{"id":70183,"date":"2017-03-13T14:00:37","date_gmt":"2017-03-13T06:00:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=70183"},"modified":"2017-03-12T09:44:28","modified_gmt":"2017-03-12T01:44:28","slug":"%e9%a6%99%e6%b8%af%e4%b8%ad%e6%96%87%e5%a4%a7%e5%ad%a6energy-environ-sci-%e9%87%8a%e6%94%be%e7%a2%98%e5%8c%96%e7%89%a9%e5%af%b9%e4%ba%8e%e9%ab%98%e8%83%bd%e9%87%8f%e9%94%8c%e5%a4%9a%e7%a2%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=70183","title":{"rendered":"\u9999\u6e2f\u4e2d\u6587\u5927\u5b66Energy Environ. Sci: \u91ca\u653e\u7898\u5316\u7269\u5bf9\u4e8e\u9ad8\u80fd\u91cf\u950c\/\u591a\u7898\u5316\u7269\u548c\u9502\/\u591a\u7898\u5316\u7269\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u7684\u5bb9\u91cf"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u50a8\u80fd\u7cfb\u7edf\u662f\u90e8\u7f72\u4e0d\u7a33\u5b9a\u548c\u95f4\u6b47\u6027\u53ef\u518d\u751f\u80fd\u6e90\uff08\u5982\u592a\u9633\u80fd\u548c\u98ce\u529b\u53d1\u7535\uff09\u7684\u5173\u952e\u56e0\u7d20\u3002 \u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\uff08RFB\uff09\u662f\u7528\u4e8e\u5b58\u50a8\u7531\u53ef\u518d\u751f\u80fd\u6e90\u4ea7\u751f\u7684\u95f4\u6b47\u80fd\u91cf\u7684\u6700\u6709\u524d\u9014\u7684\u6280\u672f\u4e4b\u4e00\uff0c\u8fd9\u662f\u7531\u4e8e\u5176\u5728\u53bb\u8026\u80fd\u91cf\u548c\u529f\u7387\u65b9\u9762\u7684\u8bbe\u8ba1\u7075\u6d3b\u6027\u3002\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\uff08LIB> 250Wh L-1<\/sup>\uff09\u76f8\u6bd4\uff0c\u5e38\u89c4\u6db2\u6d41\u7535\u6c60\u8868\u73b0\u51fa\u7ea610\u500d\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u5f00\u53d1\u9ad8\u80fd\u91cf\u5bc6\u5ea6RFB\u53ef\u4ee5\u51cf\u5c11\u7cfb\u7edf\u5360\u5730\u9762\u79ef\u548c\u5b58\u50a8\u5927\u5c0f\uff0c\u5e76\u5c06\u5176\u7528\u4e8e\u56fa\u5b9a\u50a8\u5b58\u548c\u8fd0\u8f93\u65b9\u9762\u3002<\/p>\n

