{"id":64684,"date":"2017-02-11T06:30:28","date_gmt":"2017-02-10T22:30:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=64684"},"modified":"2017-02-10T21:22:17","modified_gmt":"2017-02-10T13:22:17","slug":"nature%e5%ad%90%e5%88%8a%ef%bc%9a%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8%e7%ba%b3%e7%b1%b3%e5%a4%9a%e5%ad%94%e7%a2%b3%e7%94%b5%e6%9e%81%e4%b8%ad%e7%a6%bb%e5%ad%90%e7%ba%a6%e6%9d%9f%e5%92%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=64684","title":{"rendered":"Nature\u5b50\u520a\uff1a\u8d85\u7ea7\u7535\u5bb9\u5668\u7eb3\u7c73\u591a\u5b54\u78b3\u7535\u6781\u4e2d\u79bb\u5b50\u7ea6\u675f\u548c\u53bb\u6eb6\u5242\u5316\u8fc7\u7a0b\u7684\u91cf\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4ece\u672c\u8d28\u4e0a\u4e86\u89e3\u7eb3\u7c73\u591a\u5b54\u78b3\u7535\u6781\u6750\u6599\u4e2d\u79bb\u5b50\u7535\u5438\u9644\u8fc7\u7a0b\u662f\u63d0\u9ad8\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u80fd\u91cf\u5b58\u50a8\u6027\u80fd\u7684\u5173\u952e\u3002\u7ecf\u5178\u7684Gouy-Chapman-Stern\u53cc\u7535\u5c42\u6a21\u578b\u5728\u9ad8\u6469\u5c14\u6d53\u5ea6\u7535\u89e3\u6db2\u60c5\u51b5\u4e0b\u5df2\u7ecf\u4e0d\u518d\u9002\u7528\uff08\u5c24\u5176\u662f\u65e0\u6eb6\u5242\u4f53\u7cfb\uff0c\u5982\u79bb\u5b50\u6db2\u4f53\uff09\u3002\u5f53\u6750\u6599\u5e73\u5747\u5b54\u5f84\u63a5\u8fd1\u6eb6\u5242\u5316\u6216\u53bb\u6eb6\u5242\u5316\u79bb\u5b50\u5c3a\u5bf8\u65f6\u8be5\u6a21\u578b\u4e5f\u4e0d\u80fd\u53cd\u5e94\u771f\u5b9e\u7684\u79bb\u5b50\u5438\u9644\u8fc7\u7a0b\u3002\u4f7f\u7528\u73b0\u6709\u7684\u4f8b\u5982Donnan\u6a21\u578b\u5bf9\u91cf\u5316\u79bb\u5b50\u5728\u590d\u6742\u5b54\u7684\u5c40\u90e8\u5438\u9644\u4f4d\u7f6e\uff0c\u8bc4\u4ef7\u78b3\u539f\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3001\u6eb6\u5242\u5206\u5b50\u6216\u79bb\u5b50\u7535\u5438\u9644\u5bfc\u81f4\u7684\u7535\u6781\u5f62\u53d8\u65f6\u4e5f\u5b58\u5728\u7f3a\u9677\u3002\u56e0\u6b64\uff0c\u76f4\u89c2\u5730\u4e86\u89e3\u590d\u6742\u5b54\u73af\u5883\u4e2d\u79bb\u5b50\u7684\u5c40\u90e8\u5206\u5e03\u884c\u4e3a\u5f88\u6709\u5fc5\u8981\uff0c\u5bf9\u6211\u4eec\u8fdb\u4e00\u6b65\u7406\u89e3\u79bb\u5b50\u5728\u7eb3\u7c73\u591a\u5b54\u78b3\u4e2d\u7535\u5438\u9644\u7684\u590d\u6742\u6027\u6709\u5f88\u5927\u5e2e\u52a9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5965\u5730\u5229\u96f7\u5965\u672c\u77ff\u4e1a\u5927\u5b66\u7269\u7406\u6240\u7684<\/strong>O. Paris<\/strong>\u6559\u6388\u548c\u5fb7\u56fd<\/strong>INM-Leibniz<\/strong>\u65b0\u6750\u6599\u7814\u7a76\u6240\u3001\u5fb7\u56fd\u8428\u5c14\u5927\u5b66<\/strong>V. Presser<\/strong>\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Nature Energy \u4e0a\u53d1\u8868\u9898\u4e3a\u201cQuantification of ion confinement and desolvation in nanoporous carbon supercapacitors with modelling and in situ <\/em>X-ray scattering\u201d\u7684\u6587\u7ae0\uff0c\u4f5c\u8005\u5229\u7528\u539f\u4f4d\u5c0f\u89d2X\u5c04\u7ebf\u6563\u5c04\uff08SAXS\uff09\u83b7\u5f97\u7684\u5b9e\u9a8c\u6570\u636e\u548c\u79bb\u5b50\u5c3a\u5bf8\u6392\u5217\u7684\u8499\u7279\u5361\u7f57\u6a21\u578b\uff08Monte Carlo simulations\uff09\u534f\u540c\u7ec4\u5408\u6765\u91cf\u5316\u79bb\u5b50\u7ea6\u675f\u548c\u53bb\u6eb6\u5242\u5316\u8fc7\u7a0b\u3002\u6d4b\u91cf\u7684\u6563\u5c04\u6570\u636e\u4e0e\u6a21\u62df\u8fc7\u7a0b\u7ec4\u5408\u8bc1\u660e\u4e86Cs+<\/sup>\u548cCl–<\/sup>\u5728\u6c34\u4e2d\u4ee5\u53ca\u5e73\u5747\u5b54\u5f84\u8fdc\u8d85\u8fc71nm\u7684\u5fae\u5b54\u4ecb\u5b54\u6df7\u5408\u7ed3\u6784\u78b3\u4e2d\u5b58\u5728\u90e8\u5206\u53bb\u6eb6\u5242\u5316\u73b0\u8c61\u3002\u6c34\u6eb6\u5242\u5316\u58f3\u7684\u7d27\u5bc6\u9644\u7740\u53ef\u6709\u6548\u5730\u963b\u6b62\u79bb\u5b50\u5728\u4e9a\u7eb3\u7c73\u5b54\u4e2d\u7684\u5b8c\u5168\u53bb\u6eb6\u5242\u5316\u3002\u968f\u7740\u7535\u538b\u7684\u589e\u52a0\uff0c\u79bb\u5b50\u503e\u5411\u4e8e\u8131\u79bb\u73b0\u5904\u73af\u5883\u8fdb\u5165\u9ad8\u7ea6\u675f\u5b54\u9053\uff0c\u8fd9\u4e00\u73b0\u8c61\u51b3\u5b9a\u4e86\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u7684\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. X<\/strong>\u5c04\u7ebf\u6563\u5c04\u4e0e\u6a21\u578b\u7ed3\u5408\u5206\u6790<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

