{"id":66618,"date":"2017-02-25T06:30:26","date_gmt":"2017-02-24T22:30:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=66618"},"modified":"2017-02-24T10:31:36","modified_gmt":"2017-02-24T02:31:36","slug":"nature%e5%ad%90%e5%88%8a%e7%bb%bc%e8%bf%b0%ef%bc%9a%e6%9c%89%e5%85%b3%e9%94%82%e7%94%b5%e6%b1%a0%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e4%b8%ad%e7%9a%84%e5%9b%ba%e6%80%81%e7%94%b5%e8%a7%a3%e8%b4%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=66618","title":{"rendered":"Nature\u5b50\u520a\u7efc\u8ff0\uff1a\u6709\u5173\u9502\u7535\u6c60\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u56fa\u6001\u7535\u89e3\u8d28"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7535\u6c60\u5728\u6211\u4eec\u751f\u6d3b\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u8d77\u7740\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u5305\u62ec\u7535\u5b50\u6d88\u8d39\uff0c\u63d0\u4f9b\u6c7d\u8f66\u7684\u52a8\u529b\uff0c\u95f4\u6b47\u6027\u53ef\u518d\u751f\u80fd\u6e90\u53d1\u7535\u7684\u56fa\u5b9a\u8d1f\u8f7d\u7b49\u3002\u7136\u800c\uff0c\u76ee\u524d\u7684\u5546\u4e1a\u5316\u7535\u6c60\u5df2\u7ecf\u4e0d\u80fd\u6ee1\u8db3\u793e\u4f1a\u5feb\u901f\u53d1\u5c55\u4e0b\u7684\u9700\u6c42\uff0c\u6bd4\u5982\u4fbf\u643a\u5f0f\u7535\u5b50\u5668\u4ef6\u3001\u7535\u52a8\u8f66\u3001\u7f51\u7edc\u50a8\u80fd\u7cfb\u7edf\u7684\u7b49\u3002\u73b0\u5728\u7535\u6c60\u7684\u53d1\u5c55\u9700\u8981\u5177\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u66f4\u957f\u7684\u5faa\u73af\u5bff\u547d\uff0c\u800c\u4e14\u66f4\u5b89\u5168\u5ec9\u4ef7\u3002\u8fc7\u53bb200\u5e74\u95f4\uff0c\u7edd\u5927\u90e8\u5206\u7535\u6c60\u7684\u7814\u7a76\u5173\u6ce8\u7684\u90fd\u662f\u6db2\u6001\u7535\u89e3\u8d28\u7cfb\u7edf\uff0c\u5373\u4f7f\u5176\u5177\u6709\u9ad8\u5bfc\u7535\u6027\u548c\u4f18\u79c0\u7684\u7535\u6781\u8868\u9762\u6da6\u6e7f\u6027\uff0c\u4f46\u5176\u7535\u5316\u5b66\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\u4e0d\u597d\uff0c\u79bb\u5b50\u9009\u62e9\u6027\u4f4e\uff0c\u5b89\u5168\u6027\u5dee\u3002\u800c\u7528\u56fa\u6001\u7535\u89e3\u8d28\u66ff\u4ee3\u6db2\u6001\u7535\u89e3\u8d28\u4e0d\u4ec5\u514b\u670d\u4e86\u6db2\u6001\u7535\u89e3\u8d28\u6301\u4e45\u7684\u95ee\u9898,\u4e5f\u4e3a\u5f00\u53d1\u65b0\u7684\u5316\u5b66\u7535\u6c60\u63d0\u4f9b\u4e86\u53ef\u80fd\u6027\uff0c\u57fa\u4e8e\u8fd9\u4e9b\u4f18\u70b9\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u7535\u6c60\u7684\u7814\u7a76\u4f7f\u7528\u5df2\u7ecf\u51fa\u73b0\u8fc5\u901f\u589e\u957f\u7684\u8d8b\u52bf\u3002\u968f\u7740\u4e0d\u65ad\u5730\u7814\u7a76\uff0c\u7814\u7a76\u8005\u4eec\u4e5f\u5df2\u7ecf\u8ba4\u8bc6\u5230\u8fd9\u4e9b\u7cfb\u7edf\u6240\u9762\u4e34\u7684\u79d1\u6280\u95ee\u9898\u3002<\/p>\n<p>\u6700\u8fd1\uff0c<strong>\u5fb7\u514b\u8428\u65af\u5927\u5b66\u7684Arumugam Manthiram\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u4ee5<strong>\u201cLithium battery chemistries enabled by solid-state electrolytes\u201d<\/strong>\u4e3a\u9898\u5728<strong>Nature Reviews Materials<\/strong>\u4e0a\u53d1\u8868\u7efc\u8ff0\uff0c\u672c\u6587\u4e2d\u63d0\u4f9b\u4e86\u4e00\u4e2a\u80cc\u666f\u6982\u89c8\uff0c\u8ba8\u8bba\u4e86\u50a8\u80fd\u5e94\u7528\u4e2d\u7684\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u7684\u7c7b\u578b\u3001\u79bb\u5b50\u4f20\u8f93\u673a\u5236\u548c\u57fa\u672c\u6027\u8d28\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66619\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u603b\u89c8\u56fe-1.png\" alt=\"\" width=\"600\" height=\"431\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u603b\u89c8\u56fe-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u603b\u89c8\u56fe-1-300x216.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n<p>\u56fa\u6001\u79bb\u5b50\u5bfc\u4f53\u53d1\u5c55\u7684\u5386\u53f2\u6700\u65e9\u53ef\u4ee5\u8ffd\u6eaf\u5230\u5341\u516b\u4e16\u7eaa\u4e09\u5341\u5e74\u4ee3\uff0c\u5f53\u65f6\u6cd5\u62c9\u7b2c\u52a0\u70ed\u56fa\u6001Ag<sub>2<\/sub>S\u548cPbF<sub>2<\/sub>\u65f6\u53d1\u73b0\u4e86\u660e\u663e\u7684\u5bfc\u7535\u6027\u3002\u5341\u4e5d\u4e16\u7eaa\u516d\u5341\u5e74\u4ee3\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u9ad8\u5bfc\u7535\u6027\u56fa\u6001\u7535\u89e3\u8d28\u7684\u8f6c\u6298\u70b9\u548c\u56fa\u6001\u79bb\u5b50\u5b66\u7684\u8d77\u70b9\uff0c\u5c06\u56fa\u6001\u7535\u89e3\u8d28\u7528\u4e8e\u7535\u6c60\u7684\u7814\u7a76\u4e5f\u53ef\u8ffd\u6eaf\u52301960\u5e74\u30021973\u5e74\u53d1\u73b0\u4e86\u805a\u6c27\u5316\u4e59\u70ef\u57fa\u56fa\u6001\u805a\u5408\u7269\u6750\u6599\u4e2d\u7684\u79bb\u5b50\u4f20\u8f93\u73b0\u8c61\uff0c\u4ece\u6b64\u56