{"id":65336,"date":"2017-02-19T06:30:39","date_gmt":"2017-02-18T22:30:39","guid":{"rendered":"\/\/m.iemloyee.com\/?p=65336"},"modified":"2017-02-14T10:19:49","modified_gmt":"2017-02-14T02:19:49","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e7%ba%b3%e7%b1%b3%e7%ba%a4%e7%bb%b4%e5%a6%82%e4%bd%95%e5%8f%98%e8%ba%ab%e4%b8%ba%e9%94%82%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=65336","title":{"rendered":"\u5b66\u672f\u5e72\u8d27|\u7eb3\u7c73\u7ea4\u7ef4\u5982\u4f55\u53d8\u8eab\u4e3a\u9502\u7535\u6c60"},"content":{"rendered":"

1 \u5f15\u8a00<\/strong><\/span><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u7531\u91d1\u5c5e\u9502\u7535\u6c60\u53d1\u5c55\u800c\u6765\uff0c\u9502\u79bb\u5b50\u53ef\u5728\u91d1\u5c5e\u9502\u6b63\u6781\u548c\u53ef\u5d4c\u9502\u78b3\u8d1f\u6781\u6750\u6599\u4e4b\u95f4\u6765\u56de\u8f6c\u53d8\uff0c\u53c8\u79f0\u6447\u6905\u5f0f\u7535\u6c60[1]<\/sup>\u3002\u8fd1\u5e74\u6765\uff0c\u4eba\u4eec\u53d1\u73b0\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u5927\uff0c\u5bff\u547d\u957f\uff0c\u6c61\u67d3\u5c0f\u7b49\u4f18\u70b9\uff0c\u5f00\u59cb\u5c55\u5f00\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5927\u91cf\u7814\u7a76\uff0c\u76ee\u524d\u7684\u6210\u679c\u4ee5\u5e7f\u6cdb\u5e94\u7528\u4e8e\u667a\u80fd\u624b\u673a\u3001\u6570\u7801\u76f8\u673a\u7b49\u53ef\u643a\u5e26\u7535\u5b50\u4ea7\u54c1\u4e2d\uff0c\u6700\u8fd1\u6b63\u5728\u5174\u8d77\u7684\u65b0\u80fd\u6e90\u7535\u52a8\u8f66\u7684\u50a8\u80fd\u88c5\u7f6e\u4e2d\u5c11\u4e0d\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

2 \u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599<\/strong><\/span><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u4e3b\u8981\u7531\u6b63\u6781\u3001\u9694\u819c\u3001\u8d1f\u6781\u3001\u7535\u89e3\u6db2\u4ee5\u53ca\u7535\u6c60\u5916\u58f3\u7ec4\u6210\uff0c\u800c\u6b63\u6781\u6750\u6599\u662f\u51b3\u5b9a\u9502\u79bb\u5b50\u7535\u6c60\u4f7f\u7528\u6027\u80fd\u7684\u6838\u5fc3\u56e0\u7d20\u3002<\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u5145\u7535\u653e\u7535\u7684\u539f\u7406\u5b9e\u9645\u4e0a\u662f\u91d1\u5c5e\u7684\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\uff0c\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9502\u79bb\u5b50\u8131\u79bb\u6b63\u6781\u6750\u6599\uff0c\u4e8e\u662f\u6b63\u6781\u6750\u6599\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u88ab\u6c27\u5316\u5230\u66f4\u9ad8\u4ef7\u6001\uff0c\u968f\u7740\u653e\u7535\u7684\u8fdb\u884c\uff0c\u9502\u79bb\u5b50\u56de\u5230\u6b63\u6781\u6750\u6599\uff0c\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u8fd8\u539f\u56de\u4f4e\u4ef7\u6001\u3002\u56fe1\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u5de5\u4f5c\u8fc7\u7a0b\u793a\u610f\u56fe[2]<\/sup>\uff0c\u5176\u4e2d\uff0c\u6b63\u6781\u6750\u6599\u4f4d\u4e8e\u53f3\u4fa7\uff0c\u5de6\u4fa7\u4e3a\u8d1f\u6781\u6750\u6599\uff0c\u9502\u79bb\u5b50\u7ecf\u8fc7\u7535\u89e3\u6db2\u53d1\u751f\u8fc1\u79fb\uff0c\u7531\u4e8e\u91d1\u5c5e\u79bb\u5b50\u8fc1\u79fb\u901f\u7387\u4e00\u5b9a\uff0c\u8fc1\u79fb\u8ddd\u79bb\u8d8a\u77ed\u90a3\u4e48\u8be5\u7535\u6c60\u4f7f\u7528\u6548\u7387\u8d8a\u9ad8\u3002<\/p>\n

\"\"
\n\u56fe1 \u9502\u79bb\u5b50\u7535\u6c60\u5145\u7535\u653e\u7535\u539f\u7406[2]<\/sup><\/strong><\/p>\n

