{"id":68464,"date":"2017-03-06T06:30:20","date_gmt":"2017-03-05T22:30:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=68464"},"modified":"2017-03-01T19:05:36","modified_gmt":"2017-03-01T11:05:36","slug":"acc-chem-res-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e6%9d%90%e6%96%99%ef%bc%88mof%ef%bc%89%e5%af%b9%e4%ba%8e%e7%9b%ae%e6%a0%87%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=68464","title":{"rendered":"Acc. Chem. Res.\u6700\u65b0\u7efc\u8ff0\uff1a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\uff08MOF\uff09\u5bf9\u4e8e\u76ee\u6807\u5e94\u7528\u7684\u5408\u6210\u540e\u8c03\u63a7"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u7269\uff08MOFs\uff09\u662f\u7531\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\u6216\u56e2\u7c07\u901a\u8fc7\u914d\u4f4d\u952e\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u5177\u6709\u5206\u5b50\u5185\u5b54\u9699\u7684\u6709\u673a-\u65e0\u673a\u6742\u5316\u6750\u6599\u3002\u5728MOFs \u4e2d\uff0c\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\u6216\u56e2\u7c07\u7684\u6392\u5217\u5177\u6709\u660e\u663e\u7684\u65b9\u5411\u6027\uff0c\u53ef\u4ee5\u5f62\u6210\u4e0d\u540c\u7684\u6846\u67b6\u5b54\u9699\u7ed3\u6784\uff0c\u4ece\u800c\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u5438\u9644\u6027\u80fd\u3001\u5149\u5b66\u6027\u8d28\u3001\u7535\u78c1\u5b66\u6027\u8d28\u3002\u5b83\u5177\u6709\u9ad8\u5b54\u9699\u7387\u3001\u4f4e\u5bc6\u5ea6\u3001\u5927\u6bd4\u8868\u9762\u79ef\u3001\u5b54\u9053\u89c4\u5219\u3001\u5b54\u5f84\u53ef\u8c03\u4ee5\u53ca\u62d3\u6251\u7ed3\u6784\u591a\u6837\u6027\u548c\u53ef\u88c1\u526a\u6027\u7b49\u4f18\u70b9\u3002\u8fd9\u4e9b\u6027\u80fd\u53ef\u4ee5\u5e94\u7528\u5728\u5305\u62ec\u7164\u6c14\u7684\u50a8\u5b58\u3001\u5316\u5b66\u5206\u79bb\u3001\u6355\u5149\u3001\u5316\u5b66\u4f20\u611f\u7b49\u9886\u57df\u3002\u5bf9\u4e8eMOF\u6750\u6599\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u5c31\u662f\u5728\u5408\u6210\u4e4b\u540e\u4fee\u6539MOF\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u4f46\u662f\u76f4\u63a5\u901a\u8fc7\u5408\u6210\u4f7f\u4e4b\u5177\u6709\u7406\u60f3\u7684\u5316\u5b66\u7ed3\u6784\u5f88\u5177\u6709\u6311\u6218\u6027\u751a\u81f3\u662f\u4e0d\u53ef\u80fd\u7684\u3002<\/p>\n

\n \u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u897f\u5317\u5927\u5b66\u7684<\/strong>Omar K. Farha<\/strong>\u6559\u6388\u548c<\/strong>Joseph T. Hupp<\/strong>\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Accounts of Chemical Research<\/strong>\u671f\u520a\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cPostsynthetic Tuning of Metal\u2013Organic Frameworks for Targeted Applications<\/strong>\u201d\u7684\u7efc\u8ff0\uff0c\u6587\u4e2d\u8bba\u8ff0\u4e86\u7814\u7a76\u8005\u5728\u540e\u5408\u6210\u7b56\u7565\u7684\u5e94\u7528\u548c\u53d1\u5c55\u505a\u7684\u4e00\u4e9b\u5de5\u4f5c\uff0c\u4ee5\u53ca\u4e0d\u540c\u65b9\u6cd5\u9700\u8981\u7684\u5316\u5b66\u7ed3\u6784\u7684\u57fa\u672c\u8981\u6c42\uff0c\u540c\u65f6\u5217\u4e3e\u4e86\u51e0\u4e2a\u5178\u578b\u7684\u5217\u5b50\uff0c\u672c\u6587\u7684\u91cd\u70b9\u5728\u4e8e\uff1a\u4f20\u8fbe\u548c\u5f15\u5165\u5f88\u96be\u6216\u4e0d\u80fd\u901a\u8fc7\u76f4\u63a5\u65b9\u6cd5\u83b7\u5f97\u7684\u529f\u80fd\u578b\u7ed3\u6784\u57fa\u672c\u7684\u6982\u5ff5 \u3002\u6700\u91cd\u8981\u7684\u662f\u672c\u7bc7\u6587\u7ae0\u8bba\u8ff0\u4e86\u529f\u80fd\u5316\u7b56\u7565\u7684\u65b0\u4f8b\u5b50\u548c\u65b0\u7684\u5e94\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n

