u5982\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u7684\u7f9f\u57fa\u57fa\u56e2\u3002Lewis\u9178\u4f4d\u548cLewis\u78b1\u4f4d\u5206\u522b\u4f4d\u4e8e\u91d1\u5c5e\u6c27\u5316\u7269\u4e0a\u91d1\u5c5e\u79bb\u5b50\u548c\u914d\u4f4d\u4e0d\u9971\u548c\u7684\u7ed3\u5408\u6c27\u4f4d\u70b9\u4e0a\u3002\u7531\u4e8e\u8868\u9762\u7535\u8377\u5e76\u672a\u5e73\u8861\uff0c\u5f53\u50ac\u5316\u5242\u88ab\u52a0\u5165\u6eb6\u6db2\u4e2d\uff0c\u6c34\u5206\u5b50\u5f3a\u70c8\u5730\u5438\u9644\u5728\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u8868\u9762[11]<\/sup>\uff0c\u50ac\u5316\u5242\u4e0a\u7684Lewis \u9178\u4f4d\u4e0e\u8868\u9762\u5316\u5b66\u5438\u9644\u7684\u6c34\u5206\u5b50\u53d1\u751f\u914d\u4f4d\uff0c\u4ece\u800c\u4f7f\u6c34\u79bb\u89e3\u4ea7\u751f\u8868\u9762\u7f9f\u57fa\u3002\u56e0\u6b64\u6240\u6709\u6c27\u5316\u7269\u9762\u4e0a\u4e00\u822c\u90fd\u5b58\u5728\u7f9f\u57fa\u57fa\u56e2\u3002\u7531\u4e8e\u81ed\u6c27\u5206\u5b50\u7ed3\u6784\u4e2d\u6709\u4e00\u4e2a\u6c27\u539f\u5b50\u5177\u6709\u66f4\u9ad8\u7684\u7535\u5b50\u5bc6\u5ea6\uff0c\u5bfc\u81f4\u5bf9\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u7684Lewis\u9178\u6027\u4f4d\u70b9\u6709\u66f4\u5f3a\u7684\u4eb2\u5408\u529b\u3002\u56e0\u6b64\uff0c\u50ac\u5316\u81ed\u6c27\u53cd\u5e94\u4e2d\u50ac\u5316\u5242\u8868\u9762\u7f9f\u57fa\u662f\u91cd\u8981\u7684\u6d3b\u6027\u57fa\u56e2\uff0c\u5728\u6eb6\u6db2\u4e2d\u80fd\u591f\u5f71\u54cd\u50ac\u5316\u5242\u5728\u56fa\u6db2\u754c\u9762\u7684\u7535\u6027\uff0c\u5177\u6709\u91cd\u8981\u4f5c\u7528\u3002\u8868\u9762\u7f9f\u57fa\u6613\u4e0e\u5438\u9644\u5728\u50ac\u5316\u5242\u8868\u9762\u4e0a\u7684\u81ed\u6c27\u53d1\u751f\u53cd\u5e94\u751f\u6210\u7f9f\u57fa\u81ea\u7531\u57fa\uff0c\u6c27\u5316\u964d\u89e3\u6709\u673a\u6c61\u67d3\u7269[12]<\/sup>\u3002<\/p>\n

\u7f9f\u57fa\u81ea\u7531\u57fa\u7684\u5bc6\u5ea6\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u50ac\u5316\u5242\u7684pHpzc<\/sub>\uff0c\u5728\u6eb6\u6db2pH\uff1dpHpzc<\/sub>\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316\u5242\u8868\u9762\u8d28\u5b50\u5e73\u8861\u4ea7\u751f\u7684\u6b63\u7535\u8377\u548c\u8d1f\u7535\u8377\u603b\u91cf\u662f\u5e73\u8861\u7684\u3002\u6240\u4ee5\uff0c\u4e0d\u540c\u7684\u6eb6\u6db2pH\u503c\u4f1a\u5bfc\u81f4\u50ac\u5316\u5242\u8868\u9762\u5177\u6709\u4e0d\u540c\u7684\u8377\u7535\u72b6\u6001\u3002\u5982\u88682\u6240\u793a\uff0c\u50ac\u5316\u5242\u7684\u9ad8\u50ac\u5316\u6d3b\u6027\u662f\u5728pH\u503c\u63a5\u8fd1\u4e8epHpzc<\/sub>\u65f6\u3002<\/p>\n

\u88682 \u5728\u50ac\u5316\u81ed\u6c27\u5316\u53cd\u5e94\u4e2d\u4e0d\u540c\u50ac\u5316\u5242\u7684pHpzc<\/sub>\u548c\u6700\u4f18pH\u6bd4\u8f83[1]\"\"<\/sup><\/p>\n