\u5982\u4eca\uff0c\u4eba\u4eec\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7684\u84c4\u80fd\u80fd\u529b\u8981\u6c42\u8d8a\u6765\u8d8a\u9ad8\uff0c\u4e3a\u4e86\u5e94\u5bf9\u8be5\u6311\u6218\uff0c\u6700\u76f4\u63a5\u7684\u65b9\u6cd5\u5c31\u662f\u6539\u8fdb\u73b0\u6709\u7684\u6b63\u6781\u6750\u6599\u3002\u7406\u60f3\u7684\u6b63\u6781\u6750\u6599\u80fd\u591f\u505a\u5230\u65e0\u9650\u6b21\u63a5\u6536\u91ca\u653e\u9502\u79bb\u5b50\uff08\u5373\u5145\u7535\u653e\u7535\u8fc7\u7a0b\uff09\uff0c\u540c\u65f6\u5b8c\u6210\u8be5\u8fc7\u7a0b\u8981\u8fc5\u901f\u3002\u53ef\u4f5c\u4e3a\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u6750\u6599\u6709\uff1a\u03b1-NaFeO2<\/sub>\uff0c\u5c16\u6676\u77f3\u548c\u6a44\u6984\u7eff[3]<\/sup>\uff0c\u4f46\u5b83\u4eec\u76ee\u524d\u7684\u5c40\u9650\u5728\u4e8e\u6210\u672c\u8fc7\u9ad8\uff0c\u53ef\u4f7f\u7528\u5bff\u547d\u6709\u5f85\u5ef6\u957f\u3002\u8fd1\u51e0\u5e74\u4eba\u4eec\u5bf9\u6539\u8fdb\u5d4c\u9502\u7ed3\u6784\u6750\u6599\u7684\u6539\u8fdb\u8fdb\u884c\u4e86\u4e0d\u5c11\u7684\u7814\u7a76\u3002<\/p>\n

3 \u9759\u7535\u7eba\u4e1d\u6280\u672f<\/strong><\/span><\/p>\n

\u9759\u7535\u7eba\u4e1d\u6280\u672f\u662f\u4ece\u4e0a\u4e16\u7eaa30\u5e74\u4ee3\u53d1\u5c55\u7684\u4e00\u79cd\u65b0\u578b\u7eba\u4e1d\u65b9\u6cd5\uff0c\u5e38\u7528\u4e8e\u7eba\u5236\u7eb3\u7c73\u7ea4\u7ef4\u3001\u7eb3\u7c73\u5e26\u3001\u7eb3\u7c73\u819c\u7b49\u3002\u9996\u5148\u5c06\u805a\u5408\u7269\u914d\u7f6e\u6210\u6eb6\u6db2\uff0c\u6ce8\u5165\u6bdb\u7ec6\u7ba1\u9488\u5934\uff0c\u5229\u7528\u9ad8\u538b\u9759\u7535\u529b\u7684\u4f5c\u7528\u5f97\u5230\u5c04\u6d41\uff0c\u968f\u7740\u6eb6\u5242\u5728\u7a7a\u6c14\u4e2d\u7684\u6325\u53d1\uff0c\u6eb6\u8d28\u56fa\u5316\u5f97\u5230\u7eb3\u7c73\u7ea4\u7ef4\u3002\u7531\u4e8e\u5728\u7eba\u5236\u7eb3\u7c73\u7ea4\u7ef4\u7684\u8fc7\u7a0b\u4e2d\uff0c\u9759\u7535\u7eba\u4e1d\u6cd5\u64cd\u4f5c\u7b80\u4fbf\uff0c\u5b9e\u9a8c\u53ef\u91cd\u590d\u6027\u9ad8\uff0c\u53c2\u6570\u53ef\u63a7\uff0c\u76ee\u524d\u975e\u5e38\u53d7\u5230\u5b9e\u9a8c\u5ba4\u7684\u91cd\u89c6\u3002<\/p>\n

\u56fe2\u8868\u793a\u4e86\u9759\u7535\u7eba\u4e1d\u88c5\u7f6e\u793a\u610f\u56fe[4]<\/sup>\uff0c\u8fd9\u662f\u6700\u57fa\u672c\u7684\u5355\u8f74\u7eba\u4e1d\u8fc7\u7a0b\uff0c\u88c5\u6709\u7eba\u4e1d\u539f\u6db2\u7684\u9488\u5934\u4e3a\u6b63\u6781\uff0c\u9ad8\u538b\u7535\u53e6\u4e00\u7aef\u8fde\u63a5\u7740\u63a5\u6536\u88c5\u7f6e\uff0c\u63a5\u5730\uff0c\u4f5c\u4e3a\u8d1f\u6781\uff0c\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u9488\u5c16\u5904\u7eba\u4e1d\u539f\u6db2\u7531\u6d41\u4f53\u53d8\u4e3a\u6781\u7ec6\u7ea4\u7ef4\u65f6\u4f1a\u51fa\u73b0\u201c\u6cf0\u52d2\u9525\u201d\uff0c\u662f\u9759\u7535\u7eba\u4e1d\u7279\u6709\u7684\u73b0\u8c61\u3002\u6cf0\u52d2\u9525\u7684\u5f62\u8c8c\u968f\u7740\u7eba\u4e1d\u5de5\u827a\u53c2\u6570\u7684\u8c03\u6574\u6709\u6240\u4e0d\u540c\uff0c\u6709\u65f6\u5448\u534a\u7403\u72b6\uff0c\u6709\u65f6\u5448\u5706\u9525\u72b6\uff0c\u53e6\u5916\uff0c\u6cf0\u52d2\u9525\u7684\u957f\u5ea6\u4e5f\u4f1a\u53d7\u5230\u5de5\u827a\u53c2\u6570\u7684\u5f71\u54cd\u3002\u5173\u4e8e\u6cf0\u52d2\u9525\u7684\u5f62\u8c8c\uff0c\u5df2\u6709\u5b66\u8005\u4e13\u95e8\u505a\u8fc7\u7edf\u8ba1\uff0c\u65e8\u5728\u627e\u51fa\u6cf0\u52d2\u9525\u4e0e\u7eba\u4e1d\u5de5\u827a\u53c2\u6570\u7684\u5173\u7cfb\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 \u9759\u7535\u7eba\u4e1d\u88c5\u7f6e\u793a\u610f\u56fe\u4ee5\u53ca\u6cf0\u52d2\u9525[4]<\/sup><\/strong><\/p>\n