1 \u7b80\u4ecb<\/strong><\/p>\n

MOF\u662f\u73b0\u4ee3\u5316\u5b66\u7814\u7a76\u6700\u5e7f\u6cdb\u7684\u4e00\u79cd\u6750\u6599\uff0c\u5b83\u4eec\u7684\u5206\u5b50\u7ed3\u6784\u4ee5\u53ca\u5316\u5b66\u548c\u62d3\u6251\u7684\u591a\u6837\u6027\u4f7f\u4e4b\u5177\u6709\u6027\u80fd\u53ef\u8c03\u6027\u3002\u968f\u7740\u66f4\u591a\u5bf9\u4e8e\u8fde\u63a5\u6865\u548c\u8282\u70b9\u8bbe\u8ba1\u7684\u5173\u6ce8\uff0c\u76f4\u63a5\u5408\u6210\u7684\u65b9\u6cd5\u5bf9\u4e8e\u8c03\u6574\u5185\u8868\u9762\u7684\u8303\u56f4\u548c\u5b54\u9699\u7684\u5c3a\u5bf8\u4ee5\u53ca\u5bf9\u4e8e\u5408\u6210\u6240\u9700\u7684\u5316\u5b66\u529f\u80fd\u90fd\u5177\u6709\u5f88\u9ad8\u7684\u6548\u7387\u3002\u4f46\u662f\u60f3\u8981\u76f4\u63a5\u5f97\u5230\u6240\u9700\u7684\u529f\u80fd\u901a\u5e38\u662f\u4e0d\u53ef\u80fd\u7684\uff0c\u56e0\u6b64\uff0c\u5408\u6210\u540e\u4fee\u6539\u7ed3\u6784\uff08PSM\uff09\u53ef\u4ee5\u6709\u6548\u7684\u83b7\u5f97\u5177\u6709\u7406\u60f3\u529f\u80fd\u7684\u6846\u67b6\u7ed3\u6784\u3002\u672c\u6587\u4e3b\u8981\u8ba8\u8bbaPSM\u7684\u4e09\u79cd\u4e3b\u8981\u7b56\u7565\uff1aa\uff09\u6eb6\u5242\u8f85\u52a9\u914d\u4f53\u5408\u6210 \uff08SALI\uff09\uff0c\u5305\u62ec\u628a\u4e0d\u7a33\u5b9a\u7684\u3001\u975e\u7ed3\u6784\u7684\u65e0\u673a\u914d\u4f53\u66f4\u6362\u6210\u5177\u6709\u4e00\u5b9a\u529f\u80fd\u7684\u6709\u673a\u914d\u4f53 b\uff09MOF\u7684\u539f\u5b50\u5206\u5c42\u5806\u79ef\uff08AIM\uff09\uff0c\u8fd9\u5bf9\u4e8e\u9644\u7740\u5355\u4e00\u7684\u91d1\u5c5e\u539f\u5b50\u6216\u8005\u542b\u6709\u91d1\u5c5e\u7684\u56e2\u7c07\u5f88\u6709\u6548\u7387\u3002c\uff09\u6eb6\u5242\u8f85\u52a9\u66f4\u6362\u8fde\u63a5\u6865\uff08SALE\uff09\uff0c\u5305\u62ec\u5c06\u6709\u7ed3\u6784\u7684\u914d\u4f53\uff08\u8fde\u63a5\u6865\uff09\u66f4\u6362\u6210\u53ef\u6539\u53d8\u7684\u8fde\u63a5\u6865\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1 AIM\u4e2d\u91d1\u5c5e\u4ea4\u6362\u548c\u7ecfSALI\u7b2c\u4e8c\u529f\u80fd\u5316\u7684\u8fc7\u7a0b\u56fe\u89e3<\/strong><\/p>\n

2\u00a0 \u6eb6\u5242\u8f85\u52a9\u914d\u4f53\u5408\u6210 \uff08SALI\uff09<\/strong><\/p>\n