\u2162. \u6539\u6027\u50ac\u5316\u5242\u50ac\u5316\u81ed\u6c27\u53cd\u5e94\u673a\u7406<\/strong><\/span><\/p>\n

3.1\u6539\u6027\u50ac\u5316\u5242\u7684\u6027\u80fd<\/strong><\/p>\n

\u6d3b\u6027\u7ec4\u5206\u5728\u8f7d\u4f53\u4e0a\u7684\u5206\u5e03\u5f62\u6001\u4ee5\u53ca\u8868\u9762\u6d3b\u6027\u4f4d\u53d8\u5316\u5bf9\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u679c\u81f3\u5173\u91cd\u8981\uff0c\u76ee\u524d\u5f88\u591a\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u4e8e\u4ee5\u4e0b\u4e09\u7c7b\u50ac\u5316\u5242\u7684\u7814\u5236\uff1a\u591a\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u6539\u6027\u6d3b\u6027\u70ad\u53ca\u6539\u6027\u77ff\u7269\u3002\u8d35\u91d1\u5c5e\u5177\u6709\u5f88\u597d\u7684\u50ac\u5316\u6548\u679c\uff0c\u4f46\u6602\u8d35\u7684\u4ef7\u683c\u9650\u5236\u4e86\u5e94\u7528\uff0c\u590d\u5408\u91d1\u5c5e\u53ca\u8d1f\u8f7d\u578b\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7814\u7a76\u6700\u5f00\u59cb\u662f\u4ee5\u63ba\u6742\u8d35\u91d1\u5c5e\u5143\u7d20\u4e3a\u4e3b\u7684\u3002\u968f\u7740\u7814\u7a76\u7684\u6df1\u5165\uff0c\u53d1\u73b0\u8f7d\u4f53\u7684\u4f7f\u7528\u4e0d\u4ec5\u53ef\u964d\u4f4e\u50ac\u5316\u5242\u7684\u4f7f\u7528\u6210\u672c\uff0c\u800c\u4e14\u8f7d\u4f53\u548c\u50ac\u5316\u5242\u7684\u76f8\u4e92\u4f5c\u7528\u8fd8\u53ef\u6539\u5584\u50ac\u5316\u6027\u80fd[14]<\/sup>\u3002\u56e0\u6b64\u63ba\u6742\u4f4e\u4ef7\u91d1\u5c5e\u4ee5\u53ca\u91d1\u5c5e\u6c27\u5316\u7269\u4e3a\u4e3b\u7684\u50ac\u5316\u5242\u9010\u6e10\u6210\u4e3a\u4e3b\u6d41\u3002<\/p>\n

3.2 \u6539\u6027\u50ac\u5316\u5242\u7684\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\u50ac\u5316\u5242\u8868\u9762\u7684\u6d3b\u6027\u4f4d\u70b9\u589e\u52a0<\/u> \u8f7d\u4f53\u4e0e\u50ac\u5316\u5242\u3001\u50ac\u5316\u5242\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u76f8\u4e92\u8f85\u52a9\uff0c\u8868\u9762\u7684\u6d3b\u6027\u4f4d\u70b9\u589e\u52a0\uff0c\u80fd\u591f\u4fc3\u8fdb\u81ed\u6c27\u5206\u89e3\u4ea7\u751f\u6c27\u5316\u6d3b\u6027\u7269\u79cd\uff0c\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

\u589e\u5927\u6bd4\u8868\u9762\u79ef<\/u> \u8d1f\u8f7d\u578b\u50ac\u5316\u5242\u7684\u8f7d\u4f53\u901a\u5e38\u9009\u62e9\u6bd4\u8868\u9762\u79ef\u8f83\u5927\u7684\u7269\u8d28\uff0c\u5982Al2<\/sub>O3<\/sub>,\u6d3b\u6027\u70ad\u548c\u4ecb\u5b54\u6750\u6599\u7b49\uff0c\u76ee\u7684\u662f\u901a\u8fc7\u63d0\u9ad8\u6539\u6027\u50ac\u5316\u5242\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u63d0\u9ad8\u5438\u9644\u548c\u53cd\u5e94\u6027\u80fd\u3002<\/p>\n

