{"id":69338,"date":"2017-03-04T10:08:55","date_gmt":"2017-03-04T02:08:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=69338"},"modified":"2017-03-04T17:37:01","modified_gmt":"2017-03-04T09:37:01","slug":"science%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e5%8e%9f%e5%ad%90%e3%80%81%e5%88%86%e5%ad%90%e5%8f%8a%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e7%89%a9%e6%a1%86%e6%9e%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=69338","title":{"rendered":"Omar M. Yaghi\u6559\u6388Science\u6700\u65b0\u7efc\u8ff0\uff1a\u539f\u5b50\u3001\u5206\u5b50\u53ca\u5171\u4ef7\u6709\u673a\u7269\u6846\u67b6"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5c31\u5728\u4e00\u4e2a\u4e16\u7eaa\u524d\uff0cGilbert N. Lewis\u51fa\u7248\u4e86\u4ed6\u5212\u65f6\u4ee3\u7684\u8457\u4f5c\u201cThe Atom and the Molecule\u201d\uff08\u539f\u5b50\u4e0e\u5206\u5b50\uff09\uff0c\u4e5f\u5c31\u662f\u540e\u6765\u4e3a\u4eba\u6240\u719f\u77e5\u7684\u5171\u4ef7\u952e\u3002\u4ece\u90a3\u65f6\u8d77\uff0c\u6709\u673a\u5316\u5b66\u5bb6\u4eec\u7cfb\u7edf\u5730\u53d1\u5c55\u4e86\u5171\u4ef7\u5206\u5b50\u5316\u5b66\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u8fd9\u76f4\u63a5\u5bfc\u81f4\u4e86\u5168\u5408\u6210\u827a\u672f\u4e0e\u79d1\u5b66\u7684\u4ea7\u751f\u3002\u8d85\u8d8a\u5206\u5b50\u7684\u6709\u673a\u53cd\u5e94\u4f7f\u4e8c\u7ef4\u6216\u4e09\u7ef4\u7684\u6709\u673a\u7ed3\u6784\u4ee5\u5171\u4ef7\u952e\u8fdb\u884c\u8fde\u63a5\u5df2\u7ecf\u6210\u4e3a\u4e86\u4e00\u9879\u957f\u4e45\u7684\u76ee\u6807\u3002\u6700\u8fd1\uff0c\u8fd9\u4e2a\u76ee\u6807\u5df2\u7ecf\u5728\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7269\uff08COFs\uff09\u7684\u7f51\u72b6\u7ed3\u6784\u7684\u5408\u6210\u4e2d\u5f97\u4ee5\u5b9e\u73b0\u3002\u8fd9\u62d3\u5c55\u4e86\u591a\u5b54\u7ed3\u6784\u5168\u90e8\u7531\u8f7b\u5143\u7d20\u6784\u6210\u4ee5\u53ca\u76f8\u4e92\u95f4\u4ee5\u5f88\u5f3a\u7684\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u5b9a\u5219\u3002\u7531\u4e8e\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7269\u5177\u6709\u9ad8\u5b54\u9699\u7387\u4ee5\u53ca\u5f88\u9ad8\u7684\u70ed\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u56e0\u6b64\u8868\u73b0\u51fa\u4e86\u975e\u5e38\u7a33\u5b9a\u7684\u7ed3\u6784\uff0c\u8fd9\u5c31\u5141\u8bb8\u6709\u673a\u548c\u65e0\u673a\u53cd\u5e94\u53ef\u4ee5\u5728\u6846\u67b6\u5185\u53d1\u751f\u800c\u4e0d\u4f1a\u5f71\u54cd\u5176\u591a\u5b54\u6027\u548c\u7ed3\u6676\u6027\u3002\u8fd9\u5df2\u7ecf\u4e0a\u5347\u5230\u4e86\u201c\u6846\u67b6\u5316\u5b66\u201d\u7684\u9ad8\u5ea6\uff0cLewis\u5173\u4e8e\u539f\u5b50\u548c\u5206\u5b50\u7684\u6982\u5ff5\u5df2\u7ecf\u5ef6\u4f38\u5230\u4e86\u6846\u67b6\u7684\u7a0b\u5ea6\uff0c\u8fd9\u4e5f\u8bc1\u660e\u4eba\u4eec\u53ef\u4ee5\u8fdb\u4e00\u6b65\u5bf9\u7269\u8d28\u8fdb\u884c\u63a7\u5236\u548c\u8c03\u63a7\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u7684<\/strong>Omar M. Yaghi<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Science<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201c<\/strong>The atom, the molecule, and the covalent organic framework<\/strong>\u201d<\/strong>\u7684\u7efc\u8ff0\uff0c\u8be6\u7ec6\u603b\u7ed3\u4e86\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7269\u7684\u7814\u7a76\u8fdb\u5c55\u548c\u53d1\u5c55\u6f5c\u529b\uff0c\u6587\u4e2d\u7684\u5177\u4f53\u5185\u5bb9\u5305\u62ec\u4ee5\u4e0b\u516d\u90e8\u5206\uff1a\u5316\u5b66\u4e2d\u5206\u5b50\u6982\u5ff5\u5ef6\u4f38\u7684\u53d1\u5c55\u3001\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7269\u7684\u57fa\u672c\u6982\u5ff5\u3001\u6846\u67b6\u53cd\u5e94\u53ca\u5176\u6027\u8d28\u3001\u6846\u67b6\u4e2d\u5171\u4ef7\u952e\u548c\u673a\u68b0\u529b\u7684\u7ed3\u5408\u3001\u4e0d\u540c\u7ef4\u6570\u6846\u67b6\u7ed3\u6784\u7684\u7ea0\u7f20\u3001\u672a\u6765\u7684\u5c55\u671b\u3002<\/p>\n