\u5316\u5b66\u529f\u80fd\u7684\u53ef\u9006\u5408\u6210\u9700\u8981\u901a\u8fc7\u5c06\u975e\u7ed3\u6784\u7684\u7684\u914d\u4f53\u7c98\u63a5\u5230\u4e0d\u9971\u548c\u7684\u91d1\u5c5e\u624d\u53ef\u4ee5\u5b9e\u73b0\uff0c\u8d8a\u987d\u5f3a\u7684\u914d\u4f53\u6210\u529f\u7387\u8d8a\u9ad8\uff0c\u4f46\u662f\u87af\u5408\u4f5c\u7528\u548c\u79bb\u5b50\u7684\u7c98\u63a5\u5374\u6070\u6070\u76f8\u53cd\u3002\u7b80\u6d01\u7684\u8bf4\uff0c\u6bcf\u4e00\u4e2a\u8282\u70b9\u57fa\u70c3\u90fd\u53ef\u4ee5\u88ab\u4e00\u4e2a\u65b0\u7684\u8865\u507f\u7535\u8377\u7684\u7fa7\u9178\u8102\u3001\u81a6\u9178\u8102\u6216\u8005\u76f8\u4f3c\u7684\u7ec4\u5408\u914d\u4f53\u4ee3\u66ff\u3002\u56e0\u6b64\uff0c\u53ef\u4ee5\u9644\u7740\u5728\u6bcf\u4e2a\u8282\u70b9\u7684\u914d\u4f53\u9ad8\u8fbe\u56db\u4e2a\u3002SALI\u76f8\u5bf9\u4e8e\u5176\u4ed6\u7684\u8981\u6c42\u6bd4\u8f83\u6e29\u548c\uff0c\u8fd9\u610f\u5473\u7740\u5408\u6210\u7684\u7269\u8d28\u53ef\u4ee5\u5177\u5907\u66f4\u5fae\u5999\u7684\u529f\u80fd\u3002<\/p>\n

2.1 \u4e8c\u6c27\u5316\u78b3\u7684\u6355\u83b7<\/strong><\/p>\n

MOFs\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u7684\u5217\u4e3a\u56fa\u4f53\u5438\u9644\u5242\u7684\u5019\u9009\u8005\uff0c\u5c24\u5176\u662f\u7528\u4e8e\u4ece\u5e9f\u6c14\u4e2d\uff08\u4e3b\u8981\u662f\u6c2e\u6c14\u3001\u4e8c\u6c27\u5316\u78b3\u548c\u6c34\uff09\u5bf9\u4e8c\u6c27\u5316\u78b3\u7684\u6355\u83b7\u3002\u7531\u4e8e\u5168\u6c1f\u5316\u6709\u673a\u7269\u7684\u758f\u6c34\u6027\u4ee5\u53ca\u8d85\u4e34\u754c\u4e8c\u6c27\u5316\u78b3\u548c\u5168\u6c1f\u70c3\u7c7b\u7684\u4eb2\u5bc6\u5173\u7cfb\uff0c\u6c1f\u5316\u7684\u8fde\u63a5\u6865\u4f5c\u4e3a\u969c\u788d\u5e76\u53ef\u4ee5\u7528\u4e8e\u758f\u6c34\u7684\u548c\u4eb2\u4e8c\u6c27\u5316\u78b3\u7684MOF\u5b54\u9699\u4e2d\u7684\u6027\u8d28\u5f15\u8d77\u4e86\u5b66\u8005\u4eec\u6781\u5927\u7684\u5174\u8da3\u3002\u7814\u7a76\u8005\u53d1\u73b0\u4ee5\u7fa7\u9178\u8102\u7ed3\u5c3e\u7684\u6709\u4e0d\u540c\u957f\u5ea6\u7684\u5168\u6c1f\u70c3\u7c7b\u53ef\u4ee5\u901a\u8fc7SALI\u9644\u7740\u4e0a\uff0c\u88ab\u4fee\u6539\u7684\u7ed3\u6784\u5728\u5438\u9644\u4e8c\u6c27\u5316\u78b3\u7684\u70ed\u91cf\u65b9\u9762\u6bd4\u4e4b\u524d\u589e\u52a0\u4e86\u7b49\u503c\u7684\u70ed\u91cf\uff0c\u4e5f\u5c31\u662f\u4e0a\u5347\u81f3\u4e24\u500d\u3002<\/span><\/p>\n