\u63d0\u9ad8\u7535\u5b50\u8f6c\u79fb\u7684\u901f\u7387<\/u> \u4ee5AC-Ce-O\u4e3a\u4f8b[15]<\/sup>\u4e3a\u4f8b\uff0c\u5176\u4e2d\u6d3b\u6027\u70ad\u5728\u5408\u6210\u6837\u54c1\u4e2d\u53d1\u6325\u7684\u4f5c\u7528\u4e0e\u4ee5\u5f80\u4e0d\u540c\uff0c\u4e3a\u6709\u673a\u7269\u53ca\u81ed\u6c27\u5438\u9644\u548c\u53cd\u5e94\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5f88\u5927\u7684\u8868\u9762\u79ef\u662f\u4e00\u65b9\u9762\uff0c\u53e6\u4e00\u65b9\u9762\u5728\u6d3b\u6027\u70ad\u8868\u9762\u83b7\u5f97\u7684\u81ea\u7531\u7535\u5b50\u53ef\u4ee5\u5f15\u8d77Ce3+<\/sup>\u7684\u4ea7\u751f\uff0c\u800cCe3+<\/sup>\u5bf9\u81ed\u6c27\u5206\u89e3\u4ea7\u751f\u00b7OH\u662f\u5f88\u6709\u6548\u7684\u3002<\/p>\n

\u2163. \u00a0\u7ed3\u8bed<\/strong><\/span><\/p>\n

\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u53cd\u5e94\u662f\u4e00\u79cd\u6709\u6548\u7684\u9ad8\u7ea7\u6c27\u5316\u6280\u672f\uff0c\u4f46\u7531\u4e8e\u5747\u76f8\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u53cd\u5e94\u5b58\u5728\u7684\u5c40\u9650\u6027\uff0c\u975e\u5747\u76f8\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u6280\u672f\u56e0\u5176\u6c27\u5316\u80fd\u529b\u5f3a\u3001\u80fd\u660e\u663e\u63d0\u9ad8\u6709\u673a\u7269\u77ff\u5316\u7387\u3001\u51cf\u5c11\u81ed\u6c27\u6295\u52a0\u91cf\u7b49\u4f18\u70b9\u800c\u5907\u53d7\u5173\u6ce8\u3002\u81ed\u6c27\u5206\u89e3\u4ea7\u751f\u7684\u6c27\u6d3b\u6027\u7269\u79cd\u662f\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u53cd\u5e94\u4e2d\u964d\u89e3\u6c61\u67d3\u7269\u7684\u4e3b\u8981\u6c27\u5316\u5242\uff0c\u81ed\u6c27\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u5206\u89e3\u8fc7\u7a0b\u53ca\u542b\u6c27\u6d3b\u6027\u7269\u79cd\u7684\u79cd\u7c7b\u4e00\u76f4\u662f\u7814\u7a76\u7684\u70ed\u70b9\u3002\u81ed\u6c27\u50ac\u5316\u5242\u901a\u8fc7\u6539\u6027\u80fd\u591f\u6539\u5584\u6027\u80fd\uff0c\u63d0\u9ad8\u81ed\u6c27\u7684\u5229\u7528\u6548\u7387\uff0c\u7136\u800c\u50ac\u5316\u5242\u7684\u5408\u6210\u5b58\u5728\u5f88\u591a\u95ee\u9898\u3002\u50ac\u5316\u5242\u7684\u5408\u6210\u5de5\u827a\u867d\u7136\u65e5\u76ca\u5b8c\u5584\uff0c\u4f46\u63a7\u5236\u50ac\u5316\u5242\u5408\u6210\u7684\u673a\u7406\u3001\u50ac\u5316\u5242\u7684\u6210\u672c\u8f83\u9ad8\u53ca\u7a33\u5b9a\u6027\u90fd\u6709\u5f85\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u3002<\/p>\n

\u5728\u4eca\u540e\u7684\u7814\u7a76\u4e2d\uff0c\u4ecd\u9700\u5173\u6ce8\uff1a\uff08\uff11\uff09\u53cd\u5e94\u673a\u5236\uff0c\u5c24\u5176\u662f\u6539\u6027\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\u673a\u5236\uff0c\u5206\u6e05\u5404\u79cd\u50ac\u5316\u5242\u7ec4\u5206\u6240\u8d77\u4f5c\u7528\uff1b\uff08\uff12\uff09\u6df1\u5165\u7814\u7a76\u50ac\u5316\u5242\u8868\u9762\u5fae\u89c2\u52a8\u529b\u5b66\uff0c\u5229\u7528\u5404\u79cd\u5148\u8fdb\u7684\u6280\u672f\u4ece\u5fae\u89c2\u89d2\u5ea6\u5206\u6790\u50ac\u5316\u5242\u7684\u7ed3\u6784\u4e0e\u8868\u89c2\u6027\u80fd\u7684\u5173\u7cfb\uff0c\u660e\u786e\u50ac\u5316\u5242\u7684\u5408\u6210\u673a\u7406\u3001\u50ac\u5316\u5242\u5931\u6d3b\u7684\u539f\u56e0\uff1b\uff08\uff13\uff09\u76ee\u6807\u6c61\u67d3\u7269\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u4f5c\u7528\uff0c\u50ac\u5316\u5242\u7684\u6027\u8d28\u4e0e\u76ee\u6807\u6c61\u67d3\u7269\u7684\u964d\u89e3\u9014\u5f84\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u9488\u5bf9\u76ee\u6807\u6c61\u67d3\u7269\u9009\u62e9\u5408\u9002\u7684\u50ac\u5316\u5242\u7c7b\u578b\u3002<\/strong><\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

