{"id":68673,"date":"2017-03-05T06:30:30","date_gmt":"2017-03-04T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=68673"},"modified":"2017-03-01T21:55:22","modified_gmt":"2017-03-01T13:55:22","slug":"%e6%9c%b1%e4%bf%8a%e6%9d%b0chem-soc-rev-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e5%9f%ba%e4%ba%8e%e7%ba%b3%e7%b1%b3%e7%bb%93%e6%9e%84%e6%9d%90%e6%96%99%e7%94%9f%e7%89%a9%e7%87%83%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=68673","title":{"rendered":"\u6731\u4fca\u6770Chem. Soc. Rev. 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material-based biofuel cells: recent advances and future prospects<\/strong>\u201d\u4e3a\u9898\u5728<strong>Chemical Society 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68722\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/2-6.gif\" alt=\"\" width=\"600\" height=\"410\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2 \u9176\u4fc3\u7535\u6781\u8868\u9762\u7684\u751f\u7269\u7535\u50ac\u5316\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\uff08a\uff09\u8c03\u8282\u7535\u5b50\u8f6c\u79fb\uff1b\uff08b\uff09\u76f4\u63a5\u7535\u5b50\u8f6c\u79fb<\/strong><\/p>\n<p>\u8461\u8404\u7cd6\u5927\u91cf\u5b58\u5728\u4e8e\u751f\u7269\u4f53\u4e2d\uff0c\u6240\u4ee5\u5bf9\u4e8eEBFC\u7684\u7814\u7a76\u4e3b\u8981\u805a\u7126\u4e8e\u4ee5\u8461\u8404\u7cd6\u4e3a\u71c3\u6599\u7684\u60c5\u51b5\u3002\u5728\u6c27\u5316\u8461\u8404\u7cd6\u7684\u53cd\u5e94\u4e2d\uff0c\u6c27\u5316\u8fd8\u539f\u8f85\u56e0\u5b50\u9ec4\u7d20\u817a\u560c\u5464\u4e8c\u6838\u82f7\u9178\u57cb\u85cf\u5728\u86cb\u767d\u8d28\u5185\u90e8\uff0c\u5f88\u96be\u5728\u7535\u6781\u4e0a\u53d1\u751fDET\u53cd\u5e94\u8fc7\u7a0b\uff0c\u56e0\u6b64\u4e3a\u4e86\u63d0\u9ad8\u7535\u5b50\u4f20\u9012\uff0c\u4e00\u4e9b\u5bb9\u6613\u6269\u6563\u5728\u9176\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7684\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u5206\u5b50\u88ab\u7814\u7a76\u51fa\u6765\u7528\u4e8e\u63d0\u9ad8\u9176\u50ac\u5316\u5242\u548c\u7535\u6781\u8868\u9762\u7684\u7535\u5b50\u7535\u5bfc\u6027\u3002\u4f46\u662f\u8fd9\u79cd\u65b9\u6cd5\u4ef7\u683c\u9ad8\u3001\u6709\u6bd2\u4e14\u4e0d\u7a33\u5b9a\u3002\u4e5f\u6709\u5176\u4ed6\u7684\u4e00\u4e9b\u65b9\u6cd5\u6765\u63d0\u9ad8\u9176\u4e0e\u7535\u6781\u7684\u7535\u5bfc\u6027\u3002\u8fdb\u4e00\u6b65\uff0c\u7528\u529f\u80fd\u6750\u6599\u5c24\u5176\u662f\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u8fdb\u884c\u5316\u5b66\u4fee\u9970\u7684\u7535\u6781\u5c55\u73b0\u51fa\u5f88\u597d\u7684\u7535\u5b50\u8c03\u8282\u4f5c\u7528\uff0c\u6709\u5229\u4e8eDET\u53cd\u5e94\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u8005\u81f4\u529b\u4e8e\u5f00\u53d1\u9ad8\u6027\u80fd\u751f\u7269\u9633\u6781\uff0c\u5e76\u53d6\u5f97\u4e86\u4e00\u5b9a\u7684\u7814\u7a76\u6210\u679c\u3002<\/p>\n<p>\u751f\u7269\u9634\u6781\u4e3b\u8981\u4f7f\u7528\u6f06\u9176\u6216\u8005\u80c6\u7ea2\u7d20\u6c27\u5316\u9176\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\uff0c\u4e3b\u8981\u5229\u7528\u4e86\u8fd9\u4e24\u79cd\u9176\u4e0eCu\u7ed3\u5408\u6240\u5177\u6709\u7684\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u4f5c\u4e3a\u591a\u94dc\u6c27\u5316\u9176\uff0c\u6f06\u9176\u662f\u6700\u6709\u6548\u4e14\u6700\u5e38\u89c1\u7684\u9634\u6781\u50ac\u5316\u9176\uff0c\u56e0\u4e3a\u6f06\u9176\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b\u4e3a0.78V vs. SHE, 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\u3002<\/p>\n<p><strong>2.2 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68723\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/3-2.gif\" alt=\"\" width=\"600\" height=\"390\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3 \u5fae\u751f\u7269\u71c3\u6599\u7535\u6c60\u5de5\u4f5c\u539f\u7406\u56fe<\/strong><\/p>\n<p><strong>2.2.2 