2.2 \u50ac\u5316\u4f5c\u7528<\/strong><\/p>\n

SALI\u540c\u6837\u5728\u50ac\u5316\u4f5c\u7528\u65b9\u9762\u6709\u5f88\u597d\u7684\u5e94\u7528\u3002\u5176\u9664\u4e86\u5177\u6709\u660e\u663e\u7684\u4fc3\u8fdb\u50ac\u5316\u5242\u7684\u518d\u5229\u7528\u5916\uff0c\u8fd8\u6709\u4e00\u4e9b\u6f5c\u5728\u7684\u7528\u5904\uff0c\u4f8b\u5982\uff1a1\uff09\u50ac\u5316\u5242\u9694\u79bb \uff1b2\uff09\u50ac\u5316\u5242\u5bf9\u4e8e\u6c14\u76f8\u5316\u5b66\u8f6c\u53d8\u7684\u5e94\u7528\u3002\u4e00\u4e2a\u6700\u5177\u4ee3\u8868\u6027\u7684\u4f8b\u5b50\u5c31\u662f\u5e94\u7528\u5728\u70ef\u5c5e\u70c3\u7684\u51dd\u56fa\u6001\u6c22\u5316\u4f5c\u7528\uff0c\u76f8\u5173\u7684\u6db2\u6001\u50ac\u5316\u589e\u52a0\u4e86\u6d3b\u6027\u800c\u4e14\u5b58\u6d3b\u7684\u65f6\u95f4\u66f4\u957f\uff0c\u8fd9\u90fd\u5f52\u7ed3\u4e8e\u50ac\u5316\u5242\u4ece\u6bcf\u4e00\u4e2aMOF\u4e2d\u7684\u5206\u79bb\u3002\u901a\u5e38\u5206\u5b50\u56fa\u5b9a\u5728\u56fa\u4f53\u7684\u50ac\u5316\u4f34\u968f\u7740\u50ac\u5316\u6d3b\u6027\u7684\u964d\u4f4e\uff0c\u4f46\u8fd9\u79cd\u5931\u6d3b\u4e0d\u4f1a\u53d1\u751f\u5728\u8fd9\u91cc\uff0c\u8fd9\u53ef\u80fd\u6b63\u662fMOF\u6750\u6599\u7684\u591a\u5b54\u4ee5\u53ca\u4f4e\u5bc6\u5ea6\u7684\u6700\u597d\u53cd\u6620\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 \u7ecf\u8fc7SALI\u540e\u5176\u4e2d\u4e00\u4e2a\u5206\u5b50\u7684\u5c55\u793a\u56fe<\/strong><\/p>\n

3 MOF\u7684\u539f\u5b50\u5206\u5c42\u5806\u79ef\uff08AIM\uff09<\/strong><\/p>\n

\u539f\u5b50\u5206\u5c42\u5806\u79ef\u662f\u4e00\u79cd\u6c14\u76f8\u5408\u6210\u6280\u672f\uff0c\u5982\u4eca\u5df2\u88ab\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u5236\u9020\u8d85\u7ec6\u7684\u3001\u65e0\u5b54\u7684\u8584\u5c42\uff0c\u4f8b\u5982\u4ece\u4e0d\u7a33\u5b9a\u7684\u6709\u673a\u91d1\u5c5e\u6216\u65e0\u673a\u590d\u5408\u7269\u4e2d\u63d0\u53d6\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\u3001\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\uff1b\u4ece\u4e3b\u8981\u7ec4\u6210\u5143\u7d20\u4e2d\u63d0\u53d6\u7684\u6d3b\u6027\u8d44\u6e90\uff0c\u4f8b\u5982\u6c34\u84b8\u6c14\u3001\u6c28\u6c14\uff1b\u4e00\u79cd\u7f9f\u57fa\u5316\u7684\u57fa\u5e95\u3002\u901a\u5e38\u539f\u5b50\u5206\u5c42\u5806\u79ef\u662f\u57fa\u4e8e\u4e24\u4e2a\u6709\u5e8f\u5148\u884c\u7684\u8868\u9762\u53cd\u5e94\uff0c\u8fd9\u4e24\u4e2a\u53cd\u5e94\u4e13\u95e8\u7684\u4e0e\u4e92\u8865\u7684\u5316\u5b66\u7269\u8d28\u5728\u57fa\u5e95\u4e0a\u53d1\u751f\u53cd\u5e94\uff0c\u800c\u5b83\u4eec\u81ea\u8eab\u4e0d\u53d1\u751f\u53cd\u5e94\uff0c\u91cd\u590d\u8fd9\u4e9b\u6b65\u9aa4\u4fc3\u4f7f\u8584\u5c42\u8fdb\u4e00\u6b65\u7684\u751f\u957f\u3002\u4e00\u4e2a\u91cd\u8981\u7684\u7ed3\u679c\u5c31\u662f\u8584\u5c42\u53ef\u4ee5\u4ee5\u57c3\u7684\u7cbe\u5ea6\u7b49\u7ea7\u751f\u957f\uff0c\u53e6\u5916\uff0c\u8584\u5c42\u751a\u81f3\u5728\u591a\u5b54\u7684\u57fa\u5e95\u4e2d\u4e5f\u53ef\u4ee5\u7b49\u89d2\u751f\u957f\u3002<\/p>\n

