{"id":66977,"date":"2017-02-27T06:30:34","date_gmt":"2017-02-26T22:30:34","guid":{"rendered":"\/\/m.iemloyee.com\/?p=66977"},"modified":"2017-03-18T21:49:29","modified_gmt":"2017-03-18T13:49:29","slug":"acc-chem-res-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e8%a1%a8%e7%95%8c%e9%9d%a2%e6%9e%84%e7%ad%91%e9%9d%9e%e8%b4%b5%e9%87%91%e5%b1%9e%e7%94%b5%e5%82%ac%e5%8c%96%e5%89%82%e7%94%a8%e4%ba%8e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=66977","title":{"rendered":"\u4e54\u4e16\u748bAcc. Chem. Res. \u6700\u65b0\u7efc\u8ff0\uff1a\u8868\/\u754c\u9762\u6784\u7b51\u975e\u8d35\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u7528\u4e8e\u9ad8\u6548\u7684\u80fd\u91cf\u8f6c\u5316\u8fc7\u7a0b"},"content":{"rendered":"

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\"\"<\/p>\n

\u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n

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2\u3001\u78b3\u57fa\u7eb3\u7c73\u7ed3\u6784\u7535\u50ac\u5316\u5242<\/strong><\/p>\n

2.1 \u6742\u539f\u5b50\u63ba\u6742\u78b3\u57fa\u7535\u50ac\u5316\u5242<\/strong><\/p>\n

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\"\"<\/p>\n

\u56fe1 \u5171\u63ba\u6742\u77f3\u58a8\u70ef\u6750\u6599\u5728HER\u53cd\u5e94\u8fc7\u7a0b\u7684\u5e94\u7528<\/strong><\/p>\n

2.2 \u78b3-\u6742\u539f\u5b50\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599<\/strong><\/p>\n

\u975e\u91d1\u5c5e\u6750\u6599\u7a33\u5b9a\u6027\u597d\u4f46\u6d3b\u6027\u8f83\u5dee\uff0c\u4e0e\u78b3\u6750\u6599\u7684\u590d\u5408\u53ef\u4ee5\u8fdb\u4e00\u6b65\u589e\u5f3a\u50ac\u5316\u6d3b\u6027\u3002\u4e3b\u8981\u539f\u56e0\u5728\u4e8e\uff1a1\uff09\u53ef\u4ee5\u589e\u52a0\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\uff1b2\uff09\u63d0\u9ad8\u7535\u5b50\u7535\u5bfc\u7387\uff1b3\uff09\u6539\u53d8\u6750\u6599\u7684\u7ed9\u7535\u5b50\u6027\u8d28\u3002\u5bf9\u4e8e\u5316\u5b66\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u7ed3\u6784\uff0c\u5982N-\u63ba\u6742\u77f3\u58a8\u70ef\uff0c\u56e0\u5176\u4f4e\u7684\u6bd4\u8868\u9762\u79ef\u548c\u6d3b\u6027\u4e2d\u5fc3\u5bc6\u5ea6\uff0c\u8868\u73b0\u51fa\u4e00\u822c\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3002\u867d\u7136\u901a\u8fc7\u7269\u7406\u6216\u5316\u5b66\u6d3b\u5316\u7684\u65b9\u6cd5\u53ef\u4ee5\u4e30\u5bcc\u5176\u591a\u5b54\u6027\uff0c\u4f46\u65e2\u4e0d\u7ecf\u6d4e\u4e5f\u4e0d\u73af\u4fdd\u3002\u4f46\u662f\u6211\u4eec\u901a\u8fc7\u5f15\u5165\u5177\u6709\u4ecb\u5b54\u3001\u5927\u5b54\u7684\u78b3\u591a\u7ea7\u7f51\u7edc\u7ed3\u6784\u4f5c\u4e3a\u8f7d\u4f53\u539f\u4f4d\u751f\u957fN\u63ba\u6742\u77f3\u58a8\u70ef\u6216\u78b3\u7eb3\u7c73\u7ba1\uff0c\u8fd9\u7c7b\u590d\u5408\u7ed3\u6784\u80fd\u591f\u4f7f\u8f7d\u4f53\u548cN\u63ba\u6742\u6750\u6599\u7d27\u5bc6\u63a5\u89e6\uff0c\u964d\u4f4e\u6d3b\u5316\u80fd\uff0c\u589e\u52a0\u5316\u5b66\u8868\u9762\u79ef\u548c\u6d3b\u6027\u4f4d\u70b9\uff0c\u540c\u65f6\u8fd8\u80fd\u9632\u6b62\u77f3\u58a8\u70ef\u7684\u5806\u53e0\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3002\u518d\u6bd4\u5982\u901a\u8fc7\u03c0-\u03c0\u5171\u8f6d\u4f5c\u7528\u5c06N\u63ba\u6742\u77f3\u58a8\u70ef\u548cCNT\u8026\u5408\u5f62\u6210\u590d\u5408\u7535\u50ac\u5316\u5242\u5c55\u73b0\u51fa\u5ab2\u7f8e\u5546\u4e1a\u5316IrO2<\/sub><\/span>\u7684\u6c34\u6c27\u5316\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u8fd9\u4e9b\u975e\u91d1\u5c5e\u78b3\u57fa\u6750\u6599\u901a\u8fc7\u5408\u7406\u8bbe\u8ba1\u83b7\u5f97\u76f8\u5e94\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5176\u50ac\u5316\u6d3b\u6027\u6709\u6f5c\u529b\u8d85\u8d8a\u91d1\u5c5e\u57fa\u7535\u50ac\u5316\u5242\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 N\u63ba\u6742\u77f3\u58a8\u70ef-CNT\u590d\u5408\u50ac\u5316\u5242\u5728\u6c34\u6c27\u5316\u4e2d\u7684\u8fd0\u7528<\/strong><\/p>\n