[1] \u00a0\u5218\u83b9, \u4f55\u7ea2\u5e73, \u5434\u5fb7\u793c, \u7b49. \u975e\u5747\u76f8\u50ac\u5316\u81ed\u6c27\u6c27\u5316\u53cd\u5e94\u673a\u5236 [J]. \u5316\u5b66\u8fdb\u5c55, 2016, 28(7): 1112-1120.<\/p>\n

[2] \u00a0Cooper C, Burch R. An investigation of catalytic ozonation for the oxidation of halocarbons in drin-king water preparation [J]. Water Research, 1999, 33(18): \u00a03695-3700.<\/p>\n

[3] \u00a0Carbajo M, Rivas F J, Beltran F J, et al. Effects of different catalysts on the ozonation of pyruvic acid in water [J]. Ozone: Science and Engineering, 2006, 28(4): 229-235.<\/p>\n

[4] \u00a0Azrague K, Osterhus S W, Biomorgi J G. Degradation of pCBA by catalytic ozonation in natural water [J]. Water Science and Technology, 2009, 59(6): 1209-1217.<\/p>\n

[5]\u00a0 McKay G, McAleavey G. Ozonation and carbon adsorption in a three-phase fluidised bed for colo-ur removal from peat water [J]. Chemical Engineering Research and Design, 1998, 66(-): 531–<\/p>\n

[6] \u00a0Bulanin K M, Lavalley J C, Tsyganenko A A. Infrared Study of Ozone Adsorption on TiO2 (Anatase) [J]. Journal of Physical Chemistry, 1995, 99(25): 10294-10298.<\/p>\n

[7] \u00a0Yueming R, Qing D, Jing F et al. Magnetic porous ferrospinel NiFe2<\/sub>O4<\/sub>: A novel ozonation catalyst with strong catalytic property for degradation of di-n-butyl phthalate and convenient separation from\u00a0 water [J]. Journal of Colloid and Interface Science, 2012, 382(1): 90-96.<\/p>\n

[8] \u00a0Zhang T, Li W, Groue J P. Catalytic ozonation of oxalate with a cerium supported palladium oxide: an efficient degradation not relying on hydroxyl radical oxidation [J]. Environmental Science and Tech-nology, 2011, 45(21): 9339-9348.<\/p>\n

[9] \u00a0Julia L R, Tatiana P, Miguel A V, et al. Surface interactions and mechanistic studies of 2,4-dichlor-ophenoxyacetic acid degradation by catalytic ozonation in presence of Ni\/TiO2<\/sub> [J]. Chemical Enginee-ring Journal, 2013, 222(15): 426-434.<\/p>\n

[10] Zhang T, Li W, Groue J P. A non-acid-assisted and non-hydroxyl-radical-related catalytic ozonati-on with ceria supported copper oxide in efficient oxalate degradation in water [J]. Applied Catalysis B: Environmental, 2012, 121-122: 88-94.<\/p>\n

[11] Joseph Y, Ranke W, Weiss W. Water on FeO(111) and Fe3O4(111):\u2009 adsorption behavior on diff-erent surface terminations [J]. The Journal of Physical Chemistry B, 2000,104(14): 3224-3228.<\/p>\n

[12] Ernst M, Lurota F, Schrottera J C. Catalytic ozonation of refractory organic model compounds in aqueous solution by aluminum oxide [J]. Applied Catalysis B: Environmental, 2004 47(1): 15-25.<\/p>\n

[13] Zhao L, Ma J, Sun Z, et al. Catalytic ozonation for the degradation of nitrobenzene in aqueous so-lution by ceramic honeycomb-supported manganese [J]. Applied Catalysis B: Environmental, 2008, 83(3-4): 256-264.<\/p>\n

[14] Park C, Keane M A. Catalyst support effects: gas-phase hydrogenation of phenol over palladium [J]. Journal of Colloid and Interface Science, 2003 166(1): 183-194.<\/p>\n

[15] Liu X, Zhou Z, Jing G, et al. Catalytic ozonation of Acid Red B in aqueous solution over a Fe\u2013Cu\u2013O catalyst [J]. Separation and Purification Technology, 2013: 129-135.<\/p>\n

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