\"\"<\/p>\n

\u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n

1.\u6982\u8ff0<\/strong><\/p>\n

Gilbert N. Lewis\u5728\u5176\u8457\u4f5c\u4e2d\u53d9\u8ff0\u4e86\u4e00\u4e9b\u91cd\u8981\u95ee\u9898\u7684\u6982\u5ff5\u7814\u7a76\uff0c\u4f8b\u5982\u539f\u5b50\u662f\u5982\u4f55\u7ed3\u5408\u6210\u4e3a\u5206\u5b50\uff0c\u5982\u4f55\u63cf\u8ff0\u5206\u5b50\u4e2d\u539f\u5b50\u95f4\u7684\u7ed3\u5408\u4ee5\u53ca\u8fd9\u79cd\u7ed3\u5408\u5bf9\u4e8e\u53cd\u5e94\u6d3b\u6027\u548c\u5206\u5b50\u6027\u8d28\u7684\u5f71\u54cd\u3002\u5316\u5b66\u5bb6\u4eec\u5df2\u7ecf\u5e94\u7528\u8fd9\u4e9b\u6982\u5ff5\u52aa\u529b\u63a7\u5236\u7279\u5b9a\u5206\u5b50\u6240\u5177\u6709\u7684\u4e0d\u540c\u7ed3\u6784\u548c\u590d\u6742\u6027\uff0c\u8fd9\u76f4\u63a5\u5bfc\u81f4\u4e86\u5168\u5408\u6210\u827a\u672f\u548c\u79d1\u5b66\u7684\u4ea7\u751f\u3002\u5982\u4eca\uff0c\u7cbe\u786e\u5730\u4f7f\u6709\u673a\u5206\u5b50\u529f\u80fd\u5316\u5e76\u63a7\u5236\u5176\u51e0\u4f55\u7ed3\u6784\u5df2\u7ecf\u6210\u719f\u5e76\u8fbe\u5230\u4e86\u7406\u6027\u5408\u6210\u7684\u9636\u6bb5\u3002<\/p>\n

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\"\"<\/p>\n

\u56fe<\/strong>1 <\/strong>\u539f\u5b50\u3001\u5206\u5b50\u4ee5\u53ca\u5171\u4ef7\u6709\u673a\u7269\u6846\u67b6<\/strong><\/p>\n

