{"id":69609,"date":"2017-03-06T07:30:03","date_gmt":"2017-03-05T23:30:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=69609"},"modified":"2017-03-06T07:48:27","modified_gmt":"2017-03-05T23:48:27","slug":"%e5%ad%99%e6%98%a5%e6%96%87%e5%bc%a0%e4%b9%85%e4%bf%8anano-energy%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e5%85%a8%e5%9b%ba%e6%80%81%e5%8f%af%e5%85%85%e7%94%b5%e9%94%82%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=69609","title":{"rendered":"\u5b59\u6625\u6587&\u5f20\u4e45\u4fcaNano Energy\u6700\u65b0\u7efc\u8ff0\uff1a\u5168\u56fa\u6001\u53ef\u5145\u7535\u9502\u7535\u6c60\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n \u5316\u5b66\u7535\u6c60\u5728\u80fd\u91cf\u7684\u5b58\u50a8\u548c\u8f6c\u6362\u7b49\u65b9\u9762\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u76ee\u524d\u9502\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u76f8\u5bf9\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u800c\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u524d\u666f\u7684\u4e00\u7c7b\u7535\u6c60\u3002\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u901a\u5e38\u4f7f\u7528\u79bb\u5b50\u7535\u5bfc\u7387\u76f8\u5bf9\u8f83\u9ad8\u7684\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\uff0c\u4f46\u662f\u5b58\u5728\u7740\u5b89\u5168\u6027\u5dee\u3001\u5bff\u547d\u8f83\u77ed\u3001\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u7b49\u4e00\u7cfb\u5217\u7f3a\u70b9\u3002\u76f8\u6bd4\u4e8e\u4f7f\u7528\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u4f7f\u7528\u4e0d\u53ef\u71c3\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u5168\u56fa\u6001\u9502\u7535\u6c60\u5219\u53ef\u4ee5\u907f\u514d\u8fd9\u4e9b\u95ee\u9898\uff0c\u56e0\u800c\u6b63\u53d7\u5230\u4e16\u754c\u8303\u56f4\u7814\u7a76\u8005\u4eec\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u800c\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u95ee\u9898\u662f\u5168\u56fa\u6001\u9502\u7535\u6c60\u6240\u9762\u4e34\u7684\u6311\u6218\uff0c\u4e25\u91cd\u963b\u788d\u4e86\u5176\u53d1\u5c55\u548c\u5e94\u7528\u3002<\/p>\n \u6700\u8fd1\uff0c\u4e2d\u79d1\u9662\u5317\u4eac\u7eb3\u7c73\u80fd\u6e90\u4e0e\u7cfb\u7edf\u7814\u7a76\u6240\u5b59\u6625\u6587\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u3001<\/strong><\/span>\u4e2d\u5357\u5927\u5b66\u5218\u664b\u6559\u6388<\/strong>\u548c\u4e0a\u6d77\u5927\u5b66\u5f20\u4e45\u4fca\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49<\/span>\u5728\u80fd\u6e90\u9886\u57df\u8457\u540d\u671f\u520aNano Energy<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cRecent