{"id":67283,"date":"2017-02-27T06:30:42","date_gmt":"2017-02-26T22:30:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=67283"},"modified":"2017-02-23T20:18:13","modified_gmt":"2017-02-23T12:18:13","slug":"%e4%b8%8a%e6%b5%b7%e4%ba%a4%e5%a4%a7adv-energy-mater-%ef%bc%9a%e9%ab%98%e6%95%88mott-schottky%e6%95%b4%e4%bd%93%e6%b0%b4%e5%88%86%e8%a7%a3%e5%82%ac%e5%8c%96%e5%89%82-cocop-janus%e7%ba%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=67283","title":{"rendered":"\u4e0a\u6d77\u4ea4\u5927Adv. Energy Mater.\uff1a\u9ad8\u6548Mott\u2013Schottky\u6574\u4f53\u6c34\u5206\u89e3\u50ac\u5316\u5242-Co\/CoP Janus\u7eb3\u7c73\u7c92\u5b50"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u7535\u5316\u5b66\u6c34\u88c2\u89e3\u53cd\u5e94\uff0c\u5305\u62ec\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\uff0c\u8fd9\u4e3a\u751f\u4ea7\u9ad8\u7eaf\u6c22\u6c14\u4f5c\u4e3a\u53ef\u6301\u7eed\u71c3\u6599\u63d0\u4f9b\u4e86\u4e00\u79cd\u53ef\u884c\u7684\u65b9\u6cd5\u3002\u800c\u6b63\u5728\u7814\u7a76\u7684\u6838\u5fc3\u95ee\u9898\u662f\u5f00\u53d1\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\uff0c\u4ee5\u514b\u670d\u8fdf\u7f13\u7684\u52a8\u529b\u5b66\u548c\u52a0\u901fH2<\/sub>\u548cO2<\/sub>\u5728\u4f4e\u8d85\u7535\u52bf\u7684\u6f14\u5316\u901f\u7387\u3002\u8d35\u91d1\u5c5e\uff08\u4f8b\u5982Pt\uff0cRh\uff0cIr\uff09\u548c\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\uff08\u4f8b\u5982\uff0cIrO2<\/sub>\uff0cRuO2<\/sub>\uff09\u50ac\u5316\u5242\u5206\u522b\u5177\u6709\u6240\u9700\u7684HER\u548cOER\u6d3b\u6027\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u8d35\u91d1\u5c5e\u7684\u7a00\u7f3a\u6027\u548c\u9ad8\u6210\u672c\u963b\u788d\u4e86\u5b83\u4eec\u7684\u5927\u89c4\u6a21\u5e94\u7528\u3002\u56e0\u6b64\u4eba\u4eec\u975e\u5e38\u5e0c\u671b\u5f00\u53d1\u7528\u4e8e\u9ad8\u6548\u7387\u3001\u4f4e\u6210\u672c\u7684\u6c34\u5206\u89e3\u7535\u50ac\u5316\u5242\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5df2\u7ecf\u4e3a\u9178\u6027\u7535\u89e3\u8d28\u4e2d\u7684HER\u548c\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u7684OER\u8bbe\u8ba1\u4e86\u8bb8\u591a\u6f5c\u5728\u7684\u571f\u58e4\u4e2d\u5bcc\u542b\u7684\u6750\u6599\u5019\u9009\u7269\u3002\u7136\u800c\u5c3d\u7ba1\u4ed8\u51fa\u4e86\u5de8\u5927\u7684\u52aa\u529b\uff0c\u7528\u4e8eHER\u548cOER\u7684\u5f3a\u5927\u4e14\u666e\u901a\u7684\u6c34\u5206\u89e3\u7535\u50ac\u5316\u5242\u5728\u5404\u79cd\u7535\u89e3\u8d28\u4e2d\u5b9e\u73b0\u6709\u6548\u7684\u603b\u4f53\u6c34\u5206\u89e3\u4ecd\u7136\u5f88\u5c11\u7528\u4e8e\u5b9e\u9645\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u6709\u5438\u5f15\u529b\u7684\u662f\u5236\u9020\u5728pH0-14\u4e0b\u5bf9HER\u548cOER\u90fd\u663e\u793a\u9ad8\u6d3b\u6027\u7684\u53cc\u529f\u80fd\u50ac\u5316\u5242\u3002<\/p>\n