2. \u8d85\u8d8a\u5206\u5b50\u7684\u5316\u5b66\u5e74\u8868<\/strong><\/p>\n

\u81ea\u4eceLewis\u5173\u4e8e\u5171\u4ef7\u952e\u7684\u6982\u5ff5\u6027\u5de5\u4f5c\u4ee5\u6765\uff0c\u6709\u673a\u7269\u5408\u6210\u65b9\u6cd5\u7684\u7cfb\u7edf\u53d1\u5c55\u5bfc\u81f4\u4e86\u5316\u5b66\u4e2d\u7684\u591a\u9879\u91cd\u8981\u8fdb\u5c55\u3002\u5927\u578b\u5927\u5206\u5b50\u7ed3\u6784\uff08\u4e00\u7ef4\u805a\u5408\u7269\uff09\u7684\u53d1\u73b0\u6253\u5f00\u4e86\u6709\u673a\u529f\u80fd\u6750\u6599\u7684\u7814\u7a76\u9886\u57df\u3002\u53e6\u4e00\u4e2a\u91cc\u7a0b\u7891\u5f0f\u7684\u7814\u7a76\u6210\u679c\u5305\u62ec\u5929\u7136\u590d\u6742\u6709\u673a\u7269\u7684\u9006\u5408\u6210\u53ca\u5176\u5728\u5236\u836f\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u3002\u5408\u6210\u65b9\u6cd5\u7684\u53d1\u5c55\u4f7f\u5f97\u5408\u6210\u5206\u5b50\u5f97\u4ee5\u5b9e\u73b0\uff0c\u4f46\u662f\u5176\u4e2d\u7684\u4e00\u5927\u95ee\u9898\u5c31\u662f\u5982\u4f55\u4f7f\u8fd9\u4e9b\u5206\u5b50\u5f62\u6210\u6709\u89c4\u5f8b\u7684\u5f62\u5f0f\u6765\u5f62\u6210\u66f4\u590d\u6742\u7684\u529f\u80fd\u7cfb\u7edf\u3002\u4e00\u4e2a\u89e3\u51b3\u65b9\u6848\u5c31\u662f\u8d85\u5206\u5b50\u5316\u5b66\uff0c\u975e\u5171\u4ef7\u952e\u7684\u4f5c\u7528\u4e3b\u5bfc\u4e86\u5206\u5b50\u7684\u8bc6\u522b\u8fc7\u7a0b\uff0c\u4f8b\u5982\u5728\u539f\u59cb\u51a0\u72b6\u919a\u548c\u7a74\u72b6\u914d\u4f53\u4e2d\u7684\u9009\u62e9\u6027\u7ed3\u5408\u3002\u5206\u5b50\u8bc6\u522b\u4e0d\u4ec5\u5728\u5ba2\u4f53\u5206\u5b50\u7684\u9009\u62e9\u6027\u7ed3\u5408\u4e0a\u662f\u6709\u6548\u7684\uff0c\u800c\u4e14\u4f5c\u4e3a\u4e00\u79cd\u6a21\u677f\u7684\u65b9\u6cd5\uff0c\u5176\u5728\u5206\u5b50\u5927\u73af\u548c\u7b3c\u7684\u5408\u6210\u4e2d\u4e5f\u662f\u9002\u7528\u7684\uff0c\u8fd9\u5bfc\u81f4\u4e86\u901a\u8fc7\u5206\u5b50\u73af\u7684\u673a\u68b0\u8054\u9501\u6548\u5e94\u7ed3\u5408\u5728\u4e00\u8d77\u7684\u7d22\u70c3-\u5206\u5b50\u7684\u6a21\u677f\u5408\u6210\u6210\u4e3a\u53ef\u80fd\u3002\u8fd9\u4e5f\u4f7f\u673a\u68b0\u7ed3\u5408\u5f15\u5165\u5230\u4e86\u6846\u67b6\u7684\u5f62\u6210\u4e2d\u3002<\/p>\n

\u7279\u6b8a\u76f8\u4e92\u4f5c\u7528\u7684\u77e5\u8bc6\u53ef\u4ee5\u8fdb\u4e00\u6b65\u5e94\u7528\u5728\u7ecf\u5386\u81ea\u7ec4\u7ec7\u8fc7\u7a0b\u7684\u7cfb\u7edf\u8bbe\u8ba1\u4e2d\uff0c\u4e5f\u5c31\u662f\u8bf4\uff0c\u7531\u4e8e\u9009\u62e9\u6027\u7684\u5f31\u76f8\u4e92\u4f5c\u7528\u4f1a\u5f62\u6210\u6e05\u6670\u7684\u5ef6\u4f38\u8d85\u5206\u5b50\u7ed3\u6784\uff0c\u8fd9\u4f1a\u8fdb\u4e00\u6b65\u6784\u7b51\u5176\u5206\u5b50\u5316\u5408\u7269\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u8d85\u5206\u5b50\u7ec4\u88c5\u4f53\u5728\u4e0d\u7834\u574f\u5176\u7ed3\u6784\u7684\u6761\u4ef6\u4e0b\u8981\u8fdb\u884c\u4fee\u9970\u662f\u6781\u5176\u56f0\u96be\u7684\uff0c\u539f\u56e0\u5728\u4e8e\uff1a1\uff09\u6784\u7b51\u6a21\u5757\u7684\u4fee\u9970\u4f1a\u6539\u53d8\u6210\u5206\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5f15\u8d77\u4e0d\u540c\u7684\u7ec4\u88c5\u7ed3\u6784\uff1b2\uff09\u5728\u7ec4\u88c5\u4f53\u4e2d\u8fdb\u884c\u5316\u5b66\u4fee\u9970\u5e76\u4e0d\u7834\u574f\u5176\u7ed3\u6784\u5b8c\u6574\u6027\u662f\u5f88\u96be\u7684\uff1b3\uff09\u5176\u7ed3\u6784\u7684\u70ed\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u4f1a\u9650\u5236\u5176\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u6709\u5fc5\u8981\u5bf9\u5408\u6210\u7b56\u7565\u8fdb\u884c\u53d1\u5c55\uff0c\u5373\u8fd9\u4e9b\u5206\u5b50\u5e76\u4e0d\u7531\u8f83\u5f31\u7684\u76f8\u4e92\u4f5c\u7528\u7ed3\u5408\uff0c\u800c\u662f\u57fa\u4e8e\u4e00\u79cd\u6e05\u6670\u51e0\u4f55\u7ed3\u6784\u4e2d\u5f3a\u70c8\u7684\u5171\u4ef7\u952e\u8fdb\u884c\u6784\u7b51\u3002\u8fd9\u4e2a\u76ee\u6807\u7684\u8fbe\u6210\u4e3a\u5728\u5171\u4ef7\u952e\u6846\u67b6\u5185\u5f15\u5165\u529f\u80fd\u5316\u548c\u590d\u6742\u6027\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2 <\/strong>\u6e90\u81ea\u4e8e<\/strong>Lewis<\/strong>\u539f\u59cb\u5171\u4ef7\u952e\u6982\u5ff5\u7684\u53d1\u5c55\u5e74\u8868<\/strong><\/p>\n