\u589e\u52a0RFB\u7684\u80fd\u91cf\u5bc6\u5ea6\u53ef\u4ee5\u901a\u8fc7\u589e\u52a0\u534a\u7535\u6c60\u53cd\u5e94\u4e2d\u6d89\u53ca\u7684\u7535\u5b50\u6570\u91cf\uff0c\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u7684\u6d53\u5ea6\u548c\u7535\u6c60\u7535\u538b\u6765\u5b9e\u73b0\u3002\u73b0\u6709\u6280\u672f\u7684\u5168\u9492\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\uff08VRFB\uff09\u7684\u80fd\u91cf\u5bc6\u5ea6\u81ea\u9996\u6b21\u62a5\u9053\u4ee5\u6765\u5df2\u7ecf\u6709\u663e\u7740\u6539\u5584\uff0c\u4f46\u4ecd\u7136\u4e0d\u4ee4\u4eba\u6ee1\u610f\uff08<50Wh L-1 <\/sup>posolyte+negolyte<\/sub>\uff09\u3002\u6b64\u5916\uff0c\u5728VRFB\u4e2d\u4f7f\u7528\u5f3a\u9178\u548c\u9ad8\u6210\u672c\u7684\u9492\u7535\u89e3\u8d28\u662f\u4e0d\u53ef\u907f\u514d\u7684\u3002\u76ee\u524d\uff0c\u7814\u7a76\u4eba\u5458\u5bf9\u4e8e\u542b\u6c34RFB\u4f7f\u7528\u6c34\u6eb6\u6027\u6709\u673a\u6216\u57fa\u4e8e\u805a\u5408\u7269\u7684\u6d3b\u6027\u7269\u8d28\u6709\u8d8a\u53d1\u611f\u5174\u8da3\uff0c\u5df2\u8bc1\u660e\u80fd\u8fbe\u5230\u7ea610Wh L-1<\/sup> posolyte+negolyte<\/sub>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\uff0c\u950c\u57fa\u6c34\u6027\u6df7\u5408\u6db2\u6d41\u7535\u6c60\u7531\u4e8e\u5176\u4f4e\u6210\u672c\u548c\u9ad8\u6027\u80fd\u5df2\u63a5\u8fd1\u5546\u4e1a\u5316\u3002\u4f8b\u5982\uff0c\u950c-\u6eb4RFB\uff0c\u56e0\u4e3a\u5176\u4f4e\u6210\u672c\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff08\u301c60Wh L-1<\/sup>posolyte+negolyte<\/sub>\uff09\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u6eb4\u5177\u6709\u9ad8\u6bd2\u6027\u548c\u8150\u8680\u6027\u3002\u4e3a\u4e86\u89e3\u51b3Zn\u91d1\u5c5e\u7535\u6781\u7684\u53ef\u5ef6\u5c55\u6027\uff0c\u4f7f\u7528\u534a\u56fa\u4f53\u6280\u672f\u5f00\u53d1\u4e86\u5b8c\u5168\u53ef\u6d41\u52a8\u7684Zn\u7535\u6781\uff0c\u4ee5\u89e3\u51b3Zn\u7535\u6781\u7684\u53ef\u5ef6\u5c55\u6027\u9650\u5236\u3002<\/p>\n

