{"id":70715,"date":"2017-03-16T06:30:28","date_gmt":"2017-03-15T22:30:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=70715"},"modified":"2017-03-14T22:35:58","modified_gmt":"2017-03-14T14:35:58","slug":"jacs%e5%85%b7%e6%9c%89%e9%ab%98%e5%8e%8b%e7%94%b5%e5%ba%94%e5%8f%98%e3%80%81%e9%ab%98%e7%83%ad%e7%a8%b3%e5%ae%9a%e6%80%a7%e7%9a%84%e7%a2%b1%e9%87%91%e5%b1%9e%e9%93%8c%e9%85%b8%e7%9b%90%e6%97%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=70715","title":{"rendered":"JACS\uff1a\u5177\u6709\u9ad8\u538b\u7535\u5e94\u53d8\u3001\u9ad8\u70ed\u7a33\u5b9a\u6027\u7684\u78b1\u91d1\u5c5e\u94cc\u9178\u76d0\u65e0\u94c5\u9499\u949b\u77ff\u538b\u7535\u9676\u74f7\u6750\u6599"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u538b\u7535\u6750\u6599\u53ef\u4ee5\u5b9e\u73b0\u673a\u68b0\u80fd\u548c\u7535\u80fd\u7684\u76f8\u4e92\u8f6c\u5316\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u56fd\u9632\u3001\u751f\u7269\u533b\u5b66\u3001\u5149\u7535\u5b50\u7b49\u9886\u57df\u3002PZT\u6750\u6599\u51ed\u501f\u5176\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u5360\u636e\u7740\u4e16\u754c\u538b\u7535\u6750\u6599\u8fd9\u5757\u7edd\u5927\u90e8\u5206\u5e02\u573a\u4efd\u989d\u3002\u4f46\u968f\u7740\u4eba\u4eec\u5bf9\u73af\u5883\u95ee\u9898\u7684\u65e5\u76ca\u5173\u6ce8\uff0c\u5f00\u53d1\u4e00\u79cd\u6027\u80fd\u4f18\u79c0\u65e0\u94c5\u538b\u7535\u6750\u6599\u53d6\u4ee3\u542b\u94c5\u7684PZT\u6750\u6599\uff0c\u662f\u4e00\u4e2a\u6025\u9700\u89e3\u51b3\u7684\u95ee\u9898\u3002\uff08K\uff0cNa\uff09NbO<sub>3<\/sub>\u662f\u6700\u5177\u6709\u6f5c\u529b\u7684\u65e0\u94c5\u6750\u6599\u4f53\u7cfb\u4e4b\u4e00\uff0c\u4f46\u5176\u6e29\u5ea6\u7a33\u5b9a\u6027\u5dee\uff0c\u4e0d\u5229\u4e8e\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea<strong>\u6e05\u534e\u5927\u5b66\u738b\u8f72<\/strong>\u7b49\u4eba\u6210\u529f\u5236\u5907\u4e86\u4e00\u79cdKNN\u65e0\u94c5\u538b\u7535\u9676\u74f7\uff0c\u5176\u5177\u6709\u5f88\u9ad8\u7684\u538b\u7535\u5e94\u53d8\uff0c\u800c\u4e14\u5176\u6e29\u5ea6\u7a33\u5b9a\u6027\u4e5f\u5341\u5206\u4f18\u5f02\uff0c\u5ab2\u7f8ePZT\u9676\u74f7\u6750\u6599\uff0c\u5927\u5927\u63a8\u52a8\u4e86KNN\u65e0\u94c5\u538b\u7535\u9676\u74f7\u7684\u5e94\u7528\u3002<\/p>\n<p>\u4ed6\u4eec\u7528\u4f20\u7edf\u56fa\u76f8\u6cd5\u5236\u5907\u4e86MnO<sub>2<\/sub>\u63ba\u6742\u7684 ( Na<sub>0.5<\/sub>K<sub>0.5 <\/sub>)NbO<sub>3<\/sub>-( Bi<sub>0.5<\/sub>Li<sub>0.5 <\/sub>)TiO<sub>3<\/sub>-BaZrO<sub>3<\/sub>\u65e0\u94c5\u538b\u7535\u9676\u74f7\u6750\u6599\uff0c\u53d1\u73b0\u5176\u5927\u4fe1\u53f7\u538b\u7535\u5e94\u53d8\u7cfb\u6570(d<sub>33<\/sub>*)\u9ad8\u8fbe470 pm\/V\uff0c\u800c\u4e14\u5176\u5c45\u91cc\u6e29\u5ea6(T<sub>c<\/sub>=243 \u00b0C)\u4e5f\u8f83\u9ad8\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5176\u5177\u6709\u5f88\u597d\u7684\u6e29\u5ea6\u7a33\u5b9a\u6027\uff0c\u5927\u4fe1\u53f7\u538b\u7535\u5e94\u53d8\u7cfb\u6570(d<sub>33<\/sub>*)\u4ece\u5ba4\u6e29\u5230170 \u00b0C\u90fd\u4fdd\u6301\u7740\u8f83\u9ad8\u7684\u6c34\u5e73(100\u00b0C\u65f6\u4e3a430 pm\/V\uff0c170\u00b0C\u4e3a370 