3.1 \u91d1\u5c5e\u6c27\u5316\u7269\u7684\u539f\u5b50\u5206\u5c42\u5806\u79ef <\/strong><\/p>\n

\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc1\u5b9eAIM\u7684\u5b9e\u9a8c\uff0c\u672c\u6587\u9009\u7528\u4e86\u9ad8\u6d3b\u6027\u7684\u91d1\u5c5e\uff08\u950c\u548c\u94dd\uff09\u70c3\u57fa\u590d\u5408\u7269\u3002\u521d\u6b65\u7684\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff1aAIM\u7684\u5316\u5b66\u5408\u6210\u8fc7\u7a0b\u662f\u81ea\u6211\u9650\u5236\u7684\uff1b\u6df7\u5408\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u70c3\u5316\u7269\u53ef\u4ee5\u5728\u7b2c\u4e8c\u8f6eAIM\u5408\u6210\u65f6\u901a\u8fc7\u6539\u53d8\u539f\u5b50\u5206\u5c42\u5806\u79ef\u65b9\u5f0f\u800c\u83b7\u5f97\uff1bMOF\u6750\u6599\u7684\u7ed3\u6676\u5ea6\u548c\u591a\u5b54\u6027\u662f\u88ab\u4fdd\u7559\u7684\uff1b\u9664\u4e86\u4e00\u4e9b\u6709\u7455\u75b5\u7684\u533a\u57df\uff0c\u56e2\u7c07\u7684\u5206\u5e03\u662f\u6709\u4e00\u5b9a\u89c4\u5f8b\u6027\u7684\u3002\u542b\u954d\u7684\u56e2\u7c07\u5bf9\u4e8e\u4e59\u70ef\u7684\u6c14\u76f8\u6c22\u5316\u4f5c\u7528\u548c\u70ef\u70c3\u7684\u4f4e\u805a\u53cd\u6620\u90fd\u5c55\u73b0\u51fa\u4e86\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u53ef\u4ee5\u81ea\u52a8\u7684\u5c06\u5206\u6563\u7684\u954d\u5339\u914d\u5230\u6c27\u5316\u9506\u4e0a\u3002<\/p>\n

3.2 \u91d1\u5c5e\u786b\u5316\u7269\u7684\u539f\u5b50\u5206\u5c42\u5806\u79ef <\/strong><\/p>\n

\u8fc7\u6e21\u91d1\u5c5e\u6216\u91d1\u5c5e\u786b\u5316\u7269\u53ef\u4ee5\u4f5c\u4e3a\u8f85\u9176\u56e0\u5b50\u7528\u4e8e\u50ac\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u4f8b\u5982\u6c22\u5316\u9176\u548c\u56fa\u6c2e\u9176\u3002\u4ee5\u6b64\u4e3a\u542f\u53d1\uff0c\u672c\u6587\u4f5c\u8005\u4f7f\u7528\u4e00\u79cd\u6c14\u76f8\u7684\u65b9\u5f0f\u652f\u6301\u8282\u70b9\u786b\u5316\u94b4\u3002\u7b80\u5355\u7684\u8bf4\uff0c\u5728130\u2103\u7684\u6761\u4ef6\u4e0b\u4f9d\u9760AIM\u5408\u6210\uff0c\u5728\u8fd9\u79cd\u6761\u4ef6\u4e0b\u4f1a\u7559\u4e0b\u672a\u635f\u574f\u7684MOF\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 AIM\u65b9\u5f0f\u7b80\u4ecb\u56fe<\/strong>\u00a0<\/p>\n

\"\"<\/p>\n

\u56fe4 \u4e00\u4e9b\u539f\u5b50\u5206\u5c42\u5806\u79ef\u7684\u5316\u5b66\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