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MR-1\uff0c\u88ab\u5e7f\u6cdb\u7528\u4e8e\u65e0\u4ecb\u8d28MFC\u4e2d\u3002\u603b\u6240\u5468\u77e5\uff0cc-\u7ec6\u80de\u8272\u7d20\u542b\u6709\u4e9a\u94c1\u8840\u7ea2\u7d20\u57fa\u56e2\uff0c\u8fd9\u662f\u4e00\u79cd\u9ad8\u5ea6\u5171\u8f6d\u4e14\u5305\u56f4\u4e00\u4e2a\u94c1\u539f\u5b50\u7684\u7ed3\u6784\uff0c\u5176\u4e2d\u91d1\u5c5e\u4e2d\u5fc3\u5177\u6709\u50ac\u5316\u6d3b\u6027\uff0c\u5728DET\u7535\u5b50\u4f20\u9012\u8fc7\u7a0b\u4e2d\u626e\u6f14\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n<p>\u8fd1\u671f\uff0c\u7814\u7a76\u53d1\u73b0\u6709\u4e9b\u83cc\u7fa4\u5982\u5730\u6746\u83cc\u6216\u5e0c\u74e6\u5f0f\u83cc\u5177\u6709\u5f88\u9ad8\u7684\u7535\u5bfc\u7387\uff0c\u80fd\u591f\u5728\u7535\u5b50\u4f20\u9012\u8fc7\u7a0b\u4e2d\u8d77\u5230\u751f\u7269\u7eb3\u7c73\u7ebf\u7684\u4f5c\u7528\uff0c\u65e0\u9700\u7ec6\u80de\u4e0e\u7535\u6781\u76f4\u63a5\u63a5\u89e6\u3002\u4e4b\u540e\u53c8\u6709\u7814\u7a76\u8005\u901a\u8fc7CV\u7535\u5316\u5b66\u65b9\u6cd5\u8bc1\u660e\u4e86\u5177\u6709\u7535\u5b50\u8f6c\u79fb\u6027\u8d28\u7684\u5bfc\u7535\u7f51\u7edc\u7ed3\u6784\u3002\u6709\u8da3\u7684\u662f\uff0c\u8fd9\u4e9b\u83cc\u7fa4\u7ecf\u5e38\u4ea4\u4e92\u7f20\u7ed5\uff0c\u8fde\u63a5\u7ec6\u80de\u8272\u7d20\uff0c\u6709\u5229\u4e8e\u63d0\u9ad8\u7ec6\u80de\u4e0e\u7ec6\u80de\u4e4b\u95f4\u7535\u5b50\u4f20\u9012\u7684\u53ef\u80fd\u3002\u56e0\u6b64\uff0c\u8fd9\u4e9b\u7eb3\u7c73\u7ebf\u7684\u5f62\u6210\u5bf9\u5f00\u53d1\u539a\u7535\u50ac\u5316\u819c\u548c\u9ad8\u6027\u80fd\u9633\u6781\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68724\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/4-2.gif\" alt=\"\" width=\"600\" height=\"242\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4 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\u78b3\u57fa\u7eb3\u7c73\u6750\u6599<\/strong><\/p>\n<p>\u78b3\u57fa\u7eb3\u7c73\u6750\u6599\u56e0\u4e3a\u5177\u6709\u9ad8\u7535\u5b50\u7535\u5bfc\u6027\u4ee5\u53ca\u751f\u7269\u517c\u5bb9\u6027\uff0c\u6240\u4ee5\u5728BFC\u4e2d\u5907\u53d7\u5173\u6ce8\uff0c\u540c\u65f6\u78b3\u6750\u6599\u7684\u673a\u68b0\u6027\u80fd\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u6709\u5229\u4e8eBFC\u4e2d\u7684\u957f\u5468\u671f\u4f7f\u7528\u3002\u901a\u8fc7\u4e0d\u540c\u7684\u7eb3\u7c73\u6280\u672f\u65b9\u6cd5\u53ef\u4ee5\u5408\u6210\u4e0d\u540c\u5f62\u8c8c\u7684\u78b3\u6750\u6599\uff0c\u5982\u78b3\u7eb3\u7c73\u7ba1\u3001\u7eb3\u7c73\u9897\u7c92\u3001\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u3001\u78b3\u7eb3\u7c73\u7247\u7b49\uff0c\u4e0d\u540c\u5f62\u8c8c\u7684\u78b3\u6750\u6599\u90fd\u4f1a\u5c55\u73b0\u51fa\u4e0d\u540c\u7684\u7535\u5b50\u4f20\u9012\u6027\u80fd\u548c\u56fa\u5b9a\u751f\u7269\u7535\u50ac\u5316\u5242\u7684\u6027\u8d28\u3002\u4e3a\u4e86\u63a2\u7a76\u4e0d\u540c\u78b3\u6750\u6599\u5728BFC\u7535\u5b50\u4f20\u9012\u65b9\u9762\u7684\u529f\u80fd\uff0c\u6211\u4eec\u5217\u4e3e\u4e86\u4e09\u79cd\u5177\u6709\u4e0d\u540c\u7ef4\u5ea6\u7684\u78b3\u6750\u6599\u53ca\u5176\u884d\u751f\u7269\u3002<\/p>\n<p><strong>3.1.1 \u78b3\u7eb3\u7c73\u7ba1\uff08CNT\uff09<\/strong><\/p>\n<p>CNT \u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u9ad8\u673a\u68b0\u5f3a\u5ea6\u4ee5\u53ca\u826f\u597d\u5bfc\u7535\u6027\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u751f\u7269\u7535\u50ac\u5316\u9886\u57df\uff0c\u662f\u6700\u6709\u524d\u666f\u7684\u7535\u6781\u6750\u6599\u3002CNT\u4f5c\u4e3a\u751f\u7269\u50ac\u5316\u5242\u7684\u8f7d\u4f53\u7528\u4e8eBFC\uff0c\u5c55\u73b0\u51fa\u826f\u597d\u7684\u7535\u5b50\u4f20\u9012\u6027\u80fd\u3002<\/p>\n<p><strong>a CNT\u5728\u9176\u4fc3\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p>CNTs\u5728EBFC\u7535\u6781\u6750\u6599\u65b9\u9762\u5177\u6709\u5f88\u5927\u7684\u4f18\u52bf\uff0c\u4e0d\u4ec5\u56e0\u4e3a\u5b83\u5177\u6709\u9ad8\u7684\u5bfc\u7535\u6027\u548c\u6bd4\u8868\u9762\u79ef\uff0c\u540c\u65f6\u8fd8\u80fd\u8fde\u63a5\u9176\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u548c\u7535\u6781\u8868\u9762\uff0c\u56e0\u6b64CNTs\u88ab\u5e7f\u6cdb\u7528\u4e8e\u4fee\u9970EBFC\u4e2d\u7684\u5e95\u7269\u7535\u6781\u3002\u6bd4\u5982\uff0cMao\u7b49\u4eba\u5236\u5907\u4e86\u5177\u6709CNT\u57fa\u751f\u7269\u7535\u6781\u7684\u8461\u8404\u7cd6\/\u6c27\u6c14EBFC\u7535\u6c60\uff0cCNT\u4f5c\u4e3a\u8f7d\u4f53\u5728\u9634\u6781ORR\u8fc7\u7a0b\u4e2d\u6709\u5229\u4e8eDET\u8fc7\u7a0b\uff0c\u4f46\u662f\u6700\u540e\u7535\u6c60\u7684\u529f\u7387\u5f88\u5c0f\u3002\u6f06\u9176\u88ab\u7b80\u5355\u7684\u6d82\u8986\u4e8eCNT\u8868\u9762\uff0c\u8fd9\u589e\u5927\u4e86\u9176\u