3. \u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u6982\u5ff5\u57fa\u7840<\/strong><\/p>\n

\u6709\u673a\u5316\u5b66\u4e3a\u6784\u7b51COFs\u7684\u539f\u6599\u63d0\u4f9b\u4e86\u4e30\u5bcc\u7684\u8d44\u6e90\u3002\u4e0d\u8bba\u662fCOF\u8fd8\u662f\u5176\u4ed6\u5171\u4ef7\u952e\u5ef6\u5c55\u7ed3\u6784\u6846\u67b6\uff0c\u90fd\u662f\u7531\u4e24\u4e2a\u4e0d\u540c\u7684\u90e8\u5206\u7ec4\u6210\u7684\uff1a\u8fde\u63a5\u7269\uff08\u7ed3\u6784\u5355\u5143\uff09\u548c\u8fde\u63a5\u529b\uff08\u5728\u7f51\u72b6\u7269\u4e2d\u5355\u5143\u95f4\u5f62\u6210\u7684\u7ed3\u5408\uff09\u3002\u56e0\u6b64\uff0cCOF\u7684\u6709\u673a\u5408\u6210\u5c31\u4ece\u7ec4\u6210\u5355\u5143\u7684\u5408\u6210\u5f00\u59cb\uff0c\u5230\u5c06\u8fd9\u4e9b\u7ec4\u6210\u5355\u5143\u901a\u8fc7\u8bbe\u8ba1\u7684\u8def\u7ebf\u7ed3\u5408\u5728\u4e00\u8d77\u5f62\u6210\u7f51\u72b6\u7ed3\u6784\u7ed3\u675f\u3002\u7f51\u72b6COF\u7684\u4e00\u822c\u5408\u6210\u8def\u7ebf\u5982\u4e0b\uff1a\u7b2c\u4e00\uff0c\u76ee\u6807\u7f51\u7edc\u62d3\u6251\u7ed3\u6784\u7684\u786e\u5b9a\u53ca\u5176\u57fa\u672c\u51e0\u4f55\u5355\u5143\u7684\u89e3\u6784\uff1b\u7b2c\u4e8c\uff0c\u8bc4\u4f30\u7ec4\u6210\u90e8\u5206\u7684\u5ef6\u5c55\u6027\uff08\u8fde\u901a\u6027\uff09\u548c\u51e0\u4f55\u5916\u5f62\uff1b\u7b2c\u4e09\uff0c\u5bfb\u627e\u4e0e\u51e0\u4f55\u5355\u5143\u76f8\u5f53\u7684\u5206\u5b50\u5e76\u5c06\u5176\u4f5c\u4e3a\u8fde\u63a5\u7269\uff1b\u7b2c\u56db\uff0c\u901a\u8fc7\u8fde\u63a5\u7269\u95f4\u5f3a\u70c8\u7684\u5171\u4ef7\u952e\u5f62\u6210COF\uff1b\u7b2c\u4e94\uff0c\u5982\u679c\u4ea7\u7269\u672c\u8eab\u662f\u5355\u6676\u7684\uff0c\u90a3\u4e48\u5b83\u5c31\u53ef\u4ee5\u4f7f\u7528X\u5c04\u7ebf\u6216\u8005\u7535\u5b50\u884d\u5c04\u8fdb\u884c\u8868\u5f81\u3002\u622a\u6b62\u76ee\u524d\uff0c\u5df2\u7ecf\u6709\u8d85\u8fc7100\u79cdCOF\u7ed3\u6784\u88ab\u62a5\u9053\uff0c\u8fd9\u4e9b\u7ed3\u6784\u4e2d\u90fd\u81f3\u5c11\u7531\u4e24\u79cd\u6d3e\u751f\u7269\u7ec4\u6210\u3002\u5728\u8fd9\u4e9bCOF\u4e2d\uff0c\u90fd\u662f\u7531\u4e0a\u8ff0\u7684\u8fd9\u4e94\u4e2a\u6b65\u9aa4\u8fdb\u884c\u5408\u6210\u7684\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 COFs<\/strong>\u7684\u62d3\u6251\u8bbe\u8ba1\u53ca\u7f51\u72b6\u5408\u6210<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 <\/strong>\u8fde\u63a5\u7269\u3001\u8fde\u63a5\u529b\u4ee5\u53ca\u6846\u67b6\u7ed3\u6784<\/strong><\/p>\n