2.3 \u78b3-g-<\/strong>C3<\/sub>N4<\/sub><\/span><\/strong>\u590d\u5408\u6750\u6599<\/strong><\/p>\n

N-\u63ba\u6742\u78b3\u6750\u6599\u56e0N\u63ba\u6742\u91cf\u8fc7\u4f4e\u9650\u5236\u4e86\u50ac\u5316\u6d3b\u6027\u3002g-C3<\/sub>N4<\/sub><\/span>\u5177\u6709\u5f88\u9ad8\u7684N\u542b\u91cf\uff0c\u4f46\u5176\u5bfc\u7535\u6027\u592a\u5dee\uff0c\u5728ORR\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u8fc7\u91cf\u7684\u8fc7\u6c27\u5316\u7269\u5806\u79ef\uff0c\u4e0d\u5229\u4e8e4e–<\/sup>\u53cd\u5e94\u5386\u7a0b\uff0c\u964d\u4f4e\u4e86\u50ac\u5316\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u5b9e\u9a8c\u4e2d\u5c06g-C3<\/sub>N4<\/sub>\u4e0e\u5177\u6709\u9ad8\u5bfc\u7535\u6027\u7684\u4ecb\u5b54\u78b3\u6750\u6599\u7ed3\u5408\u5f62\u6210\u590d\u5408\u6750\u6599\uff0c\u8868\u73b0\u51fa\u5353\u8d8a\u7684ORR\u6d3b\u6027\u3002\u5bfc\u7535\u78b3\u57fa\u5e95\u7684\u52a0\u5165\u63d0\u9ad8\u4e86\u7535\u5b50\u4f20\u9012\u901f\u7387\uff0c\u6d88\u9664\u4e86OH–<\/sup><\/span>\u8fdb\u4e00\u6b65\u8fd8\u539f\u7684\u58c1\u5792\uff0c\u8fdb\u800c\u63d0\u9ad8\u4e86O2<\/sub>\u5206\u5b50\u7684\u5438\u9644\uff0c\u5229\u4e8e4e–<\/sup>\u53cd\u5e94\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 g-C3<\/sub>N4<\/sub><\/span>-\u4ecb\u5b54\u78b3\u590d\u5408\u7535\u50ac\u5316\u5242\u5728ORR\u53cd\u5e94\u4e2d\u7684\u8fd0\u7528<\/strong><\/p>\n

