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\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6709\u673a\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\uff08\u4ee5\u4e0b\u7b80\u79f0HOIPs\uff09\u7531\u4e0d\u540c\u7684\u6210\u5206\u7ec4\u6210\uff0c\u8fd9\u4e9b\u7ec4\u6210\u5305\u62ec\u5364\u5316\u7269\u7c7b\u3001\u7532\u9178\u76d0\u3001\u6c30\u5316\u7269\u3001\u4e8c\u6c30\u80fa\u4ee5\u53ca\u4e8c\u6c30\u57fa\u91d1\u5c5e\u9178\u76d0\u51e0\u7c7b\u3002\u8fd9\u4e9b\u6750\u6599\u5177\u6709\u5171\u540c\u7684\u7279\u5f81\uff0c\u5982\u5178\u578b\u7684ABX3<\/sub>\u9499\u949b\u77ff\u6784\u578b\uff08A\u4e00\u822c\u4e3a\u6709\u673a\u80fa\uff09\u3002\u5c3d\u7ba1\u5176\u5b83\u7684\u9499\u949b\u77ff\u6750\u6599\u4e5f\u5177\u6709\u4e0d\u540c\u7684\u7269\u7406\u6027\u80fd\uff0c\u4f46\u76ee\u524d\u5927\u90e8\u5206\u7684\u7814\u7a76\u96c6\u4e2d\u4e8e\u91d1\u5c5e\u5364\u5316\u7269\u7c7b\u7684HOIPs\uff0c\u8be5\u7c7b\u6750\u6599\u5728\u592a\u9633\u80fd\u7535\u6c60\u4ee5\u53ca\u5149\u7535\u5668\u4ef6\u7684\u8fd0\u7528\u4e0a\u7a81\u663e\u51fa\u4e86\u4f18\u826f\u7684\u6027\u80fd\u3002<\/p>\n

\u5317\u4eac\u65f6\u95f42017\u5e742\u67087\u65e5\uff0c\u6765\u81ea\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u7684\u674e\u4f1f\u6559\u6388\u3001\u5317\u4eac\u5927\u5b66\u7684\u9ad8\u677e\u6559\u6388\u3001\u5251\u6865\u5927\u5b66\u7684Richard H. Friend\u4ee5\u53caAnthony K. Cheetham\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u5728Nature Reviews Materials<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cChemically diverse and multifunctional hybrid organic\u2013inorganic perovskites\u201d<\/strong>\u7684\u7efc\u8ff0\u3002\u8fd9\u7bc7\u7efc\u8ff0\u91cd\u70b9\u8ba8\u8bba\u4e86\u6709\u673a\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u4e2d\u8f83\u4e3a\u5e38\u89c1HOIP\u7c7b\u6750\u6599\u7684\u5316\u5b66\u53d8\u5316\u3001\u7ed3\u6784\u5dee\u5f02\u4ee5\u53ca\u5168\u9762\u7684\u7269\u7406\u6027\u8d28\uff08\u5305\u62ec\u5149\u4f0f\u7279\u6027\u3001\u4ecb\u7535\u3001\u5149\u7535\u3001\u78c1\u6027\u3001\u94c1\u7535\u3001\u94c1\u5f39\u548c\u591a\u6027\uff09\u3002<\/p>\n


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<\/p>\n

\u56fe<\/strong>5<\/strong> \u7532\u9178\u76d0\u7c7bHOIPs\u7684\u7269\u7406\u6027\u8d28<\/strong><\/p>\n

\uff08a\uff09[DMA][Fe(HCOO)3<\/sub>]\uff08DMA=\u4e8c\u7532\u94f5\uff09\u517c\u5177\u8fdc\u7a0b\u659c\u4ea4\u53cd\u94c1\u78c1\u6027(CAFM)\u4e0e\u5b64\u7acb\u5355\u79bb\u5b50\u91cf\u5b50\u78c1\u6027(SIQM)<\/p>\n