4. \u6846\u67b6\u53cd\u5e94\u53ca\u5176\u6027\u8d28<\/strong><\/p>\n

\u6750\u6599\u7684\u8bbe\u8ba1\u8981\u4f7f\u5f97\u7279\u5b9a\u7684\u6027\u8d28\u548c\u529f\u80fd\u51fa\u73b0\u5728COF\u7684\u652f\u67f1\u4e2d\u3002COFs\u7684\u529f\u80fd\u5316\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u65b9\u6cd5\u6765\u5b9e\u73b0\uff1a\u5c06\u5206\u5b50\u7ec4\u6210\u6a21\u5757\u8fdb\u884c\u529f\u80fd\u5316\u7684\u9884\u5148\u5408\u6210\u6216\u5c06\u9884\u5148\u5f62\u6210\u7684\u6846\u67b6\u8fdb\u884c\u540e\u5408\u6210\u7684\u4fee\u9970\u3002\u9009\u62e9\u8fd9\u4e24\u4e2a\u65b9\u6cd5\u7684\u539f\u5219\u5c31\u662f\u8fd9\u4e9b\u529f\u80fd\u5316\u96c6\u56e2\u80fd\u5426\u4e0eCOF\u5f62\u6210\u53cd\u5e94\u5171\u5b58\u3002\u5e76\u4e0d\u662f\u6240\u6709\u7684\u5316\u5b66\u529f\u80fd\u5316\u90fd\u80fd\u7528\u4e8eCOF\u7684\u5f62\u6210\uff0c\u4f8b\u5982\u5171\u4ef7\u952e\u4e5f\u8bb8\u592a\u8fc7\u5f3a\u70c8\u4ee5\u81f3\u4e8e\u6ca1\u6709\u8db3\u591f\u7684\u53ef\u9006\u6027\uff0c\u56e0\u6b64\uff0c\u4e00\u4e9b\u5316\u5b66\u529f\u80fd\u5316\u7684\u90e8\u5206\u5fc5\u987b\u52a0\u5165\u73b0\u6709\u7684\u6846\u67b6\u4e2d\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u6709\u673a\u4e3b\u5e72\u4e2d\u5f00\u653e\u5e76\u4e14\u53ef\u8fdb\u5165\u7684\u5b54\u4f7f\u5f97\u7ed3\u6784\u5185\u90e8\u7a7a\u95f4\u4e2d\u7684\u7cbe\u786e\u529f\u80fd\u5316\u6210\u4e3a\u53ef\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 <\/strong>\u5c06\u529f\u80fd\u5316\u7cbe\u786e\u5f15\u5165<\/strong>COF<\/strong>\u4e3b\u5e72<\/strong><\/p>\n

5. \u6846\u67b6\u4e2d\u5171\u4ef7\u952e\u548c\u673a\u68b0\u529b\u7684\u7ed3\u5408<\/strong><\/p>\n

