{"id":70296,"date":"2017-03-20T06:30:38","date_gmt":"2017-03-19T22:30:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=70296"},"modified":"2017-03-17T21:18:18","modified_gmt":"2017-03-17T13:18:18","slug":"%e9%ab%98%e5%9b%bd%e5%8d%8e%e7%89%9f%e5%a4%a9%e6%88%90chem-rev-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e7%a6%bb%e5%ad%90%e6%b6%b2%e4%bd%93%e6%98%af%e5%8c%96%e5%ad%a6%e7%a8%b3%e5%ae%9a%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=70296","title":{"rendered":"\u9ad8\u56fd\u534e&#038;\u725f\u5929\u6210Chem. Rev.\u6700\u65b0\u7efc\u8ff0\uff1a\u79bb\u5b50\u6db2\u4f53\u662f\u5316\u5b66\u7a33\u5b9a\u7684\u5417\uff1f"},"content":{"rendered":"<p>\u3010\u5f15\u8a00\u3011<\/p>\n<p>\u8fd1\u5e74\u6765\u79bb\u5b50\u6db2\u4f53\u5f15\u8d77\u4e86\u4eba\u4eec\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5b83\u4eec\u53ef\u4ee5\u5e94\u7528\u5728\u5305\u62ec\u5316\u5b66\u3001\u7269\u7406\u3001\u751f\u7269\u3001\u5de5\u7a0b\u7b49\u591a\u4e2a\u9886\u57df\u3002\u901a\u5e38\u79bb\u5b50\u6db2\u4f53\u7684\u7a33\u5b9a\u6027\u88ab\u8ba4\u4e3a\u662f\u7a81\u51fa\u7684\u4e00\u4e2a\u4f18\u52bf\uff0c\u4f46\u662f\u79bb\u5b50\u6db2\u4f53\u771f\u7684\u5728\u6240\u6709\u60c5\u51b5\u4e0b\u90fd\u7a33\u5b9a\u5417\uff1f<\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea<strong>\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u7684\u9ad8\u56fd\u534e\u6559\u6388\u548c\u4e2d\u56fd\u4eba\u6c11\u5927\u5b66\u7684\u725f\u5929\u6210\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u5bf9\u79bb\u5b50\u6db2\u4f53\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u505a\u4e86\u76f8\u5173\u7814\u7a76\uff0c\u7740\u91cd\u7814\u7a76\u4e86\u6700\u8fd1\u6d41\u884c\u7684\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u5728C2\u3001N1\u3001N3\u3001C4\u3001C5\u7ed3\u6784\u4f4d\u7f6e\u7684\u6d3b\u6027\u4ee5\u53ca\u54aa\u5511\u73af\u7684\u5206\u89e3\u3002\u53e6\u5916\u8fd8\u8bba\u8ff0\u4e86\u5b63\u94f5\u76d0\u548c\u78f7\u79bb\u5b50\u6db2\u4f53\u7684\u5206\u89e3\u4ee5\u53ca\u79bb\u5b50\u6db2\u4f53\u7684\u9634\u79bb\u5b50\u7684\u6c34\u89e3\u548c\u4eb2\u6838\u53cd\u5e94\u3002\u4e0a\u8ff0\u5185\u5bb9\u4ee5<strong>\u201cAre Ionic Liquids Chemically Stable?\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728\u4e86<strong>Chemical Reviews<\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70870\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/000-2.png\" alt=\"\" width=\"600\" height=\"307\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/000-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/000-2-300x154.