\uff08b\uff09\u78c1\u5316\u2013\u78c1\u573a\u5f3a\u5ea6\uff08M-H\uff09\u7684\u78c1\u6ede\u56de\u7ebf\u51fa\u73b0\u4e86\u5206\u6bb5\u7684\u7279\u5f81\uff0c\u8bf4\u660e\u53d1\u751f\u4e86\u91cf\u5b50\u5171\u632f\u96a7\u7a7f\u78c1\u5316<\/p>\n

\uff08c\uff09[(CD3<\/sub>)2<\/sub>ND2<\/sub>][Co(DCOO)3<\/sub>]\u7684\u94c1\u7535\u76f8\u53d8<\/p>\n

\uff08d\uff09\u504f\u632f-\u573a\u5f3a\uff08P-E\uff09\u7684\u78c1\u6ede\u56de\u7ebf\uff08\u5728\u7279\u5b9a\u9891\u738750 Hz\u4e14\u4f4e\u4e8e\u8f6c\u53d8\u6e29\u5ea6TC<\/sub>\u7684\u6761\u4ef6\u4e0b\uff09<\/p>\n

\uff08e\uff09\u5782\u76f4\u4e8e\uff08012\uff09\u9762\u7684\u7535\u6781\u5316\u60c5\u51b5\uff08\u57280\u548c7T\u78c1\u573a\u4e0b\uff09<\/p>\n

\uff08f\uff09\u78c1\u573a\u7535\u573a\u5728\u540c\u4e00\u4e2a\u65b9\u5411\u65f6\u7684P-T\u56fe<\/p>\n

\uff08g\uff09[AZE][Mn(HCOO)3<\/sub>]\u4e0e[GUA][Mn(HCOO)3<\/sub>] (AZE=\u6c2e\u6742\u73af\u4e01\u4e8c\u70ef\uff0cGUA=\u80cd)\u7684\u6846\u67b6\u7ed3\u6784<\/p>\n

\uff08h\uff09\u4e24\u79cdHOIPs\u6750\u6599\u7684\u6768\u6c0f\u6a21\u91cf\uff08E\uff09\u548c\u786c\u5ea6\uff08H\uff09\u503c<\/p>\n

6\u3001\u53e0\u6c2e\u5316\u7269HOIPs\u7684\u6027\u8d28<\/strong><\/p>\n

\u672c\u6587\u5bf9\u8be5\u7c7bHOIPs\u7684\u8ba8\u8bba\u4e3b\u8981\u5728\u5176\u76f8\u8f6c\u53d8\u3001\u78c1\u6027\u3001\u94c1\u5f39\u6027\u548c\u4ecb\u7535\u6027\u80fd\u4e0a\u3002\u4ee5[TrMA][Mn(N3<\/sub>)3<\/sub>]\u4e3a\u4f8b\uff0c\u5176\u7ed3\u6784\u7531\u4e00\u4e2a\u8f83\u5c0f\u7684\u6709\u673a\u80fa\u9633\u79bb\u5b50\u548c\u5177\u6709\u78c1\u6027\u7684Mn2+<\/sup>\u7ec4\u6210\uff0c\u5728305K\u65f6\u7531\u5355\u659c\u76f8\u5411\u8d5d\u7acb\u65b9\u76f8\u8f6c\u53d8\u3002\u76ee\u524d\uff0c\u6709\u4e9b\u7814\u7a76\u96c6\u4e2d\u5728\u5229\u7528\u5176\u76f8\u53d8\u5f15\u53d1\u7684\u7269\u7406\u6027\u8d28\u6539\u53d8\u800c\u5236\u5907\u76f8\u5173\u7684\u6e29\u5ea6\u54cd\u5e94\u5668\u4ef6\u3002\u867d\u7136\u53e0\u6c2e\u5316\u7269HOIPs\u5177\u6709\u8bb8\u591a\u72ec\u7279\u7684\u6027\u8d28\uff0c\u4f46\u662f\u5b83\u4eec\u662f\u53ef\u80fd\u53d1\u751f\u7206\u70b8\u7684\u5371\u9669\u4ea7\u54c1\u4e14\u5177\u6709\u4e00\u5b9a\u7684\u6bd2\u6027\uff0c\u6240\u4ee5\u65e0\u8bba\u5728\u5236\u5907\u8fd8\u662f\u7814\u7a76\u65b9\u9762\u90fd\u9700\u8981\u505a\u597d\u9632\u62a4\u63aa\u65bd\u3002<\/p>\n