\u6838\u9178\u6216\u86cb\u767d\u8d28\u8fd9\u4e9b\u751f\u7269\u5927\u5206\u5b50\u7684\u4e00\u4e2a\u6709\u8da3\u7684\u7279\u6027\u5c31\u662f\u5b83\u4eec\u6709\u4e00\u4e2a\u7531\u5f3a\u70c8\u5171\u4ef7\u952e\u5f62\u6210\u7684\u4e3b\u8981\u7ed3\u6784\uff0c\u7136\u800c\u5176\u4e2d\u51b3\u5b9a\u7cfb\u7edf\u7a7a\u95f4\u53d6\u5411\u7684\u4e8c\u7ea7\u548c\u4e09\u7ea7\u7ed3\u6784\u5374\u662f\u7531\u6c22\u952e\u8fd9\u79cd\u8f83\u5f31\u7684\u975e\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u3002\u632f\u5e45\u8f83\u5927\u7684\u7ed3\u6784\u8fd0\u52a8\u4f1a\u91cd\u590d\u53ef\u9006\u51fa\u73b0\uff0c\u4f46\u662f\u4e0d\u4f1a\u635f\u5931\u5176\u7ed3\u6784\u5b8c\u6574\u6027\u3002\u8fd9\u5c31\u4e3a\u56fa\u6001\u6750\u6599\uff0c\u5c24\u5176\u662f\u6846\u67b6\u5316\u5b66\u4e2d\u8981\u8fbe\u5230\u7684\u52a8\u6001\u6062\u590d\u63d0\u4f9b\u4e86\u6781\u597d\u7684\u8303\u4f8b\uff0c\u56e0\u4e3a\u5728\u6750\u6599\u7684\u5b9e\u9645\u5e94\u7528\u4e2d\u4f1a\u7ecf\u5e38\u9047\u5230\u5e94\u529b\u548c\u5e94\u53d8\u7684\u5faa\u73af\uff0c\u8fd9\u4f1a\u5bfc\u81f4\u6750\u6599\u7684\u75b2\u52b3\u548c\u635f\u4f24\u3002\u7136\u800c\uff0c\u622a\u81f3\u76ee\u524d\uff0c\u5bf9\u4e8e\u8fd9\u4e2a\u95ee\u9898\u7684\u89e3\u51b3\u8fd8\u6ca1\u6709\u63d0\u51fa\u4e00\u4e2a\u53ef\u884c\u7684\u89e3\u51b3\u65b9\u6848\u3002\u8d85\u5206\u5b50\u7ec4\u88c5\u4f53\u7531\u4e8e\u5176\u7ec4\u6210\u5355\u5143\u95f4\u5927\u5e45\u5ea6\u7684\u8fd0\u52a8\u4f1a\u7ecf\u5386\u7ed3\u6784\u52a3\u5316\u7684\u8fc7\u7a0b\u3002\u5728\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u6846\u67b6\u4e2d\uff0c\u5927\u5e45\u5ea6\u7684\u8fd0\u52a8\u4f1a\u7834\u574f\u952e\u7684\u8fde\u63a5\uff0c\u8fd9\u5c31\u4f1a\u4ea7\u751f\u7ed3\u6784\u7684\u7f3a\u9677\u8fdb\u800c\u53d1\u751f\u7ed3\u6784\u7684\u5d29\u584c\u3002\u5176\u4e2d\u4e00\u4e2a\u53ef\u7528\u4e8e\u5206\u5b50\u5c42\u9762\u7684\u8fd0\u52a8\u7684\u7b56\u7565\u5c31\u662f\u673a\u68b0\u8054\u9501\uff0c\u4e5f\u5c31\u662f\u4e24\u5206\u5b50\u4ee5\u673a\u68b0\u65b9\u5f0f\u7ea0\u7f20\uff0c\u5728\u6ca1\u6709\u81f3\u5c11\u4e00\u4e2a\u5171\u4ef7\u952e\u65ad\u88c2\u7684\u60c5\u51b5\u4e0b\u4e92\u76f8\u5206\u79bb\u3002\u5bf9\u4e8e\u5171\u4ef7\u952e\u548c\u673a\u68b0\u8fde\u63a5\u7684\u7ed3\u5408\u529b\u7684\u9886\u4f1a\u6709\u52a9\u4e8e\u5bf9\u673a\u68b0\u8fde\u63a5\u53d8\u5316\u8fc7\u7a0b\u7684\u8003\u8651\u3002<\/p>\n

6. \u4e0d\u540c\u7ef4\u6570\u6846\u67b6\u7ed3\u6784\u7684\u7ea0\u7f20<\/strong><\/p>\n