\u6700\u8fd1\uff0c\u4e00\u4e9b\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\u5df2\u7ecf\u901a\u8fc7\u5728\u4e00\u4e2a\u7eb3\u7c73\u590d\u5408\u6750\u6599\u4e2d\u7ed3\u5408HER\u548cOER\u6d3b\u6027\u7ec4\u5206\u800c\u6210\u529f\u5730\u5408\u6210\u3002\u5728\u8fd9\u4e9b\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\u4e2d\uff0c\u8fc7\u6e21\u91d1\u5c5e\u57fa\u7eb3\u7c73\u590d\u5408\u6750\u6599\u5177\u6709\u4f5c\u4e3a\u7528\u4e8e\u5927\u91cf\u751f\u4ea7\u6c22\u6c14\u7684\u4fbf\u5b9c\u4e14\u7a33\u5b9a\u7684\u7535\u6781\u6750\u6599\u7684\u5de8\u5927\u6f5c\u529b\u3002\u6709\u8fd9\u6837\u4e00\u4e2a\u5171\u8bc6\uff0cHER\u548cOER\u6d3b\u6027\u7ec4\u5206\u4e4b\u95f4\u7684\u5f3a\u5076\u8054\u754c\u9762\u7531\u4e8e\u53ef\u80fd\u7684\u534f\u540c\u6548\u5e94\u548c\u5728\u4e0d\u540c\u7ec4\u5206\u7684\u754c\u9762\u5904\u7684\u589e\u5f3a\u7684\u7535\u5b50\u8f6c\u79fb\u6548\u7387\uff0c\u901a\u5e38\u663e\u7740\u4fc3\u8fdb\u8fd9\u4e9b\u6df7\u5408\u7535\u50ac\u5316\u5242\u7684\u6700\u7ec8\u6027\u80fd\u3002\u9664\u4e86\u8fd9\u4e9b\u57fa\u4e8e\u8fc7\u6e21\u91d1\u5c5e-\u7eb3\u7c73\u590d\u5408\u7269\u7684\u7535\u50ac\u5316\u5242\u7684\u5b98\u80fd\u5316\u548c\u5076\u8054\u4e4b\u5916\uff0c\u6269\u5c55\u8fd9\u4e9b\u7535\u50ac\u5316\u5242\u4e0e\u7535\u89e3\u8d28\u7c7b\u578b\u7684\u76f8\u5bb9\u6027\u4e5f\u5df2\u7ecf\u6210\u4e3a\u7535\u50ac\u5316\u9886\u57df\u4e2d\u6700\u91cd\u8981\u7684\u7814\u7a76\u8bfe\u9898\u4e4b\u4e00\u3002\u4f8b\u5982\uff0c\u5df2\u7ecf\u7814\u7a76\u4e86\u91d1\u5c5e\u548c\u91d1\u5c5e\u78f7\u5316\u7269\u57fa\u6750\u6599\u4f5c\u4e3a\u5728\u9178\u6027\u548c\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u4e00\u822cHER\u7535\u50ac\u5316\u5242\u3002\u4f5c\u4e3a\u6d89\u53ca\u4e24\u4e2a\u6c34\u5206\u5b50\u7684\u56db\u7535\u5b50\u6c27\u5316\u53cd\u5e94\u7684\u80fd\u91cf\u4e0a\u5761\u53cd\u5e94\uff0cOER\u7279\u522b\u9700\u8981\u6bd4\u7528\u4e8eHER\u7684\u8fc7\u7535\u4f4d\u5927\u5f97\u591a\u7684\u8fc7\u7535\u4f4d\u3002\u901a\u5e38\uff0c\u4fc3\u8fdbOER\u7535\u50ac\u5316\u5242\u5728\u9178\u6027\u548c\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u7684\u6d3b\u6027\u4ecd\u7136\u662f\u5bf9\u7528\u4e8e\u5728\u5bbdpH\u8303\u56f4\u5185\u7684\u6574\u4f53\u6c34\u5206\u89e3\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1\u7684\u5de8\u5927\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u8fd1\u65e5\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u7684\u674e\u65b0\u660a<\/span><\/strong>\u8bfe\u9898\u7ec4\u5728Adv. Energy Mater<\/em>.<\/strong><\/span>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\u201cJanus Co\/CoP Nanoparticles as Efficient Mott<\/em><\/strong>\u2013<\/em><\/strong>Schottky Electrocatalysts for Overall Water Splitting in Wide pH Range<\/em><\/strong><\/span>\u201d<\/strong><\/em>\u3002\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u79cd\u6982\u5ff5\u9a8c\u8bc1\u7b56\u7565\uff0c\u901a\u8fc7\u5728\u91d1\u5c5e-\u534a\u5bfc\u4f53\u754c\u9762\u7684Janus (\u4e24\u9762\u795e)Co \/ CoP\u7eb3\u7c73\u7c92\u5b50\u7684Mott\u2013Schottky\u6548\u5e94\uff0c\u5728\u9178\u6027\u3001\u4e2d\u6027\u548c\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u4fc3\u8fdb\u94b4\u548c\u94b4\u7684\u4e8c\u5143\u4f53\u7684HER\u548cOER\u6d3b\u6027\u3002\u5e94\u7528\u771f\u7a7a\u6269\u6563\u6cd5\u63a7\u5236\u78b3\u5305\u8986\u7684Co\u7eb3\u7c73\u9897\u7c92\u7684\u78f7\u5316\u7a0b\u5ea6\u3002\u5408\u7406\u63a7\u5236Janus Co \/ CoP\u7eb3\u7c73\u9897\u7c92\u4e2d\u7684CoP\u542b\u91cf\u5e76\u56e0\u6b64\u6784\u5efa\u4f18\u5316\u7684Mott-Schottky\u7535\u50ac\u5316\u5242\u7684\u6210\u529f\u5bfc\u81f4\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u4ece\u9178\u5230\u78b1\u7684\u663e\u7740\u4fc3\u8fdb\u7684OER\u548cHER\u6d3b\u6027\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u53cc\u529f\u80fdCo \/ CoP\u7535\u50ac\u5316\u5242\u66f4\u591f\u957f\u671f\u5de5\u4f5c\uff0c\u800c\u6ca1\u6709\u660e\u663e\u7684\u6c34\u5206\u89e3\u6d3b\u6027\u7684\u964d\u4f4e\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe\u4e00\uff1a\u6750\u6599\u7684\u5408\u6210\u53ca\u5f62\u8c8c<\/strong><\/span><\/p>\n