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n<p><strong>1 \u7b80\u4ecb<\/strong><\/p>\n<p>\u79bb\u5b50\u6db2\u4f53\u662f\u7194\u70b9\u5c0f\u4e8e\u6216\u7b49\u4e8e100\u6444\u6c0f\u5ea6\u7684\u4e00\u79cd\u7194\u76d0\u30021914\u5e74\uff0cWalden\u62a5\u9053\u4e86\u7b2c\u4e00\u79cd\u79bb\u5b50\u6db2\u4f53\u4e59\u57fa\u785d\u9178\u94f5\uff08EAN\uff09\uff0c\u8fd9\u79cd\u7269\u8d28\u7531\u6d53\u785d\u9178\u548c\u4e59\u80fa\u53cd\u5e94\u5236\u5f97\uff0c EAN\u5c55\u793a\u4e86\u548c\u6c34\u76f8\u4f3c\u7684\u7269\u7406\u6027\u8d28\u2014\u2014\u65e0\u8272\u65e0\u5473\uff0c\u6e05\u6f88\u900f\u660e\uff0c\u53e6\u5916\u8fd8\u6709\u8d85\u9ad8\u7684\u7c98\u6027\u30021951\u5e74Hurley\u548cWier\u901a\u8fc7\u70f7\u57fa\u5421\u5576\u6c2f\u5316\u7269\u4e0eAlCl<sub>3<\/sub>\u7684\u5408\u6210\u53d1\u73b0\u4e86\u7b2c\u4e8c\u4ee3\u79bb\u5b50\u6db2\u4f53\uff0c\u4f46\u662f\u5927\u90e8\u5206\u7b2c\u4e8c\u4ee3\u79bb\u5b50\u6db2\u4f53\u5728\u6f6e\u6e7f\u7684\u60c5\u51b5\u4e0b\u5e76\u4e0d\u7a33\u5b9a\uff0c\u800c\u4e14\u5b83\u4eec\u7684\u9178\u78b1\u5ea6\u4e5f\u4e0d\u5bb9\u6613\u63a7\u5236\u3002\u76f4\u52301992\u5e74\uff0cWilkes\u548cZaworotko\u53d1\u73b0\u4e86\u4ee5\u54aa\u5511\u548c\u56db\u6c1f\u787c\u9178\u76d0\u4e3a\u57fa\u7684\u79bb\u5b50\u6db2\u4f53\u53ef\u4ee5\u5728\u6f6e\u6e7f\u7684\u6761\u4ef6\u4e0b\u4ee5\u53ca\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d\u4fdd\u6301\u7a33\u5b9a\u3002\u79bb\u5b50\u6db2\u4f53\u5de8\u5927\u7684\u4f18\u52bf\u4f7f\u5b83\u4eec\u591a\u5e74\u6765\u4e0d\u8bba\u662f\u5728\u5b66\u672f\u8fd8\u662f\u5728\u751f\u4ea7\u4e2d\u90fd\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002<\/p>\n<p>\u79bb\u5b50\u6db2\u4f53\u7531\u4e8e\u5177\u6709\u4f4e\u7684\u6325\u53d1\u6027\uff0c\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u53ef\u80fd\u4ee3\u66ff\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\uff08VOCs\uff09\u7684\u6eb6\u5242\u3002\u8fd1\u5e74\u6765\uff0c\u79bb\u5b50\u6db2\u4f53\u5728\u5305\u62ec\u5316\u5b66\u3001\u751f\u7269\u3001\u7269\u7406\u3001\u5de5\u7a0b\u7b49\u7684\u5f88\u591a\u5b66\u79d1\u9886\u57df\u90fd\u6210\u4e3a\u4e86\u70ed\u70b9\u7684\u7814\u7a76\u8bdd\u9898\u3002\u4e0d\u65ad\u5730\u6709\u4ee4\u4eba\u9707\u60ca\u7684\u65b0\u53d1\u73b0\u65b0\u5e94\u7528\u5448\u73b0\u5728\u4e16\u4eba\u9762\u524d\uff0c\u4f8b\u5982\u6c14\u4f53\u5438\u9644\u5242\u3001\u6da6\u6ed1\u5242\u3001\u50ac\u5316\u5242\u3001\u8403\u53d6\u5242\u3001\u79bb\u5b50\u6db2\u6676\u3001\u7206\u70b8\u7269\u548c\u63a8\u8fdb\u5242\u71c3\u6599\u3002\u79bb\u5b50\u6db2\u4f53\u7531\u4e8e\u5176\u72ec\u7279\u7684\u6027\u80fd\uff08\u4f8b\u5982\u6781\u4f4e\u7684\u84b8\u6c7d\u538b\u3001\u53ef\u8c03\u7684\u6781\u6027\u3001\u4e0d\u6613\u71c3\u6027\u4ee5\u53ca\u9ad8\u7684\u7a33\u5b9a\u6027\u7b49\uff09\u5df2\u7ecf\u5728\u79d1\u5b66\u5708\u5df2\u7ecf\u5f15\u53d1\u4e86\u4e00\u573a\u65b0\u7684\u9769\u547d\u3002\u5c24\u5176\u662f\u7a33\u5b9a\u6027\u5728\u8bb8\u591a\u5e94\u7528\u4e2d\u626e\u6f14\u8005\u4e0d\u53ef\u6216\u7f3a\u7684\u89d2\u8272\u3002<\/p>\n<p>\u5728\u4e0a\u4e2a\u4e16\u7eaa\uff0c\u79bb\u5b50\u6db2\u4f53\u88ab\u8ba4\u4e3a\u662f\u60f0\u6027\u6eb6\u5242\uff0c\u4f46\u662f\u79bb\u5b50\u6db2\u4f53\u771f\u7684\u7a33\u5b9a\u5417\uff1f\u5982\u679c\u4e0d\u7a33\u5b9a\uff0c\u5b83\u7684\u5206\u89e3\u4f1a\u9020\u