\u5b9e\u9645\u4e0a\uff0c\u6211\u4eec\u53d1\u73b0\u4e0d\u540c\u7684\u5408\u6210\u65b9\u6cd5\u4f1a\u5f71\u54cdg-C3<\/sub>N4<\/sub>\u548cN\u63ba\u6742\u78b3\u6750\u6599\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8fdb\u800c\u5f71\u54cd\u7535\u5316\u5b66\u6027\u80fd\u3002\u901a\u8fc7\u9759\u7535\u7ec4\u88c5\uff0c\u03c0-\u03c0\u5806\u79ef\u6548\u5e94\uff0c\u6211\u4eec\u53ef\u4ee5\u5236\u5907\u5177\u6709\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\u9ad8\u542b\u6c2e\u91cf\u7684g-C3<\/sub>N4<\/sub>\u7eb3\u7c73\u7247\u548cCNT\u6742\u5316\u6750\u6599\uff0c\u56e0g-C3<\/sub>N4<\/sub>\u4e2d\u5b58\u5728\u5927\u91cf\u7684\u5421\u5576\u6c2e\u7c7b\u7269\u79cd\uff0c\u63d0\u9ad8\u4e86\u6b63\u7535\u8377\u5bc6\u5ea6\uff0c\u5229\u4e8e\u9634\u79bb\u5b50\uff08OH–<\/sup>\uff09\u7684\u5438\u9644\u548c\u7535\u5b50\u8f6c\u79fb\uff0c\u8fdb\u800c\u63d0\u9ad8\u4e86OER\u53cd\u5e94\u6d3b\u6027\u3002\u53e6\u5916\uff0c\u5c42\u72b6g-C3<\/sub>N4<\/sub>\u548cN\u63ba\u6742\u77f3\u58a8\u70ef\u7247\u5c42\u7ed3\u6784\u8026\u5408\u5f62\u6210\u7684\u6742\u5316\u6750\u6599\uff0c\u56e0\u5b58\u5728\u8f83\u597d\u7684H\u5438\u8131\u9644\u884c\u4e3a\uff0c\u663e\u793a\u51fa\u4f18\u4e8e\u91d1\u5c5e\u57fa\u6750\u6599\u7684HER\u53cd\u5e94\u6d3b\u6027\u3002\u6700\u540e\uff0c\u8fd8\u53ef\u4ee5\u8fdb\u884c\u6742\u539f\u5b50\u5982P\u63ba\u6742g-C3<\/sub>N4<\/sub>\u6765\u63d0\u9ad8\u6d3b\u6027\u4f4d\u70b9\uff0c\u6539\u53d8\u7535\u5b50\u7ed3\u6784\uff0c\u8fdb\u4e00\u6b65\u63d0\u5347\u50ac\u5316\u6027\u80fd\u3002\u8fd9\u79cd\u6742\u5316\u6750\u6599\u5728\u950c-\u7a7a\u6c14\u7535\u6c60\u4e2d\u8868\u73b0\u51fa\u4f4e\u7684\u8fc7\u7535\u52bf\u548c\u8f83\u597d\u7684\u8010\u4e45\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 g-C3<\/sub>N4<\/sub><\/span>-N\u63ba\u6742\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\u5728HER\u53cd\u5e94\u4e2d\u7684\u8fd0\u7528<\/strong><\/p>\n

3\u3001\u91d1\u5c5e-\u975e\u91d1\u5c5e\u6742\u5316\u7535\u50ac\u5316\u5242<\/strong><\/p>\n

\u00a03.1 \u4ee5M-N-C\u4e3a\u6d3b\u6027\u4f4d\u70b9\u7684\u91d1\u5c5e-\u975e\u91d1\u5c5e\u7535\u50ac\u5316\u5242<\/strong><\/p>\n