<\/p>\n

\u56fe<\/strong>6<\/strong> \u53e0\u6c2e\u5316\u7269HOIPs\u7684\u76f8\u53d8\u53ca\u5176\u76f8\u5173\u6027\u8d28<\/strong><\/p>\n

\uff08a\uff09[TrMA][Mn(N3<\/sub>)3<\/sub>] (TrMA=\u4e09\u7532\u80fa)\u53d1\u751f\u76f8\u53d8\u4ece\u800c\u5bfc\u81f4\u7ed3\u6784\u6846\u67b6\u7684\u5bf9\u79f0\u6027\u88ab\u7834\u574f\uff08296 K\u65f6\uff09<\/p>\n

\uff08b\uff09[MA][Mn(N3<\/sub>)3<\/sub>]\uff0c[DMA][Mn(N3<\/sub>)3<\/sub>]\uff0c[TrMA][Mn(N3<\/sub>)3<\/sub>]\u4ee5\u53ca[TMA][Mn(N3<\/sub>)3<\/sub>] (MA=\u94f5\uff0cDMA=\u4e8c\u7532\u57fa\u94f5\u4ee5\u53caTMA=\u56db\u7532\u57fa\u94f5)\u7684\u78c1\u6ede\u56de\u7ebf<\/p>\n

\uff08c\uff09[DMA][Cd(N3<\/sub>)3<\/sub>]\u7684\u94c1\u5f39\u76f8\u53d8\u53ca\u5176\u76f8\u5173\u7684\u4ecb\u7535\u6027\u80fd<\/p>\n

\uff08d\uff09\u4ecb\u7535\u5e38\u6570\u7684\u5b9e\u90e8\uff08\u03b5\u2019\uff09\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb<\/p>\n

7\u3001\u6c30\u5316\u7269HOIPs\u7684\u6027\u8d28<\/strong><\/p>\n

\u4e8c\u6c30\u80fa\u57fa(DCA)\u914d\u5408\u7269\u4e0eN(CN)2\u2212<\/sup>\u5c5e\u4e8eV\u578b\u7684\u5206\u5b50\u6784\u578b\uff0c\u7531\u5206\u5b50\u4e24\u7aef\u957f\u95f4\u8ddd\u7684\u6865\u63a5\u3002\u6839\u636eGoldschmidt\u7684\u516c\u5dee\u56e0\u5b50\u5224\u65ad\uff0cA\u4f4d\u80fa\u9633\u79bb\u5b50\u5360\u4f4d\u660e\u663e\u5927\u4e8e\u5176\u4ed6\u9633\u79bb\u5b50\uff0c\u8fd9\u662f\u56e0\u4e3a\u5177\u6709\u8f83\u957f\u7684DCA\u6865\u63a5\uff0c\u662f\u533a\u522b\u4e8e\u5176\u5b83HOIPs X\u4f4d\u9634\u79bb\u5b50\u7684\u7279\u5f81\u4e4b\u5904\u3002\u9664\u4e86\u5728\u7279\u5b9a\u6e29\u5ea6\u4e0b\u53d1\u751f\u76f8\u53d8\uff0c\u8be5\u6750\u6599\u5728\u76f8\u7684X\u4f4d\u8fde\u63a5\u5904\u4ea6\u5b58\u5728\u76f8\u53d8\uff0c\u800c\u6b64\u7c7b\u76f8\u53d8\u5728\u5176\u5b83HOIPs\u4e2d\u5f88\u5c11\u89c1\u3002\u6b64\u5916\uff0c\u9ad8\u538b\u91cf\u70ed\u6cd5\u8868\u660e\u9530\u548c\u94b4\u7c7b\u4f3c\u7269\u7684\u76f8\u53d8\u5bf9\u9759\u6c34\u5916\u523a\u6fc0\u5341\u5206\u654f\u611f\u3002<\/p>\n