3.1\u5173\u4e8e\u9759\u7535\u7eba\u4e1d\u6280\u672f\u7684\u5de5\u827a\u63a7\u5236<\/strong><\/p>\n

\u9759\u7535\u7eba\u4e1d\u8fc7\u7a0b\u4e2d\uff0c\u7eb3\u7c73\u7ea4\u7ef4\u7684\u5f62\u8c8c\u53d6\u51b3\u4e8e\u591a\u79cd\u53d8\u91cf[5]<\/sup>\uff0c\u800c\u5176\u4e2d\uff0c\u6eb6\u6db2\u6027\u8d28\u662f\u6700\u4e3a\u91cd\u8981\u7684\u56e0\u7d20\u3002
\n\u9996\u5148\u662f\u6eb6\u6db2\u6d53\u5ea6\u6216\u8005\u662f\u76f8\u5173\u7c98\u5ea6\u7684\u5f71\u54cd\u3002\u9759\u7535\u7eba\u4e1d\u55b7\u5c04\u7684\u8fc7\u7a0b\u4e2d\u9700\u8981\u7ecf\u8fc7\u6eb6\u5242\u6325\u53d1\u7684\u56fa\u5316\u4f5c\u7528\uff0c\u5f62\u6210\u7ea4\u7ef4\u3002\u4f4e\u7c98\u5ea6\u4e0b\uff0c\u6eb6\u5242\u4e0d\u5bb9\u6613\u6325\u53d1\u5b8c\u5168\uff0c\u5bfc\u81f4\u7ea4\u7ef4\u56fa\u5316\u96be\u5ea6\u589e\u52a0\uff0c\u63a5\u6536\u88c5\u7f6e\u4e0a\u6709\u6eb6\u5242\u6b8b\u7559\uff0c\u5f97\u5230\u4e0d\u89c4\u6574\u7684\u7ea4\u7ef4\uff0c\u7ea4\u7ef4\u8d28\u91cf\u4e0b\u964d\u3002\u5982\u679c\u6d53\u5ea6\u8fc7\u9ad8\uff0c\u5219\u7ea4\u7ef4\u5bb9\u6613\u51fa\u73b0\u4e32\u73e0\u73b0\u8c61\uff0c\u4e0d\u5229\u4e8e\u7eb3\u7c73\u6750\u6599\u7684\u6027\u80fd\u3002\u7406\u60f3\u7684\u7ea4\u7ef4\u662f\u89c4\u6574\uff0c\u5177\u6709\u5706\u67f1\u5f62\u622a\u9762\u7684\u7ea4\u7ef4\u3002<\/p>\n

\u5176\u6b21\uff0c\u6eb6\u8d28\u5206\u5b50\u91cf\u7684\u5927\u5c0f\u9700\u8981\u8003\u8651\uff0c\u5982\u679c\u5206\u5b50\u91cf\u8fc7\u9ad8\uff0c\u66f4\u5bb9\u6613\u53d1\u751f\u7f20\u7ed3\uff0c\u5bfc\u81f4\u6eb6\u6db2\u7c98\u5ea6\u589e\u52a0\uff0c\u5176\u540e\u679c\u7c7b\u4f3c\u9ad8\u6d53\u5ea6\u6eb6\u6db2\uff0c\u5f97\u5230\u7684\u7ea4\u7ef4\u6613\u51fa\u73b0\u4e32\u73e0\u73b0\u8c61\u3002\u53e6\u5916\uff0c\u6eb6\u8d28\u7684\u6027\u80fd\u4e5f\u5f88\u5173\u952e\uff0c\u5982PEO\uff0c\u867d\u7136\u751f\u7269\u76f8\u5bb9\u6027\u597d\uff0c\u6bd2\u6027\u4f4e\uff0c\u52a0\u5de5\u6027\u80fd\u4f18\u826f\uff0c\u4f46\u5b83\u5374\u4e0d\u9002\u5408\u4f7f\u7528\u9759\u7535\u7eba\u4e1d\u65b9\u6cd5\u3002\u56e0\u6b64\uff0c\u5728\u914d\u7f6e\u5408\u9002\u7684\u7eba\u4e1d\u539f\u6db2\u524d\uff0c\u9700\u8981\u7efc\u5408\u8003\u91cf\u4ee5\u4e0a\u56e0\u7d20\u3002<\/p>\n