6210\u600e\u6837\u7684\u6d88\u6781\u5f71\u54cd\uff1f\u8fd9\u662f\u4e00\u4e2a\u503c\u5f97\u6bcf\u4e00\u4e2a\u4eba\u90fd\u5e94\u8be5\u6df1\u5165\u601d\u8003\u7684\u95ee\u9898\u3002\u672c\u6587\u5bf9\u79bb\u5b50\u6db2\u4f53\u7684\u7a33\u5b9a\u6027\u505a\u4e86\u76f8\u5173\u603b\u7ed3\uff0c\u4e3b\u8981\u7814\u7a76\u4e86\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u5728\u54aa\u5511\u73af\u4e0d\u540c\u4f4d\u7f6e\u7684\u53cd\u5e94\u7b49\uff0c\u5bf9\u5176\u4e2d\u7684\u7591\u60d1\u505a\u4e86\u76f8\u5173\u89e3\u7b54\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70789\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/01-4.jpg\" alt=\"\" width=\"600\" height=\"450\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/01-4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/01-4-300x225.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1 \u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u5728\u4e0d\u540c\u4f4d\u7f6e\u7684\u53cd\u5e94<\/strong><\/p>\n<p><strong>2 \u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u7684\u53cd\u5e94<\/strong><\/p>\n<p>\u54aa\u5511\u73af\u662f\u4e00\u4e2a\u5e73\u9762\u7684\u3001\u6709\u89c4\u5219\u7684\u3001\u03c0\u5171\u8f6d\u7684\u4e94\u5143\u6742\u73af\u7ed3\u6784\uff0c\u72ec\u7279\u7684\u7ed3\u6784\u4f7f\u54aa\u5511\u76d0\u6709\u4e86\u826f\u597d\u7684\u7269\u7406\u5316\u5b66\u6027\u80fd\u4ee5\u53ca\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\u3002\u54aa\u5511\u76d0\u662f\u8fd1\u5e74\u6765\u6700\u53d7\u6b22\u8fce\u7684\u79bb\u5b50\u6db2\u4f53\uff0c\u5728\u5f88\u591a\u9886\u57df\u90fd\u5f97\u5230\u4e86\u5e94\u7528\uff0c\u4f8b\u5982\u592a\u9633\u80fd\u7535\u6c60\u7535\u89e3\u8d28\uff0c\u78b3\u6750\u6599\u524d\u9a71\u4f53\u548c\u78b1\u6027\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u7b49\u3002\u901a\u5e38\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u88ab\u8ba4\u4e3a\u662f\u60f0\u6027\u7684\uff0c\u4f46\u662f\u7814\u7a76\u53d1\u73b0\u8fd9\u5e76\u4e0d\u9002\u7528\u4e8e\u6240\u6709\u7684\u60c5\u51b5\u3002\u00a0\u672c\u6587\u5bf9\u79bb\u5b50\u6db2\u4f53\u5728C2\u3001N1\u3001N3\u3001C4\u3001C5\u7ed3\u6784\u4f4d\u7f6e\u7684\u6d3b\u6027\u4ee5\u53ca\u79bb\u5b50\u6db2\u4f53\u7684\u5206\u89e3\u505a\u4e86\u8bba\u8ff0\u3002<\/p>\n<p><strong>2.1 \u5728C2\u4f4d\u7f6e\u7684\u53cd\u5e94<\/strong><\/p>\n<p>\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u7684C2\u4f4d\u7f6e\u662f\u6bd4\u8f83\u6d3b\u8dc3\u7684\u4f4d\u7f6e\uff0c\u4e3b\u8981\u662f\u7531\u4e8eC2\u8d28\u5b50\u9178\u6027\u5f88\u5f31\u3002\u8bb8\u591a\u6210\u5206\u90fd\u53ef\u4ee5\u548c\u54aa\u5511\u76d0\u5728C2\u4f4d\u7f6e\u53cd\u5e94\uff0c\u5c24\u5176\u662f\u5728\u78b1\u7684\u5b58\u5728\u4e0b\uff0c\u8fd9\u4e9b\u53cd\u5e94\u7269\u5305\u62ec\u6709\u673a\u6210\u5206\u3001\u751f\u7269\u8d28\u3001\u65e0\u673a\u6210\u5206\u548c\u6c27\u5316\u5242\u3002<\/p>\n<p><strong>2.1.1 \u4e0e\u6709\u673a\u7269\u7684\u53cd\u5e94<\/strong><\/p>\n<p>\u5728\u78b1\u7684\u5b58\u5728\u4e0b\uff0c\u54aa\u5511\u76d0\u5728 C2 \u4f4d\u7f6e\u53d1\u751f\u53bb\u8d28\u5b50\u5316\u4ea7\u751f\u5177\u6709\u6d3b\u6027\u7684\u4eb2\u6838\u7269\u8d28\uff0c\u4ea7\u751f\u7684\u4eb2\u6838\u7269\u8d28\u4f1a\u8fdb\u4e00\u6b65\u7684\u548c\u4eb2\u7535\u7269\u8d28\u53d1\u751f\u53cd\u5e94\uff0c\u4f8b\u5982\u919b\u3001\u70f7\u57fa\u5364\u3001\u7532\u9178\u4e59\u916f\u3001\u4e59\u9178\u9150\u548c\u5f02\u786b\u6c30\u9178\u916f\u3002\u5728\u5f3a\u78b1\u7684\u4f5c\u7528\u4e0b\uff0c\u54aa\u5511\u76d0\u540c\u6837\u8981\u53d1\u751f\u53cd\u5e94\uff0c\u5927\u91cf\u7684\u5b9e\u9a8c\u8868\u660e\u54aa\u5511\u73af\u5728C2\u4f4d\u7f6e\u5e76\u4e0d\u662f\u60f3\u8c61\u4e2d\u7684\u7a33\u5b9a\u3002\u53e6\u5916\uff0c\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u5df2\u7ecf\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u6709\u673a\u91d1\u5c5e\u7684\u50ac\u5316\uff0c\u4f46\u662f\u5b9e\u9a8c\u8bc1\u660e\u5728\u8fc7\u6e21\u65cf\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5b58\u5728\u4e0b\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u4e0e\u6709\u673a\u7269\u7684\u53cd\u5e94\u4e5f\u4e0d\u7a33\u5b9a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70790\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/02-3.jpg\" alt=\"\" width=\"600\" height=\"154\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/02-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/02-3-300x77.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2 \u78b1\u6027\u6761\u4ef6\u4e0b\u54aa\u5511\u76d0\u5728C2\u4f4d\u7f6e\u4e0e\u6709\u673a\u4eb2\u7535\u7269\u8d28\u7684\u53cd\u5e94<\/strong><\/p>\n<p><strong>2.1.2 \u4e0e\u751f\u7269\u8d28\u7684\u53cd\u5e94<\/strong><\/p>\n<p>\u548c\u8bb8\u591a\u53ef\u518d\u751f\u7ed9\u6599\u4e00\u6837\uff0c\u7ec6\u80de\u819c\u8d28\u662f\u4e0d\u6eb6\u4e8e\u6c34\u548c\u4f20\u7edf\u6709\u673a\u6eb6\u5242\u7684\uff0c\u8fd9\u4ee3\u8868\u7740\u60f3\u8981\u66f4\u597d\u7684\u5e94\u7528\u751f\u7269\u8d28\u9700\u8981\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\u30022002\u5e74Rogers\u7b49\u4eba\u9996\u6b21\u5c06\u79bb\u5b50\u6db2\u4f53\u4f5c\u4e3a\u975e\u81ea\u7136\u5316\u7684\u6eb6\u5242\u5e94\u7528\u4e8e\u7ec6\u80de\u819c\u8d28\u4e2d\uff0c\u81f3\u6b64\u4ee5\u540e\uff0c\u5176\u4ed6\u79d1\u7814\u4eba\u5458\u53c8\u76f8\u7ee7\u62a5\u9053\u4e86\u5f88\u591a\u79bb\u5b50\u6db2\u4f53\u5728\u751f\u7269\u8d28\u65b9\u9762\u7684\u5e94\u7528\u3002\u5927\u591a\u6570\u7684\u5b9e\u9a8c\u7ed3\u679c\u90fd\u8868\u660e\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u53ef\u4ee5\u4e0e\u7ec6\u80de\u819c\u8d28\u548c\u53ca\u5176\u884d\u751f\u7269\u53d1\u751f\u5316\u5b66\u53cd\u5e94\u3002\u5176\u4e2d\u6700\u8457\u540d\u7684\u5c31\u662fRosenau\u7b49\u4eba\u7684\u7814\u7a76\uff0c\u4ed6\u4eec\u5c06\u7528\u78b3\u6807\u8bb0\u7684\u03b1\u548c\u03b2\u8461\u8404\u7cd6\u82f7\u548c[Bmim][OAc]\u6df7\u5408\uff0c\u5728\u5ba4\u6e29\u4e0b\u653e\u7f6e7\u5929\u540e\u53d1\u73b0\u4e3a\u4e86\u7ed9\u54aa\u5511\u52a0\u5408\u7269\u52a0\u8f7dC2\u7f9f\u70f7\u57fa\u53d6\u4ee3\u57fa \uff0c[Bmim][OAc]\u4e0e\u8461\u8404\u7cd6\u53d1\u751f\u4e86\u53cd\u5e94\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70842\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/03-3.jpg\" alt=\"\" width=\"600\" height=\"206\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/03-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/03-3-300x103.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3 [Bmim][OAc]\u4e0e\u8461\u8404\u7cd6\u5728\u5ba4\u6e29\u4e0b\u53d1\u751f\u53cd\u5e94 <\/strong><\/p>\n<p><strong>2.1.3 \u4e0eCO<sub>2<\/sub>\u3001CS<sub>2<\/sub>\u3001OCS\u4ee5\u53ca\u542b\u786b\u5316\u5408\u7269\u53d1\u751f\u53cd\u5e94<\/strong><\/p>\n<p>\u6b63\u5982\u4e0a\u6587\u4e2d\u63d0\u5230\u7684\u90a3\u6837\uff0c\u5728\u901a\u5e38\u60c5\u51b5\u4e0b\u54aa\u5511\u76d0\u53ef\u4ee5\u4e0e\u6709\u673a\u4eb2\u7535\u7269\u8d28\u53d1\u751f\u53cd\u5e94\u3002\u7c7b\u4f3c\u7684\uff0c\u53bb\u8d28\u5b50\u5316\u7684\u54aa\u5511\u76d0\u540c\u6837\u53ef\u4ee5\u4e0e\u65e0\u673a\u7684\u4eb2\u7535\u7269\u8d28\u53d1\u751f\u53cd\u5e94\uff0c\u4f8b\u5982CO<sub>2<\/sub>\u3001CS<sub>2<\/sub>\u3001OCS\u4ee5\u53ca\u542b\u786b\u5316\u5408\u7269\u3002<\/p>\n<p><strong>2.1.4 \u4e0e\u6c27\u5316\u5242\u53d1\u751f\u53cd\u5e94<\/strong><\/p>\n<p>\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u88ab\u8bc1\u660e\u53ef\u4ee5\u5728C2\u4f4d\u7f6e\u548c\u6c27\u6c14\u53d1\u751f\u6c27\u5316\u53cd\u5e94\u3002Farmer\u548cWelton\u5c06\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u4f5c\u4e3a\u6eb6\u5242\u7528\u4e8e\u9152\u7cbe\u5bf9\u4e8e\u919b\u548c\u916e\u7684\u6c27\u5316\u53cd\u5e94\uff0c\u4ed6\u4eec\u53d1\u73b0[Bmin][NTf<sub>2<\/sub>]\u88ab\u6c27\u5316\u800c\u76f8\u53cd\u7684C2\u53d6\u4ee3\u57fa\u5728\u76f8\u540c\u7684\u60c5\u51b5\u4e0b\u6ca1\u6709\u88ab\u6c27\u5316\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70845\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/04-3.jpg\" alt=\"\" width=\"600\" height=\"124\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/04-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/04-3-300x62.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4 Bmin][NTf<sub>2<\/sub>] \u4e0e\u6c27\u6c14\u7684\u6c27\u5316\u53cd\u5e94<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>2.2<\/strong>\u00a0<strong>N1\u548cN3\u7684\u4f4d\u7f6eC-N\u5e26\u7684\u5206\u88c2<\/strong><\/p>\n<p style=\"text-align: left;\">\u968f\u7740\u54aa\u5511\u7269\u8d28\u7684\u4ea7\u751f\uff0c\u54aa\u5511\u76d0\u7684C-N\u5e26\u5728N1\u548cN3\u7684\u4f4d\u7f6e\u5206\u88c2\u5bfc\u81f4\u4e86N\u53d6\u4ee3\u57fa\u7684\u79fb\u52a8\u3002\u8fd9\u79cd\u5206\u89e3\u7531\u4e8e\u54aa\u5511\u7684\u4eb2\u7535\u6027\u5df2\u7ecf\u53ef\u4ee5\u5728\u7279\u6b8a\u7684\u7269\u7406\u548c\u5316\u5b66\u6761\u4ef6\u4e0b\u88ab\u89c2\u5bdf\u5230\u3002<\/p>\n<p