fa\u6001\u79bb\u5b50\u7684\u8303\u56f4\u4e0d\u518d\u9650\u5236\u5728\u65e0\u673a\u6750\u6599\u4e4b\u4e2d\u3002\u5341\u4e5d\u4e16\u7eaa\u516b\u5341\u5e74\u4ee3\uff0cZEBRA\u7535\u6c60\u6210\u4e3a\u4f7f\u7528\u03b2-\u6c27\u5316\u94dd\u94a0\u79bb\u5b50\u5bfc\u7535\u7684\u53e6\u4e00\u7c7b\u578b\u9ad8\u6e29\u7535\u6c60\u7cfb\u7edf\uff0c\u4eca\u5929\u65e5\u672c\u5df2\u7ecf\u5c06ZEBRA\u7535\u6c60\u5546\u4e1a\u5316\u3002\u4ece2000\u5e74\u5f00\u59cb\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u5e94\u7528\u5728\u4ee5\u6c14\u6001\u6216\u6db2\u6001\u6750\u6599\u505a\u7535\u6781\u7684\u9502\u7535\u6c60\u4e2d\uff0c\u6bd4\u5982\u9502\u786b\u7535\u6c60\u548c\u9502\u7a7a\u6c14\u7535\u6c60\u7b49\u3002\u6700\u8fd1\u51e0\u5e74\uff0c\u53c8\u63d0\u51fa\u4e00\u79cd\u72ec\u7279\u7684\u4ecb\u8d28\u79bb\u5b50\u7535\u6c60\u6982\u5ff5\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u88ab\u5e94\u7528\u5728\u9ad8\u80fd\u4f4e\u4ef7\u7684\u6c34\u7cfb\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u4e2d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-66645 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u65e0\u6807\u9898-2.jpg\" alt=\"\" width=\"600\" height=\"233\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u65e0\u6807\u9898-2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u65e0\u6807\u9898-2-300x117.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>1. <\/strong><strong>\u56fa\u6001\u7535\u89e3\u8d28\u7535\u6c60\u53d1\u5c55\u7684\u65f6\u95f4\u8fdb\u7a0b<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>1.\u56fa\u4f53\u4e2d\u7684\u79bb\u5b50\u4f20\u8f93\u673a\u5236<\/strong><\/p>\n<p>\u5728\u6676\u4f53\u6750\u6599\u4e2d\uff0c\u79bb\u5b50\u8fd0\u8f93\u901a\u5e38\u4f9d\u8d56\u4e8e\u7f3a\u9677\u7684\u6d53\u5ea6\u548c\u5206\u5e03\uff0c\u57fa\u4e8e\u8096\u7279\u57fa\u7f3a\u9677\u548c\u5f17\u4f26\u514b\u5c14\u70b9\u7f3a\u9677\u7684\u79bb\u5b50\u6269\u6563\u673a\u5236\u5305\u62ec\u7b80\u5355\u7684\u7a7a\u4f4d\u673a\u5236\u548c\u76f8\u5bf9\u590d\u6742\u7684\u6269\u6563\u673a\u5236\uff0c\u5982\u53cc\u7a7a\u4f4d\u673a\u5236\uff0c\u95f4\u9699\u673a\u5236\uff0c\u7a7a\u9699\u53d6\u4ee3\u4ea4\u6362\u673a\u5236\u548c\u96c6\u4f53\u673a\u5236\u3002\u7136\u800c\uff0c\u4e00\u4e9b\u7279\u6b8a\u7ed3\u6784\u7684\u6750\u6599\u53ef\u4ee5\u5728\u6ca1\u6709\u9ad8\u6d53\u5ea6\u7f3a\u9677\u6761\u4ef6\u4e0b\u5b9e\u73b0\u9ad8\u7684\u79bb\u5b50\u5bfc\u7387\uff0c\u8fd9\u79cd\u7ed3\u6784\u901a\u5e38\u7531\u4e24\u4e2a\u8d28\u5b50\u548c\u7531\u56fa\u5b9a\u7684\u79bb\u5b50\u548c\u79fb\u52a8\u7684\u6676\u683c\u7ec4\u5408\u7684\u4e00\u4e2a\u6676\u4f53\u6846\u67b6\u7ec4\u6210\u3002\u4e3a\u5b9e\u73b0\u5feb\u901f\u7684\u79bb\u5b50\u5bfc\u7535\uff0c\u8fd9\u79cd\u7ed3\u6784\u5fc5\u987b\u6ee1\u8db3\u4e09\u4e2a\u57fa\u672c\u51c6\u5219\uff1a\u79fb\u52a8\u79bb\u5b50\u5360\u636e\u53ef\u7528\u7b49\u4ef7\u4f4d\u70b9\u7684\u6570\u91cf\u5fc5\u987b\u5927\u4e8e\u53ef\u79fb\u52a8\u79bb\u5b50\u6570\u91cf\uff1b\u53ef\u7528\u5171\u4ef7\u4f4d\u70b9\u4e4b\u95f4\u7684\u8fc1\u79fb\u963b\u788d\u80fd\u5e94\u8be5\u4f4e\u4e8e\u79bb\u5b50\u5728\u4f4d\u70b9\u4e4b\u95f4\u8fc1\u79fb\u7684\u80fd\u91cf\uff1b\u8fd9\u4e9b\u53ef\u7528\u4f4d\u70b9\u4e00\u5b9a\u8981\u8fde\u63a5\u8d77\u6765\u5f62\u6210\u4e00\u4e2a\u8fde\u7eed\u5730\u6269\u6563\u8def\u5f84\u3002\u7c7b\u4f3c\u4e8e\u6676\u4f53\u7ed3\u6784\u4e2d\u7684\u6269\u6563\u8fc7\u7a0b, \u73bb\u7483\u6750\u6599\u7684\u79bb\u5b50\u8fd0\u8f93\u4ece\u539f\u4f4d\u79bb\u5b50\u5f00\u59cb\uff0c\u539f\u4f4d\u79bb\u5b50\u88ab\u9886\u4f4d\u4f4d\u70b9\u6fc0\u6d3b\uff0c\u7136\u540e\u5728\u5b8f\u89c2\u8303\u56f4\u5185\u96c6\u4e2d\u6269\u6563\u3002\u5bf9\u5927\u591a\u6570\u73bb\u7483\u6750\u6599\uff0c\u65e0\u5b9a\u578b\u7ed3\u6784\u4e2d\u4ecd\u5b58\u5728\u77ed\u7a0b\u6709\u5e8f\u548c\u4e2d\u7a0b\u6709\u5e8f\uff0c\u8f7d\u6d41\u5b50\u7535\u8377\u548c\u9aa8\u67b6\u7ed3\u6784\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4e0d\u80fd\u5ffd\u7565\u3002<\/p>\n<p>2.