\u5f97\u76ca\u4e8e\u7eb3\u7c73\u7ea4\u7ef4\u7684\u4e00\u7ef4\u7ed3\u6784\uff0c\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u80fd\u7f29\u77ed\u9502\u79bb\u5b50\u7684\u8fc1\u79fb\u8ddd\u79bb\uff0c\u5bfc\u7535\u6548\u7387\u5f97\u5230\u63d0\u9ad8\uff0c\u5bf9\u4e8e\u6027\u80fd\u63d0\u5347\u5f88\u6709\u5e2e\u52a9[6]<\/sup>\u3002<\/p>\n

3.2 \u540c\u8f74\u6cd5<\/strong><\/p>\n

\u968f\u7740\u73b0\u5728\u9759\u7535\u7eba\u4e1d\u5de5\u827a\u7684\u9010\u6e10\u5b8c\u5584\uff0c\u5bf9\u7eb3\u7c73\u7ea4\u7ef4\u7684\u7814\u7a76\u8d8a\u6765\u8d8a\u6df1\u5165\uff0c\u9700\u8981\u5236\u5907\u6838\u58f3\u7ed3\u6784\u7684\u590d\u5408\u7eb3\u7c73\u7ea4\u7ef4\uff0c\u5c3d\u7ba1\u65b9\u6cd5\u5f88\u591a\uff0c\u8fd9\u5f53\u4e2d\u540c\u8f74\u6cd5\u5236\u5907\u6838\u58f3\u7ed3\u6784\u7b26\u5408\u7eb3\u7c73\u7ea4\u7ef4\u6700\u4e3a\u7b80\u4fbf\u3002\u539f\u7406\u8bbe\u5907\u5982\u56fe3\u6240\u793a\uff0c\u4e0e\u5355\u8f74\u6cd5\u4e0d\u540c\u7684\u662f\uff0c\u540c\u8f74\u6cd5\u4f7f\u7528\u4e24\u6839\u6ce8\u5c04\u5668\uff0c\u4e00\u6839\u6ce8\u5c04\u5668\u9488\u5934\u5185\u90e8\u88c5\u6709\u6bdb\u7ec6\u7ba1\uff0c\u6bdb\u7ec6\u7ba1\u4e00\u7aef\u4e0e\u53e6\u4e00\u6839\u9488\u5934\u76f8\u8fde\uff0c\u53e6\u4e00\u6839\u548c\u5916\u90e8\u9488\u5c16\u5bf9\u51c6\u63a5\u6536\u88c5\u7f6e\uff0c\u8fd9\u5c31\u662f\u540c\u8f74\u6cd5\u7684\u5de5\u4f5c\u539f\u7406\uff0c\u5176\u4ed6\u548c\u5355\u8f74\u6cd5\u76f8\u540c\u3002\u56fe3\u4e2d\u4e5f\u80fd\u770b\u51fa\uff0c\u590d\u5408\u7eb3\u7c73\u7ea4\u7ef4\u4e5f\u5177\u6709\u6cf0\u52d2\u9525\uff0c\u6838\u58f3\u6210\u5206\u6e05\u6670\u53ef\u89c1\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3\u540c\u8f74\u6cd5\u7eba\u4e1d\u88c5\u7f6e\u793a\u610f\u56fe\u548c\u6cf0\u52d2\u9525[7]<\/sup><\/strong><\/p>\n

\u56fe4\u4e3a\u5177\u6709\u6838\u58f3\u7ed3\u6784\u7684\u590d\u5408\u7eb3\u7c73\u7ea4\u7ef4\u7684\u900f\u5c04\u7535\u955c\u56fe[8]<\/sup>\uff0c\u53ef\u4ee5\u770b\u5230\u7ea4\u7ef4\u6df1\u6d45\u4e0d\u5747\u4e00\uff0c\u8bf4\u660e\u5176\u5177\u6709\u6838\u58f3\u7ed3\u6784\u7684\u7279\u5f81\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 \u6838\u58f3\u7ed3\u6784\u590d\u5408\u7eb3\u7c73\u7ea4\u7ef4\u7535\u955c\u56fe\uff0ca\uff09TEM\u56fe\uff1bb\uff09HR-TEM\u56fe[8]<\/sup><\/strong><\/p>\n

4 \u9759\u7535\u7eba\u4e1d\u6280\u672f\u5728\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u4e2d\u7684\u5e94\u7528<\/strong><\/span><\/p>\n

\u7531\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u4f7f\u7528\u8fc7\u7a0b\u662f\u9502\u79bb\u5b50\u8131\u5d4c\u4ee5\u53ca\u56de\u5230\u6b63\u6781\u6750\u6599\u7684\u8fc7\u7a0b\uff0c\u672c\u8d28\u4e0a\u662f\u91d1\u5c5e\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u4e3a\u4e86\u80fd\u63d0\u9ad8\u50a8\u80fd\u6548\u7387\uff0c\u8981\u4fdd\u8bc1\u8131\u5d4c\u8ddd\u79bb\u77ed\uff0c\u6b63\u6781\u6750\u6599\u8868\u9762\u79ef\u5927\uff0c\u9502\u79bb\u5b50\u5c31\u80fd\u5c3d\u91cf\u591a\u7684\u5d4c\u5165\u6b63\u6781\u6750\u6599\uff0c\u63d0\u9ad8\u7535\u5bb9\u91cf\u3002<\/p>\n