\u7531\u4e8e\u7898\u5316\u7269\u5728\u6c34\u6027\u548c\u975e\u6c34\u6027\u4ecb\u8d28\u4e2d\u7684\u9ad8\u6eb6\u89e3\u6027\u3001\u5feb\u901f\u52a8\u529b\u5b66\u548c\u9ad8\u53ef\u9006\u6027\uff0c\u5df2\u7ecf\u88ab\u9274\u5b9a\u4e3a\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u7684\u6700\u6709\u524d\u666f\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u4e4b\u4e00\u3002\u4f8b\u5982\uff0c\u5728Li-I\u6c34\u6d41\u7535\u6c60\u7cfb\u7edf\u4e2d\uff0cLiI\u5728\u6c34\u4e2d\u5177\u6709\u9ad8\u8fbe8.2M\u7684\u9ad8\u6eb6\u89e3\u5ea6\uff08147 Ah L-1<\/sup> posolyte<\/sub>\uff09\uff0c\u5176\u663e\u7740\u9ad8\u4e8e\u5e38\u89c4VRFB\uff08\u301c2M\uff0c25 Ah L-1<\/sup> posolyte + negolyte<\/sub>\uff09\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\u673a\u68b0\u4e0e\u81ea\u52a8\u5316\u5de5\u7a0b\u7cfb\u7684\u5362\u6021\u541b\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bfe\u9898\u7ec4\u5728Energy & Environmental Science<\/em><\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\u201cUnlocking the capacity of iodide for high-energy-density zinc\/polyiodide and lithium\/polyiodide redox flow batteries\u201d<\/em><\/strong>\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528\u6eb4\u79bb\u5b50\uff08Br–<\/sup>\uff09\u4f5c\u4e3a\u7edc\u5408\u5242\u7a33\u5b9a\u6e38\u79bb\u7898\uff0c\u5f62\u6210\u7898\u6eb4\u79bb\u5b50\uff08I2<\/sub>Br–<\/sup>\uff09\u4f5c\u4e3a\u91ca\u653e\u7898\u79bb\u5b50\u7535\u8377\u5b58\u50a8\u7684\u65b9\u5f0f\u3002\u867d\u7136\u539f\u5219\u4e0a\u6c2f\u5316\u950c\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u7a33\u5b9a\u5242\uff0c\u4f46\u662f\u5df2\u77e5\u5176\u4f1a\u8868\u73b0\u51fa\u4e25\u91cd\u7684\u6c34\u89e3\u95ee\u9898\u3002\u6eb4\u79bb\u5b50\u4ee5\u5f62\u6210\u7898\u6eb4\u5316\u7269\uff08I2<\/sub>Br–<\/sup>\uff09\u7a33\u5b9a\u7898\u3002\u4e2d\u5fc3\u5bf9\u79f0I3-<\/sup>\u548c\u4e0d\u5bf9\u79f0I2<\/sub>Br–<\/sup>\u5177\u6709\u7ebf\u6027\uff08\u6216\u63a5\u8fd1\u7ebf\u6027\uff09\u7684\u4e09\u5364\u5316\u7269\u7ed3\u6784\uff0c\u5e76\u4e14\u662f\u70ed\u529b\u5b66\u7a33\u5b9a\u7684\u3002\u5728\u8fd9\u79cd\u65b9\u6cd5\u4e2d\uff0cZIBB\u7684\u7535\u6c60\u7684\u7535\u538b\u88ab\u6709\u76ee\u7684\u5730\u63a7\u5236\u4ee5\u6392\u9664\u6765\u81ea\u6eb4\u5316\u7269\/\u6eb4\u5bf9\u7684\u80fd\u91cf\u8d21\u732e\uff08\u4f8b\u5982\u950c\/\u6eb4\u7684\u5e73\u8861\u7535\u6c60\u7535\u4f4d\u4e3a1.76V\uff09\uff0c\u907f\u514d\u5f62\u6210\u6709\u6bd2\u548c\u8150\u8680\u6027\u7684\u6eb4\u3002\u7814\u7a76\u4eba\u5458\u8fd0\u7528\u8fd9\u4e2a\u7b56\u7565\u5f97\u5230\u4e86\u80fd\u91cf\u5bc6\u5ea6\u4e3a101 Wh L-1<\/sup> posolyte+negolyte<\/sub>\uff08\u6216202 Wh L-1<\/sup>posolyte<\/sub>\uff09\u7684\u65b0\u578b\u950c\/\u7898\u6eb4\u5316\u7269\uff08I2<\/sub>Br–<\/sup>\uff09\u7535\u6c60\uff08ZIBB\uff09\uff0c\u8be5\u80fd\u91cf\u5bc6\u5ea6\u662f\u8fc4\u4eca\u4e3a\u6b62\u6c34\u6027\u6db2\u6d41\u7535\u6c60\u5b9e\u9a8c\u4e2d\u83b7\u5f97\u7684\u6700\u9ad8\u7684\u3002\u540c\u65f6\uff0c\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7535\u55b7\u96fe\u79bb\u5b50\u5316\u8d28\u8c31\u4eea\uff08ESI-MS\uff09\u7814\u7a76\u8fd9\u79cd\u7b56\u7565\u7684\u6709\u6548\u6027\uff0c\u4ee5\u7814\u7a76\u5728\u6eb4\u5316\u7269\u79bb\u5b50\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u7898\u5316\u7269\u6c27\u5316\u540e\u7684\u542b\u5364\u7d20\u7269\u8d28\u3002\u8fdb\u4e00\u6b65\u8868\u660e\uff0c\u8be5\u7b56\u7565\u53ef\u4ee5\u5728\u6c34\u6027\u548c\u975e\u6c34\u6027\u7898\u5316\u7269\u57fa\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u4e2d\u63a8\u5e7f\uff0c\u63d0\u4f9b\u4e86\u8fdb\u4e00\u6b65\u589e\u52a0\u6c34\u6027\u548c\u975e\u6c34\u6027\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u7684\u65b0\u673a\u4f1a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe\u4e00\uff1a\u79bb\u5b50\u7ed3\u6784\u56fe\u548c\u5faa\u73af\u4f0f\u5b89\u56fe<\/strong><\/span><\/p>\n

<\/p>\n

\uff08a\uff09\u6eb4\u5316\u7269\u4f5c\u4e3a\u7a33\u5b9a\u7898\u7684\u7edc\u5408\u5242\u7684\u6982\u5ff5\u56fe\u3002<\/p>\n

\uff08b\uff09I2<\/sub>Br–<\/sup>\u79bb\u5b50\u7684\u7ed3\u6784\u3002<\/p>\n

\uff08c\uff09I3<\/sub>–<\/sup>\u79bb\u5b50\u7684\u7ed3\u6784\u3002 \u591a\u5364\u5316\u950c\u7684\u591a\u5364\u5316\u7269\u79bb\u5b50\u7684\u952e\u957f\u7531\u7b2c\u4e00\u539f\u7406\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u5f97\u5230\u3002<\/p>\n