style=\"text-align: left;\"><strong>2.3 \u5728C4\u548cC5\u4f4d\u7f6e\u7684\u53cd\u5e94<\/strong><\/p>\n<p style=\"text-align: left;\">Laali\u548cGettwert\u7b49\u4eba\u5728\u79bb\u5b50\u6db2\u4f53\u4e2d\u7814\u7a76\u4e86\u82b3\u9999\u690d\u7269\u7684\u4eb2\u7535\u5b50\u785d\u5316\u3002\u5f53NO<sub>2<\/sub>BF<sub>4<\/sub>\u4f5c\u4e3a\u785d\u9178\u76d0\uff0c[Emin][ BF<sub>4<\/sub>]\u548c [Emin][ PF<sub>6<\/sub>]\u4f5c\u4e3a\u6eb6\u5242\u65f6\uff0c\u54aa\u5511\u73af\u7684C4\u548cC5\u4f4d\u7f6e\u5728\u5ba4\u6e29\u4e0b\u88ab\u785d\u5316\u3002\u88ab\u785d\u5316\u7684\u54aa\u5511\u76d0\u8868\u73b0\u51fa\u5f88\u9ad8\u7684\u7c98\u6027\uff0c\u9650\u5236\u4e86\u5b83\u4eec\u5728\u785d\u5316\u53cd\u5e94\u4e2d\u7684\u4f7f\u7528\u3002\u53e6\u5916\uff0c\u5728\u6c27\u6c14\u7684\u5b58\u5728\u4e0b\uff0c\u54aa\u5511\u73af\u7684C4\u548cC5\u4f4d\u7f6e\u540c\u6837\u4f1a\u53d1\u751f\u6c27\u5316\u53cd\u5e94\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70860\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/05-1.jpg\" alt=\"\" width=\"600\" height=\"189\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/05-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/05-1-300x95.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5 \u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u4e0eNO<sub>2<\/sub>BF<sub>4<\/sub>\u00a0\u7684\u53cd\u5e94<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>2.4 \u54aa\u5511\u73af\u7684\u5f00\u73af\u53cd\u5e94<\/strong><\/p>\n<p style=\"text-align: left;\">\u5728\u54aa\u5511\u73af\u4e0a\u7684\u53cd\u5e94\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u5f00\u73af\u5206\u89e3\uff0c\u4e3b\u8981\u662f\u7531\u5728\u54aa\u5511\u73af\u7684C2\u4f4d\u7f6e\u5f3a\u78b1\u7684\u4eb2\u6838\u653b\u51fb\u5f15\u8d77\u7684\u3002\u7814\u7a76\u4eba\u5458\u5bf9\u54aa\u5511-2-\u4e9a\u57fa\u7684\u6c34\u89e3\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u53d1\u73b0\u5728\u5f3a\u78b1\u7684\u4f5c\u7528\u4e0b\u54aa\u5511C2\u8d28\u5b50\u7684\u62bd\u8c61\u5316\u5f62\u6210\u4e86\u5f00\u73af\u7269\u8d28\u3002\u8fd9\u6837\u7684\u7ed3\u679c\u610f\u5473\u7740\u54aa\u5511\u57fa\u79bb\u5b50\u6db2\u4f53\u53ef\u80fd\u5728\u6c34\u6eb6\u6db2\u4e2d\u53d1\u751f\u5f00\u73af\u53cd\u5e94\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70866\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/06-1.jpg\" alt=\"\" width=\"600\" height=\"100\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/06-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/06-1-300x50.