\u9759\u7535\u7eba\u4e1d\u5236\u5907\u7684\u7eb3\u7c73\u7ea4\u7ef4\u5177\u6709\u5f88\u5927\u7684\u957f\u5f84\u6bd4\uff0c\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u7ea4\u7ef4\u4e0d\u6613\u53d1\u751f\u56e2\u805a\uff0c\u8fd9\u4e9b\u6027\u80fd\u5927\u5927\u7f29\u77ed\u9502\u79bb\u5b50\u8fc1\u79fb\u7684\u8ddd\u79bb\uff0c\u56e0\u6b64\u7814\u7a76\u9759\u7535\u7eba\u4e1d\u5236\u5907\u5de5\u827a\uff0c\u5bf9\u63d0\u9ad8\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u4f7f\u7528\u6027\u80fd\u6709\u5f88\u5927\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

4.1 \u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u7c7b\u6b63\u6781\u6750\u6599<\/strong><\/p>\n

\u7406\u60f3\u7684\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u7c7b\u6b63\u6781\u6750\u6599\u7ed3\u6784\u5982\u56fe5\u6240\u793a\uff0c\u6c27\u9634\u79bb\u5b50\uff08\u4e3a\u4e86\u6e05\u6670\u56fe\u4e2d\u7701\u7565\uff09\u57286\u4e2a\u914d\u4f53\u7684\u516b\u9762\u4f53\u6676\u683c\u4e2d\u5f62\u6210\u4e86\u7d27\u5bc6\u5305\u88f9\u7684\u9762\u5fc3\u7acb\u65b9\u6676\u683c\uff0c\u8fc7\u6e21\u91d1\u5c5e\u5c42\u9502\u79bb\u5b50\u4ea4\u9519\u53e0\u653e\u7740\u3002\u867d\u7136\u8be5\u7ed3\u6784\u5df2\u7ecf\u6709\u4ea7\u54c1LiCoO2<\/sub>\u5b9e\u73b0\u5546\u4e1a\u5316\uff0c\u4f46\u9057\u61be\u7684\u662f\u5176\u50a8\u80fd\u6548\u7387\u4e0d\u9ad8\uff0c\u4ec5\u8fbe\u5230\u7406\u8bba\u503c\u5f97\u4e00\u534a\u3002\u5f88\u5927\u7a0b\u5ea6\u4e0a\u662f\u7531\u4e8e\u5185\u90e8\u7ed3\u6784\u4e0d\u7a33\u5b9a\u6240\u81f4\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u4f7f\u7528\u7684\u8fc7\u6e21\u91d1\u5c5e\u5b58\u5728\u6bd2\u6027\u4ee5\u53ca\u6210\u672c\u4e5f\u9ad8\uff0c\u4f1a\u5bfc\u81f4\u73af\u5883\u6c61\u67d3\u7b49\u95ee\u9898\uff0c\u603b\u4e4b\u4e0d\u662f\u4e00\u4e2a\u957f\u8fdc\u7684\u5e94\u7528\u5bf9\u8c61\u3002\u968f\u7740\u7814\u7a76\u7684\u6df1\u5165\uff0c\u7814\u7a76\u8005\u76ee\u524d\u5df2\u7ecf\u53d1\u73b0\u73af\u4fdd\u4f4e\u6bd2\u7684\u66ff\u4ee3\u8fc7\u6e21\u91d1\u5c5e\uff0c\u5982\u954d\uff0c\u9530\u7b49\u3002\u76ee\u524d\u5e38\u7528\u7684\u6b63\u6781\u6750\u6599\u4e3b\u8981\u662f\u4ee5\u4e24\u79cd\u91d1\u5c5e\u4ee51:1\u7684\u6bd4\u4f8b\u6dfb\u52a0\u5728\u5c42\u4e2d\uff0c\u53c8\u79f0\u4e3aNMC\u578b\u6b63\u6781\u6750\u6599\u3002<\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u56fe5 \u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u7c7b\u6b63\u6781\u6750\u6599\u7ed3\u6784\u793a\u610f\u56fe[2]<\/sup><\/strong><\/p>\n