advances in all-solid-state rechargeable lithium batteries\u201d<\/strong><\/span>\u7684\u7efc\u8ff0\uff0c\u7cfb\u7edf\u603b\u7ed3\u4e86\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u548c\u4ea7\u4e1a\u5316\u8fdb\u7a0b\uff0c\u91cd\u70b9\u8ba8\u8bba\u4e86\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u5b58\u5728\u7684\u95ee\u9898\u4ee5\u53ca\u73b0\u6709\u7684\u89e3\u51b3\u65b9\u6cd5\uff0c\u4e3a\u5168\u56fa\u6001\u9502\u7535\u6c60\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u548c\u65b0\u578b\u56fa\u4f53\u7535\u89e3\u8d28\u6750\u6599\u4ee5\u53ca\u7535\u6c60\u7ed3\u6784\u8bbe\u8ba1\u7b49\u65b9\u9762\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u53c2\u8003\u3002<\/p>\n \u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n 1.<\/strong>\u5168\u56fa\u6001\u9502\u7535\u6c60\u4e2d\u7684\u56fa\u4f53\u7535\u89e3\u8d28<\/strong><\/span><\/p>\n 1.1 <\/strong>\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7406\u8bba<\/strong><\/span><\/p>\n \u7f3a\u9677\u5bf9\u6676\u4f53\u6027\u8d28\u6709\u7740\u91cd\u8981\u7684\u5f71\u54cd\uff0c\u79bb\u5b50\u7535\u5bfc\u6765\u6e90\u4e8e\u6676\u4f53\u4e2d\u7a7a\u4f4d\u6216\u586b\u9699\u79bb\u5b50\u7b49\u70b9\u7f3a\u9677\u7684\u79fb\u52a8\u3002\u8fc7\u6e21\u91d1\u5c5e\u7531\u4e8e\u4ef7\u6001\u8f83\u591a\u53ef\u5f62\u6210\u975e\u5316\u5b66\u8ba1\u91cf\u6bd4\u7684\u5177\u6709\u8f83\u9ad8\u672c\u5f81\u7f3a\u9677\u6d53\u5ea6\u7684\u6c27\u5316\u7269\u3002\u901a\u8fc7\u63ba\u6742\u7b49\u65b9\u6cd5\u53ef\u6709\u6548\u63d0\u9ad8\u6676\u4f53\u7684\u975e\u672c\u5f81\u7f3a\u9677\u4ece\u800c\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u805a\u5408\u7269\u7535\u89e3\u8d28\u4f53\u7cfb\u975e\u5e38\u590d\u6742\uff0c\u4e14\u7f3a\u4e4f\u7b80\u5355\u7684\u7ed3\u6784\u4e0e\u6027\u8d28\u4e4b\u95f4\u7684\u5173\u8054\uff0c\u8fd9\u4e9b\u4f53\u7cfb\u4e2d\u79bb\u5b50\u8f93\u8fd0\u8fc7\u7a0b\u7684\u63cf\u8ff0\u975e\u5e38\u56f0\u96be\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\u901a\u5e38\u7531VTF\u65b9\u7a0b\u6765\u63cf\u8ff0\u3002\u5bf9\u4e8e\u7531\u5bfc\u7535\u76f8\u548c\u975e\u5bfc\u7535\u76f8\u7ec4\u6210\u7684\u590d\u5408\u6750\u6599\u7535\u89e3\u8d28\u800c\u8a00\uff0c\u5176\u7535\u5bfc\u7387\u5219\u53ef\u901a\u8fc7\u6709\u6548\u4ecb\u8d28\u7406\u8bba\u6765\u89e3\u91ca\u3002<\/p>\n 1.2 <\/strong>\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u7ed3\u6784\u548c\u7535\u5316\u5b66\u8fc7\u7a0b<\/strong><\/span><\/p>\n \u5168\u56fa\u6001\u9502\u7535\u6c60\u7531\u6b63\u6781\u3001\u7535\u89e3\u8d28\u3001\u8d1f\u6781\u548c\u96c6\u6d41\u4f53\u7ec4\u6210\u3002\u56fa\u4f53\u7535\u89e3\u8d28\u5728\u5168\u56fa\u6001\u9502\u7535\u6c60\u4e2d\u65e2\u5145\u5f53\u79bb\u5b50\u5bfc\u4f53\u53c8\u626e\u6f14\u9694\u819c\u7684\u89d2\u8272\uff0c\u4e24\u7aef\u5206\u522b\u4e0e\u6b63\u6781\u548c\u8d1f\u6781\u76f8\u8fde\u3002\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u4e0e\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u7c7b\u4f3c\uff1a\u5145\u7535\u65f6\uff0c\u9502\u79bb\u5b50\u4ece\u6b63\u6781\u8131\u5d4c\u5e76\u901a\u8fc7\u79bb\u5b50\u5bfc\u4f53\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u8fc1\u79fb\u5230\u8d1f\u6781\uff0c\u7535\u5b50\u5219\u901a\u8fc7\u5916\u7535\u8def\u8fc1\u79fb\uff1b\u653e\u7535\u65f6\uff0c\u9502\u79bb\u5b50\u4ece\u8d1f\u6781\u8131\u5d4c\u5e76\u901a\u8fc7\u56fa\u4f53\u7535\u89e3\u8d28\u8fc1\u79fb\u5230\u6b63\u6781\uff0c\u7535\u5b50\u901a\u8fc7\u5916\u7535\u8def\u6765\u9a71\u52a8\u8bbe\u5907\u5de5\u4f5c\u3002\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u7684\u53cd\u5e94\u8fc7\u7a0b\u4e3b\u8981\u5305\u62ec\u4ee5\u4e0b\u51e0\u6b65\uff1a\uff081\uff09\u7535\u89e3\u8d28\u4e2d\u9502\u79bb\u5b50\u7684\u6269\u6563\uff0c\uff082\uff09\u5728\u7535\u6781\u8868\u9762\u7684\u5438\u9644\uff0c\uff083\uff09\u7535\u8377\u8f6c\u79fb\uff0c\uff084\uff09\u5d4c\u5165\u7535\u6781\uff0c\uff085\uff09\u9502\u79bb\u5b50\u5d4c\u5165\u7535\u6781\u4e2d\u548c\uff086\uff09\u8868\u9762\u53cd\u5e94\u7b49\u3002<\/p>\n \u56fe<\/strong>1 <\/strong>\u5168\u56fa\u6001\u9502\u7535\u6c60\u5de5\u4f5c\u539f\u7406\u793a\u610f\u56fe<\/strong><\/span><\/p>\n 1.3 <\/strong>\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u529f\u80fd\u548c\u6027\u80fd<\/strong><\/span><\/p>\n \u56fa\u4f53\u7535\u89e3\u8d28\u5bf9\u4e8e\u5168\u56fa\u6001\u53ef\u5145\u7535\u9502\u7535\u6c60\u6765\u8bf4\u662f\u81f3\u5173\u91cd\u8981\u7684\u90e8\u5206\u3002\u56fa\u4f53\u7535\u89e3\u8d28\u5e94\u8be5\u5177\u5907\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u3001\u53ef\u5ffd\u7565\u7684\u7535\u5b50\u7535\u5bfc\u3001\u8f83\u5bbd\u7684\u5de5\u4f5c\u7535\u538b\u7a97\u53e3\u4ee5\u53ca\u4e0e\u7535\u6781\u4e4b\u95f4\u5177\u6709\u8f83\u597d\u7684\u5316\u5b66\u76f8\u5bb9\u6027\u3002\u76ee\u524d\u6709\u4e24\u7c7b\u5168\u56fa\u6001\u7535\u6c60\u53ef\u4e92\u4e3a\u8865\u5145\u6765\u6ee1\u8db3\u8fd9\u4e9b\u8981\u6c42\u3002\u4e00\u7c7b\u4ee5\u805a\u5408\u7269\u8584\u819c\u4f5c\u4e3a\u7535\u89e3\u8d28\uff0c\u53e6\u4e00\u7c7b\u4ee5\u65e0\u673a\u73bb\u7483\u6216\u9676\u74f7\u4f5c\u4e3a\u7535\u89e3\u8d28\u3002\u5728\u8fc7\u53bb\u5341\u591a\u5e74\u7684\u7814\u7a