<strong>\u5148\u8fdb\u7684\u56fa\u6001\u7535\u89e3\u8d28<\/strong><\/p>\n<p>\u79bb\u5b50\u5bfc\u7535\u6027\u662f\u56fa\u6001\u7535\u89e3\u8d28\u4e00\u4e2a\u91cd\u8981\u7684\u6027\u80fd\uff0c\u4f46\u662f\u5728\u7535\u5316\u5b66\u50a8\u80fd\u548c\u8f6c\u6362\u7cfb\u7edf\u7684\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u5176\u4ed6\u6027\u80fd\u4e5f\u81f3\u5173\u91cd\u8981\u3002\u56fa\u6001\u7535\u89e3\u8d28\u7684\u4e3b\u8981\u6027\u80fd\u6709\uff1a\u9ad8\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u3001\u4f4e\u7684\u79bb\u5b50\u9762\u79ef\u6bd4\u7535\u963b\u3001\u9ad8\u7684\u7535\u5b50\u9762\u79ef\u6bd4\u7535\u963b\u3001\u9ad8\u7684\u79bb\u5b50\u9009\u62e9\u6027\u3001\u5bbd\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u3001\u597d\u7684\u5316\u5b66\u517c\u5bb9\u6027\u3001\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u3001\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u7b80\u5355\u7684\u5236\u5907\u8fc7\u7a0b\u3001\u4ef7\u683c\u4f4e\u5ec9\u3001\u6613\u6574\u5408\u548c\u73af\u5883\u53cb\u597d\u3002\u65e0\u8bba\u662f\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\u8fd8\u662f\u6709\u673a\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u5c31\u63d0\u9ad8\u4e0a\u8ff0\u6027\u80fd\u7684\u7814\u7a76\u5df2\u7ecf\u6709\u5f88\u5927\u8fdb\u6b65\u3002\u4e0b\u8868\u5217\u51fa\u4e86\u4e00\u4e9b\u5df2\u7ecf\u62a5\u9053\u7684\u56fa\u6001\u7535\u89e3\u8d28\u53ca\u5176\u6027\u80fd\uff0c\u5e76\u4e14\u4ee5\u96f7\u8fbe\u56fe\u7684\u5f62\u5f0f\u5c55\u793a\u5982\u4e0b\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66621\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u88681-1.jpg\" alt=\"\" width=\"600\" height=\"437\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u88681-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u88681-1-300x219.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u88681. \u9502\u79bb\u5b50\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u6982\u8981<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-66646\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u9898.jpg\" alt=\"\" width=\"600\" height=\"363\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u9898.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u9898-300x182.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u4e0d\u540c\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u7684\u6027\u80fd<\/strong><\/p>\n<p><strong>2.1 <\/strong><strong>\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28<\/strong><\/p>\n<p>\u56fa\u6001\u7535\u6c60\u4e2d\u4e3b\u8981\u7684\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\u5df2\u7ecf\u62a5\u9053\u7684\u7c7b\u578b\u6709\u9499\u949b\u77ff\u578b\uff0cNASICON\u578b\uff0c\u77f3\u69b4\u77f3\u578b\uff0c\u786b\u5316\u7269\u578b\u3002\u5178\u578b\u7684\u9499\u949b\u77ff\u56fa\u6001\u7535\u89e3\u8d28\u662fLi<sub>3x<\/sub>La<sub>2\/3 <\/sub><sub>\u2212<\/sub><sub> x<\/sub>TiO<sub>3<\/sub>\uff0c\u5177\u6709\u4f18\u5f02\u7684\u9502\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u5728\u5ba4\u6e29\u4e0b\u8fbe\u523010<sup>-3<\/sup>S\/cm\u3002\u5c3d\u7ba1\u8fd9\u79cd\u6750\u6599\u5f15\u8d77\u4e86\u5f88\u591a\u7814\u7a76\u8005\u7684\u5174\u8da3\uff0c\u4f46\u5b83\u5728\u9502\u7535\u6c60\u65b9\u9762\u7684\u5e94\u7528\u88ab\u8ba4\u4e3a\u662f\u4e0d\u5408\u9002\u7684\uff0c\u56e0\u4e3a\u6750\u6599\u548c\u91d1\u5c5e\u9502\u7684\u63a5\u89e6\u4f1a\u51cf\u5c11Ti<sup>4+<\/sup>\u6570\u91cf\u3002NASICON\u578b\u590d\u5408\u7269\u5728\u5341\u4e5d\u4e16\u7eaa\u516d\u5341\u5e74\u4ee3\u9996\u6b21\u88ab\u53d1\u73b0\uff0c\u7ecf\u8fc7Na <sub>1+x<\/sub>Zr<sub>2<\/sub>Si<sub>x<\/sub>P<sub>3 <\/sub><sub>\u2212<\/sub><sub> x<\/sub>O<sub>12<\/sub>\u7c7b\u6750\u6599\u7684\u53d1\u5c55\u540e\u57281976\u5e74\u547d\u540d\u4e3a\u201cNASICON\u201d\u3002NASICON\u578b\u6750\u6599\u88ab\u8ba4\u4e3a\u662f\u5f88\u9002\u5408\u9ad8\u538b\u56fa\u6001\u7535\u89e3\u8d28\u7535\u6c60\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u3002\u77f3\u69b4\u77f3\u578b\u6750\u6599\u7684\u901a\u5f0f\u4e3aA<sub>3<\/sub>B<sub>2<\/sub>Si<sub>3<\/sub>O<sub>12<\/sub>\uff0cA\u9633\u79bb\u5b50\u548cB\u9633\u79bb\u5b50\u5206\u522b\u662f\u516b\u914d\u4f4d\u548c\u516d\u914d\u4f4d\uff0c\u4ece1969\u5e74\u7b2c\u4e00\u6b21\u53d1\u73b0Li<sub>3<\/sub>M<sub>2<\/sub>Ln<sub>3<\/sub>O<sub>12<\/sub> (M = W \u6216\u8005Te)\u540e\uff0c\u4e00\u7cfb\u5217\u77f3\u69b4\u77f3\u578b\u6750\u6599\u88ab\u76f8\u7ee7\u53d1\u73b0\uff0c\u5178\u578b\u7684\u7cfb\u7edf\u6709Li<sub>5<\/sub>La<sub>3<\/sub>M<sub>2<\/sub>O<sub>12<\/sub> (M = Nb \u6216Ta), Li<sub>6<\/sub>ALa<sub>2<\/sub>M<sub>2<\/sub>O<sub>12<\/sub> (A = Ca, Sr \u6216 Ba; M = Nb \u6216 Ta), Li<sub>5.5<\/sub>La<sub>3<\/sub>M<sub>1.75<\/sub>B<sub>0.25<\/sub>O<sub>12<\/sub> (M = Nb \u6216 Ta; B = In \u6216 Zr) \u548c\u7acb\u65b9\u6676\u7cfb Li<sub>7<\/sub>La<sub>3<\/sub>Zr<sub>2<\/sub>O<sub>12<\/sub> \u548c Li<sub>7.06<\/sub>M<sub>3<\/sub>Y<sub>0.06<\/sub>Zr<sub>1.94<\/sub>O<sub>12<\/sub> (M = La, Nb \u6216 Ta)\uff0c\u5176\u4e2dLi<sub>6.5<\/sub>La<sub>3<\/sub>Zr<sub>1.75<\/sub>Te<sub>0.25<\/sub>O<sub>12<\/sub>\u5728\u5ba4\u6e29\u4e0b\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u9ad8\u8fbe1.02 \u00d7 10<sup>\u2212<\/sup><sup>3<\/sup> S \/cm\u3002\u57281986\u5e74\u5f00\u59cb\u7814\u7a76\u786b\u5316\u7269\u578b\u7684\u56fa\u6001\u7535\u89e3\u8d28Li<sub>2<\/sub>S-SiS<sub>2<\/sub>\u7cfb\u7edf\uff0c\u6b64\u540e\u8be5\u7cfb\u7edf\u5f00\u59cb\u88ab\u5e7f\u6cdb\u7814\u7a76\uff0c\u62a5\u9053\u4e2d\u7684\u6700\u9ad8\u7684\u5bfc\u7535\u6027\u6750\u6599\u662f\u63ba\u6742Li<sub>3<\/sub>PO<sub>4<\/sub>\u7684Li<sub>2<\/sub>S-SiS<sub>2<\/sub>\u4f53\u7cfb\uff0c\u5bfc\u7535\u6027\u53ef\u8fbe6.9 \u00d7 10<sup>\u2212<\/sup><sup>4<\/sup> S\/cm\u3002<\/p>\n<p><strong>2.2 <\/strong><strong>\u805a\u5408\u7269\u548c\u590d\u5408\u7269\u56fa\u6001\u7535\u89e3\u8d28<\/strong><\/p>\n<p>\u9502\u7535\u6c60\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u53d1\u5c55\u53ef\u4ee5\u5206\u4e3a\u4e09\u4e2a\u7c7b\u522b:\u5e72\u71e5\u7684\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\uff0c\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u548c\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\u3002\u7136\u800c\uff0c\u968f\u7740\u51dd\u80f6\u805a\u5408\u7269\u4e0d\u518d\u662f\u56fa\u6001\uff0c\u56e0\u6b64\u4e0d\u5728\u8fd9\u91cc\u8ba8\u8bba\u3002\u5728\u5e72\u71e5\u7684\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28\u4e2d\uff0c\u805a\u5408\u7269\u4e3b\u4f53\u4e0e\u9502\u76d0\u4f5c\u4e3a\u56fa\u4f53\u6eb6\u5242(\u6ca1\u6709\u4efb\u4f55\u6db2\u4f53)\uff0c\u4f46\u662f\u5e72\u71e5\u7684\u56fa\u6001\u805a\u5408\u7269\u79bb\u5b50\u5bfc\u7535\u6027\u5f88\u5dee\u3002\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\u662f\u7531\u9676\u74f7\u586b\u6599\u96c6\u6210\u5230\u6709\u673a\u805a\u5408\u7269\u4e3b\u4f53\u4e0a, \u901a\u8fc7\u964d\u4f4e\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u6765\u5e2e\u52a9\u63d0\u9ad8\u5bfc\u7535\u7387\u3002\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u805a\u5408\u7269\u4e3b\u9898\u901a\u5e38\u662fPEO\u3001PAN\u3001PMMA\u3001PVC\u6216\u8005PVDF\uff0c\u5176\u4e2d\uff0cPEO\u7684\u5e94\u7528\u6700\u4e3a\u5e7f\u6cdb\u3002<\/p>\n<p><strong>2.3 <\/strong><strong>\u8584\u819c\u56fa\u6001\u7535\u89e3\u8d28<\/strong><\/p>\n<p>\u4e00\u4e9b\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u53ef\u4ee5\u901a\u8fc7\u6c14\u76f8\u6c89\u79ef\u6280\u672f\u5f97\u5230\u8d85\u8584\u7684\u8584\u819c\uff0c\u6bd4\u5982\u8109\u51b2\u6fc0\u5149\u6c89\u79ef\u6280\u672f\u3001\u65e0\u7ebf\u7535\u9891\u6e85\u5c04\u6280\u672f\u4ee5\u53ca\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6280\u672f\u3002\u8584\u819c\u56fa\u6001\u7535\u4ecb\u8d28\u7684\u53d1\u5c55\u4ece\u5341\u4e5d\u4e16\u7eaa\u516b\u5341\u5e74\u4ee3\u5f00\u59cb\uff0c\u6700\u5f00\u59cb\u7684\u6750\u6599\u662fLi<sub>12<\/sub>Si<sub>3<\/sub>P<sub>2<\/sub>O<sub>20<\/sub>, Li<sub>4<\/sub>P<sub>2<\/sub>S<sub>7<\/sub> \u548c Li<sub>3<\/sub>PO<sub>4<\/sub>\u2013P<sub>2<\/sub>S<sub>5<\/sub>\u3002\u5728\u5341\u4e5d\u4e16\u7eaa\u4e5d\u5341\u5e74\u4ee3\uff0c\u6a61\u6811\u5cad\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u62a5\u9053\u4e86\u4e00\u79cdLiPON\u57fa\u8584\u819c\u56fa\u6001\u7535\u89e3\u8d28\u53d6\u5f97\u7684\u5de8\u5927\u8fdb\u5c55\uff0c\u8fd9\u79cd\u7535\u89e3\u8d28\u662f\u8584\u819c\u7535\u6c60\u7684\u6807\u51c6\u7535\u89e3\u8d28\u3002\u6700\u8fd1\uff0c\u4e00\u4e9b\u4ee5\u787c\u9178\u9502\u73bb\u7483\u3001\u78f7\u9178\u9502\u73bb\u7483\u3001\u787c\u78f7\u9178\u9502\u73bb\u7483\u4e3a\u57fa\u7684\u5176\u4ed6\u7cfb\u5217\u8584\u819c\u56fa\u6001\u7535\u4ecb\u8d28\u88ab\u8ba4\u4e3a\u662f\u4ee3\u66ffLiPON\u7684\u6709\u529b\u5019\u9009\u8005\uff0c\u539f\u5b50\u5c42\u6c89\u79ef\u6280\u672f\u4e5f\u5df2\u7ecf\u6210\u4e3a\u5236\u5907\u7edf\u4e00\u9002\u5f62\u8584\u819c\u7684\u9996\u9009\u6280\u672f\u3002<\/p>\n<p><strong>3.\u56fa\u6001\u7535\u89e3\u8d28\u7535\u6c60<\/strong><\/p>\n<p><strong>3.1 <\/strong><strong>\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n<p>\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u53ef\u4ee5\u63d0\u4f9b\u9ad8\u4e8e\u4f20\u7edf\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u88ab\u89c6\u4e3a\u4e0b\u4e00\u4ee3\u6700\u91cd\u8981\u7684\u50a8\u80fd\u6280\u672f\u4e4b\u4e00\u3002\u56fa\u6001\u7535\u89e3\u8d28\u4e0d\u4ec5\u80fd\u4fdd\u6301\u9502\u79bb\u5b50\u5bfc\u7535\u6027\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u7535\u6c60\u5206\u79bb\u5668\u3002\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u548c\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u4f3c\uff08\u6bd4\u5982\u9502\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u786b\u5316\u7269\uff09\uff1b\u5927\u591a\u6570\u8d1f\u6781\u6750\u6599\u662f\u9502\u91d1\u5c5e\u3001\u9502\u5408\u91d1\u548c\u77f3\u58a8\u70ef\u3002\u6839\u636e\u56