pm\/V)\u3002\u4ed6\u4eec\u8fd8\u5bf9\u8be5\u9676\u74f7\u6750\u6599\u8fdb\u884c\u4e86\u70ed\u9000\u6781\u5316\u7535\u6d41TSDC\u5206\u6790\uff0c\u4ece\u5b8f\u89c2\u89d2\u5ea6\u63ed\u793a\u4e86MnO<sub>2<\/sub>\u63ba\u6742\u7684KNN\u9676\u74f7\u6750\u6599\u5177\u6709\u66f4\u5c11\u7684\u7f3a\u9677\u548c\u66f4\u5f3a\u7684\u94c1\u7535\u6027\u3002\u53e6\u5916\uff0c\u4ed6\u4eec\u8fd8\u5bf9\u8be5\u9676\u74f7\u6750\u6599\u8fdb\u884c\u4e86\u5c40\u57df\u6781\u5316\u5b9e\u9a8c\u548cSS-PFM(\u7574\u8f6c\u5149\u8c31-\u538b\u7535\u529b\u663e\u5fae\u955c)\u8868\u5f81\uff0c\u4ece\u5fae\u89c2\u89d2\u5ea6\u63ed\u793a\u4e86\u5176\u589e\u5f3a\u7684\u94c1\u7535\u6027\u548c\u7574\u7684\u8fd0\u52a8\u3002\u4e0d\u540c\u7684\u6676\u7c92\u751f\u957f\u548c\u76f8\u89d2\u7684\u63d0\u9ad8\u53ef\u80fd\u662fMnO<sub>2<\/sub>\u63ba\u6742\u7684KNN\u9676\u74f7\u6027\u80fd\u63d0\u5347\u7684\u539f\u56e0\u3002<\/p>\n<p>\u4ed6\u4eec\u5236\u5907\u7684MnO<sub>2<\/sub>\u63ba\u6742\u7684KNN\u9676\u74f7\u5177\u6709\u9ad8\u7684\u5927\u4fe1\u53f7\u538b\u7535\u5e94\u53d8\u7cfb\u6570(d<sub>33<\/sub>*)\uff0c\u5f88\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u80fd\uff0c\u6709\u671b\u53d6\u4ee3\u4f20\u7edf\u7684PZT\u538b\u7535\u6750\u6599\uff0c\u6781\u5927\u5730\u63a8\u52a8\u4e86\u65e0\u94c5\u538b\u7535\u9676\u74f7\u6750\u6599\u7684\u53d1\u5c55\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1\u00a0 KNN<\/strong><strong>\u9676\u74f7\u6750\u6599\u7ed3\u6784\u548c\u7535\u5b66\u6027\u80fd\u7684\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70716\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b7.png\" alt=\"\" width=\"500\" height=\"346\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b7.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b7-300x208.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\uff08a\uff09XRD\u56fe\u8c31\uff0c2\u03b8\u8303\u56f4\u662f20\u00b0\u221260\u00b0\u3002<\/p>\n<p>\uff08b\uff09\u672a\u6781\u5316\u7684KNN-BLT-BZ-xMn ( x= 0.0\u22122.0 ) \u9676\u74f7\u7684\u4ecb\u7535\u6e29\u8c31\u4e0e\u635f\u8017\u8c31\u3002<\/p>\n<p>\uff08c\uff09KNN-BLT-BZ-xMn ( x= 0.0\u22122.0 ) \u9676\u74f7\u5355\u6781\u5e94\u53d8\u4e0e\u6e29\u5ea6\u7684\u66f2\u7ebf\u3002<\/p>\n<p>\uff08d\uff09KNN-BLT-BZ-xMn ( x= 0.0\u22122.0 ) \u9676\u74f7\u5927\u4fe1\u53f7\u538b\u7535\u5e94\u53d8\u7cfb\u6570 ( d<sub>33<\/sub>* ) \u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u66f2\u7ebf\uff0c\u6e29\u5ea6\u4ece\u5ba4\u6e29\u5230170 \u00b0C\uff0c\u6d4b\u8bd5\u9891\u7387\u4e3a1Hz\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>2\u00a0 <\/strong><strong>\u4e0d\u540c<\/strong><strong>MnO2<\/strong><strong>\u63ba\u6742\u91cf\u7684<\/strong><strong>KNN-BLT-BZ<\/strong><strong>\u538b\u7535\u9676\u74f7\u7684\u8868\u9762\u5f62\u8c8c<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70720\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b71.png\" alt=\"\" width=\"500\" height=\"372\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b71.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b71-300x223.