\u73b0\u4eca\uff0c\u4f1a\u6709\u56db\u79cd\u4e0d\u540c\u7684\u7ea0\u7f20\u6a21\u5f0f\u5b58\u5728\uff0c\u5373\u4e09\u7ef4\u4e92\u76f8\u7a7f\u63d2\u3001\u4e8c\u7ef4\u4e92\u76f8\u7a7f\u63d2\u3001\u4e00\u7ef4\u7f16\u7ec7\u548c\u96f6\u7ef4\u8fde\u9501\u3002\u5176\u4e2d\uff0c\u4e09\u7ef4\u6216\u4e8c\u7ef4\u7ed3\u6784\u95f4\u7684\u7ea0\u7f20\u79f0\u4e3a\u4e92\u76f8\u7a7f\u63d2\uff0c\u53c8\u79f0\u4e3a\u591a\u8fde\u9501\u3002\u6587\u4e2d\u5b9a\u4e49\u4e00\u7ef4\u94fe\u7684\u673a\u68b0\u8fde\u63a5\u4e3a\u7f16\u7ec7\uff0c\u96f6\u7ef4\u73af\u7684\u673a\u68b0\u7ea0\u7f20\u4e3a\u8fde\u9501\u3002\u73b0\u5728\u53ea\u6709\u4e09\u7ef4\u7684\u4e92\u76f8\u7a7f\u63d2\u548c\u4e00\u7ef4\u7684\u7f16\u7ec7\u7ed3\u6784\u5728COF\u5316\u5b66\u9886\u57df\u89c1\u8bf8\u62a5\u9053\u3002\u5728\u56fa\u6001\u4e2d\u63a7\u5236\u673a\u68b0\u7ea0\u7f20\u4e0d\u4ec5\u662f\u57fa\u672c\u7684\u5174\u8da3\uff0c\u4e5f\u5bfc\u81f4\u4e86\u5177\u5907\u91cd\u8981\u5408\u6210\u76ee\u6807\u7684\u67d4\u6027\u3001\u52a8\u6001\u6750\u6599\u7684\u4ea7\u751f\u3002\u6587\u4e2d\u9884\u671f\u6750\u6599\u7684\u7ea0\u7f20\u52a8\u529b\u5b66\u4e0e\u7ec4\u6210\u90e8\u5206\u7684\u7ef4\u6570\u76f4\u63a5\u76f8\u5173\u3002<\/p>\n

\u5728\u4e8c\u7ef4\u548c\u4e09\u7ef4\u7684\u4e92\u76f8\u7a7f\u63d2\u7ed3\u6784\u4e2d\uff0c\u7531\u4e8e\u6574\u4e2a\u5ef6\u5c55\u4e8c\u7ef4\u548c\u4e09\u7ef4\u6846\u67b6\u7684\u79fb\u4f4d\uff0c\u56e0\u6b64\u6bcf\u4e00\u90e8\u5206\u7684\u8fd0\u52a8\u6f5c\u529b\u88ab\u9650\u5236\u3002\u800c\u7f16\u7ec7\u6216\u8fde\u9501\u7684\u5ef6\u5c55\u7ed3\u6784\u957f\u5ea6\u5f88\u957f\uff0c\u56e0\u6b64\u4f1a\u5141\u8bb8\u5176\u4e2d\u6bcf\u4e00\u90e8\u5206\u5177\u6709\u66f4\u591a\u7684\u81ea\u7531\u5ea6\uff0c\u4f1a\u5b58\u5728\u5927\u91cf\u7684\u7a7a\u95f4\u504f\u5dee\uff0c\u4f46\u662f\u5374\u4e0d\u4f1a\u5bf9\u5176\u6574\u4e2a\u7ed3\u6784\u4ea7\u751f\u5f71\u54cd\u3002\u9664\u4e86\u4e09\u7ef4\u7684\u4e92\u76f8\u7a7f\u63d2\u7ed3\u6784\u7684\u5b58\u5728\u5916\uff0c\u53e6\u5916\u4e09\u79cd\u7ef4\u6570\u7a7f\u63d2\u7ed3\u6784\u5b58\u5728\u7684\u53ef\u80fd\u6027\u5c31\u4e0d\u5927\u4e86\u3002\u5728\u4e8c\u7ef4\u7247\u7ec4\u6210\u7684COFs\u4e2d\uff0c\u8fd9\u4e9b\u7247\u4f1a\u8d8b\u5411\u4e8e\u5171\u9762\u4f7f\u8303\u5fb7\u534e\u529b\u6700\u5927\u5316\u3002\u4e0e\u6b64\u76f8\u540c\uff0c\u4e00\u7ef4\u94fe\u66f4\u5bb9\u6613\u5e73\u884c\u6392\u5217\uff0c\u540c\u65f6\uff0c\u96f6\u7ef4\u73af\u4e2d\u6ca1\u6709\u70ed\u529b\u5b66\u7684\u9a71\u52a8\u529b\u4f7f\u5176\u5f62\u6210\u8fde\u9501\u7ed3\u6784\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6 <\/strong>\u6846\u67b6\u4e2d\u7684\u56db\u79cd\u7ea0\u7f20\u5f62\u5f0f<\/strong><\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