fa\u6001\u7535\u89e3\u8d28\u7684\u4f7f\u7528\uff0c\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u53ef\u4ee5\u5206\u4e3a\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\u7535\u6c60\u548c\u805a\u5408\u7269\u7535\u6c60\u3002\u73b0\u5728\u9700\u8981\u89e3\u51b3\u7684\u51e0\u4e2a\u5173\u952e\u7684\u6311\u6218\u4f9d\u7136\u5b58\u5728\uff1a\u4f8b\u5982\uff0c\u7535\u6781\u6750\u6599\u4f53\u79ef\u53d8\u5316\uff0c\u5927\u754c\u9762(\u7535\u6781\/\u7535\u89e3\u8d28)\u7535\u963b\uff0c\u7535\u6781\u6d3b\u6027\u6750\u6599\u7684\u4f4e\u8d1f\u8f7d\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u7b49\u3002\u5176\u4e2d\u6025\u9700\u89e3\u51b3\u7684\u4e00\u4e2a\u91cd\u8981\u95ee\u9898\u662f\u5982\u4f55\u63d0\u9ad8\u7535\u6781\u548c\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u4e4b\u95f4\u7684\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u7684\u4e3b\u8981\u76ee\u6807\u662f\u5728\u4f4e\u6210\u672c\u60c5\u51b5\u4e0b\uff0c\u4e0e\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u6bd4\u5b9e\u73b0\u66f4\u597d\u7684\u5faa\u73af\u6027\u80fd\u548c\u5b89\u5168\u6027\u80fd\uff0c\u540c\u65f6\u4fdd\u6301\u76f8\u540c\u6216\u66f4\u9ad8\u7684\u529f\u7387\u548c\u80fd\u91cf\u5bc6\u5ea6\u3002\u7136\u800c\u8981\u5b9e\u73b0\u8fd9\u4e9b\u76ee\u6807\u662f\u4e00\u9879\u8270\u5de8\u7684\u6311\u6218\uff0c\u514b\u670d\u8fd9\u4e9b\u95ee\u9898\u7684\u5173\u952e\u662f\u5728\u56fa\u4f53\u7535\u6781\u548c\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u5236\u9020\u51fa\u6709\u5229\u7684\u56fa\u4f53\/\u56fa\u4f53\u754c\u9762\uff0c\u540c\u65f6\u9700\u8981\u8003\u8651\u4e09\u4e2a\u65b9\u9762\uff1a\u56fa\u6001\u6750\u6599\u7684\u53ef\u6e7f\u6027\u3001\u56fa\u4f53\/\u56fa\u4f53\u754c\u9762\u7684\u7a33\u5b9a\u6027\u548c\u754c\u9762\u4e4b\u95f4\u79bb\u5b50\u7684\u4f20\u8f93\u901f\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66680\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/1-1-3.png\" alt=\"\" width=\"600\" height=\"525\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/1-1-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/1-1-3-300x263.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u5168\u56fa\u6001\u7535\u6c60<\/strong><\/p>\n<p><strong>3.2 <\/strong><strong>\u6db2\u6001\u6c14\u6001\u7535\u6781\u4e2d\u7684\u56fa\u6001\u7535\u89e3\u8d28<\/strong><\/p>\n<p><strong>3.2.1 <\/strong><strong>\u9502\u7a7a\u6c14\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u7a7a\u6c14\u7535\u6c60\u662f\u57fa\u4e8e\u9502\u9633\u6781\u548c\u7a7a\u6c14\u9634\u6781\u7684\u9ad8\u7535\u5bb9\u7535\u6c60\uff0c\u5176\u9502\u6c27\u6c14\u7535\u5316\u5b66\u5bf9\u6709\u9ad8\u7684\u5de5\u4f5c\u7535\u538b\uff0c\u53ef\u4ee5\u4ea7\u751f\u4e00\u4e2a\u5f02\u5e38\u9ad8\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff0c\u53ef\u5145\u7535\u9502\u6c27\u7535\u6c60\u7b2c\u4e00\u6b21\u62a5\u9053\u662f\u57281987\u5e74\uff0c\u5176\u914d\u7f6e\u7c7b\u4f3c\u4e8e\u56fa\u6001\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\u3002\u7531\u4e8e\u662f\u975e\u8d28\u5b50\u7535\u89e3\u8d28\uff0c\u9502\u6c27\u7535\u6c60\u5b58\u5728\u4e00\u4e9b\u95ee\u9898\uff0c\u6bd4\u5982\u5ba4\u6e29\u4e0b\u975e\u6c34\u6eb6\u5242\u7535\u89e3\u8d28\u7684\u9000\u5316\u548c\u4e0d\u6eb6\u7684\u653e\u7535\u4ea7\u7269\u5bfc\u81f4\u591a\u5b54\u9634\u6781\u7a7a\u6c14\u6269\u6563\u51fa\u73b0\u5835\u585e\u3002\u4e3a\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u548c\u9502\u7a7a\u6c14\u7535\u6c60\u90fd\u63d0\u51fa\u4e86\u201c\u53cc\u7535\u89e3\u8d28\u201d\u6982\u5ff5\uff0c\u5728\u6df7\u5408\u52a8\u529b\u7535\u6c60\u4e2d\uff0c\u6709\u673a\u7535\u89e3\u8d28\u7528\u4e8e\u9633\u6781\u4e00\u4fa7\u7684\u6c34\u7535\u89e3\u8d28(\u9633\u6781\u7535\u89e3\u6db2)\u548c\u9634\u6781\u4e00\u4fa7(\u9634\u6781\u7535\u89e3\u6db2)\u7684\u4e24\u4e2a\u56fa\u4f53\u7535\u89e3\u8d28\u7531\u819c\u9694\u5206\u5f00\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66681\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/2-1-1.png\" alt=\"\" width=\"600\" height=\"283\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/2-1-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/2-1-1-300x142.