50ac\u5316\u5242\u4e0eCNT\u4e4b\u95f4\u7684\u8ddd\u79bb\uff0c\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u524a\u5f31\u4e86\u7535\u5b50\u4f20\u9012\u8fc7\u7a0b\u3002\u5728\u4e4b\u540e\u7684\u7814\u7a76\u4e2d\uff0c\u4eba\u4eec\u901a\u8fc7\u63a7\u5236CNT\u4e0e\u9176\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u8ddd\u79bb\u6765\u63d0\u9ad8EBFC\u4f53\u7cfb\u4e2d\u7535\u5b50\u7684\u4f20\u9012\u901f\u7387\u3002\u4e3a\u4e86\u5b9e\u73b0\u8fd9\u4e00\u76ee\u7684\uff0c\u4f7f\u5f97\u9176\u50ac\u5316\u5242\u5177\u6709\u5f88\u597d\u5bfc\u5411\u6027\u662f\u4e00\u4e2a\u4e0d\u9519\u7684\u7b56\u7565\u3002\u8003\u8651\u5230DNA\u548cBOD\u9176\u7684\u517c\u5bb9\u6027\uff0cSalimi\u7b49\u4eba\u5c06DNA\u4e0e\u9176\u590d\u5408\u5236\u5907\u51fa\u8461\u8404\u7cd6\/O<sub>2<\/sub>\u751f\u7269\u7535\u6c60\u3002\u5982\u56fe5\u6240\u793a\uff0c\u5728\u8be5\u4f53\u7cfb\u4e2d\uff0cDNA\u4f7f\u5f97CNT\u57fa\u7535\u6781\u5e26\u8d1f\u7535\u8377\u4ece\u800c\u63a7\u5236\u4e86BOD\u9176\u7684\u65b9\u5411\uff0c\u4ece\u800c\u4f7f\u5f97\u7535\u6781\u5c55\u73b0\u51fa\u5f88\u597d\u7684\u7535\u50ac\u5316ORR\u6d3b\u6027\uff0c\u8d77\u59cb\u7535\u4f4d0.57V\uff0c\u7535\u6d41\u5bc6\u5ea6277 \u03bcAcm<sup>-2<\/sup> 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68725\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/5-2.gif\" alt=\"\" width=\"600\" height=\"552\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5 \u78b3\u7eb3\u7c73\u7ba1\/DNA\u590d\u5408\u6750\u6599\u5728EBFC\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68726\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/6-3.gif\" alt=\"\" width=\"600\" height=\"602\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6 CNT\/GO\u590d\u5408\u6750\u6599\u4ee5\u53ca\u6db2\u76f8\u6536\u7f29CNT\u4fee\u9970\u7535\u6781\u5728EBFC\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p><strong>b CNT\u7528\u4e8e\u5fae\u751f\u7269\u71c3\u6599\u7535\u6c60<\/strong><\/p>\n<p>\u901a\u5e38\u4ea7\u7535\u83cc\u682a\u5728\u9633\u6781\u7528\u4e8eMFC\u7535\u6d41\u7684\u4ea7\u751f\uff0c\u56e0\u6b64\u9633\u6781\u63a5\u53d7\u7535\u5b50\u7684\u80fd\u529b\u76f4\u63a5\u5f71\u54cd\u7535\u5b50\u7684\u4f20\u9012\u901f\u7387\u548cMFC\u7684\u7535\u6c60\u6027\u80fd\u3002CNTs\u4f5c\u4e3a\u5bfc\u7535\u6750\u6599\uff0c\u80fd\u591f\u52a0\u5f3a\u83cc\u682a\u4e0e\u7535\u6781\u7684\u63a5\u89e6\uff0c\u4f5c\u4e3a\u9633\u6781\u6539\u6027\u6750\u6599\u80fd\u591f\u63d0\u9ad8\u5bfc\u7535\u6027\u548c\u7535\u6c60\u6027\u80fd\u3002\u7814\u7a76\u4e2d\uff0c\u4ea7\u7535\u83cc\u682a\u5728\u9633\u6781\u6ce8\u5165\u5f62\u6210\u751f\u7269\u819c\uff0c\u5e76\u8986\u76d6CNTs\u3002\u4f46\u662f\uff0c\u7ec6\u83cc\u548cCNTs\u4e4b\u95f4\u6709\u4e00\u5b9a\u8ddd\u79bb\u4e14\u751f\u7269\u819c\u5bfc\u7535\u6027\u8f83\u5dee\uff0c\u4ea7\u751f\u7684\u7535\u5b50\u5f88\u96be\u4ee5DET\u65b9\u5f0f\u4f20\u9012\uff0c\u56e0\u6b64\u9700\u8981\u5236\u5907\u5bfc\u7535\u751f\u7269\u819c\u3002Liang\u7b49\u4eba\u5229\u7528CNTs\u7684\u9ad8\u5bfc\u7535\u6027\u548c\u6bd4\u8868\u9762\u79ef\uff0c\u5c06CNTs\u4e0e\u786b\u8fd8\u539f\u5730\u6746\u83cc\u6df7\u5408\u5728MFC\u9633\u6781\u5f62\u6210\u590d\u5408\u751f\u7269\u819c\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u751f\u7269\u819c\u7684\u7535\u5316\u5b66\u6d3b\u6027\u548c\u4ea7\u7535\u6027\u80fd\u3002\u8fdb\u4e00\u6b65\uff0c\u901a\u8fc7N\u63ba\u6742\u80fd\u591f\u63d0\u9ad8\u7535\u5b50\u4f20\u9012\u901f\u7387\u3002\u6bd4\u5982He\u7b49\u4eba\u5236\u5907\u4e86\u7af9\u8282\u5f62\u8c8c\u7684NCNT\u6539\u6027\u9633\u6781\u6750\u6599\uff0c\u63d0\u9ad8\u4e86MFC\u7684\u7535\u6d41\u5bc6\u5ea6\u548c\u8f93\u51fa\u529f\u7387\uff0c\u5982\u56fe7a\u6240\u793a\u3002\u9664\u4e86\u9ad8\u7535\u5bfc\u6027\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u589e\u52a0\u9633\u6781\u8868\u9762\u79ef\u4e5f\u6709\u5229\u4e8e\u63d0\u9ad8MFC\u6027\u80fd\u3002Xie\u7b49\u4eba\u5236\u5907\u4e86CNTs-\u7ec7\u7269\u590d\u5408\u591a\u7ea7\u5b54\u7ed3\u6784\u7684\u9633\u6781\uff0c\u5fae\u5b54-\u5927\u5b54\u7ed3\u6784\u3002\u5fae\u5b54CNT\u5c42\u6d82\u8986\u5728\u5927\u5b54\u7ec7\u7269\u4e0a\uff0c\u5927\u5b54\u7ed3\u6784\u6709\u5229\u4e8e\u5f62\u6210\u5f00\u653e\u7684\u4e09\u7ef4\u7a7a\u95f4\uff0c\