76\u4e2d\uff0cLi3<\/sub>N\uff0cLiPON\uff0cLi2<\/sub>S\u57fa\u73bb\u7483\uff0cNaSICON\u578b\u6c27\u5316\u7269Li1-x<\/sub>Alx<\/sub>Ti2-x<\/sub>(PO4<\/sub>)3<\/sub>\uff0c\u9499\u949b\u77ff\u578bLi0.05-3x<\/sub>La0.5+x<\/sub>TiO3<\/sub>\uff0c\u77f3\u69b4\u77f3\u578bLi7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub>\u4ee5\u53ca\u805a\u5408\u7269\u7535\u89e3\u8d28\u7b49\u5747\u8868\u73b0\u51fa\u76f8\u5f53\u597d\u7684\u9502\u79bb\u5b50\u4f20\u5bfc\u7279\u6027\u3002<\/p>\n 1.3.1 <\/strong>\u56fa\u4f53\u9676\u74f7\u7535\u89e3\u8d28<\/strong><\/span><\/p>\n \u6700\u65e9\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u9502\u78f7\u6c27\u6c2e\uff08LiPON\uff09\u7531Bates\u7b49\u4eba\u63d0\u51fa\uff0c\u7531\u4e8eLiPON\u7684\u5ba4\u6e29\u7535\u5bfc\u7387\u8f83\u4f4e(2\u00d710\u22126<\/sup> S cm\u22121<\/sup>)\uff0c\u5176\u53d1\u5c55\u53d7\u5230\u4e86\u963b\u788d\u3002Li2<\/sub>S-GeS2<\/sub>\uff0cLi2<\/sub>S-P2<\/sub>S5<\/sub>\uff0cLi2<\/sub>S-B2<\/sub>S3<\/sub>\u548cLi2<\/sub>S-SiS2<\/sub>\u7b49\u786b\u5316\u7269\u9502\u79bb\u5b50\u5bfc\u4f53\u73bb\u7483\u5728\u5ba4\u6e29\u4e0b\u5177\u6709\u9ad8\u4e8e10\u22124<\/sup> S cm\u22121<\/sup>\u7684\u7535\u5bfc\u7387\uff0c\u800c70Li2<\/sub>S-30P2<\/sub>S5<\/sub>\u7b49\u5fae\u6676\u73bb\u7483\u7684\u7535\u5bfc\u7387\u5219\u66f4\u9ad8\uff083.2\u00d710\u22123<\/sup> S cm\u22121<\/sup>\uff09\u3002\u73bb\u7483\u6001\u7535\u89e3\u8d28\u7684\u6700\u5927\u7f3a\u70b9\u5c31\u662f\u5176\u5bf9\u6e7f\u5ea6\u8fc7\u4e8e\u654f\u611f\u3002\u6700\u8fd1\u65e5\u672c\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66\u7b49Kanno\u6559\u6388\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u4e09\u7ef4\u6846\u67b6\u7ed3\u6784\u7684\u56fa\u4f53\u7535\u89e3\u8d28Li10<\/sub>GeP2<\/sub>S12<\/sub>\uff0c\u5176\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u9ad8\u8fbe12 mS cm\u22121<\/sup>\uff0c\u4f46\u662f\u8be5\u7c7b\u6750\u6599\u7684\u7f3a\u70b9\u662f\u5bb9\u6613\u4e0e\u5927\u6c14\u4e2d\u7684\u6c34\u6c7d\u53d1\u751f\u53cd\u5e94\u3002\u56fe2\u4e3aLi10<\/sub>GeP2<\/sub>S12<\/sub>\u4e0e\u5176\u5b83\u7535\u89e3\u8d28\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u5bf9\u6bd4\u3002\u56fe3\u4e3aLi10<\/sub>GeP2<\/sub>S12<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n \u56fe<\/strong>2 Li10<\/sub>GeP2<\/sub>S12<\/sub><\/strong>\u4e0e\u5176\u5b83\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u5bf9\u6bd4<\/strong><\/p>\n \u56fe<\/strong>3 Li10<\/sub>GeP2<\/sub>S12<\/sub><\/strong>\u7684\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n (a)\u00a0<\/strong>\u6846\u67b6\u7ed3\u6784\u4ee5\u53ca\u53c2\u4e0e\u79bb\u5b50\u5bfc\u7535\u7684\u9502\u79bb\u5b50\uff1b<\/strong>(b) Li10<\/sub>GeP2<\/sub>S12<\/sub><\/strong>\u7684\u6846\u67b6\u7ed3\u6784\uff1b<\/strong>(c)\u00a0<\/strong>\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u9014\u5f84<\/strong><\/p>\n \u77f3\u69b4\u77f3\u7ed3\u6784\u7684Li7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub>\uff08LLZO\uff09\u5728\u5ba4\u6e29\u4e0b\u7684\u7535\u5bfc\u7387\u4e3a5\u00d710\u22124<\/sup> S cm\u22121<\/sup>\uff0c\u5177\u6709\u975e\u5e38\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u5316\u5b66\u76f8\u5bb9\u6027\uff0c\u4f46\u662f\u5bcc\u9502\u7684\u77f3\u69b4\u77f3\u7ed3\u6784LLZO\u5728\u6c34\u3001\u7a00\u9178\u7b49\u73af\u5883\u4e2d\u6613\u4e8e\u53d1\u751f\u8d28\u5b50\u4ea4\u6362\u3002\u5176\u7ed3\u6784\u548c\u79bb\u5b50\u8f93\u8fd0\u673a\u7406\u5982\u56fe4\u6240\u793a\u3002\u9502\u539f\u5b50\u5728Li2\u4f4d\u7f6e\u7684\u65e0\u5e8f\u5316\u548c\u90e8\u5206\u5360\u636e\u5bf9\u4e8e\u9502\u79bb\u5b50\u7684\u4f20\u5bfc\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n (a)\u00a0<\/strong>\u7acb\u65b9<\/strong>Li7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub><\/strong>\u7684\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n (b) Li1<\/strong>\u4f4d\u548c<\/strong>Li2<\/strong>\u4f4d\u7684\u914d\u4f4d\u591a\u9762\u4f53<\/strong><\/p>\n (c)\u00a0<\/strong>\u7acb\u65b9<\/strong>Li7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub><\/strong>\u4e2d\u9502\u79bb\u5b50\u7684\u4e09\u7ef4\u4f20\u5bfc\u7f51\u7edc<\/strong><\/p>\n 1.3.2 <\/strong>\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28<\/strong><\/span><\/p>\n \u4e0e\u65e0\u673a\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u6db2\u4f53\u7535\u89e3\u8d28\u76f8\u6bd4\uff0c\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08SPE\uff09\u67d4\u97e7\u6027\u66f4\u597d\u3001\u66f4\u5b89\u5168\u3002SPE\u53ef\u901a\u8fc7\u5c06\u9502\u76d0\u6eb6\u89e3\u5728\u805a\u5408\u7269\u4e2d\u5f97\u5230\u3002\u9502\u79bb\u5b50\u901a\u8fc7\u805a\u5408\u7269\u94fe\u7684\u6eb6\u5242\u5316\uff0c\u53d8\u5f97\u53ef\u4ee5\u901a\u8fc7\u94fe\u7684\u8fd0\u52a8\u800c\u79fb\u52a8\uff0c\u81ea\u7531\u9502\u79bb\u5b50\u6570\u91cf\u548c\u94fe\u7684\u53ef\u79fb\u52a8\u6027\u663e\u8457\u5f71\u54cdSPE\u4e2d\u9502\u79bb\u5b50\u7684\u8fc1\u79fb\u7387\u3002\u5ba4\u6e29\u4e0bSPE\u7684\u9502\u79bb\u5b50\u8fc1\u79fb\u7387\u6bd4\u6db2\u4f53\u7535\u89e3\u8d28\u548c\u65e0\u673a\u56fa\u4f53\u7535\u89e3\u8d28\u90fd\u8981\u4f4e\uff0c\u7814\u7a76\u5176\u79bb\u5b50\u5bfc\u7535\u673a\u7406\u5bf9\u4e8e\u63d0\u9ad8\u5176\u7535\u5bfc\u7387\u800c\u8a00\u5c24\u4e3a\u91cd\u8981\u3002<\/p>\n