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>4. <\/strong><strong>\u53cc\u7535\u89e3\u8d28\u9502\u7a7a\u6c14\u7535\u6c60<\/strong><\/p>\n<p><strong>3.2.2 <\/strong><strong>\u9502\u786b\u7535\u6c60<\/strong><\/p>\n<p>\u57fa\u4e8e\u975e\u6c34\u9502\u786b\u5316\u5b66\u7684\u53ef\u5145\u7535\u7535\u6c60\u7cfb\u7edf\u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u91cc\u5f97\u5230\u4e86\u5f88\u5927\u5173\u6ce8\uff0c\u9633\u6781\u7535\u5bb9\u67093800mA\/g\uff0c\u9634\u6781\u7535\u5bb9\u67091675 mA\/g\uff0c\u9502\u786b\u7535\u6c60\u7cfb\u7edf\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u53ef\u9ad8\u8fbe2600Wh\/kg\uff0c\u5f00\u8def\u7535\u538b\u662f2V\u3002\u56e0\u4e3a\u9634\u6781\u4f7f\u7528\u5929\u7136\u786b\u53ef\u4ee5\u964d\u4f4e\u6210\u672c\uff0c\u56e0\u6b64\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u786b\u7535\u6c60\u6210\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u5b9e\u9645\u5e94\u7528\u7684\u6709\u529b\u5019\u9009\u4eba\uff0c\u5305\u62ec\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u3001\u7535\u52a8\u6c7d\u8f66\u548c\u7535\u7f51\u50a8\u80fd\u7b49\u3002\u5c3d\u7ba1\u901a\u8fc7\u591a\u5e74\u7684\u7814\u7a76\u9502\u786b\u7535\u6c60\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\uff0c\u4f46\u6b64\u6280\u672f\u4ecd\u9762\u4e34\u76f8\u5f53\u5927\u7684\u6280\u672f\u6311\u6218\u3002\u4e0e\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u4e0d\u540c\uff0c\u9502\u786b\u7535\u6c60\u7cfb\u7edf\u7684\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u6d89\u53ca\u4e00\u7cfb\u5217\u53ef\u6eb6\u6027\u7684\u4e2d\u95f4\u4ea7\u54c1\uff0c\u5b83\u6eb6\u89e3\u5728\u65e0\u6c34\u7684\u7535\u89e3\u6db2\u4e2d\u5b58\u5728\u5404\u79cd\u5f62\u5f0f\u7684\u591a\u786b\u5316\u5408\u7269\u3002\u9502\u786b\u7535\u6c60\u5728\u5de5\u4f5c\u6761\u4ef6\u4e0b\uff08\u5145\u653e\u7535\u8fc7\u7a0b\uff09\u53ef\u6eb6\u6027\u805a\u786b\u5316\u7269\u79cd\u7c7b\u901a\u8fc7\u9634\u6781\u8fc1\u79fb\u5230\u591a\u5b54\u9633\u6781\u4e0e\u91d1\u5c5e\u9502\u53d1\u751f\u5316\u5b66\u53cd\u5e94\u3002\u8fd9\u79cd\u201c\u805a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u201d\u884c\u4e3a\u4e25\u91cd\u964d\u4f4e\u4e86\u786b\u7535\u6781\u6d3b\u8dc3\u7684\u7684\u53ef\u884c\u6027\uff0c\u4f1a\u964d\u4f4e\u7535\u6c60\u7684\u5faa\u73af\u6548\u7387\u5e76\u5bfc\u81f4\u7535\u5bb9\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u8870\u9000\u3002\u6b64\u5916\uff0c\u5982\u679c\u4f7f\u7528\u4f20\u7edf\u7684\u591a\u5b54\u9694\u819c\uff0c\u9502\u91d1\u5c5e\u9633\u6781\u9502\u786b\u7535\u6c60\u4e0d\u53ef\u907f\u514d\u5730\u4f1a\u5bfc\u81f4\u591a\u4f59\u7684\u9502\u679d\u6676\u5f62\u6210\u95ee\u9898\uff0c\u56e0\u6b64\u5b58\u5728\u5b89\u5168\u9690\u60a3\u3002\u8fd9\u4e24\u4e2a\u95ee\u9898\u2014\u2014\u805a\u786b\u5316\u7269\u7a7f\u68ad\u548c\u679d\u6676\u9502\u5bfc\u81f4\u7535\u6c60\u77ed\u8def\u2014\u2014\u662f\u9502\u786b\u7535\u6c60\u6280\u672f\u6700\u91cd\u8981\u7684\u6311\u6218\u3002\u7814\u7a76\u8005\u4eec\u5c31\u89e3\u51b3\u805a\u786b\u5316\u7269\u7a7f\u68ad\u7684\u95ee\u9898\u505a\u51fa\u4e86\u8bb8\u591a\u52aa\u529b\uff0c\u6bd4\u5982\u5728\u9634\u6781\u5305\u88c5\u805a\u786b\u5316\u7269\uff0c\u8fd8\u6709\u65b0\u7684\u9634\u6781\u7ed3\u6784\u7684\u53d1\u5c55\uff0c\u8fdb\u4e00\u6b65\u53d1\u5c55\u7535\u6c60\u914d\u7f6e\u6280\u672f\uff0c\u548c\u589e\u5f3a\u805a\u786b\u5316\u7269\u4e0e\u9634\u6781\u77e9\u9635\u7684\u76f8\u4e92\u4f5c\u7528\u7b49\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u53ea\u80fd\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u7f13\u89e3\u805a\u786b\u5316\u7269\u7684\u6269\u6563\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66682\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/3-1-1.png\" alt=\"\" width=\"600\" height=\"328\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/3-1-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/3-1-1-300x164.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>5. <\/strong><strong>\u56fa\u6001\u7535\u89e3\u8d28\u57fa\u9502\u786b\u7535\u6c60<\/strong><\/p>\n<p><strong>3.2.3 <\/strong><strong>\u9502\u6eb4\u7535\u6c60<\/strong><\/p>\n<p>\u6eb4\u4f5c\u4e3a\u6db2\u6001\u9634\u6781\u7684\u9ad8\u8d28\u91cf\u80fd\u91cf\u5bc6\u5ea6\u5f15\u5bfc\u4e86\u9502\u6eb4\u7535\u6c60\u7684\u51fa\u73b0\uff0c\u81f3\u4eca\u5df2\u7ecf\u62a5\u9053\u4e86\u4e00\u4e9b\u4e0d\u540c\u7c7b\u578b\u7684\u53ef\u5145\u7535\u9502\u6eb4\u7535\u6c60\uff0c\u901a\u5e38\u662f\u4f7f\u7528\u6eb4\u5316\u7269\u6eb6\u6db2\u9634\u6781\uff0c\u9502\u91d1\u5c5e\u9633\u6781\u548c\u56fa\u6001\u7535\u89e3\u8d28\u7ec4\u88c5\u800c\u6210\u3002\u9502\u79bb\u5b50\u5bfc\u7535\u56fa\u6001\u7535\u89e3\u8d28\u7684\u53d1\u5c55\u6709\u52a9\u4e8e\u9502\u6eb4\u7535\u6c60\u7684\u53d1\u5c55\uff0c\u56e0\u4e3a\u8981\u6c42\u6db2\u6001\u6eb4\u548c\u9ad8\u6d3b\u6027\u9502\u91d1\u5c5e\u9633\u6781\u5b8c\u5168\u5206\u79bb\u3002\u901a\u5e38\uff0c\u9502\u6eb4\u7535\u6c60\u7cfb\u7edf\u5305\u62ec\u65e0\u6c34\u9633\u6781\u7535\u89e3\u6db2\u6765\u5b8c\u6210\u9633\u6781\u53cd\u5e94\uff0c\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