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\uff08a\uff09x=0 KNN\u9676\u74f7\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u56fe\u3002<\/p>\n<p>\uff08b\uff09x=1.0 KNN\u9676\u74f7\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u56fe\u3002<\/p>\n<p>\uff08c\uff09x=0 KNN\u9676\u74f7\u538b\u7535\u529b\u663e\u5fae\u955c\u5782\u76f4\u89c2\u6d4b\u76f8\u56fe\u3002<\/p>\n<p>\uff08d\uff09x=1.0 KNN\u9676\u74f7\u538b\u7535\u529b\u663e\u5fae\u955c\u4fa7\u9762\u89c2\u6d4b\u76f8\u56fe\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3\u00a0 <\/strong><strong>KNN-BLT-BZ<\/strong>-xMn<strong>\u538b\u7535\u9676\u74f7<\/strong><strong>\u7684\u963b\u6297<\/strong><strong>\u3001<\/strong><strong>\u76f8\u89d2\u4e0e\u9891\u7387\u7684\u5173\u7cfb<\/strong><strong>\u4ee5\u53ca<\/strong><strong>\u70ed\u9000\u6781\u5316\u7535\u6d41<\/strong><strong>\u3001<\/strong><strong>\u8ba1\u7b97\u7684\u5269\u4f59\u6781\u5316\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70718\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b72-1.png\" alt=\"\" width=\"500\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b72-1.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b72-1-300x204.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\uff08a\uff09x=0 \u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7\u5ba4\u6e29\u4e0b\u7684\u963b\u6297\u548c\u76f8\u89d2\u4e0e\u9891\u7387\u7684\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n<p>\uff08b\uff09x=1.5 \u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7\u5ba4\u6e29\u4e0b\u7684\u963b\u6297\u548c\u76f8\u89d2\u4e0e\u9891\u7387\u7684\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n<p>\uff08c\uff09x=0\u30011.5 \u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7\u9000\u6781\u5316\u7535\u6d41\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n<p>\uff08d\uff09x=0\u30011.5 \u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u8ba1\u7b97\u5269\u4f59\u6781\u5316\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>4\u00a0 \u00a0\u00a0<\/strong><strong>KNN-BLT-BZ<\/strong>-xMn<strong>\u538b\u7535\u9676\u74f7\u6781\u5316\u884c\u4e3a<\/strong><strong>\u3001<\/strong><strong>\u538b\u7535\u54cd\u5e94\u6ede\u56de\u7ebf<\/strong><strong>\u3001<\/strong><strong>\u5178\u578b\u7684\u8774\u8776\u5f62\u632f\u5e45\u4e0e\u7535\u538b\u5173\u7cfb\u66f2\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70719\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b73.png\" alt=\"\" width=\"500\" height=\"232\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b73.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/\u6355\u83b73-300x139.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\uff08a\uff09x=0.0\u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7PFM\u9762\u5916\u6a21\u5f0f\u4e0b\u632f\u5e45\u56fe\uff0c\u5927\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff084 \u00d7 4 \u03bcm<sup>2<\/sup>\uff09\u5148\u88ab-15v\u7684\u76f4\u6d41\u7535\u538b\u6781\u5316\uff0c\u7136\u540e\u5c0f\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff081 \u00d7 