Hosono[9]<\/sup>\u4ee5\u805a\u4e59\u70ef\u9187\uff08PVA\uff09\u4e3a\u6eb6\u8d28\uff0c\u4ee5\u6c34\u3001\u918b\u9178\u548c\u4e59\u9187\u7684\u6df7\u5408\u6db2\u4e3a\u6eb6\u5242\uff0c\u914d\u7f6e\u524d\u9a71\u4f53\u6eb6\u6db2\uff0c\u4ee5LiCoO2<\/sub>\u4e3a\u6b63\u6781\u6750\u6599\uff0c\u5206\u4e3a\u4e24\u7ec4\uff0c\u4e00\u7ec4\u52a0\u5165\u6c14\u76f8\u751f\u957f\u78b3\u7ea4\u7ef4\uff08VGCF\uff09\uff0c\u53e6\u4e00\u7ec4\u4ec0\u4e48\u90fd\u4e0d\u52a0\uff0c\u4f5c\u4e3a\u5bf9\u7167\u7ec4\u3002\u5b9e\u9a8c\u8fc7\u7a0b\u56fe\u548c\u4e24\u7ec4\u626b\u63cf\u7535\u955c\u62cd\u6444\u7684\u5b9e\u9a8c\u56fe\u5982\u56fe6\u6240\u793a\u3002\u4e24\u7ec4\u6eb6\u6db2\u90fd\u6210\u6210\u529f\u7eba\u5236\u6210\u7eb3\u7c73\u7ea4\u7ef4\uff0c\u4f46\u662f\u52a0\u6709\u6c14\u76f8\u751f\u957f\u78b3\u7ea4\u7ef4\u90a3\u4e00\u7ec4\u5f97\u5230\u7ea4\u7ef4\u8981\u6bd4\u5bf9\u7167\u7ec4\u4e0d\u6dfb\u52a0\u7684\u8981\u7ec6\u5f88\u591a\uff0c\u5728\u7ecf\u8fc7\u9ad8\u6e29\u5904\u7406\u540e\uff0c\u539f\u672c\u5149\u6ed1\u7684\u8868\u9762\u5f00\u59cb\u53d8\u5f97\u4e0d\u5e73\u6574\uff0c\u8fd9\u6837\u5b50\u5927\u5927\u589e\u52a0\u4e86\u7ea4\u7ef4\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u63d0\u9ad8\u4e86\u6b63\u6781\u6750\u6599\u7684\u50a8\u80fd\u6548\u7387\u3002\u53ea\u662f\uff0c\u7ecf\u8fc7\u591a\u6b21\u653e\u7535\u5145\u7535\u7684\u5b9e\u9a8c\uff0c\u52a0\u6709\u6c14\u76f8\u751f\u957f\u78b3\u7ea4\u7ef4\u90a3\u4e00\u7ec4\u6b63\u6781\u6750\u6599\u8868\u73b0\u51fa\u660e\u663e\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u6750\u6599\u7684\u5e93\u4f26\u6548\u7387\u63a5\u8fd1100%\uff0c\u653e\u7535\u6bd4\u5bb9\u91cf\u66f4\u662f\u9ad8\u8fbe108mAh\/g\u3002\u539f\u56e0\u53ef\u80fd\u662f\u7531\u4e8e\u52a0\u5165\u6c14\u76f8\u751f\u957f\u78b3\u7ea4\u7ef4\u7684\u90a3\u4e00\u7ec4\u7ea4\u7ef4\u76f4\u5f84\u53d8\u7ec6\uff0c\u76f8\u6bd4\u8f83\u800c\u8a00\u5177\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u4e5f\u5c31\u80fd\u83b7\u5f97\u66f4\u5927\u7684\u7535\u5bb9\u91cf\u3002<\/p>\n

\"\"
\n\u56fe6 \u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6b63\u6781\u6750\u6599\u7ed3\u6784\uff0c\u4e0b\u56fe\u8868\u793a\u52a0\u6709\u6c14\u76f8\u751f\u957f\u78b3\u7ea4\u7ef4\uff0c\u76f4\u5f84\u660e\u663e\u6bd4\u4ec0\u4e48\u90fd\u4e0d\u6dfb\u52a0\u7684\u5bf9\u7167\u7ec4\u7ec6\u5f88\u591a[9]<\/sup><\/strong><\/p>\n

4.2 \u9530\u7cfb\u5c16\u6676\u77f3\u7ed3\u6784<\/strong><\/p>\n

\u5c16\u6676\u77f3\u7ed3\u6784\u7684\u6b63\u6781\u6750\u6599\u5982\u56fe7\u6240\u793a\u3002LiMnO4<\/sub>\u4e2d\uff0c\u6c27\u7684\u6846\u67b6\u548cLiMO2<\/sub>\u7cfb\u76f8\u540c\u3002\u8fc7\u6e21\u91d1\u5c5eM\u5904\u4e8e\u516b\u9762\u4f53\u7ed3\u6784\uff0c\u5176\u4e2d\uff0c1\/4\u90e8\u5206\u548cLi\u5c42\u5206\u4eab\u540c\u4e00\u4e2a\u5e73\u9762\uff0c\u5269\u4e0b\u7684\u4e0e\u7a7a\u7684\u4e00\u5c42\u5206\u4eab\u540c\u4e00\u5e73\u9762\u3002\u9502\u79bb\u5b50\u4f4d\u4e8e\u56db\u9762\u4f53\u4e2d\u5fc3\u3002\u5927\u6982\u7ed3\u6784\u4e3aMO2<\/sub>\u7cfb\u5f62\u6210\u57fa\u672c\u7684\u4e09\u7ef4\u7acb\u4f53\u6846\u67b6\u4e3a\u4e3b\uff0c\u5269\u4e0b\u7684\u7a7a\u95f4\u7528\u4e8e\u4f5c\u4e3a\u9502\u79bb\u5b50\u8fc1\u79fb\u7684\u901a\u9053\u3002\u5c16\u6676\u77f3LiMn2<\/sub>O4<\/sub>\u88ab\u8ba4\u4e3a\u662f\u5f88\u7406\u60f3\u7684\u9502\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u7136\u800c\u8fc7\u4e0d\u4e45\u4fbf\u6253\u8138\u4e86\uff0c\u56e0\u4e3a\u5c16\u6676\u77f3\u6b63\u6781\u6750\u6599\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u51fa\u73b0\u7535\u5bb9\u91cf\u8fc5\u901f\u8870\u51cf\u7684\u95ee\u9898\u3002\u4e24\u4e2a\u539f\u56e0\u53ef\u80fd\u5bfc\u81f4\u4e86\u5bb9\u91cf\u7684\u8870\u51cf\uff0c\u9996\u5148\u662f\u4e8c\u4ef7\u9530\u79bb\u5b50\u53ef\u80fd\u5728\u653e\u7535\u5145\u7535\u53cd\u5e94\u4e2d\u6eb6\u89e3\u5165\u7535\u89e3\u6db2\uff0c\u4e3b\u8981\u53cd\u5e94\u4e3a\u4e09\u4ef7\u9530\u79bb\u5b50\u53d1\u751f\u6b67\u5316\u53cd\u5e94\u3002\u5176\u6b21\uff0c\u53ef\u80fd\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u51fa\u73b0\u4e86\u65b0\u76f8\uff0c\u5bfc\u81f4\u964d\u4f4e\u4e86\u7535\u5bb9\u91cf\u3002\u4f46\u4e0d\u7ba1\u4ec0\u4e48\u539f\u56e0\uff0c\u76ee\u524d\u5bfb\u627eMn\u7684\u66ff\u4ee3\u91d1\u5c5e\u662f\u91cd\u8981\u8bfe\u9898\uff0c\u56e0\u4e3a\u8fd9\u662f\u5c16\u6676\u77f3\u6027\u80fd\u7684\u91cd\u8981\u56e0\u7d20\uff0c\u751a\u81f3\u662f\u5f71\u54cd\u5c16\u6676\u77f3\u63d0\u5347\u5faa\u73af\u4f7f\u7528\u6b21\u6570\u7684\u5173\u952e\u3002<\/p>\n