a<\/strong> PEO<\/strong>\u57fa\u56fa\u4f53\u7535\u89e3\u8d28<\/strong><\/span><\/p>\n PEO\u662f\u4ee5\u4f4e\u805a\u919a(-CH2<\/sub>-CH2<\/sub>-O-)n<\/sub>\u4e3a\u5355\u4f53\u5f62\u6210\u7684\u805a\u5408\u7269\u3002\u4ee5PEO\u4e3a\u57fa\u4f53\u7684SPE\u5ba4\u6e29\u4e0b\u7684\u7535\u5bfc\u7387\u6bd4\u8f83\u4f4e(10\u22127<\/sup> S cm\u22121<\/sup>)\uff0c\u901a\u5e38\u9700\u8981\u5728\u5f15\u5165\u5176\u5b83\u7eb3\u7c73\u7ea7\u7684\u6c27\u5316\u7269\u586b\u5145\u7269\u5f62\u6210\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08CPE\uff09\u4ee5\u63d0\u9ad8\u5176\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u4f8b\u5982\uff1a\u5728PEO\u4e2d\u5f15\u5165\u7eb3\u7c73\u5c3a\u5ea6\u7684\u9676\u74f7\u7c89\u672b\uff0c\u53ef\u6291\u5236\u805a\u5408\u7269\u7ed3\u6676\uff0c\u589e\u5f3aPEO\u4e0e\u79bb\u5b50\u5bfc\u7535\u76f8\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4f7f\u79bb\u5b50\u7535\u5bfc\u7387\u63d0\u53471-2\u4e2a\u6570\u91cf\u7ea7\uff1b\u5728PEO\u4e2d\u5f15\u5165\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u7eb3\u7c73\u9897\u7c92\u5f62\u6210\u7684\u8584\u819c\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387\u53ef\u8fbe3.16\u00d710\u22125<\/sup> S cm\u22121<\/sup>\u3002\u901a\u5e38\uff0cCPE\u901a\u8fc7\u673a\u68b0\u6df7\u5408\u9676\u74f7\u9897\u7c92\u548c\u805a\u5408\u7269\u7684\u65b9\u6cd5\u5f97\u5230\u3002\u6700\u8fd1\uff0c\u901a\u8fc7\u539f\u4f4d\u6c34\u89e3\u6cd5\u5728PEO\u805a\u5408\u7269\u4e2d\u76f4\u63a5\u5408\u6210\u9676\u74f7\u586b\u5145\u7269\uff0c\u5f97\u5230\u4e8630o<\/sup>C\u4e0b\u7535\u5bfc\u7387\u4e3a4.4\u00d710\u22125<\/sup> S cm\u22121<\/sup>\u7684CPE\uff08\u56fe5\uff09\u3002<\/p>\n \u5de6\uff1a\u5728<\/strong>PEO<\/strong>\u94fe\u548c\u5355\u5206\u6563\u7684<\/strong>SiO2<\/sub><\/strong>\u7eb3\u7c73\u9897\u7c92\u4e4b\u95f4\u5f62\u6210\u5316\u5b66\u952e\u5408\u548c\u673a\u68b0\u7f20\u7ed5\u4e24\u79cd\u53ef\u80fd\u7684\u76f8\u4e92\u4f5c\u7528\u673a\u7406<\/strong><\/p>\n \u53f3\uff1a<\/strong>4<\/strong>\u79cd\u4e0d\u540c<\/strong>PEO<\/strong>\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u963f\u7d2f\u5c3c\u4e4c\u65af\u5173\u7cfb\u66f2\u7ebf<\/strong><\/p>\n b\u00a0<\/strong>\u805a\u7845\u6c27\u70f7<\/strong>\u57fa\u56fa\u4f53\u7535\u89e3\u8d28<\/strong><\/span><\/p>\n \u7531\u4e8e\u805a\u7845\u6c27\u70f7\u9aa8\u67b6\u67d4\u97e7\u6027\u975e\u5e38\u9ad8\uff0c\u73bb\u7483\u8f6c\u53d8\u6e29\u5ea6\u4f4e\uff0c\u81ea\u7531\u4f53\u79ef\u5927\uff0c\u5176\u79bb\u5b50\u7535\u5bfc\u7387\u76f8\u5bf9\u800c\u8a00\u6bd4\u8f83\u9ad8\u3002\u8be5\u7c7b\u7535\u89e3\u8d28\u7684\u7814\u7a76\u91cd\u70b9\u4e3b\u8981\u662f\u5728\u805a\u7845\u6c27\u70f7\u9aa8\u67b6\u4e0a\u5ac1\u63a5\u529f\u80fd\u6027\u7684\u57fa\u56e2\u3002\u56fe6\u4e3a\u53cc\u529f\u80fd\u7684\u805a\u7845\u6c27\u70f7\uff08VC-PMHS\uff09\u7684\u5408\u6210\u8def\u7ebf\uff0c\u5176\u5ba4\u6e29\u7535\u5bfc\u7387\u8fbe1.55\u00d710\u22124<\/sup> S cm\u22121<\/sup>\u3002<\/p>\n \u56fe<\/strong>6 <\/strong>\u53cc\u529f\u80fd\u7684\u805a\u7845\u6c27\u70f7\uff08<\/strong>VC-PMHS<\/strong>\uff09\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/span><\/p>\n c\u00a0<\/strong>\u5355\u9502\u79bb\u5b50\u5bfc\u4f53\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28<\/strong><\/span><\/p>\n \u7531\u4e8e\u8be5\u7c7b\u7535\u89e3\u8d28\u4e2d\u7684\u9634\u79bb\u5b50\u4e0e\u805a\u5408\u7269\u952e\u5408\u6216\u8005\u88ab\u9634\u79bb\u5b50\u53d7\u4f53\u56fa\u5b9a\uff0c\u9634\u79bb\u5b50\u7684\u6781\u5316\u53ef\u5ffd\u7565\u4e0d\u8ba1\uff0c\u9502\u79bb\u5b50\u7684\u8fc1\u79fb\u6570\u53ef\u63a5\u8fd1\u4e8e1\u3002\u7136\u800c\u5176\u5ba4\u6e29\u7535\u5bfc\u7387\u8f83\u4f4e\uff0c\u7814\u7a76\u8005\u4eec\u5e38\u901a\u8fc7\u6742\u5316\u590d\u5408\u7684\u65b9\u6cd5\u6765\u6539\u5584\u5176\u6027\u80fd\u3002\u6700\u8fd1\u7814\u7a76\u4eba\u5458\u5408\u6210\u4e86\u9502\u79bb\u5b50\u8fc1\u79fb\u6570\u4e3a0.91\u300190o<\/sup>C\u4e0b\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a1.35\u00d710\u22124<\/sup> S cm\u22121<\/sup>\u7684LiPSsTFSI\/PEO\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\u3002<\/p>\n \u56fe<\/strong>7 LiX\/PEO(X=PSS, PSTFSI, PSsTFSI, TFSI)<\/strong>\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28<\/strong>(EO\/Li+<\/sup>=20\/1)<\/strong>\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb<\/strong><\/p>\n 2.<\/strong>\u5168\u56fa\u6001\u9502\u7535\u6c60<\/strong><\/span><\/p>\n \u56fa\u4f53\u7535\u89e3\u8d28\u662f\u5168\u56fa\u6001\u9502\u7535\u6c60\u6700\u91cd\u8981\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u6839\u636e\u5168\u56fa\u6001\u7535\u6c60\u6240\u4f7f\u7528\u7684\u7535\u89e3\u8d28\u7684\u7c7b\u578b\u53ef\u5c06\u5176\u5206\u6210\u4e0d\u540c\u7684\u7c7b\u522b\u3002<\/p>\n 2.1 <\/strong>\u9502\u78f7\u6c27\u6c2e\uff08<\/strong>LiPON<\/strong>\uff09\u7535\u89e3\u8d28\u57fa\u5168\u56fa\u6001\u9502\u7535\u6c60<\/strong><\/span><\/p>\n