u5229\u4e8e\u517b\u5206\u7684\u4f9b\u7ed9\uff0c\u526f\u4ea7\u7269\u7684\u79fb\u9664\u4ee5\u53ca\u5185\u90e8\u56fa\u5b9a\u3002\u5fae\u5b54\u7ed3\u6784\u6709\u5229\u4e8e\u7535\u5b50\u4ece\u5fae\u751f\u7269\u819c\u4f20\u9012\u81f3CNTs-\u7ec7\u7269\u9633\u6781\uff0c\u5982\u56fe7b\u6240\u793a\u3002\u4e0e\u4f20\u7edf\u78b3\u5e03\u9633\u6781\u4f5c\u5bf9\u6bd4\uff0c\u8be5\u7c7b\u9633\u6781\u7535\u6c60\u80fd\u591f\u83b7\u5f97\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\u548c\u6700\u5927\u529f\u7387\u5bc6\u5ea6\u3002<\/p>\n<p>CNTs\u4e5f\u53ef\u4ee5\u4f5c\u4e3aMFC\u9634\u6781ORR\u50ac\u5316\u5242\uff0c\u5176\u4e2d\u5316\u5b66N\u63ba\u6742\u7684CNTs\u5177\u6709\u975e\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\uff0c\u6709\u5229\u4e8eORR\u50ac\u5316\u53cd\u5e94\u3002Wang\u7b49\u4eba\u5236\u5907\u4e86\u7af9\u8282\u72b6NCNT\u9633\u6781ORR\u50ac\u5316\u5242\uff0c\u5982\u56fe7c\u6240\u793a\u3002\u5176\u7535\u6c60\u529f\u7387\u5bc6\u5ea6\u8fbe\u52301600Mwcm<sup>-2<\/sup>\uff0c\u9ad8\u4e8ePt\/C\u76841393mWcm<sup>-2<\/sup>\u3002\u4e0d\u50cfEBFC\u7535\u6c60\u901a\u5e38\u7528\u9176\u4f5c\u4e3a\u9634\u6781\u50ac\u5316\u5242\uff0cMFC\u901a\u5e38\u91c7\u7528\u5316\u5b66ORR\u50ac\u5316\u5242\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5fae\u751f\u7269\u50ac\u5316ORR\u53cd\u5e94\uff0c\u5728\u78b3\u7eb8\u7535\u6781\u4e0a\u7535\u6c89\u79efCNTs\/\u58f3\u805a\u7cd6\uff0c\u52a0\u5f3a\u4e86\u6d3b\u6027\u4f4d\u70b9\u4e0e\u7ec6\u83cc\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u6709\u5229\u4e8e\u7535\u5b50\u7684\u4f20\u9012\u3002\u5982\u56fe7d\u6240\u793a\uff0c\u8be5\u7c7b\u751f\u7269\u9634\u6781\u76f8\u5bf9\u4e8e\u78b3\u7eb8\u751f\u7269\u9634\u6781\u529f\u7387\u63d0\u9ad8\u4e8630%\u3002\u7531\u4e8e\u8d35\u91d1\u5c5e\u4ef7\u683c\u6602\u8d35\uff0c\u56e0\u6b64\u5f00\u53d1\u5ec9\u4ef7\u7a33\u5b9a\u9ad8\u6548\u7684ORR\u7535\u50ac\u5316\u5242\u662f\u76ee\u524d\u7814\u7a76MFC\u7684\u91cd\u70b9\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68727\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/7-5.gif\" alt=\"\" width=\"600\" height=\"486\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7 \u4e0d\u540cCNTs\u57fa\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u5728MFC\u7535\u6781\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p><strong>3.1.2 \u77f3\u58a8\u70ef<\/strong><\/p>\n<p>\u77f3\u58a8\u70ef\u662f\u4e00\u79cd\u4e8c\u7ef4\u7247\u5c42\u7ed3\u6784\u6750\u6599\uff0c\u5177\u6709\u9ad8\u7535\u5bfc\u6027\u3001\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u5f88\u9ad8\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u5728\u7535\u5316\u5b66\u8bbe\u5907\u5c24\u5176\u662f\u751f\u7269\u71c3\u6599\u7535\u6c60\u4e2d\u662f\u4e00\u79cd\u5f88\u597d\u7684\u7535\u6781\u6750\u6599\u3002\u901a\u5e38\u77f3\u58a8\u70ef\u662f\u901a\u8fc7\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u5236\u5907\u7684\uff0c\u5373rGO\u3002\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u56e0\u6c27\u5316\u57fa\u56e2\u8fd8\u539f\u4e0d\u5f7b\u5e95\uff0c\u5177\u6709\u4eb2\u6c34\u6027\uff0c\u6709\u5229\u4e8e\u751f\u7269\u50ac\u5316\u5242\u7684\u56fa\u5b9a\u3002\u540c\u65f6rGO\u80fd\u591f\u5316\u5b66\u529f\u80fd\u5316\uff0c\u6709\u5229\u4e8e\u52a0\u5f3arGO\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u53e6\u5916\uff0c\u7531\u4e8e\u77f3\u58a8\u70ef\u7279\u6b8a\u7684\u7ed3\u6784\u548c\u7269\u7406\u6027\u8d28\uff0c\u80fd\u591f\u5f62\u6210\u65b0\u578b\u591a\u5b54\u7ed3\u6784\uff0c\u5e76\u63d0\u9ad8\u4f20\u8d28\u6548\u7387\u548c\u6269\u5927\u7535\u50ac\u5316\u6d3b\u6027\u9762\u79ef\u3002\u56e0\u6b64\uff0c\u77f3\u58a8\u70ef\u57fa\u6750\u6599\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u6709\u5229\u4e8e\u63d0\u9ad8\u751f\u7269\u50ac\u5316\u5242\u4e0e\u7535\u6781\u8868\u9762\u7684\u7535\u5b50\u4f20\u9012\u3002<\/p>\n<p><strong>a \u77f3\u58a8\u70ef\u7528\u4e8eEBFC<\/strong><\/p>\n<p>Li\u7b49\u4eba\u9996\u6b21\u62a5\u9053\u4e86\u77f3\u58a8\u70ef\u7247\/\u9176\u590d\u5408\u50ac\u5316\u5242\u5728\u751f\u7269\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u5e94\u7528\uff0c\u8fd9\u63d0\u9ad8\u4e86\u7535\u5b50\u4f20\u9012\u548c\u4ea7\u7535\u80fd\u529b\uff0c\u5177\u6709\u5f88\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u3002\u4ece\u6b64\u4ee5\u540e\uff0c\u5173\u4e8e\u77f3\u58a8\u70ef\u4ee5\u53ca\u884d\u751f\u7269\u5728EBFC\u4e2d\u7684\u7814\u7a76\u8d8a\u6765\u8d8a\u591a\u3002\u4e0e\u77f3\u58a8\u70ef\u76f8\u6bd4\uff0cN\u63ba\u6742\u77f3\u58a8\u70ef\u56e0\u5176\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u6240\u4ee5\u5177\u6709\u5f88\u9ad8\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3002\u5176\u4e2d\uff0c\u5c06N\u63ba\u6742\u77f3\u58a8\u70ef\/\u91d1\u7eb3\u7c73\u9897\u7c92\/\u7532\u9178\u8131\u6c22\u9176\u751f\u7269\u9633\u6781\u7528\u4e8e\u7532\u9178\/O<sub>2<\/sub>EBFC\u7535\u6c60\u540e\uff0c\u589e\u5f3a\u4e86\u7535\u5b50\u4f20\u9012\u901f\u7387\uff0c\u7535\u6c60\u7684\u6700\u5927\u529f\u7387\u5bc6\u5ea6\u548c\u5f00\u8def\u7535\u538b\u5206\u522b\u8fbe\u52301.96mWcm<sup>-2<\/sup>\u548c0.95V\uff0c\u5982\u56fe8a\u3002\u901a\u8fc7N\u63ba\u6742\uff0c\u7535\u5b50\u4f20\u9012\u6548\u7387\u5f97\u5230\u4e86\u5f88\u660e\u663e\u7684\u589e\u5f3a\uff0c\u56e0\u6b64CNT\/g-C<sub>3<\/sub>N<sub>4<\/sub>\/Au\u590d\u5408\u6750\u6599\u88ab\u7528\u4f5cEBFC\u7535\u6781\u6750\u6599\uff08\u56fe8b\uff0cc\uff09\u3002\u56e0\u4e3aC<sub>3<\/sub>N<sub>4<\/sub>\u5177\u6709\u5f88\u9ad8\u7684\u6c2e\u542b\u91cf\uff0c\u540c\u65f6\u4e3b\u8981\u542b\u6709\u5421\u5576\u6c2e\u548c\u77f3\u58a8\u6c2e\u5f62\u5f0f\uff0c\u6709\u5229\u4e8e\u63d0\u9ad8\u7535\u5b50\u8f6c\u79fb\u548c\u7535\u50ac\u5316\u6d3b\u6027\u3002CNTs\u4e09\u7ef4\u7f51\u7edc\u7684\u52a0\u5165\u4e5f\u6709\u5229\u4e8e\u7535\u5b50\u7684\u4f20\u9012\u3002\u8be5\u4e09\u5143\u6742\u5316\u6750\u6599\u6700\u5927\u529f\u7387\u5bc6\u5ea6\u53ef\u8fbe249\u03bcWcm<sup>-2<\/sup>\u3002\u4e09\u7ef4\u77f3\u58a8\u70ef\u7ed3\u6784\u5177\u6709\u5927\u6bd4\u8868\u9762\u79ef\u3001\u76f8\u4e92\u8fde\u901a\u7684\u5bfc\u7535\u7f51\u7edc\u7ed3\u6784\u548c\u5feb\u901f\u7684\u7269\u8d28\u4f20\u8f93\uff0c\u6709\u5229\u4e8e\u7535\u5b50\u7684\u4f20\u9012\uff0c\u56e0\u6b64\u4e09\u7ef4\u77f3\u58a8\u70ef\u7ed3\u6784\u88ab\u5e7f\u6cdb\u7528\u4e8eEBFC\u4f53\u7cfb\u4e2d\u3002\u5982\u56fe8d\uff0ce\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68728\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/8-4.gif\" alt=\"\" width=\"600\" height=\"647\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe8 \u4e0d\u540c\u77f3\u58a8\u70ef\u57fa\u78b3\u6750\u6599\u5728EBFC\u7535\u6781\u4e2d\u7684\u5b9e\u9645\u5e94\u7528<\/strong><\/p>\n<p><strong>b \u77f3\u58a8\u70ef\u5728MFC\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p>\u57fa\u4e8e\u77f3\u58a8\u70ef\u4f18\u5f02\u7684\u5bfc\u7535\u6027\u548c\u5927\u6bd4\u8868\u9762\u79ef\uff0c\u77f3\u58a8\u70ef\u6539\u6027\u7535\u6781\u6709\u5229\u4e8e\u63d0\u9ad8MFC\u6027\u80fd\uff0c\u6709\u5229\u4e8e\u7ec6\u83cc\u56fa\u5b9a\u548c\u7535\u5b50\u6536\u96c6\u3002\u5e26\u6b63\u7535\u8377\u7684\u79bb\u5b50\u6db2\u4f53\u529f\u80fd\u5316\u77f3\u58a8\u70ef\u7247\u5c42\u6750\u6599\u53ef\u4ee5\u7528\u6765\u4fee\u9970MFC\u751f\u7269\u9633\u6781\u3002\u79bb\u5b50\u6db2\u4f53\u5e26\u6b63\u7535\uff0c\u7ec6\u83cc\u5e26\u8d1f\u7535\uff0c\u901a\u8fc7\u9759\u7535\u4f5c\u7528\uff0c\u53ef\u4ee5\u52a0\u5f3a\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u5b50\u4f20\u9012\u3002\u8be5MFC\u80fd\u591f\u83b7\u5f97\u66f4\u9ad8\u7684\u9633\u6781\u7535\u6d41\u3002\u5982\u56fe9a\u6240\u793a\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u589e\u5f3a\u7535\u5b50\u4f20\u9012\u6548\u7387\uff0c\u7ec6\u83cc\u4e0e\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u4e09\u7ef4\u591a\u5b54\u6742\u5316\u6750\u6599\uff0c\u76f8\u4e92\u8fde\u901a\u7684rGO\u7f51\u7edc\u589e\u52a0\u4e86\u5bfc\u7535\u8def\u5f84\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u6742\u5316\u751f\u7269\u819c\u6750\u6599\u5c55\u73b0\u51fa\u6781\u597d\u7684\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u5982\u56fe9b\uff0cc\u3002\u5177\u6709\u4e09\u7ef4\u5927\u5b54\u7ed3\u6784\u7684\u77f3\u58a8\u70ef\u4e5f\u88ab\u7528\u6765\u5236\u5907\u9ad8\u6027\u80fdMFC\u3002\u6b64\u5916\uff0c\u8fdb\u884c\u6c2e\u5143\u7d20\u63ba\u6742\u53ef\u4ee5\u63d0\u9ad8\u77f3\u58a8\u70ef\u7684\u7535\u5bfc\u6027\uff0c\u4f7f\u5176\u5e26\u6b63\u7535\u8377\uff0c\u6709\u5229\u4e8e\u50ac\u5316\u7ec6\u83cc\u4e0e\u77f3\u58a8\u70ef\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u8fdb\u4e00\u6b65\uff0c\u5177\u6709\u9ad8\u542b\u6c2e\u91cf\u7684\u63ba\u6742\u4e09\u7ef4\u5927\u5b54\u77f3\u58a8\u70ef\u53ef\u4ee5\u5927\u5e45\u5ea6\u63d0\u9ad8\u7535\u5b50\u4f20\u9012\u6548\u7387\u548c\u7535\u6c60\u6027\u80fd\uff0c\u5982\u56fe9d\u6240\u793a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68729\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/9-4.gif\" alt=\"\" width=\"600\" height=\"515\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe9 \u77f3\u58a8\u70ef\u6539\u6027\u6750\u6599\u53ca\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u5728MFC\u4e2d\u5e94\u7528<\/strong><\/p>\n<p><strong>3.1.3 \u5176\u4ed6\u78b3\u57fa\u6750\u6599\u5728BFC\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p>\u5176\u4ed6\u78b3\u6750\u6599\u5982\u96f6\u7ef4\u78b3\u7eb3\u7c73\u9897\u7c92CNP\uff0c\u5177\u6709\u9ad8\u7535\u5bfc\u7387\u3001\u597d\u7684\u751f\u7269\u517c\u5bb9\u6027\u4ee5\u53ca\u9ad8\u6bd4\u8868\u9762\u79ef\uff0c\u540c\u65f6\u8fd8\u5177\u6709\u6c27\u5316\u8fd8\u539f\u7279\u5f81\uff0c\u80fd\u591f\u8c03\u8282\u7535\u5b50\u4f20\u9012\u8fc7\u7a0b\uff0c\u56e0\u6b64CNP\u9002\u5408\u7528\u4e8eBFC\u4f53\u7cfb\u4e2d\uff0c\u6bd4\u5982Willner\u7b49\u4eba\u8bbe\u8ba1\u51fa\u4ecb\u5b54\u78b3\u7eb3\u7c73\u9897\u7c92-\u9176\u590d\u5408\u7535\u6781\uff0c\u964d\u4f4e\u4e86\u4ecb\u8d28\u6269\u6563\u8ddd\u79bb\uff0c\u589e\u5f3a\u7535\u6781\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u76f4\u63a5\u7535\u5b50\u4f20\u9012\u8fc7\u7a0b\uff0c\u4f7fEBFC\u5c55\u73b0\u51fa\u8f83\u9ad8\u7684\u8f93\u51fa\u529f\u7387\u3002\u78b3\u7eb3\u7c73\u70b9\u4e5f\u88ab\u7528\u6765\u4f5c\u4e3aEBFC\u7535\u6781\u6750\u6599\uff0c\u52a0\u901f\u7535\u5b50\u4f20\u9012\u8fc7\u7a0b\uff0c\u4f7f\u5f97\u65e0\u4ecb\u8d28\u8461\u8404\u7cd6\/\u6c27\u6c14EBFC\u7684\u5f00\u8def\u7535\u538b\u8fbe\u52300.93V\uff0c\u6700\u5927\u8f93\u51fa\u529f\u7387\u4e3a40.8\u03bcWcm<sup>-2<\/sup>\u3002\u5728MFC\u4f53\u7cfb\u4e2d\uff0c\u7528\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u9897\u7c92\u6216\u7eb3\u7c73\u70b9\u4fee\u9970\u7535\u6781\u53ef\u4ee5\u63d0\u9ad8\u9633\u6781\u5bf9\u9ec4\u7d20\u7684\u5438\u9644\u4ee5\u53ca\u76f8\u5e94\u9633\u6781\u4fa7\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6027\u8d28\uff0c\u8fdb\u800c\u589e\u5f3aDET\u4f20\u9012\u8fc7\u7a0b\uff0c\u63d0\u9ad8\u7535\u6c60\u7684\u8f93\u51fa\u529f\u7387\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5173\u4e8e\u78b3\u7eb3\u7c73\u9897\u7c92\u7528\u4e8eMFC\u7684\u7814\u7a76\u8fd8\u662f\u76f8\u5bf9\u6709\u9650\u7684\uff0c\u56e0\u6b64\u6211\u4eec\u8981\u8fdb\u4e00\u6b65\u5229\u7528\u7eb3\u7c73\u7c92\u5b50\u7279\u522b\u7684\u6027\u8d28\uff0c\u5236\u5907\u51fa\u9ad8\u6027\u80fd\u7684CNP\u57fa\u751f\u7269\u71c3\u6599\u7535\u6c60\u3002<\/p>\n<p><strong>3.2 \u5bfc\u7535\u805a\u5408\u7269<\/strong><\/p>\n<p>\u5bfc\u7535\u805a\u5408\u7269\u56e0\u4e3a\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u4ee5\u53ca\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\u88ab\u89c6\u4e3a\u6700\u6709\u5e0c\u671b\u7684\u751f\u7269\u71c3\u6599\u7535\u6c60\u6d3b\u6027\u66ff\u4ee3\u6750\u6599\u3002\u57fa\u4e8e\u5927\u8868\u9762\u79ef\uff0c\u9ad8\u7535\u5bfc\u7387\u548c\u8f83\u597d\u7684\u7075\u6d3b\u6027\u7b49\u4f18\u70b9\uff0c\u7eb3\u7c73\u7ed3\u6784\u805a\u5408\u7269\u5728BFC\u4e2d\u5907\u53d7\u5173\u6ce8\u3002<\/p>\n<p><strong>3.2.1 \u805a\u5408\u7269\u6750\u6599\u7528\u4e8eEBFC<\/strong><\/p>\n<p>\u5bfc\u7535\u805a\u5408\u5305\u62ec\u805a\u82ef\u80fa\uff08PANI\uff09\u3001\u805a\u5421\u54af\uff08PPy\uff09\u548c\u805a\u4e59\u70ef\u4e9a\u80fa\uff08PEI\uff09\u53ca\u5176\u590d\u5408\u6750\u6599\u9002\u5408\u7528\u4e8eEBFC\u4f53\u7cfb\u4e2d\uff0c\u7528\u4e8e\u589e\u52a0\u8868\u9762\u79ef\u548c\u7535\u5b50\u7535\u5bfc\u6027\uff0c\u4ece\u800c\u589e\u52a0\u9176\u7684\u8d1f\u8f7d\u91cf\u548c\u8010\u4e45\u6027\u3002PANI\u662f\u5e38\u7528\u7684\u5bfc\u7535\u805a\u5408\u7269\uff0c\u4f5c\u4e3a\u9176\u548c\u53cd\u5e94\u5e95\u7269\u4e4b\u95f4\u7684\u7535\u5b50\u6865\u6881\uff0c\u589e\u5f3a\u7535\u5b50\u4f20\u9012\u3002PEI\u5e26\u6