1\u03bcm<sup>2<\/sup>\uff09\u88ab\u4e0d\u540c\u6570\u503c\uff080v\u30015v\u300110v\u300115v\uff09\u7684\u6b63\u5411\u7535\u538b\u6781\u5316\u3002<\/p>\n<p>\uff08b\uff09x=0.0\u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7PFM\u9762\u5916\u6a21\u5f0f\u4e0b\u76f8\u56fe\uff0c\u5927\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff084 \u00d7 4 \u03bcm<sup>2<\/sup>\uff09\u5148\u88ab-15v\u7684\u76f4\u6d41\u7535\u538b\u6781\u5316\uff0c\u7136\u540e\u5c0f\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff081 \u00d7 1\u03bcm<sup>2<\/sup>\uff09\u88ab\u4e0d\u540c\u6570\u503c\uff080v\u30015v\u300110v\u300115v\uff09\u7684\u6b63\u5411\u7535\u538b\u6781\u5316\u3002<\/p>\n<p>\uff08c\uff09x=0.0\u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7\u538b\u7535\u54cd\u5e94\u6ede\u56de\u7ebf\u548c\u5178\u578b\u7684\u8774\u8776\u5f62\u632f\u5e45\u4e0e\u7535\u538b\u5173\u7cfb\u66f2\u7ebf<\/p>\n<p>\uff08d\uff09x=0.15\u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7PFM\u9762\u5916\u6a21\u5f0f\u4e0b\u632f\u5e45\u56fe\uff0c\u5927\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff084 \u00d7 4 \u03bcm<sup>2<\/sup>\uff09\u5148\u88ab-10v\u7684\u76f4\u6d41\u7535\u538b\u6781\u5316\uff0c\u7136\u540e\u5c0f\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff081 \u00d7 1\u03bcm<sup>2<\/sup>\uff09\u88ab\u4e0d\u540c\u6570\u503c\uff080v\u30013.3v\u30016.6v\u300110v\uff09\u7684\u6b63\u5411\u7535\u538b\u6781\u5316\u3002<\/p>\n<p>\uff08e\uff09x=1.5\u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7PFM\u9762\u5916\u6a21\u5f0f\u4e0b\u76f8\u56fe\uff0c\u5927\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff084 \u00d7 4 \u03bcm<sup>2<\/sup>\uff09\u5148\u88ab-15v\u7684\u76f4\u6d41\u7535\u538b\u6781\u5316\uff0c\u7136\u540e\u5c0f\u7684\u6b63\u65b9\u5f62\u533a\u57df\uff081 \u00d7 1\u03bcm<sup>2<\/sup>\uff09\u88ab\u4e0d\u540c\u6570\u503c\uff080v\u30013.3v\u30016.6v\u300110v\uff09\u7684\u6b63\u5411\u7535\u538b\u6781\u5316\u3002<\/p>\n<p>\uff08f\uff09x=1.5\u7684KNN-BLT-BZ-xMn\u538b\u7535\u9676\u74f7\u538b\u7535\u54cd\u5e94\u6ede\u56de\u7ebf\u548c\u5178\u578b\u7684\u8774\u8776\u5f62\u632f\u5e45\u4e0e\u7535\u538b\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u4ed6\u4eec\u7814\u5236\u51fa\u4e86\u4e00\u79cd\u9ad8\u538b\u7535\u5e94\u53d8\u3001\u9ad8\u70ed\u6e29\u5ea6\u6027\u7684KNN\u57fa\u65e0\u94c5\u538b\u7535\u9676\u74f7\u6750\u6599\uff0c\u5e76\u7528\u5b8f\u89c2\u548c\u5fae\u89c2\u8868\u5f81\u624b\u6bb5\u8bc1\u660e\u4e86MnO<sub>2<\/sub>\u63ba\u6742\u53ef\u4ee5\u63d0\u9ad8KNN\u57fa\u65e0\u94c5\u538b\u7535\u9676\u74f7\u7684\u538b\u7535\u6027\u80fd\u548c\u94c1\u7535\u6027\u80fd\u3002\u4ed6\u4eec\u7814\u5236\u7684\u8fd9\u79cd\u9ad8\u6027\u80fd\u7684KNN\u57fa\u65e0\u94c5\u538b\u7535\u9676\u74f7\u6750\u6599\uff0c\u5ab2\u7f8ePZT\uff0c\u6709\u671b\u91cf\u4ea7\u5e94\u7528\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong><strong>\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.7b00520\" target=\"_blank\">High and Temperature-Insensitive Piezoelectric Strain in Alkali Niobate Lead-free<\/a><\/strong>\uff08J. Am. Chem. 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