\u5f53\u524d\u5173\u4e8e\u91d1\u5c5e-\u6c2e\u7ed3\u6784\u7684\u7814\u7a76\u4e3b\u8981\u805a\u7126\u4e8e\u8fc7\u6e21\u91d1\u5c5e(Fe\u3001Co\u3001Ni)-\u5927\u73af\u5316\u5408\u7269\uff08\u915e\u83c1\uff0c\u90bb\u4e8c\u6c2e\u6742\u83f2\u7b49\uff09\u590d\u5408\u6750\u6599\u3002\u8fd9\u4e9b\u91d1\u5c5e-\u5927\u73af\u5316\u5408\u7269\u56e0\u4e3a\u7535\u5b50\u79bb\u57df\u6548\u5e94\u6709\u5229\u4e8e\u7535\u5b50\u4f20\u9012\uff0c\u4ea7\u751f\u4e86\u50ac\u5316\u6d3b\u6027\uff0c\u4f46\u7a33\u5b9a\u5dee\u963b\u788d\u4e86\u5b9e\u9645\u8fd0\u7528\u3002\u8fdb\u4e00\u6b65\u53ef\u4ee5\u5728\u60f0\u6027\u6c14\u6c1b\u4e0b\u76f4\u63a5\u78b3\u5316\u91d1\u5c5e\u5927\u73af\u5316\u5408\u7269\u5f62\u6210M-NX-C\u6750\u6599\uff0c\u5176\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u901a\u8fc7DFT\u8ba1\u7b97\u8868\u660eN\u5143\u7d20\u7684\u63ba\u6742\u964d\u4f4e\u4e86\u8868\u9762\u78b3\u7684\u529f\u51fd\uff0c\u63d0\u9ad8\u4e86\u7535\u5b50\u4ece\u5185\u5d4c\u91d1\u5c5e\u7c92\u5b50\u5230\u5916\u5c42\u78b3\u7684\u4f20\u9012\u901f\u7387\uff0c\u8fdb\u800c\u63d0\u9ad8\u4e86\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 M-NX-C\u6750\u6599\u7684\u5206\u5b50\u7ed3\u6784\u6a21\u578b<\/strong><\/p>\n

\u8fdb\u4e00\u6b65\u7814\u7a76\u53d1\u73b0\u540c\u65f6\u7145\u70e7\u6c2e\u6e90\u3001\u8fc7\u6e21\u91d1\u5c5e\u6e90\u548c\u78b3\u6e90\u4e5f\u53ef\u4ee5\u5f62\u6210M-Nx-C\u6750\u6599\uff0c\u56e0\u6b64\uff0c\u91d1\u5c5e\u5927\u73af\u5316\u5408\u7269\u53ef\u4ee5\u88ab\u4e00\u4e9b\u4f4e\u4ef7\u524d\u9a71\u4f53\u6240\u53d6\u4ee3\uff0c\u6bd4\u5982\u8fc7\u6e21\u91d1\u5c5e\u6e90\uff08\u785d\u9178\u76d0\u3001\u786b\u9178\u76d0\u3001\u918b\u9178\u76d0\u3001\u6c2f\u9178\u76d0\uff09\uff0c\u6c2e\u6e90\uff08\u805a\u82ef\u80fa\u3001\u4e09\u805a\u6c30\u80fa\u3001\u4e59\u8148\uff09\u548c\u78b3\u6e90\uff08\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u3001\u6d3b\u6027\u70ad\uff09\u3002\u7814\u7a76\u8868\u660e\uff0c\u9009\u62e9\u5408\u9002\u7684\u524d\u9a71\u4f53\u548c\u5408\u6210\u5de5\u827a\u53c2\u6570\uff08\u5982\u70ed\u89e3\u6e29\u5ea6\u3001\u4fdd\u6e29\u65f6\u95f4\u3001\u524d\u9a71\u4f53\u5728\u6eb6\u6db2\u4e2d\u7684\u53cd\u5e94\u548c\u540e\u5904\u7406\u5de5\u827a\u7b49\uff09\u5bf9\u5236\u5907\u51fa\u9ad8\u6d3b\u6027\u7535\u50ac\u5316\u5242\u5177\u6709\u91cd\u8981\u5f71\u54cd\u3002\u76ee\u524d\uff0c\u5bf9\u4e8eM-Nx-C\u6750\u6599\u7684\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u4e0d\u660e\u786e\uff0c\u4f46\u662f\u591a\u5b54\u6027\u548c\u5fae\u7eb3\u7c73\u7ed3\u6784\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4f1a\u5f71\u54cd\u50ac\u5316\u6d3b\u6027\uff0c\u901a\u8fc7\u9178\u6d17\u5904\u7406\u53ef\u4ee5\u589e\u52a0\u4e00\u5b9a\u7684\u6bd4\u8868\u9762\u79ef\u3002\u4f46\u662f\uff0c\u6750\u6599\u5728\u9ad8\u6e29\u7145\u70e7\u548c\u9178\u6d17\u8fc7\u7a0b\u4f1a\u5bfc\u81f4\u7ed3\u6784\u574d\u584c\uff0c\u6d3b\u6027\u4f4d\u6d41\u5931\uff0c\u964d\u4f4e\u50ac\u5316\u6027\u80fd\u3002\u4e3a\u4e86\u907f\u514d\u4ee5\u4e0a\u95ee\u9898\uff0c\u7845\u7eb3\u7c73\u9897\u7c92\u3001\u9633\u6781\u6c27\u5316\u94dd\u7b49\u786c\u6a21\u677f\u88ab\u5f15\u5165\u81f3\u78b3\u5316\u8fc7\u7a0b\u3002\u4f46\u662f\u786c\u6a21\u677f\u7684\u540e\u5904\u7406\u548c\u5408\u6210\u6b65\u9aa4\u8d39\u65f6\u8d39\u529b\u963b\u788d\u4e86\u6279\u91cf\u751f\u4ea7\uff0c\u6240\u4ee5\u53c8\u5f15\u5165\u4e86PS\u7403\u548cF127\u7b49\u805a\u5408\u7269\u6a21\u677f\uff0c\u56e0\u4e3a\u5728\u9ad8\u6e29\u7145\u70e7\u8fc7\u7a0b\u4e2d\u591a\u5b54M-NX-C\u7ed3\u6784\u7684\u5f62\u6210\u548c\u6a21\u677f\u7684\u79fb\u9664\u662f\u540c\u65f6\u8fdb\u884c\u7684\u3002\u8fd9\u79cd\u5177\u6709\u591a\u7ea7\u5b54\u7ed3\u6784\u548c\u4f18\u826f\u7535\u5bfc\u7387\u7684\u590d\u5408\u6750\u6599\u8868\u73b0\u51fa\u5353\u8d8a\u7684ORR\u6d3b\u6027\u3002<\/p>\n