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6 \u54aa\u5511\u76d0\u5728\u6c34\u6eb6\u6db2\u4e2d\u53d1\u751f\u5f00\u73af\u53cd\u5e94<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>3 \u5b63\u94f5\u548c\u78f7\u79bb\u5b50\u6db2\u4f53\u7684\u5206\u89e3<\/strong><\/p>\n<p style=\"text-align: left;\">\u5b63\u94f5\u79bb\u5b50\u6db2\u4f53\u88ab\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u5f88\u591a\u9886\u57df\uff0c\u4f8b\u5982\u50ac\u5316\u3001\u6eb6\u5242\u3001\u7535\u89e3\u8d28\u3001\u6c14\u4f53\u5438\u6536\u7b49\u3002\u5b63\u94f5\u7684\u4f4e\u9634\u6781\u7535\u4f4d\u5728\u7535\u5316\u5b66\u6709\u5f88\u91cd\u8981\u7684\u5e94\u7528\uff0c\u8fd9\u4e9b\u76d0\u53ef\u4ee5\u4f5c\u4e3a\u7535\u89e3\u8d28\u63d0\u9ad8\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u88c5\u7f6e\u7684\u5b89\u5168\u6027\uff0c\u4f8b\u5982\u9502\u7535\u6c60\u548c\u7535\u5316\u5b66\u7535\u5bb9\u5668\u3002\u6700\u8fd1\uff0c\u5b63\u94f5\u76d0\u88ab\u7528\u6765\u5236\u5907\u78b1\u6027\u71c3\u6599\u7535\u6c60\u7684\u9634\u79bb\u5b50\u4ea4\u6362\u819c\uff0c\u56e0\u6b64\u66f4\u591a\u7684\u6ce8\u610f\u529b\u90fd\u653e\u5728\u4e86\u5b63\u94f5\u76d0\u78b1\u6027\u7684\u7a33\u5b9a\u6027\u4e0a\u3002\u7ed3\u679c\u53d1\u73b0\u5b63\u94f5\u76d0\u4f1a\u4ea7\u751f\u4e0d\u540c\u7684\u5206\u89e3\u673a\u5236\u3002<\/p>\n<p style=\"text-align: left;\">\u5b63\u78f7\u79bb\u5b50\u6db2\u4f53\u76f8\u5bf9\u6c2e\u79bb\u5b50\u6db2\u4f53\u800c\u8a00\u5728\u5f88\u591a\u5e94\u7528\u4e0a\uff08\u4f8b\u5982\u63d0\u53d6\u5242\u3001\u6eb6\u5242\u3001\u7535\u89e3\u8d28\uff09\u90fd\u6709\u8f83\u597d\u7684\u6027\u80fd\uff0c\u00a0\u5c3d\u7ba1\u76f8\u5bf9\u4e8e\u54aa\u5511\u79bb\u5b50\u6db2\u4f53\u5df2\u7ecf\u5c55\u793a\u51fa\u4e86\u5f88\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u4f46\u5b63\u78f7\u4e0d\u5b8c\u5168\u662f\u60f0\u6027\u7684\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-70867\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/07.jpg\" alt=\"\" width=\"600\" height=\"395\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/07.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/07-300x198.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7 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left;\">\u79bb\u5b50\u6db2\u4f53\u7684\u9634\u79bb\u5b50\u4e00\u534a\u662f\u6709\u673a\u7684\u4e00\u534a\u662f\u65e0\u673a\u7684\uff0c\u53ef\u4ee5\u8c03\u8282\u6c34\u6df7\u6eb6\u6027\u3002\u9634\u79bb\u5b50\u5728\u4e8c\u6c27\u5316\u78b3\u7684\u5438\u6536\u4e2d\u540c\u6837\u8d77\u4e86\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u4f7f\u5f97\u79bb\u5b50\u6db2\u4f53\u6355\u83b7\u4e8c\u6c27\u5316\u78b3\u6210\u4e3a\u6700\u8282\u80fd\u7684\u65b9\u5f0f\u4e4b\u4e00\u3002\u4e00\u4e9b\u6587\u7ae0\u5df2\u7ecf\u62a5\u9053\u4e86\u79bb\u5b50\u6db2\u4f53\u7684\u9634\u79bb\u5b50\u53ef\u4ee5\u4f5c\u4e3a\u6c22\u952e\u53d7\u4f53\u6fc0\u53d1\u50ac\u5316\u53cd\u5e94\u4e2d\u4eb2\u6838\u8bd5\u5242\u7684\u6d3b\u6027\uff0c\u8fd9\u4e9b\u79bb\u5b50\u6db2\u4f53\u7684\u9634\u79bb\u5b50\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u5df2\u7ecf\u88ab\u6df1\u5165\u7814\u7a76\u3002\u4f46\u662f\u6c1f\u57fa\u9634\u79bb\u5b50\u7684\u6c34\u89e3\u53cd\u5e94\u548c\u4eb2\u6838\u53cd\u5e94\u5374\u5f88\u5bb9\u6613\u88ab\u5ffd\u7565\u3002<\/p>\n<p 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class=\"para\">\u00a0<\/div>\n<div