\uff08d\uff09\u572850mV s -1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\u76840.1M ZnI2<\/sub>\uff0c0.1M ZnI2<\/sub> + 0.05M ZnBr2<\/sub>\u548c0.1M ZnBr2<\/sub>\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\u3002<\/p>\n

\uff08e\uff09\u6240\u63d0\u51fa\u7684ZIBB\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08f\uff09\u5177\u67095M ZnI2<\/sub> + 2.5M ZnBr2<\/sub>\u4f5c\u4e3a\u9633\u6781\u7535\u89e3\u8d28\u548c\u9634\u6781\u7535\u89e3\u8d28\u7684ZIBB\u7cfb\u7edf\u7684\u6052\u7535\u6d41\u7535\u538b\u5206\u5e03\uff0c\u6d41\u901f\u4e3a10mL \/ min\u3002\u5305\u62ec\u5728\u76f8\u540c\u6761\u4ef6\u4e0b\u4ec5\u7898\u5316\u4f53\u7cfb\uff085.0M ZnI2<\/sub>\uff09\u7684\u6027\u80fd\u3002 \u6b64\u5916\uff0c\u5305\u62ec\u5177\u6709\u4e24\u4e2a\u622a\u6b62\u7535\u538b\uff0c1.5V\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u548c2.0V\uff08\u7eff\u8272\u66f2\u7ebf\uff09\u7684\u4ec5\u6eb4\u5316\u7269\uff082.5M ZnBr2<\/sub>\uff09\u4f53\u7cfb\u7528\u4e8e\u6bd4\u8f83\u3002\u5145\u653e\u7535\u7535\u6d41\u5bc6\u5ea6\u4e3a5mA cm-2<\/sup>\u3002<\/p>\n

\u56fe\u4e8c\uff1a\u653e\u7535\u6781\u5316\u66f2\u7ebf<\/strong><\/span><\/p>\n

<\/p>\n

\uff08a\uff09\u5bf9\u4e8eZIBB\u548c\u73b0\u6709\u6280\u672f\u6db2\u6d41\u7535\u6c60\uff08AQS \/ Br\uff0cFe \/ Cr\uff0cZn\/ Br\uff0cTEMPO \/ Viol\uff0cVRF\uff08\u6dfb\u52a0\u5242\uff09\uff0cVRF\uff08\u6df7\u5408\u9178\uff09\u548c\u950c\/\u805a\u7898\u5316\u7269\uff09\u7684\u80fd\u91cf\u5bc6\u5ea6\u4f5c\u4e3a\u6d3b\u6027\u7269\u8d28\u6d53\u5ea6\u51fd\u6570\u7684\u5bf9\u6bd4\u3002<\/p>\n

\uff08b\uff09\u572810 mL min-1<\/sup>\u4e0b\uff0cZIBB\u7684\u653e\u7535\u6781\u5316\u66f2\u7ebf\uff0c3.5 M ZnI2<\/sub> + 1.75 M ZnBr2<\/sub>\u4f5c\u4e3a\u9633\u6781\u7535\u89e3\u6db2\u548c\u9634\u6781\u7535\u89e3\u6db2\u3002<\/p>\n

\u56fe\u4e09\uff1a\u6052\u6d41\u7535\u538b\u66f2\u7ebf<\/strong><\/span><\/p>\n

<\/p>\n

\uff08a\uff09\u572810mL min-1<\/sup>\u4e0b\uff0c 3.5 M ZnI2<\/sub> + 1.75 M ZnBr2<\/sub>\u4f5c\u4e3a\u9633\u6781\u7535\u89e3\u6db2\u548c\u9634\u6781\u7535\u89e3\u6db2\uff0cZIBB\u7684\u6052\u6d41\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u572810 mL min-1<\/sup>\uff0c5 M ZnI2<\/sub> + 2.5 M ZnBr2<\/sub>\u4f5c\u4e3a\u9633\u6781\u7535\u89e3\u6db2\u548c\u9634\u6781\u7535\u89e3\u6db2\uff0cZIBB\u7684\u6052\u6d41\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\uff08c\uff09\u5e93\u4ed1\u6548\u7387\u548c\u653e\u7535\u5bb9\u91cf\uff0c\u4e24\u4e2a\u4f53\u7cfb\u5728\u7ea670\uff05\u7684\u5145\u7535\u72b6\u6001\uff08SOC\uff09\u4e0b\u5de5\u4f5c\u3002<\/p>\n