\u53e6\u5916\uff0c\u901a\u8fc7\u5229\u7528M-NX\u76f8\u4e92\u4f5c\u7528\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u4e8c\u7ef4\u77f3\u58a8\u5316g-C3<\/sub>N4<\/sub>\u548c\u78b3\u5316\u949b\u7eb3\u7c73\u7247\u590d\u5408\u819c\u72b6\u7535\u50ac\u5316\u5242\uff0c\u5c55\u73b0\u51fa\u6781\u597d\u7684\u4ee5Ti-N \u7ed3\u6784\u4e3a\u6d3b\u6027\u4f4d\u70b9\u7684OER\u50ac\u5316\u6d3b\u6027\u3002\u4f46\u662f\uff0c\u91d1\u5c5e\u5728M-N-C\u7ed3\u6784\u4e2d\u6240\u8d77\u7684\u50ac\u5316\u4f5c\u7528\u4f9d\u7136\u6ca1\u6709\u76f4\u63a5\u8bc1\u636e\u3002\u5173\u4e8e\u6d3b\u6027\u4f4d\u70b9\u7684\u63a2\u7a76\u9700\u8981\u501f\u52a9\u7406\u8bba\u8ba1\u7b97\u548c\u5148\u8fdb\u7684\u6750\u6599\u5206\u6790\u624b\u6bb5\uff08\u5982X\u5c04\u7ebf\u8fd1\u8fb9\u5438\u6536\u8c31\uff0c\u7a46\u65af\u5821\u5c14\u8c31\uff09\u8fdb\u4e00\u6b65\u5206\u6790\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6 g-C3<\/sub>N4<\/sub><\/span>\u548c\u78b3\u5316\u949b\u590d\u5408\u6750\u6599\u5728OER\u4e2d\u7684\u8fd0\u7528<\/strong><\/p>\n

3.2 \u91d1\u5c5e\u6c27\u5316\u7269\/\u6c22\u6c27\u5316\u7269-\u6c2e\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599<\/strong><\/p>\n

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\"\"<\/p>\n

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\u3010\u603b\u7ed3<\/strong>\u3011<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Surface and Interface Engineering of Noble-Metal-Free Electrocatalysts for Efficient Energy Conversion Processes<\/a> (Acc. Chem. Res., 2017, DOI: 10.1021\/acs.accounts.6b00635)<\/p>\n

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