4 \u6eb6\u5242\u8f85\u52a9\u66f4\u6362\u8fde\u63a5\u6865\uff08SALE\uff09<\/strong><\/p>\n

SALE\u53ef\u4ee5\u88ab\u5e94\u7528\u5728\u4e00\u4e0b\u65b9\u9762\uff1a1\uff09\u5408\u6210\u65b0\u7684MOFs\u6216\u8005\u5f15\u5165\u65b0\u7684\u5316\u5b66\u529f\u80fd\uff1b 2\uff09\u63a7\u5236\u5b54\u9699\u7684\u5c3a\u5bf8\u548c\u5f62\u72b6\uff1b 3\uff09\u83b7\u53d6\u4e0d\u4e3a\u4eba\u77e5\u7684\u7279\u6b8a\u7684\u8fde\u63a5\u6865\u548c\u8282\u70b9\u7684\u62d3\u6251\u7ed3\u6784\u3002SALE\u8fc7\u7a0b\u662f\u4ee5\u66b4\u9732\u4e00\u4e2a\u6bcd\u6e90MOF\u5230\u4e00\u4e2a\u65b0\u7684\u8fde\u63a5\u6865\u7684\u6d53\u7f29\u6eb6\u6db2\u5f00\u59cb\u7684\uff0c\u7ed3\u679c\u662f\u5b50\u6846\u67b6\u53ef\u4ee5\u57281%\u5230100%\u7684\u6d53\u5ea6\u91cc\u4efb\u610f\u83b7\u5f97\u4e00\u4e2a\u65b0\u7684\u8fde\u63a5\u6865\u3002\u6700\u91cd\u8981\u7684\u662f\u81ea\u6846\u67b6\u5927\u4f53\u4e0a\u4fdd\u7559\u4e86\u6bcd\u6846\u67b6\u7684\u62d3\u6251\u7ed3\u6784\u3002<\/p>\n

4.1 \u8c03\u6574\u5b54\u6d1e\u5c3a\u5bf8<\/strong><\/p>\n

\u4f7f\u7528SALE\u8c03\u6574\u5b54\u6d1e\u5c3a\u5bf8\u6ca1\u6709\u6539\u53d8\u6bcd\u6846\u67b6\u7684\u62d3\u6251\u7ed3\u6784\u8fd9\u4e00\u70b9\u662f\u975e\u5e38\u6709\u7528\u7684\u3002\u8fde\u63a5\u6865\u78b1\u6027\u5ea6\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u4e2a\u7ebd\u5e26\u548c\u9884\u6d4b\u8005\u9884\u5224SALE\u53cd\u6620\u662f\u5426\u4f1a\u53d1\u751f\u3002\u7b80\u5355\u7684\u8bf4\uff0c\u9ad8\u78b1\u6027\u5ea6\u7684\u8fde\u63a5\u6865\u53ef\u4ee5\u8f7b\u800c\u6613\u4e3e\u7684\u66ff\u6362\u4f4e\u78b1\u6027\u5ea6\u7684\u8fde\u63a5\u6865\uff0c\u4f46\u662f\u76f8\u53cd\u7684\u8fc7\u7a0b\u5374\u4e0d\u80fd\u8fdb\u884c\u3002<\/p>\n

4.2 \u50ac\u5316\u4f5c\u7528<\/strong><\/p>\n

\u6d3b\u8dc3\u7684\u535f\u5549MOFs\uff08RPMs\uff09\u53ef\u4ee5\u662f\u4e24\u79cd\u4e0d\u540c\u7684\u91d1\u5c5e\u535f\u5549\u79bb\u5b50\u5728\u4e00\u4e2a\u5355\u4e00\u7684\u6846\u67b6\u91cc\u534f\u8c03\uff0c\u8fd9\u5bf9\u4e8e\u4e24\u6b65\u50ac\u5316\u5177\u6709\u5f88\u5927\u7684\u5438\u5f15\u529b\u3002\u5927\u591a\u6570\u7684\u91d1\u5c5e\u548c\u91d1\u5c5e\u7684\u7ed3\u5408\u4f53\u53ef\u4ee5\u76f4\u63a5\u83b7\u5f97\uff0c\u4f46\u662f\u6709\u4e00\u4e9b\u5374\u4e0d\u80fd\u3002\u53e6\u5916\uff0c\u8bd5\u56fe\u5408\u6210\u81ea\u7531\u57fa\u535f\u5549\u8fd8\u6ca1\u6709\u6210\u529f\uff0c\u56e0\u4e3a\u81ea\u7531\u57fa\u7684\u81ea\u7136\u91d1\u5c5e\u5316\u9700\u8981\u8282\u70b9\u3002\u4e00\u4e2a\u4f8b\u5b50\u5c31\u662f\u950c\u94dd RPMs\uff0c\u4e00\u79cdSALE\u884d\u751f\u7684MOF\uff0c\u88ab\u8bc1\u5b9e\u662f\u6700\u6709\u6548\u7387\u7684 RPM\uff0c\u53ef\u4ee5\u7528\u4e8e\u73af\u6c27\u5316\u7269\u7684\u5f00\u73af\u4f5c\u7528\u3002<\/p>\n