class=\"para\">\u4ece\u7406\u8bba\u4e0a\u8bb2\u79bb\u5b50\u6db2\u4f53\u53ef\u80fd\u67091\u4e07\u4ebf\u79cd\uff0c\u5316\u5b66\u5bb6\u548c\u751f\u4ea7\u4f01\u4e1a\u53ef\u4ee5\u4ece\u4e2d\u9009\u62e9\u9002\u5408\u81ea\u5df1\u5de5\u4f5c\u9700\u8981\u7684\u79bb\u5b50\u6db2\u4f53\u3002\u5bf9\u79bb\u5b50\u6db2\u4f53\u7684\u5408\u6210\u4e0e\u5e94\u7528\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u5982\u4f55\u63d0\u9ad8\u79bb\u5b50\u6db2\u4f53\u7684\u7a33\u5b9a\u6027,\u964d\u4f4e\u79bb\u5b50\u6db2\u4f53\u7684\u751f\u4ea7\u6210\u672c\uff0c\u89e3\u51b3\u79bb\u5b50\u6db2\u4f53\u4e2d\u9ad8\u6cb8\u70b9\u6709\u673a\u7269\u7684\u5206\u79bb\u4ee5\u53ca\u5f00\u53d1\u65e2\u80fd\u7528\u4f5c\u50ac\u5316\u53cd\u5e94\u6eb6\u5242\uff0c\u53c8\u80fd\u7528\u4f5c\u50ac\u5316\u5242\u7684\u79bb\u5b50\u6db2\u4f53\u65b0\u4f53\u7cfb\u7b49\u9886\u57df\u3002\u968f\u7740\u4eba\u4eec\u5bf9\u79bb\u5b50\u6db2\u4f53\u8ba4\u8bc6\u7684\u4e0d\u65ad\u6df1\u5165\uff0c\u76f8\u4fe1\u79bb\u5b50\u6db2\u4f53\u7eff\u8272\u6eb6\u5242\u7684\u5927\u89c4\u6a21\u5de5\u4e1a\u5e94\u7528\u6307\u65e5\u53ef\u5f85\uff0c\u5e76\u7ed9\u4eba\u7c7b\u5e26\u6765\u4e00\u4e2a\u9762\u8c8c\u5168\u65b0\u7684\u7eff\u8272\u5316\u5b66\u9ad8\u79d1\u6280\u4ea7\u4e1a\u3002<\/div>\n<div class=\"para\">\u00a0<\/div>\n<div class=\"para\"><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.chemrev.6b00594\" target=\"_blank\">Are Ionic Liquids Chemically Stable?<\/a>\uff08Chem. Rev.2017\uff0cDOI: 10.1021\/acs.chemrev.6b00594\uff09<\/div>\n<div class=\"para\">\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u674e\u4f26\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\u79bb\u5b50\u6db2\u4f53\u5f15\u8d77\u4e86\u4eba\u4eec\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5b83\u4eec\u53ef\u4ee5\u5e94\u7528\u5728\u5305\u62ec\u5316\u5b66\u3001\u7269\u7406\u3001\u751f\u7269\u3001\u5de5\u7a0b\u7b49\u591a\u4e2a\u9886\u57df\u3002\u901a\u5e38\u79bb\u5b50\u6db2\u4f53\u7684\u7a33\u5b9a\u6027\u88ab\u8ba4\u4e3a\u662f\u7a81\u51fa\u7684\u4e00\u4e2a\u4f18\u52bf\uff0c\u4f46\u662f\u79bb\u5b50\u6db2\u4f53\u771f\u7684\u5728&#8230;<\/p>\n","protected":false},"author":349,"featured_media":70788,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[],"class_list":["post-70296","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/70296"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=70296"}],"version-history":[{"count":12,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/70296\/revisions"}],"predecessor-version":[{"id":71874,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/70296\/revisions\/71874"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/70788"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=70296"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=70296"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=70296"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}