<\/p>\n

a<\/strong>\uff09\u5408\u6210\u65b9\u6cd5\uff0cb\uff09TEM\u548cc\uff09\u78b3\u5305\u8986\u7684Janus Co \/ CoP-5\u7eb3\u7c73\u9897\u7c92\u7684HRTEM\u56fe\u50cf\u3002 d\uff09XRD\u56fe\u8c31\u548ce\uff09Co\u548cCo \/ CoP-5\u6837\u54c1\u7684Co 2p XPS\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e8c\uff1aLSV\u66f2\u7ebf\u4ee5\u53caTafel\u659c\u7387<\/strong><\/span><\/p>\n

<\/p>\n

\u76f8\u5bf9\u4e8eCo\uff0cCo \/ CoP-x\uff08x = 3,5\u548c7\uff09\u548cCoP\u6837\u54c1\u7684 a\uff09<\/strong>HER\u548c b\uff09<\/strong>OER\u7684iR\u6821\u6b63\u7684LSV\u66f2\u7ebf\u4ee5\u53ca\u57281M KOH\u7535\u89e3\u8d28\u4e2d c\uff09<\/strong>HER\u548cd\uff09OER\u76f8\u5e94\u7684Tafel\u659c\u7387\uff08\u50ac\u5316\u5242\u8d1f\u8f7d\uff1a0.22mg cm-2<\/sup>\uff09\u3002<\/p>\n

\u56fe\u4e09\uff1a\u603b\u4f53\u6c34\u7535\u89e3\u7684iR\u6821\u6b63\u7684LSV\u66f2\u7ebf\u548c\u76f8\u5e94\u7684\u8ba1\u65f6\u7535\u4f4d\u66f2\u7ebf<\/strong><\/span><\/p>\n

<\/p>\n

\u4f7f\u7528Co \/ CoP-5\u4f5c\u4e3a\u53cc\u529f\u80fd\u7535\u6781\u6750\u6599\u4ee5\u53ca\u5728<\/p>\n

a\uff0cb\uff091.0M KOH\uff0cc\uff0cd\uff091.0M PBS\u548c e\uff0cf\uff090.5M H2<\/sub>SO4<\/sub>\u4e2d\u7684\u603b\u4f53\u6c34\u7535\u89e3\u7684iR\u6821\u6b63\u7684LSV\u66f2\u7ebf\u548c\u76f8\u5e94\u7684\u8ba1\u65f6\u7535\u4f4d\u66f2\u7ebf\u3002 \u50ac\u5316\u5242\u8d1f\u8f7d\uff1a5.0mg cm -2<\/sup>\u3002<\/p>\n

\u56fe\u56db\uff1a\u6750\u6599\u7684HRTEM\u56fe\u50cf\u53caXPS\u5149\u8c31<\/strong><\/span><\/p>\n