4.3 \u8fde\u9501\u63a7\u5236<\/strong><\/p>\n

\u5c3d\u7ba1\u8fde\u73af\u6846\u67b6\u6709\u4e00\u4e9b\u5e94\u7528\uff0c\u4f46\u662f\u975e\u8fde\u73af\u7684\u6846\u67b6\u53ef\u4ee5\u63d0\u4f9b\u66f4\u9ad8\u7684\u8868\u9762\u8303\u56f4\u548c\u591a\u5b54\u6027\u3002\u7136\u800c\u73b0\u5b58\u83b7\u5f97\u975e\u8fde\u73af\u7684\u6846\u67b6\u7684\u65b9\u6cd5\u4f8b\u5982\u8c03\u6574\u5408\u6210\u6761\u4ef6\u3001\u6df7\u5408\u7269\u5bc6\u5ea6\u5206\u79bb\u8fd8\u6ca1\u6709\u88ab\u666e\u904d\u7684\u5e94\u7528\u3002SALE\u63d0\u4f9b\u4e86\u4e00\u4e2a\u53ef\u66ff\u6362\u7684\u65b9\u6cd5\u3002\u4e00\u4e2a\u6210\u529f\u7684\u7b80\u5355\u4f8b\u5b50\u5c31\u662f\u975e\u8fde\u73af\u7684\u67f1\u72b6\u8f6e\u6868\u7684\u5408\u6210\u3002<\/p>\n

4.4 \u8d77\u50ac\u5316\u4f5c\u7528\u7684\u6df7\u5408\u6750\u6599<\/strong><\/p>\n

\u5177\u6709\u83b7\u5f97\u76f8\u540c\u62d3\u6251\u7ed3\u6784\u548c\u5b54\u9699\u5c3a\u5bf8\u4f46\u662f\u4e0d\u540c\u5b54\u6d1e\u5c3a\u5bf8\u7684\u80fd\u529b\u662f\u975e\u5e38\u6709\u7528\u7684\u3002\u4e00\u4e2a\u5178\u578b\u7684\u4f8b\u5b50\u5c31\u662f\u901a\u8fc7SALE\u5408\u6210\u7684\u590d\u5408\u6750\u6599Pt@ZIF-8(\u7528 ZIF-8\u5305\u88f9Pt\u7eb3\u7c73\u7c92\u5b50\uff09\uff0c\u53ef\u4ee5\u50ac\u5316\u5df1\u70ef\u7684\u6c22\u5316\u4f5c\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 \u7ecf\u8fc7SALE\u540e\u5b54\u5f84\u6269\u5f20<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe6 \u901a\u8fc7SALE\u5408\u6210MOF\u793a\u610f\u56fe\u89e3<\/strong><\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