\"\"
\n\u56fe7 \u9530\u7cfb\u5c16\u6676\u77f3\u7ed3\u6784\u793a\u610f\u56fe[2]<\/sup><\/strong><\/p>\n

Aravindan[10]<\/sup>\u62a5\u9053\u4e86\u4e00\u79cd\u7535\u5bb9\u91cf\u7279\u522b\u5927\u7684\u591a\u5b54LiMnO4<\/sub>\u4e2d\u7a7a\u7eb3\u7c73\u7ea4\u7ef4\uff0c\u901a\u8fc7\u9759\u7535\u7eba\u4e1d\u5f97\u5230\u3002\u8fd9\u5bf9\u4e8e\u5b9e\u9a8c\u6765\u8bf4\u610f\u4e49\u975e\u5e38\u91cd\u5927\u3002\u5229\u7528\u9759\u7535\u7eba\u4e1d\u65b9\u6cd5\u5f97\u5230\u7684LiMnO4<\/sub>\u4e2d\u7a7a\u7eb3\u7c73\u7ea4\u7ef4\u57281C\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u53d1\u751f1250\u6b21\u653e\u7535\u5145\u7535\u7684\u5faa\u73af\uff0c\u8fd8\u80fd\u4fdd\u6301\u521d\u59cb\u72b6\u600187%\u7684\u7535\u5bb9\u91cf\u3002\u53e6\u5916\uff0c\u5982\u679c\u63d0\u9ad8\u7535\u6d41\u5bc6\u5ea6\uff0c\u7535\u5bb9\u91cf\u53c8\u4f1a\u51fa\u73b0\u4e0d\u4e00\u6837\u7684\u7ed3\u679c\u3002\u56fe8\u4e3a\u76f8\u5173\u7535\u955c\u56fe\uff0c\u53ef\u4ee5\u770b\u5230\u8be5\u7ea4\u7ef4\u5177\u6709\u591a\u5b54\u7ed3\u6784\uff0c\u8fd8\u662f\u7a7a\u5fc3\u7ea4\u7ef4\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8 \u7535\u955c\u5b9e\u9a8c\u56fe a\uff09LiMn<\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>4<\/b><\/sub><\/strong>\u7eb3\u7c73\u7ea4\u7ef4\u7684FE-SEM\uff1bb\uff09\u7eb3\u7c73\u7ea4\u7ef4\u5728800\u2103\u7684\u9ad8\u6e29\u4e0b\u7145\u70e75\u5c0f\u65f6\u7684\u56fe\u7247\uff1bc\uff09\u5355\u6839\u4e2d\u7a7a\u7ea4\u7ef4\u5f62\u8c8c\u7684\u653e\u5927\u56fe\uff1bd\uff09\u900f\u5c04\u7535\u955c\u56fe\uff0c\u7a7a\u5fc3\u7ed3\u6784\u4e00\u76ee\u4e86\u7136[10]<\/sup><\/strong><\/p>\n

4.3 \u6a44\u6984\u77f3\u7ed3\u6784\u6b63\u6781\u6750\u6599<\/strong><\/p>\n

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\"\"
\n\u56fe9 \u6a44\u6984\u77f3\u7ed3\u6784\u6b63\u6781\u6750\u6599\u793a\u610f\u56fe[2]<\/sup><\/strong><\/p>\n