LiPON\u901a\u5e38\u88ab\u7528\u5728\u8584\u819c\u7535\u6c60\u4e2d\u3002\u5168\u56fa\u6001\u8584\u819c\u7535\u6c60\u53ef\u901a\u8fc7\u987a\u5e8f\u5730\u6c89\u79ef\u7535\u6781\u3001\u56fa\u6001\u7535\u89e3\u8d28\u548c\u96c6\u6d41\u4f53\u6765\u5236\u5907\uff0c\u5176\u603b\u539a\u5ea6\u4ec5\u670910-15 \u00b5m\u3002\u56fe8\u662f\u8584\u819c\u7535\u6c60\u7684\u5178\u578b\u7ed3\u6784\u3002\u8be5\u7c7b\u7535\u6c60\u5c06\u4f1a\u5728\u4f20\u611f\u5668\u3001\u7535\u5b50\u6807\u7b7e\u548c\u667a\u80fd\u5361\u7b49\u5c0f\u578b\u8bbe\u5907\u5f97\u5230\u5e94\u7528\u3002<\/p>\n \u56fe<\/strong>8 <\/strong>\u5e26\u6709\u652f\u6491\u57fa\u7247\u7684\u8584\u819c\u7535\u6c60\u7684\u622a\u9762\u56fe<\/strong><\/p>\n \u56fe9\u4e3a\u56fa\u60013D\u5fae\u578b\u7535\u6c60\u7684\u793a\u610f\u56fe\u3002\u6b63\u6781LiFePO4<\/sub>\u5c42\u91c7\u7528\u5c04\u9891\u6e85\u5c04\u6c89\u79ef\u7684\u65b9\u6cd5\u5f97\u5230\uff0c\u8d1f\u6781\u4e3a\u91c7\u7528\u6df1\u5c42\u79bb\u5b50\u523b\u8680\u6280\u672f\u548c\u4f4e\u6210\u672c\u7684\u5149\u523b\u5de5\u827a\u5f97\u5230\u7684\u9ad8\u7eb5\u6a2a\u6bd4\u7684\u7845\u7eb3\u7c73\u67f1\uff08SiNPL\uff09\uff0cLiPON\u56fa\u6001\u7535\u89e3\u8d28\u6c89\u79ef\u5728\u7845\u7eb3\u7c73\u67f1\u9635\u5217\u4e2d\u95f4\u3002<\/p>\n \u56fe<\/strong>9 <\/strong>\u9502\u79bb\u5b50\u56fa\u6001\u5fae\u578b\u7535\u6c60\u7684\u793a\u610f\u56fe<\/strong><\/p>\n 2.2 <\/strong>\u786b\u5316\u7269\u73bb\u7483\u56fa\u4f53\u7535\u89e3\u8d28\u57fa\u5168\u56fa\u6001\u9502\u7535\u6c60<\/strong><\/span><\/p>\n Li2<\/sub>S-P2<\/sub>S5<\/sub>\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u8f83\u5bbd\u7684\u7535\u5316\u5b66\u7a97\u53e3\u3002\u4ee5LiCoO2<\/sub>\u548c80Li2<\/sub>S.20P2<\/sub>S5<\/sub>\u7ec4\u6210\u4e3a\u7535\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u5c55\u73b0\u51fa\u8f83\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002\u7ec4\u6210\u4e3aIn-Li\/70Li2<\/sub>S.29P2<\/sub>S5<\/sub>.1P2<\/sub>S3<\/sub>\u73bb\u7483\u9676\u74f7\/Li4<\/sub>Ti5<\/sub>O12<\/sub>\u7684\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u5145\u653e\u7535\u6027\u80fd\u66f2\u7ebf\u8868\u660e\uff0c\u8be5\u7535\u6c60\u53ef\u5728\u9ad8\u4e8e10 mA cm\u22122<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u53ef\u9006\u5730\u5de5\u4f5c\u3002<\/p>\n<\/strong><\/p>\n
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\u56fe<\/strong>4 Li7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub>\uff08LLZO\uff09\u7684\u7ed3\u6784<\/strong><\/p>\n
\u56fe<\/strong>5 \u76f8\u4e92\u4f5c\u7528\u673a\u7406\u548c\u963f\u7d2f\u5c3c\u4e4c\u65af\u5173\u7cfb\u66f2\u7ebf <\/strong><\/p>\n
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