\u56fe\u56db\uff1a\u6052\u6d41\u7535\u538b\u66f2\u7ebf\u548c\u653e\u7535\u5bb9\u91cf\u7684\u5faa\u73af\u4fdd\u6301\u7387<\/strong><\/span><\/p>\n

<\/p>\n

\uff08a\uff09\u5177\u67092.5M LiI + 1.25M LiBr\u4f5c\u4e3a\u9633\u6781\u7535\u89e3\u6db2\u7684LIBB\u7684\u6052\u6d41\u7535\u538b\u66f2\u7ebf\u3002 \u4f7f\u75282.5M LiI\u4f5c\u4e3a\u9633\u6781\u7535\u89e3\u6db2\u7684\u4f53\u7cfb\u7528\u4e8e\u6bd4\u8f83\u3002\u5145\u653e\u7535\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1mA cm-2<\/sup>\u3002<\/p>\n

\uff08b\uff09\u5177\u67092.5M LiI + 1.25M LiBr\u4f5c\u4e3a\u9633\u6781\u7535\u89e3\u6db2\u7684LIBB\u4f53\u7cfb\u7684\u6548\u7387\u548c\u653e\u7535\u5bb9\u91cf\u7684\u5faa\u73af\u4fdd\u6301\u7387\u3002\u5145\u653e\u7535\u7535\u6d41\u5bc6\u5ea6\u4e3a0.44mA cm -2<\/sup>\u3002 \u4e24\u4e2a\u6d4b\u8bd5\u5728\u5145\u7535\u72b6\u6001\uff08SOC\uff09100\uff05\u4e0b\u8fdb\u884c\u3002<\/p>\n

\u56fe\u4e94\uff1a\u7535\u55b7\u96fe\u8d28\u8c31\u56fe<\/strong><\/span><\/p>\n

<\/p>\n

\uff08a\uff09\u5b8c\u5168\u5145\u7535\u7684ZIBB\u9633\u6781\u7535\u89e3\u8d28\uff085M ZnI 2 <\/sub>+ 2.5M ZnBr 2<\/sub>\uff09\u7684ESI-MS\u3002\u5305\u62ec\u521d\u59cb\u7535\u89e3\u8d28\u7528\u4e8e\u6bd4\u8f83\u3002<\/p>\n

\uff08b\uff09\u5b8c\u5168\u5145\u7535\u7684LIBB\u9633\u6781\u7535\u89e3\u8d28\uff082.5M LiI + 1.25M LiBr\uff09\u7684ESI-MS\u3002\u5305\u62ec\u521d\u59cb\u7535\u89e3\u8d28\u7528\u4e8e\u6bd4\u8f83\u3002\u540c\u4f4d\u7d20\u6a21\u5f0f\uff0c\u4f4d\u4e8em \/ z = 446.1\u548cm \/ z = 399.1\u7684\u5cf0\u5206\u522b\u5f52\u5c5e\u4e8e\u950c\u9178\u6839\u79bb\u5b50ZnI3-<\/sup>\u548cZnI2<\/sub>Br–<\/sup>\u3002\u5cf01,2,3\u548c4\u53ef\u4ee5\u5206\u522b\u5f52\u5c5e\u4e8eZnIBr 2 –<\/sup> \uff0cZnBr 3 –<\/sup> \uff0cIBr\uff08H 2 <\/sub>O\uff09– <\/sup>\u548cIBr\uff08DMF\uff09– <\/sup>\u7684\u7269\u8d28\u6216\u5b83\u4eec\u7684\u76f8\u5bf9\u540c\u4f4d\u7d20\u3002\u5cf0\u5f3a\u5ea6\u53ef\u4e0d\u8868\u793a\u7535\u89e3\u8d28\u4e2d\u7684\u76f8\u5e94\u79bb\u5b50\u6d53\u5ea6\uff0c\u56e0\u4e3a\u6d4b\u8bd5\u6eb6\u6db2\u88ab\u7a00\u91ca\uff08ZIBB\u9633\u79bb\u5b50\uff1a\u901a\u8fc7H2<\/sub>O\uff0cLIBB\u9633\u79bb\u5b50\uff1a\u901a\u8fc7DMF\uff09\u7ea6100000\u500d\uff0c\u4ee5\u83b7\u5f97\u9ad8\u5206\u8fa8\u7387\u5149\u8c31\uff0c\u5e76\u4e14ESI-MS\u4e0d\u5141\u8bb8\u5b9a\u91cf\u8fd9\u4e9b\u5e73\u8861\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/span><\/p>\n