u65e0\u6c34\u9633\u6781\u7535\u89e3\u6db2\u4e2d\u7684\u9502\u91d1\u5c5e\u88ab\u6c27\u5316\u6210\u9502\u79bb\u5b50\uff0c\u901a\u8fc7\u9502\u79bb\u5b50\u5bfc\u7535\u56fa\u6001\u7535\u89e3\u8d28\u8fc1\u79fb\u5230\u9634\u6781\uff0c\u56e0\u6b64\u7535\u5b50\u901a\u8fc7\u5916\u7535\u8def\u5230\u8fbe\u9634\u6781\u3002\u5728\u9634\u6781\u8868\u9762\uff0c\u56e0\u4e3a\u8fc1\u5165\u7684\u7535\u5b50\uff0c\u6eb4\u51cf\u5c11\u5f62\u6210\u6eb4\u79bb\u5b50(Br<sup>\u2212<\/sup>)\uff0c\u7d27\u968f\u5176\u540e\u4e0e\u6eb4\u5feb\u901f\u7edc\u5408\u5f62\u6210\u7a33\u5b9a\u7684\u4e09\u6eb4\u5316\u7269\u79bb\u5b50(Br<sup>3\u2212<\/sup>)\uff0c\u5145\u7535\u8fc7\u7a0b\u4e2d\u53cd\u5e94\u662f\u53ef\u9006\u7684\u3002\u76f4\u5230\u6700\u8fd1\uff0c\u9502\u6eb4\u7535\u6c60\u9762\u4e34\u7684\u4e3b\u8981\u6311\u6218\u662f\u56fa\u6001\u7535\u89e3\u8d28\u9676\u74f7\u819c\u5728\u7535\u6c60\u7ec4\u88c5\u4e2d\u7684\u9000\u5316\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66683\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/5-1-1.png\" alt=\"\" width=\"600\" height=\"288\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/5-1-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/5-1-1-300x144.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>6. <\/strong><strong>\u56fa\u6001\u9502\u6eb4\u7535\u6c60<\/strong><\/p>\n<p><strong>3.3 <\/strong><strong>\u4ecb\u8d28\u79bb\u5b50\u56fa\u6001\u7535\u89e3\u8d28\u7535\u6c60<\/strong><\/p>\n<p>\u4ece\u5b9e\u7528\u548c\u7ecf\u6d4e\u7684\u89c2\u70b9\u6765\u770b\u7535\u5316\u5b66\u50a8\u80fd\u6280\u672f\uff0c\u6db2\u6001\u7535\u6c60\u7cfb\u7edf\u901a\u5e38\u901a\u8fc7\u4e00\u4e2a\u6574\u4f53\u4f18\u52bf\u4f18\u4e8e\u65e0\u6c34\u7535\u6c60\u7cfb\u7edf\uff0c\u6bd4\u5982\u7535\u6c60\u7cfb\u7edf\u7684\u7ef4\u62a4\uff0c\u7535\u6c60\u7ec4\u4ef6\u7684\u64cd\u4f5c\u5b89\u5168\u6027\u3001\u6210\u672c\u548c\u53ef\u9760\u6027\u3002\u4f9d\u636e\u6750\u6599\u7684\u6210\u672c\u548c\u7535\u5316\u5b66\u80fd\u91cf\u8f6c\u6362\uff0c\u5730\u7403\u4e0a\u6709\u8bb8\u591a\u4e30\u5bcc\u6216\u5bb9\u6613\u5408\u6210\u7684\u6750\u6599\uff0c\u5728\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u4f4e\u6210\u672c\u548c\u5b89\u5168\u6db2\u6001\u7535\u6c60\u7535\u6781\u7684\u5f00\u53d1\u4e2d\u5177\u6709\u5f88\u597d\u7684\u524d\u666f\uff0c\u4e0d\u8fc7\uff0c\u4f7f\u7528\u4f20\u7edf\u7684\u591a\u5b54\u805a\u5408\u7269\u9694\u819c\u7684\u7535\u6c60\uff0c\u5728\u4e24\u4e2a\u7535\u6781\u4e4b\u95f4\u6db2\u4f53\u6216\u6c14\u4f53\u7684\u5316\u5b66\u7535\u6781\u6750\u6599\u7684\u4ea4\u53c9,\u4f1a\u5bfc\u81f4\u81ea\u653e\u7535\u548c\u6548\u7387\u964d\u4f4e\u3002\u8fd9\u4e9b\u95ee\u9898\u53ef\u4ee5\u901a\u8fc7\u4f7f\u7528\u56fa\u4f53\u7535\u89e3\u8d28\u5206\u79bb\u5668\u6765\u89e3\u51b3\uff0c\u7136\u800c\uff0c\u76ee\u524d\u5ba4\u6e29\u4e0b\u56fa\u4f53\u7535\u89e3\u8d28\u4ec5\u9650\u4e8e\u9502\u548c\u94a0\u79bb\u5b50\u5bfc\u7535\u6750\u6599\uff0c\u4e3b\u8981\u7528\u5728\u975e\u6c34\u9502\u6216\u94a0\u57fa\u7684\u7535\u6c60\u4e2d\u3002\u4e8c\u4ef7\u79bb\u5b50\u57fa\u6216\u4e09\u4ef7\u79bb\u5b50\u57fa\u9633\u6781\u5316\u5b66\u53cd\u5e94(\u4f8b\u5982\u94c1\uff0c\u950c\u548c\u94dd)\u9002\u7528\u4e8e\u6c34\u7cfb\u7535\u6c60\uff0c\u4f46\u56fa\u6001\u7535\u89e3\u8d28\u80fd\u591f\u8fd0\u8f93\u4e8c\u4ef7\u6216\u4e09\u4ef7\u79bb\u5b50\u5374\u56e0\u4e3a\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u8377\u548c\u8f83\u91cd\u7684\u79bb\u5b50\u8d28\u91cf\u800c\u51e0\u4e4e\u4e0d\u53ef\u7528\uff0c\u56e0\u6b64\uff0c\u7528\u5f53\u524d\u53ef\u7528\u78b1\u91d1\u5c5e\u5bfc\u7535\u56fa\u6001\u7535\u89e3\u8d28\u53d1\u5c55\u5b8c\u5168\u6c34\u7cfb\u7535\u6c60(\u542b\u6c34\u7535\u89e3\u6db2\u9633\u6781\u548c\u9634\u6781)\u4f3c\u4e4e\u662f\u4e0d\u53ef\u80fd\u7684\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u4e2d\uff0c\u9502\u79bb\u5b50\u5bfc\u7535\u56fa\u6001\u7535\u89e3\u8d28\u5df2\u7ecf\u96c6\u6210\u5230\u6df7\u5408\u7535\u89e3\u8d28\u7535\u6c60\u4e2d(\u975e\u6c34\u7535\u89e3\u8d28\u7535\u6c60\u9633\u6781\u7535\u89e3\u6db2\u548c\u6c34\u9634\u6781\u7535\u89e3\u6db2)\uff0c\u7814\u7a76\u8005\u7684\u56e2\u961f\u6700\u8fd1\u63d0\u51fa\u4e86\u4e00\u4e2a\u72ec\u7279\u7684\u201c\u4ecb\u8d28\u79bb\u5b50\u201d\u7684\u6c34\u7cfb\u7535\u6c60\uff0c\u901a\u8fc7\u5904\u7406\u5f53\u524d\u53ef\u7528\u78b1\u91d1\u5c5e\u79bb\u5b50\u56fa\u6001\u7535\u89e3\u8d28\u4f5c\u4e3a\u6b63\u6781(\u9633\u6781\u7535\u89e3\u6db2)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66627\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/7-1-1.jpg\" alt=\"\" width=\"600\" height=\"1195\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/7-1-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/7-1-1-151x300.jpg 