\u8fc7\u53bb\u6570\u5e74\u5df2\u7ecf\u5236\u5907\u4e86\u4e0d\u540c\u7c7b\u578b\u7684MOFs\u6750\u6599\uff0c\u5e76\u5728\u6c22\u6c14\u5b58\u50a8\u3001\u6c14\u4f53\u5438\u9644\u4e0e\u5206\u79bb\u3001\u4f20\u611f\u5668\u3001\u836f\u7269\u7f13\u91ca\u3001\u50ac\u5316\u53cd\u5e94\u7b49\u9886\u57df\u90fd\u6709\u91cd\u8981\u7684\u5e94\u7528\u3002\u968f\u7740MOFs\u6750\u6599\u79cd\u7c7b\u7684\u65e5\u76ca\u589e\u591a\u4ee5\u53ca\u590d\u5408MOFs\u6750\u6599\u7684\u9010\u6e10\u5174\u8d77\uff0cMOFs\u6750\u6599\u5c06\u6709\u4e0d\u53ef\u4f30\u91cf\u7684\u5e94\u7528\u524d\u666f\u3002\u5728\u6c14\u4f53\u5438\u9644\u4e0e\u5206\u79bb\u65b9\u9762\uff0c\u5408\u6210\u5177\u6709\u66f4\u9ad8\u5438\u9644\u6027\u80fd\u7684MOFs\u6750\u6599\u7528\u4e8e\u6c22\u6c14\u50a8\u5b58\u3001\u6709\u6bd2\u6709\u5bb3\u6c14\u4f53\u5438\u9644\u4e0e\u5206\u79bb\uff0c\u53ef\u89e3\u51b3\u4e00\u90e8\u5206\u4eba\u4eec\u9762\u4e34\u7684\u65e5\u76ca\u4e25\u91cd\u7684\u73af\u5883\u95ee\u9898\u3002\u5728\u50ac\u5316\u5e94\u7528\u65b9\u9762\uff0c\u5229\u7528\u4e0d\u540c\u91d1\u5c5e\u6df7\u5408\u6784\u5efa\u5177\u6709\u9ad8\u6548\u50ac\u5316\u529f\u80fd\u7684\u590d\u5408MOFs\u6750\u6599\u5c06\u8fdb\u4e00\u6b65\u63d0\u9ad8\u50ac\u5316\u6548\u7387\u3002\u53e6\u5916\uff0c\u5728\u5206\u79bb\u9886\u57df\uff0c\u5236\u5907\u5177\u6709\u78c1\u6027\u7684\u590d\u5408MOFs\u6750\u6599\u53ef\u7528\u4e8e\u6709\u6bd2\u6709\u5bb3\u7269\u8d28\u3001\u91cd\u91d1\u5c5e\u7684\u5438\u9644\u4e0e\u5206\u79bb\u4ee5\u53ca\u590d\u6742\u4f53\u7cfb\u4e2d\u76ee\u6807\u86cb\u767d\u8d28\u7684\u63d0\u53d6\u4e0e\u5206\u79bb\u3002\u7279\u522b\u5728\u751f\u7269\u533b\u5b66\u9886\u57df\uff0c\u7531\u4e8e\u5176\u53ef\u63a7\u7684\u5b54\u5f84\u5927\u5c0f\u3001\u529f\u80fd\u57fa\u56e2\u4ee5\u53ca\u826f\u597d\u7684\u751f\u7269\u517c\u5bb9\u6027\uff0c\u5236\u5907\u7eb3\u7c73\u7ea7\u7684MOFs\u6750\u6599\u7528\u4e8e\u6d3b\u7ec6\u80de\u4e2d\u836f\u7269\u7f13\u91ca\u4e0e\u4ee3\u8c22\u3001\u751f\u547d\u4f53\u6d3b\u52a8\u7684\u5b9e\u65f6\u76d1\u6d4b\u7b49\uff0c\u5bf9\u4eba\u4eec\u4e86\u89e3\u751f\u7269\u4f53\u5185\u91cd\u8981\u7684\u751f\u547d\u6d3b\u52a8(\u5982\u86cb\u767d\u8d28\u7684\u529f\u80fd\u3001\u86cb\u767d\u8d28\u95f4\u7684\u76f8\u4e92\u4f5c\u7528)\u3001\u8c03\u63a7\u86cb\u767d\u8d28\u7684\u6fc0\u6d3b\u673a\u5236\u4ee5\u53ca\u91cd\u5927\u75be\u75c5\u76f8\u5173\u7684\u86cb\u767d\u8d28\u8c03\u63a7\u901a\u8def\u7b49\u5177\u6709\u91cd\u5927\u7684\u751f\u7269\u5b66\u610f\u4e49\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u529f\u80fd\u591a\u6837\u6027\u7684MOFs\u4ee5\u53ca\u590d\u5408MOFs\u6750\u6599\uff0c\u5e76\u5e94\u7528\u4e8e\u4e0d\u540c\u9886\u57df\uff0c\u5c06\u6781\u5927\u5730\u4fc3\u8fdb\u5b66\u79d1\u95f4\u7684\u76f8\u4e92\u53d1\u5c55\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Postsynthetic Tuning of Metal\u2013Organic Frameworks for Targeted Applications<\/a>\uff08Acc. Chem. Res.,2016,DOI:10.1021\/acs.accounts.6b00577)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u7ec4\u674e\u4f26\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0e\u751f\u7269\u6750\u6599\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u751f\u7269\u6750\u6599\u5c0f\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u4ea4\u6d41\u7fa4\uff08124806506\uff09\u3002<\/p>\n

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