\u5bf9\u4e8e\u6c30\u5316\u7269HOIPs\uff0c\u7531\u4e8e\u8be5\u6709\u673a\u9633\u79bb\u5b50\u5177\u6709\u6781\u6027\uff0c\u5176\u8fd0\u52a8\u7531\u65e0\u5e8f\u53d8\u4e3a\u6709\u5e8f\u4ece\u800c\u4f7f\u5f97\u4ecb\u7535\u5e38\u6570\u51fa\u73b0\u5f02\u5e38\u3002<\/p>\n

<\/p>\n

\u56fe7<\/strong> \u4e8c\u6c30\u80fa\u4e0e\u6c30\u5316\u7269HOIPs\u7684\u76f8\u8f6c\u53d8\u53ca\u5176\u76f8\u5173\u6027\u8d28<\/strong><\/p>\n

\uff08a\uff09[TPrA][Mn(DCA)3<\/sub>] (TPrA=\u56db\u4e19\u57fa\u80fa)\u4e8e329 K\u4e0b\u7684\u6676\u4f53\u7ed3\u6784\u53d1\u751f\u8f6c\u53d8<\/p>\n

\uff08b\uff09\u4e0d\u540c\u538b\u529b\uff08P\uff09\u4e0b\u7684\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u66f2\u7ebf<\/p>\n

\uff08c\uff09[HIM]2<\/sub>[KFe(CN)6<\/sub>] (HIM=\u54aa\u5511\u9393\u76d0)\u7684\u53cc\u9499\u949b\u77ff\u7ed3\u6784\u4e8e158 K\u4e0b\u7531\u9ad8\u6e29\u65e0\u5e8f\u76f8\u5411\u4f4e\u6e29\u6709\u5e8f\u76f8\u8f6c\u53d8<\/p>\n

\uff08d\uff09\u6cbf\u7740\u4e24\u4e2a\u4e0d\u540c\u7684\u6676\u5411\u7684\u4ecb\u7535\u5e38\u6570\u7684\u5b9e\u90e8\uff08\u03b5\u2019\uff09\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u6709\u673a\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u901a\u8fc7\u7ed3\u6784\u66ff\u6362\uff0c\u5f88\u53ef\u80fd\u4f1a\u4f7f\u6750\u6599\u7684\u7269\u7406\u6027\u8d28\u5f97\u5230\u5f88\u597d\u7684\u8c03\u63a7\u3002\u5176\u4e2d\uff0c\u6709\u673a\u5206\u5b50\u57fa\u56e2\u5728\u6750\u6599\u7684\u76f8\u53d8\u8fc7\u7a0b\u4e2d\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u603b\u800c\u8a00\u4e4b\uff0c\u6709\u673a\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u5728\u8bf8\u591a\u529f\u80fd\u6750\u6599\u9886\u57df\u6709\u7740\u5de8\u5927\u6f5c\u529b\uff0c\u540c\u65f6\u4e5f\u6709\u5f88\u591a\u5173\u952e\u6027\u95ee\u9898\u9700\u8981\u53bb\u63a2\u7d22\u548c\u89e3\u51b3\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aChemically diverse and multifunctional hybrid organic\u2013inorganic perovskites<\/a>\uff08Nature Reviews Materials,2017,doi:10.1038\/natrevmats.2016.99\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7eb3\u7c73\u7ec4pengyuman\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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