709\u6b63\u7535\uff0c\u80fd\u591f\u5438\u5f15\u5e26\u8d1f\u7535\u8377\u7684GOx\uff0c\u540c\u65f6\u6e38\u79bb\u7684\u6c28\u57fa\u57fa\u56e2\u5bb9\u6613\u56fa\u5b9aGOx\uff0c\u901a\u5e38\u4f1a\u52a0\u5165\u4e00\u4e9b\u4ea4\u8054\u5242\u6765\u63d0\u9ad8PEI-GOx\u4e4b\u95f4\u7684\u7535\u5b50\u4f20\u9012\u3002\u6b64\u5916\uff0c\u7eb3\u7c73\u7ed3\u6784\u5bfc\u7535\u805a\u5408\u7269\u4e5f\u4f1a\u5f71\u54cdEBFC\u7684\u7535\u5b50\u4f20\u9012\u548c\u7535\u6c60\u6027\u80fd\u3002\u5c06PPy\u7eb3\u7c73\u7ebf\u548c\u7eb3\u7c73\u819c\u8fdb\u884c\u5bf9\u6bd4\uff0c\u53d1\u73b0\u7eb3\u7c73\u7ebf\u7684\u7535\u6c60\u8f93\u51fa\u529f\u7387\u8f83\u9ad8\uff0c\u56e0\u4e3aPPy\u7eb3\u7c73\u7ebf\u6709\u5229\u4e8e\u589e\u52a0\u7535\u5b50\u4f20\u9012\u3002\u7528\u5bfc\u7535\u805a\u5408\u7269\u5bf9\u7535\u5b50\u4ecb\u8d28\u8fdb\u884c\u529f\u80fd\u5316\uff0c\u4e5f\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7535\u5b50\u4f20\u9012\u6548\u7387\u3002<\/p>\n<p><strong>3.2.2 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-68730\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/10-3.gif\" alt=\"\" width=\"600\" height=\"425\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe10 \u4e0d\u540c\u5bfc\u7535\u805a\u5408\u5728MFC\u4e2d\u7684\u5e94\u7528\u5b9e\u4f8b<\/strong><\/p>\n<p><strong>3.3 \u91d1\u5c5e-\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599<\/strong><\/p>\n<p>\u8fc7\u53bb\u5341\u5e74\uff0c\u91d1\u5c5e\u6216\u8005\u91d1\u5c5e\u6c27\u5316\u7269\u56e0\u5176\u50a8\u91cf\u5927\u3001\u5ec9\u4ef7\u3001\u7a33\u5b9a\u7b49\u4f18\u70b9\u5907\u53d7\u5173\u6ce8\uff0c\u5e76\u88ab\u5e7f\u6cdb\u7528\u4e8e\u4f20\u611f\u5668\u3001\u592a\u9633\u80fd\u7535\u6c60\u4ee5\u53ca\u50a8\u80fd\u8bbe\u5907\u4e2d\u3002<\/p>\n<p><strong>3.3.1 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\u91d1\u5c5e\u6c27\u5316\u7269\u7528\u4e8eMFC<\/strong><\/p>\n<p>\u7535\u5b50\u4ece\u819c\u5916\u86cb\u767d\u8d28\u4f20\u9012\u81f3\u7535\u6781\u7684\u8ddd\u79bb\u8fc7\u957f\u5c06\u4e0d\u5229\u4e8e\u7535\u6d41\u7684\u4ea7\u751f\uff0c\u9650\u5236MFC\u7535\u6c60\u7684\u53d1\u5c55\u3002\u7eb3\u7c73\u7ed3\u6784\u91d1\u5c5e\u53ca\u91d1\u5c5e\u6c27\u5316\u7269\u6709\u5229\u4e8e\u7535\u5b50\u7684\u4f20\u9012\u3002\u6bd4\u5982Fe<sub>3<\/sub>O<sub>4<\/sub>\/Au\u590d\u5408\u7eb3\u7c73\u9897\u7c92\u5c31\u88ab\u7528\u5728MFC\u4e2d\uff0c\u5176\u5177\u6709\u9ad8\u7684\u5bfc\u7535\u6027\u548c\u751f\u7269\u517c\u5bb9\u6027\uff0c\u53ef\u4ee5\u7528\u4e8e\u589e\u5f3a\u7535\u6781\u8868\u9762\u6c27\u5316\u8fd8\u539f\u7535\u5b50\u4ea4\u4e92\u4f5c\u7528\u3002\u8fdb\u4e00\u6b65\uff0c\u53c8\u5236\u5907\u51fa\u4e86\u4e09\u7ef4\u77f3\u58a8\u70ef-MWCNT-Fe<sub>3<\/sub>O<sub>4<\/sub>\u590d\u5408\u6750\u6599\u5e76\u7528\u4e8eMFC\u9633\u6781\uff0c\u4e5f\u53ef\u4ee5\u5927\u5e45\u63d0\u9ad8\u7535\u5b50\u5728\u7ec6\u83cc\u50ac\u5316\u5242\u548c\u7535\u6781\u754c\u9762\u7684\u8f6c\u79fb\u901f\u7387\u3002\u56e0\u6b64\uff0c\u5c06\u8fd9\u4e9b\u5177\u6709\u751f\u7269\u517c\u5bb9\u6027\u7684\u7eb3\u7c73\u9897\u7c92\u7ed3\u5408\u4e8e\u7ec6\u83cc\u751f\u7269\u819c\u4e2d\uff0c\u53ef\u4ee5\u63d0\u9ad8\u7ec6\u83cc-\u7535\u6781\u7535\u5b50\u4f20\u9012\uff0c\u662f\u76ee\u524dMFC\u7814\u7a76\u4e2d\u5f88\u6709\u524d\u666f\u7684\u65b9\u5411\u3002<\/p>\n<p><strong>4\u3001\u5e94\u7528<\/strong><\/p>\n<p>\u4f5c\u4e3a\u53ef\u6301\u7eed\u7eff\u8272\u80fd\u6e90\uff0c\u751f\u7269\u71c3\u6599\u7535\u6c60\u5177\u6709\u5f88\u5e7f\u6cdb\u7684\u5b9e\u9645\u5e94\u7528\uff0c\u5305\u62ec\u81ea\u53d1\u7535\u4f20\u611f\u5668\u3001\u6c34\u5904\u7406\u7b49\u3002<\/p>\n<p><strong>4.1 