\u672c\u5de5\u4f5c\u4f7f\u7528\u6eb4\u79bb\u5b50\uff08Br–<\/sup>\uff09\u4f5c\u4e3a\u7edc\u5408\u5242\u6765\u7a33\u5b9a\u6e38\u79bb\u7898\u5e76\u5f62\u6210\u7898\u6eb4\u79bb\u5b50\uff08I2<\/sub>Br–<\/sup>\uff09\uff0c\u4ece\u800c\u589e\u52a0\u7898\u79bb\u5b50\u7684\u5bb9\u91cf\u3002\u5728Br–<\/sup>\u79bb\u5b50\u5b58\u5728\u4e0b\u7898\u5316\u7269\u7684\u5bb9\u91cf\u53ef\u4ee5\u589e\u52a0\uff0c\u800c\u4e0d\u6d89\u53caBr– <\/sup>\/ Br 3 –<\/sup> \u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u8fd0\u7528\u8fd9\u4e2a\u7b56\u7565\uff0c\u7814\u7a76\u4eba\u5458\u5c55\u793a\u4e00\u4e2a\u65b0\u7684\u950c\/\u7898\u6eb4\u5316\u7269\uff08I2<\/sub>Br–<\/sup>\uff09\u7535\u6c60\uff08ZIBB\uff09\u5b9e\u73b0101 Wh L-1 \u00a0\u00a0<\/sup>posolyte+negolyte<\/sub>\uff08\u6216202 Wh L-1<\/sup>posolyte<\/sub>\uff09\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8fd9\u662f\u5df2\u5b9e\u73b0\u7684\u6db2\u6d41\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u4e2d\u6700\u9ad8\u7684\u3002\u8be5\u7b56\u7565\u4f7f\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u6c27\u5316\u8fd8\u539f\u5316\u5b66\u5177\u6709\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u548c\u9ad8\u6548\u7387\uff0c\u53ef\u4ee5\u63a8\u5e7f\u5230\u975e\u6c34\u6027\u4ecb\u8d28\uff0c\u4e3a\u6539\u8fdb\u9ad8\u80fd\u7898\u5316\u7269\u50a8\u80fd\u6280\u672f\u63d0\u4f9b\u65b0\u7684\u673a\u4f1a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong> Unlocking the capacity of iodide for high-energy-density\u00a0<\/strong>zinc\/polyiodide and lithium\/polyiodide redox flow batteries<\/strong><\/a>\u00a0\uff08Energy Environ. Sci.<\/em>, 2017, DOI: 10.1039\/C6EE03554J\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4 \u80cc\u9006\u65f6\u5149 \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<\/strong>\u6750\u6599\u4eba<\/strong><\/a>\u3001\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u50a8\u80fd\u7cfb\u7edf\u662f\u90e8\u7f72\u4e0d\u7a33\u5b9a\u548c\u95f4\u6b47\u6027\u53ef\u518d\u751f\u80fd\u6e90\uff08\u5982\u592a\u9633\u80fd\u548c\u98ce\u529b\u53d1\u7535\uff09\u7684\u5173\u952e\u56e0\u7d20\u3002 \u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\uff08RFB\uff09\u662f\u7528\u4e8e\u5b58\u50a8\u7531\u53ef\u518d\u751f\u80fd\u6e90\u4ea7\u751f\u7684\u95f4\u6b47\u80fd\u91cf\u7684\u6700\u6709\u524d\u9014\u7684\u6280…<\/p>\n","protected":false},"author":272,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-70183","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/70183"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=70183"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/70183\/revisions"}],"predecessor-version":[{"id":70833,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/70183\/revisions\/70833"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=70183"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=70183"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=70183"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}