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\u7b2c\u4e00\uff0c\u6846\u67b6\u5316\u5b66\u4e3a\u7ed3\u6784\u4e2d\u57fa\u672c\u539f\u5b50\u7684\u6392\u5217\u7ed9\u51fa\u4e86\u7cbe\u786e\u5b9a\u4e49\u3002\u5728\u6846\u67b6\u4e2d\uff0c\u754c\u9762\u5c31\u662f\u6846\u67b6\u4e0e\u886c\u5e95\u76f8\u4e92\u4f5c\u7528\u7684\u754c\u9650\uff0c\u4e0d\u540c\u4e8e\u5176\u4ed6\u754c\u9762\uff0c\u8fd9\u4e00\u754c\u9762\u662f\u88ab\u7cbe\u786e\u786e\u5b9a\u7684\uff0c\u5e76\u4e14\u5c06\u5176\u6539\u53d8\u65f6\uff0c\u4e0d\u4f1a\u7834\u574f\u7ed3\u6784\u4e3b\u5e72\u7684\u5b8c\u6574\u6027\u3002\u8fd9\u5c31\u4e3a\u6539\u53d8\u886c\u5e95\u5206\u5b50\u548c\u6846\u67b6\u95f4\u7684\u754c\u9762\u8fdb\u800c\u5f71\u54cd\u5176\u7279\u5b9a\u53cd\u5e94\u8fc7\u7a0b\u63d0\u4f9b\u4e86\u7075\u6d3b\u6027\u3002<\/p>\n

\u7b2c\u4e8c\uff0c\u6846\u67b6\u5728\u672c\u8d28\u4e0a\u4f1a\u7ed9\u4e88\u5185\u8868\u9762\u51e0\u4f55\u987a\u5e8f\u7684\u590d\u6742\u6027\u3002\u8fd9\u5c31\u8981\u6c42\u4e0d\u4ec5\u8981\u63a7\u5236\u7ed3\u5408\u4f4d\u7f6e\u7684\u7ec4\u6210\uff0c\u8fd8\u8981\u5728\u660e\u786e\u5b9a\u4e49\u3001\u6709\u5e8f\u7684\u51e0\u4f55\u7ed3\u6784\u4e2d\u7cbe\u786e\u5ea6\u91cf\u6846\u67b6\u7684\u5185\u8868\u9762\u7ed3\u5408\u4f4d\u7f6e\u3002<\/p>\n

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\u672c\u6587\u5bf9\u4e8e\u539f\u5b50\u3001\u5206\u5b50\u4ee5\u53ca\u7531\u6709\u673a\u5206\u5b50\u7ec4\u6210\u7684\u5171\u4ef7\u952e\u6846\u67b6\u7ed3\u6784\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u9610\u8ff0\uff0c\u4ece\u65f6\u95f4\u7ef4\u5ea6\u5bf9\u5171\u4ef7\u952e\u6982\u5ff5\u4ee5\u53ca\u5171\u4ef7\u952e\u6846\u67b6\u7ed3\u6784\u7684\u53d1\u5c55\u8fdb\u884c\u4e86\u68b3\u7406\uff0c\u5e76\u5bf9\u5171\u4ef7\u952e\u6846\u67b6\u7ed3\u6784\u7684\u57fa\u672c\u6982\u5ff5\u548c\u6027\u8d28\u7b49\u65b9\u9762\u8fdb\u884c\u4e86\u603b\u7ed3\u3002\u5171\u4ef7\u952e\u6846\u67b6\u7ed3\u6784\u4f5c\u4e3a\u4e00\u79cd\u6781\u5177\u5e94\u7528\u6f5c\u529b\u548c\u7814\u7a76\u4ef7\u503c\u7684\u9886\u57df\u4e3a\u7814\u7a76\u8005\u4eec\u6307\u660e\u4e86\u65b9\u5411\uff0c\u4f46\u662f\u5176\u53d1\u5c55\u548c\u5b8c\u5584\u4e5f\u9700\u8981\u7406\u8bba\u4ee5\u53ca\u5b9e\u9a8c\u7684\u901a\u529b\u5408\u4f5c\u624d\u80fd\u66f4\u597d\u5730\u5b8c\u6210\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>The atom, the molecule, and the covalent organic framework<\/a>\uff08Science, 2017, DOI: 10.1126\/science.aal1585\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7535\u5b50\u7535\u5de5\u5b66\u672f\u7ec4\u5927\u57ce\u5c0f\u7231\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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