EBFC\u57fa\u81ea\u4f9b\u7535\u751f\u7269\u4f20\u611f\u5668<\/strong><\/p>\n<p>EBFC\u7684\u53d1\u5c55\u662f\u4e3a\u4e86\u63d0\u9ad8\u7535\u6c60\u7684\u8f93\u51fa\u529f\u7387\u548c\u5bff\u547d\uff0c\u4f46\u662f\u4e5f\u9700\u8981\u8003\u5bdf\u5728\u65b0\u9886\u57df\u7684\u5e94\u7528\u53ef\u884c\u6027\uff0c\u6bd4\u5982\u81ea\u4f9b\u80fd\u578b\u751f\u7269\u4f20\u611f\u5668\u3002\u4e0e\u4f20\u7edf\u751f\u7269\u4f20\u611f\u5668\u76f8\u6bd4\uff0c\u81ea\u4f9b\u80fd\u5f0f\u751f\u7269\u4f20\u611f\u5668\u5177\u6709\u4ee5\u4e0b\u51e0\u4e2a\u7279\u70b9\uff1a\uff081\uff09\u65e0\u9700\u5916\u754c\u529f\u80fd\uff0c\u7ed3\u6784\u53ea\u6709\u751f\u7269\u9633\u6781\u548c\u9634\u6781\uff1b\uff082\uff09\u65e0\u5916\u754c\u529f\u80fd\uff0c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u53ef\u4ee5\u6709\u6548\u8bc4\u4ef7\u3002\u56e0\u6b64\u57fa\u4e8eEBFC\u7684\u81ea\u4f9b\u80fd\u578b\u751f\u7269\u4f20\u611f\u5668\u5728\u5f88\u591a\u9886\u57df\u5177\u6709\u5f88\u5927\u5e94\u7528\u524d\u666f\uff0c\u6bd4\u5982\u751f\u7269\u5206\u5b50\u3001\u6709\u6bd2\u5206\u5b50\u7684\u68c0\u6d4b\u9274\u5b9a\u3001\u514d\u75ab\u68c0\u6d4b\u4ee5\u53ca\u80bf\u7624\u8bca\u65ad\u7b49\u3002\u503c\u5f97\u6307\u51fa\u7684\u662f\u5b9e\u9a8c\u4e2d\u5236\u5907\u7684EBFC\u57fa\u81ea\u4f9b\u80fd\u751f\u7269\u4f20\u611f\u5668\u662f\u9996\u6b21\u7528\u4e8e\u68c0\u6d4b\u80bf\u7624\u7ec6\u80de\u3002\u4f46\u662f\u7531\u4e8e\u764c\u75c7\u7ec6\u80de\u7684\u7a7a\u95f4\u4f4d\u963b\u4ee5\u53ca\u9759\u7535\u6392\u65a5\u4f5c\u7528\uff0c\u964d\u4f4e\u4e86EBFC\u7535\u6c60\u8f93\u51fa\u529f\u7387\u548c\u68c0\u6d4b\u7075\u654f\u5ea6\u3002\u8fdb\u4e00\u6b65\uff0c\u5b9e\u9a8c\u4e2d\u53c8\u8bbe\u8ba1\u4e86\u7528\u4e8e\u68c0\u6d4b\u764c\u7ec6\u80de\u7684\u5916\u90e8\u7ec6\u80de\u65e0\u6c27\u5316\u8fd8\u539f\u7ec6\u80de\u4f20\u611f\u5668\u5e73\u53f0\u3002\u6b64\u4f53\u7cfb\u4e2d\uff0cBOD\u7528\u4e8eORR\u9634\u6781\u50ac\u5316\u5242\uff0c\u751f\u7269\u9633\u6781\u7528PQQ-GDH\u4f5c\u4e3a\u8461\u8404\u7cd6\u6c27\u5316\u50ac\u5316\u5242\u3002\u56fe11\u4e3a\u81ea\u4f9b\u80fd\u751f\u7269\u4f20\u611f\u5668\uff0c\u5f88\u660e\u663e\u65e0\u5916\u90e8\u80fd\u91cf\u6216\u8005\u53cd\u5e94\u7269\u52a0\u5165\u8be5\u7535\u6c60\u3002\u8fd9\u79cd\u6709\u6548\u7684\u57fa\u4e8eEBFC\u7684\u81ea\u4f9b\u80fd\u751f\u7269\u4f20\u611f\u5668\u53ef\u4ee5\u7528\u4e8e\u764c\u7ec6\u80de\u7684\u8bca\u65ad\u3002<\/p>\n<p><img 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href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2017\/cs\/c6cs00044d#!divAbstract\" target=\"_blank\">Nanostructured material-based biofuel cells:recent advances and future prospects<\/a>\u00a0(Chem. Soc. Rev.,2017, DOI: 10.1039\/c6cs00044d)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u6750\u6599\u5b66\u672f\u7ec4Star\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-68945 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/QQ\u56fe\u724720170301214816.jpg\" alt=\"\" width=\"430\" height=\"430\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/QQ\u56fe\u724720170301214816.jpg 430w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/QQ\u56fe\u724720170301214816-150x150.jpg 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/QQ\u56fe\u724720170301214816-300x300.jpg 300w\" sizes=\"(max-width: 430px) 100vw, 430px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u5927\u5206\u5b50\u5fae\u4fe1\u4e8c\u7ef4\u7801<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5168\u7403\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u6c61\u67d3\u52a0\u901f\u4e86\u6211\u4eec\u5bf9\u53ef\u6301\u7eed\u6e05\u6d01\u80fd\u6e90\u7684\u7814\u7a76\u3002\u751f\u7269\u71c3\u6599\u7535\u6c60\u56e0\u80fd\u591f\u5c06\u751f\u7269\u53ef\u964d\u89e3\u7269\u8d28\u4e2d\u7684\u5316\u5b66\u80fd\u8f6c\u5316\u4e3a\u7535\u80fd\u800c\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u751f\u7269\u71c3\u6599\u7535\u6c60\u4e2d\u6240\u7528\u7684\u751f\u7269\u50ac&#8230;<\/p>\n","protected":false},"author":60,"featured_media":68735,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[33],"class_list":["post-68673","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-nano"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/68673"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/60"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=68673"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/68673\/revisions"}],"predecessor-version":[{"id":68949,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/68673\/revisions\/68949"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/68735"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=68673"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=68673"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=68673"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}