Maier[11]<\/sup>\u62a5\u9053\u4e86\u5355\u6676\u78b3\u5c42\u8986\u76d6\u7684LiFePO4<\/sub>\u7eb3\u7c73\u7ebf\uff0c\u901a\u8fc7\u9759\u7535\u7eba\u4e1d\u65b9\u5f0f\u5236\u5907\u3002\u5176\u7ed3\u6784\u5982\u56fe10\u6240\u793a\uff0c\u7eb3\u7c73\u7ebf\u6cbf\u7740c\u8f74\u65b9\u5411\u8fde\u7eed\u751f\u957f\uff0c\u76f4\u5f84\u89c4\u6574\u3002\u5229\u7528\u8be5\u65b9\u6cd5\uff0c\u80fd\u5f62\u6210\u5bfc\u7535\u6548\u7387\u5f88\u9ad8\u7684\u7f51\u7edc\uff0c\u5176\u4e2d\u8fc1\u79fb\u8ddd\u79bb\u4e5f\u5c0f\uff0c\u8fd9\u6837\u80fd\u4f7f\u7535\u5bb9\u91cf\u7684\u8870\u51cf\u9002\u5f53\u51cf\u7f13\uff0c\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u63d0\u9ad8\u4e86\u5bfc\u7535\u6548\u7387\u3002<\/p>\n

\"\"
\n\u56fe10 \u8986\u76d6\u5355\u5c42\u78b3\u7684LiFePO4<\/sub>\u7eb3\u7c73\u7ebf\u7684\u7535\u955c\u56fe[11]<\/sup><\/strong><\/p>\n

5 \u7ed3\u8bed<\/strong><\/span><\/p>\n

\u9759\u7535\u7eba\u4e1d\u4f5c\u4e3a\u4e00\u79cd\u65b0\u5174\u7eba\u4e1d\u6280\u672f\uff0c\u662f\u76ee\u524d\u5236\u5907\u7eb3\u7c73\u7ea4\u7ef4\u5e38\u7528\u7684\u65b9\u6cd5\uff0c\u4e14\u8bbe\u5907\u7a0d\u52a0\u6539\u8fdb\uff0c\u4fbf\u80fd\u5236\u5907\u6838\u58f3\uff0c\u4e2d\u7a7a\uff0c\u591a\u5b54\u7b49\u590d\u6742\u7ed3\u6784\u7684\u7eb3\u7c73\u7ea4\u7ef4\u3002\u540c\u65f6\uff0c\u5176\u4e00\u7ef4\u7ed3\u6784\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u6709\u5f88\u5927\u7684\u4f5c\u7528\uff0c\u80fd\u5927\u5927\u51cf\u5c11\u653e\u7535\u5145\u7535\u65f6\u9502\u79bb\u5b50\u7684\u8fc1\u79fb\u8ddd\u79bb\uff0c\u63d0\u9ad8\u4f7f\u7528\u6027\u80fd\u3002\u5728\u672a\u6765\uff0c\u9502\u79bb\u5b50\u7684\u4f7f\u7528\u8303\u56f4\u4f1a\u8fdb\u4e00\u6b65\u6269\u5927\uff0c\u9759\u7535\u7eba\u4e1d\u7684\u6280\u672f\u4e5f\u4f1a\u4e0d\u65ad\u7684\u8fdb\u6b65\uff0c\u5de5\u827a\u53c2\u6570\u66f4\u52a0\u5b8c\u5584\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

[1]\u7f57\u6807, \u5f20\u6c38\u65b0, \u8096\u542f\u632f,\u7b49. \u9759\u7535\u7eba\u4e1d\u6280\u672f\u5728\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u4e2d\u7684\u5e94\u7528\u4e0e\u5c55\u671b?[J]. \u529f\u80fd\u6750\u6599, 2016, 47(12).
\n[2]Xu B, Qian D, Wang Z, et al. ChemInform Abstract: Recent Progress in Cathode Materials Research for Advanced Lithium Ion Batteries[J]. Materials Science & Engineering R Reports, 2012, 73(5-6):51-65.
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\n[5]Li H, Bai Y, Wu F, et al. Budding willow branches shaped Na 3 V 2 (PO 4 ) 3 \/C nanofibers synthesized via an electrospinning technique and used as cathode material for sodium ion batteries[J]. Journal of Power Sources, 2015, 273:784-792.
\n[6]Niu C, Meng J, Wang X, et al. General synthesis of complex nanotubes by gradient electrospinning and controlled pyrolysis[J]. Nature Communications, 2015, 6:7402.
\n[7]Longson T J, Bhowmick R, Gu C, et al. Core\u2013Shell Interactions in Coaxial Electrospinning and Impact on Electrospun Multiwall Carbon Nanotube Core, Poly(methyl methacrylate) Shell Fibers[J]. J.phys.chem.c, 2011, 115(26):12742-12750.
\n[8]Longson T J, Bhowmick R, Gu C, et al. Core\u2013Shell Interactions in Coaxial Electrospinning and Impact on Electrospun Multiwall Carbon Nanotube Core, Poly(methyl methacrylate) Shell Fibers[J]. J.phys.chem.c, 2011, 115(26):12742-12750.
\n[9]Mizuno Y, Hosono E, Saito T, et al. Electrospinning Synthesis of Wire-Structured LiCoO2 for Electrode Materials of High-Power Li-Ion Batteries[J]. J.phys.chem.c, 2012, 116(19):10774-10780.
\n[10]Jayaraman S, Aravindan V, Suresh K P, et al. Synthesis of porous LiMn2O4 hollow nanofibers by electrospinning with extraordinary lithium storage properties.[J]. Chemical Communications, 2013, 49(59):6677-9.
\n[11]Zhu C. Electrospinning of highly electroactive carbon-coated single-crystalline LiFePO4 nanowires.[J]. Angewandte Chemie, 2011, 50(28):6278-82.<\/p>\n

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