151w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/7-1-1-514x1024.jpg 514w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>7. <\/strong><strong>\u4f7f\u7528\u4ecb\u8d28\u79bb\u5b50\u56fa\u6001\u7535\u89e3\u8d28\u7684\u6db2\u4f53\u7535\u6c60<\/strong><\/p>\n<p>\u6587\u4e2d\u5df2\u7ecf\u63cf\u8ff0\u4e86\u56fa\u6001\u7535\u89e3\u8d28\u53c2\u4e0e\u7684\u5404\u79cd\u7535\u6c60\u5316\u5b66\u53cd\u5e94\uff0c\u5305\u62ec\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\uff0c\u9502\u786b\u7535\u6c60\u548c\u9502\u6eb4\u7535\u6c60\uff0c\u4ee5\u53ca\u56fa\u6001\u7535\u89e3\u8d28\u5728\u6c34\u7cfb\u7535\u6c60\u4e2d\u7684\u53ef\u884c\u6027\u3002\u4f5c\u8005\u5c31\u7535\u6c60\u7cfb\u7edf\u76ee\u524d\u53d1\u5c55\u9636\u6bb5\u7684\u4e00\u4e9b\u6027\u80fd\u6307\u6807(\u5373\u80fd\u91cf\u5bc6\u5ea6\u3001\u529f\u7387\u5bc6\u5ea6\u3001\u5faa\u73af\u5bff\u547d\u548c\u5176\u4ed6\u76f8\u5173\u53c2\u6570)\u8fdb\u884c\u4e86\u603b\u7ed3\uff0c\u5982\u4e0b\u88682\u4e2d\u6240\u793a\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-66628\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u88682-1.jpg\" alt=\"\" width=\"600\" height=\"377\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u88682-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u88682-1-300x189.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u88682. \u5404\u79cd\u56fa\u6001\u7535\u89e3\u8d28\u7535\u6c60\u6027\u80fd\u53c2\u6570\u6982\u8981<\/strong><\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u76ee\u524d,\u9ad8\u6e29\u94a0\u786b\u7535\u6c60\u662f\u4f7f\u7528\u56fa\u6001\u7535\u89e3\u8d28\u552f\u4e00\u53ef\u884c\u7684\u50a8\u80fd\u6280\u672f\uff0c\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u5df2\u63a8\u884c\u591a\u5e74\uff0c\u5e76\u4e14\u76f8\u6bd4\u4e8e\u6db2\u6001\u6709\u673a\u7535\u89e3\u8d28\u7684\u5546\u4e1a\u9502\u79bb\u5b50\u7535\u6c60\u6709\u90e8\u5206\u91cd\u8981\u7684\u4f18\u52bf \uff08\u5305\u62ec\u63d0\u9ad8\u5b89\u5168\u6027\uff0c\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u66f4\u5e7f\u6cdb\u7684\u64cd\u4f5c\u6e29\u5ea6\uff09\u3002\u63d0\u9ad8\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7684\u53ef\u9760\u6027\u4f7f\u5176\u53ef\u4ee5\u6709\u5927\u89c4\u6a21\u7684\u5b9e\u9645\u5e94\u7528\uff0c\u7136\u800c\u5bf9\u4e8e\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u5173\u952e\u7684\u6311\u6218\u4f9d\u7136\u5b58\u5728\uff0c\u6bd4\u5982\u7535\u6781\u7684\u4f53\u79ef\u53d8\u5316\u3001\u754c\u9762\u7535\u8377\u8f6c\u79fb\u7535\u963b\u3001\u7075\u6d3b\u6027\u548c\u8f83\u5dee\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u7b49\u95ee\u9898\u3002\u805a\u5408\u7269\u56fa\u6001\u7535\u89e3\u8d28\u514b\u670d\u4e86\u65e0\u673a\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u8fd9\u4e9b\u5c40\u9650\u6027\uff0c\u4e5f\u5c31\u662f\u8bf4\uff0c\u5b83\u4eec\u6709\u826f\u597d\u7684\u7075\u6d3b\u6027\u5e76\u4e14\u80fd\u4e0e\u7535\u6781\u7d27\u5bc6\u63a5\u89e6\uff0c\u4f46\u662f\u5b83\u4eec\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u5c0f\u3001\u79bb\u5b50\u7535\u5bfc\u7387(\u5ba4\u6e29)\u5dee\uff0c\u4e5f\u662f\u76ee\u524d\u963b\u788d\u5168\u56fa\u6001\u805a\u5408\u7269\u9502\u79bb\u5b50\u7535\u6c60\u53d1\u5c55\u7684\u539f\u56e0\u3002\u603b\u7684\u6765\u8bf4\uff0c\u76ee\u524d\u6709\u7528\u7684\u52aa\u529b\u662f\u9f13\u52b1\u7814\u7a76\u57fa\u4e8e\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7535\u6c60\uff0c\u5b9e\u73b0\u56fa\u6001\u7535\u89e3\u8d28\u5177\u6709\u5fc5\u8981\u7684\u53c2\u6570\uff0c\u4e0d\u4ec5\u8981\u80fd\u6ee1\u8db3\u65b0\u7535\u6c60\u7684\u5316\u5b66\u53cd\u5e94\u5e76\u4e14\u5ec9\u4ef7\uff0c\u8fd8\u8981\u5177\u6709\u5148\u8fdb\u7684\u7535\u6c60\u7cfb\u7edf\uff0c\u5728\u672a\u6765\u53ef\u4ee5\u5f7b\u5e95\u6539\u53d8\u53ef\u5145\u7535\u7535\u6c60\u9886\u57df\uff0c\u5e76\u63d0\u4f9b\u826f\u597d\u7684\u5b89\u5168\u6027\uff0c\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u957f\u65f6\u95f4\u7684\u9759\u6001\u548c\u52a8\u6001\u7a33\u5b9a\u6027\uff0c\u6ca1\u6709\u81ea\u653e\u7535\u4e14\u5faa\u73af\u5bff\u547d\u957f\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/www.nature.com\/articles\/natrevmats2016103\" target=\"_blank\">Lithium battery chemistries enabled by solid-state electrolytes.<\/a>( Nature Reviews Materials, 2017, DOI:\u00a010.1038\/natrevmats.2016.103)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Jane915126\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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