<\/p>\n

a\uff09\u5bf9\u4e8eHER\u548cOER\uff0c\u57281.0M KOH\u7535\u89e3\u8d28\u4e2d\u7684Co\uff0cCo \/ CoP-x\u548cCoP\u6837\u54c1\u5728-0.30\u548c1.60V(\u76f8\u5bf9\u4e8eRHE)\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

b\uff09\u5178\u578b\u7684Co \/ CoP-5\u7eb3\u7c73\u9897\u7c92\u7684\u7ec4\u6210\u7ebf\u8f6e\u5ed3\u3002<\/p>\n

c\uff09\u91d1\u5c5eCo\uff0cCoP\u548cCo \/ CoP\u57faMott-Schottky\u63a5\u89e6\uff08EF\uff1a\u529f\u51fd\u6570; EC\uff1a\u5bfc\u5e26; EV\uff1a\u4ef7\u5e26\uff09\u7684\u7535\u5b50\u7ed3\u6784\u3002<\/p>\n

d\uff09\u5178\u578b\u7684Co \/ CoP-5\u7eb3\u7c73\u9897\u7c92\u7684HRTEM\u56fe\u50cf\u3002 Co\uff08\u84dd\u8272\uff09\u548cCoP\uff08\u7ea2\u8272\uff09\u7684\u754c\u9762\u5728\uff08d\uff09\u4e2d\u7528\u9ec4\u8272\u865a\u7ebf\u6807\u8bb0\u3002<\/p>\n

\u00a0e\uff09\u57fa\u4e8eXPS\u5206\u6790\u7ed3\u679c\uff0cCo\uff0cCo \/ CoP-x\u548cCoP\u6837\u54c1\u8868\u9762\u4e0a\u7684\u78f7\u542b\u91cf\u3002<\/p>\n

f\uff09Co \/ CoP-3\uff0cCo \/ CoP-5\u548cCoP\u6837\u54c1\u7684Co 2p XPS\u5149\u8c31\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/span><\/p>\n

\u672c\u6587\u901a\u8fc7\u5c06Co\u7eb3\u7c73\u9897\u7c92\u9010\u6b65\u78f7\u5316\u6210Janus\uff08\u4e24\u9762\u795e\uff09 Co \/ CoP\u7eb3\u7c73\u9897\u7c92\u6765\u5236\u5907Mott-Schottky\u7535\u50ac\u5316\u5242\u3002 \u5728Co \/ CoP\u754c\u9762\u5904\u7684\u7535\u5b50\u7684\u518d\u5206\u5e03\u901a\u5e38\u4fc3\u8fdb\u9178\u3001\u78b1\u548c\u4e2d\u6027\u7535\u89e3\u8d28\u4e2d\u7684HER\u548cOER\u6d3b\u6027\uff0c\u6781\u5927\u5730\u5ef6\u957f\u4e86\u5b83\u4eec\u5728\u6c34\u5206\u89e3\u88c5\u7f6e\u4e2d\u4f5c\u4e3a\u9ad8\u6548\u4e14\u7a33\u5b9a\u7684\u7535\u6781\u6750\u6599\u7684\u5e94\u7528\u3002\u8fd9\u9879\u7814\u7a76\u5f00\u8f9f\u4e86\u4e00\u4e2a\u4ee4\u4eba\u5174\u594b\u7684\u65b0\u9014\u5f84\uff0c\u63a2\u8ba8\u7531\u8fc7\u6e21\u91d1\u5c5e\u53ca\u5176\u6c27\u5316\u7269\u3001\u786b\u65cf\u5316\u7269\u3001\u6c2e\u5316\u7269\u6216\u78f7\u5316\u7269\u5236\u6210\u7684Mott-Schottky\u7535\u50ac\u5316\u5242\u7528\u4e8e\u6c34\u5206\u89e3\u53cd\u5e94\uff0c\u71c3\u6599\u7535\u6c60\u548c\u6709\u673a\u5408\u6210\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Janus Co\/CoP Nanoparticles as Efficient Mott\u2013Schottky Electrocatalysts for Overall Water Splitting in Wide pH Range<\/a><\/strong>\uff08<\/strong>Adv. Energy Mater<\/strong>\uff0c<\/strong>2017<\/strong>\uff0c<\/strong>DOI: 10.1002\/aenm.201602355<\/strong>\uff09<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4 \u80cc\u9006\u65f6\u5149 \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<\/strong>\u6750\u6599\u4eba<\/strong><\/a>\u3001\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u5316\u5b66\u6c34\u88c2\u89e3\u53cd\u5e94\uff0c\u5305\u62ec\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\uff0c\u8fd9\u4e3a\u751f\u4ea7\u9ad8\u7eaf\u6c22\u6c14\u4f5c\u4e3a\u53ef\u6301\u7eed\u71c3\u6599\u63d0\u4f9b\u4e86\u4e00\u79cd\u53ef\u884c\u7684\u65b9\u6cd5\u3002\u800c\u6b63\u5728\u7814\u7a76\u7684\u6838\u5fc3\u95ee\u9898\u662f\u5f00\u53d1\u9ad8\u6548\u7684\u7535\u50ac…<\/p>\n","protected":false},"author":272,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-67283","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/67283"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=67283"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/67283\/revisions"}],"predecessor-version":[{"id":67617,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/67283\/revisions\/67617"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=67283"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=67283"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=67283"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}