(a)SAXS\u5f3a\u5ea6\u4e0e\u6563\u5c04\u77e2\u91cf\u957f\u5ea6\u6570\u636e\uff08\u9ed1\u70b9\uff09\uff0c\u4ee5\u53ca\u6570\u636e\u7684\u6a21\u578b\u62df\u5408\uff08\u7ea2\u7ebf\uff09\uff1b<\/p>\n

(b)\u4f7f\u7528\u9ad8\u65af\u968f\u673a\u573a\u7684\u6982\u5ff5\u5f97\u5230\u7684\u7a7a\u95f4\u5b54\u7ed3\u6784\uff0815\u00d715\u00d715nm3<\/sup>\uff09\uff1b<\/p>\n

(c)\u6c34\u76f8\u7535\u89e3\u6db2\u4e2d\uff0c\u5747\u5300\u586b\u5145\u6709\u9633\u79bb\u5b50\uff08\u84dd\u8272\uff09\u548c\u9634\u79bb\u5b50\uff08\u9ec4\u8272\uff09\u7684\u5b54\u7ed3\u6784\uff087\u00d77\u00d77nm3<\/sup>\uff09\uff1b<\/p>\n

(d)\u6a21\u62df\u7684SAXS\u5f3a\u5ea6\u4e0e\u5b9e\u6d4bSAXS\u5f3a\u5ea6\u6bd4\u8f83\uff1b<\/p>\n

(d)\u8bd5\u9a8c\u4e2d\u65bd\u52a0\u7684\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>2. <\/strong>\u7ea6\u675f\u548c\u53bb\u6eb6\u5242\u5316\u7a0b\u5ea6\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

3D\u5b54\u7ed3\u6784\u6a2a\u622a\u9762\u793a\u610f\u56fe\uff0c\u5206\u522b\u8868\u793a\u7535\u538b\u65bd\u52a0\u524d\u540e\u7ea6\u675f\u7a0b\u5ea6\uff08DoC\uff09\u548c\u53bb\u6eb6\u5242\u5316\u7a0b\u5ea6\uff08DoDS\uff09\u7684\u53d8\u5316\u8fc7\u7a0b\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u5145\u7535\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u7684\u5c40\u90e8\u91cd\u6392\u540e\u7ea6\u675f\u7a0b\u5ea6\u7684\u91cf\u5316
\n<\/strong><\/p>\n

\"\"\"\"<\/strong><\/p>\n

(a-c)\u4e0d\u540c\u78b3\u6750\u6599\u5145\u7535\u8fc7\u7a0b\u4e2dCs+<\/sup>\u548cCl–<\/sup>\u5e73\u5747\u79bb\u5b50\u7ea6\u675f\u7a0b\u5ea6\uff1b\uff08\u6d3b\u6027\u70adAC1\u5e73\u5747\u5b54\u5f841.3nm\uff1bAC2-0.9nm\uff1b\u78b3\u5316\u949b\u884d\u751f\u7684\u78b3CDC 0.65nm\uff09<\/p>\n

(d-f)\u9634\u9633\u79bb\u5b50\u57280V\u3001-0.6V\u79bb\u5b50\u7ea6\u675f\u7a0b\u5ea6\u76f4\u65b9\u56fe\uff1b\uff08\u7ea2\u8272\u5782\u7ebf\u5de6\u53f3\u5206\u522b\u4e3a\u5f31\u3001\u5f3a \u7ea6\u675f\u533a\uff09<\/p>\n

(g-i)\u4e09\u79cd\u78b3\u6750\u6599\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4e24\u7c7b\u9634\u9633\u79bb\u5b50\u6d53\u5ea6\u76f8\u5bf9\u503c\u53d8\u5316\u56fe\u3002<\/p>\n

\u56fe<\/strong>4.<\/strong> \u5c40\u90e8\u73af\u5883\u5bf9\u78b3\u7535\u6781\u7535\u5bb9\u6027\u80fd\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\" \"\"<\/strong><\/p>\n

(a)\u4e0d\u540c\u78b3\u6e90\u6700\u5927\u8d1f\u5916\u52a0\u7535\u538b\uff08-0.6V\uff09\u4e0b\u9633\u79bb\u5b50\uff08\u84dd\u8272\uff09\u548c\u9634\u79bb\u5b50\uff08\u9ec4\u8272\uff09\u53ef\u89c6\u5316\u56fe\u3002\uff08\u7ea2\u8272\u533a\u57df\u4ee3\u8868\u7535\u8377\u5bc6\u5ea6\u4e3a\u8d1f\u503c\u53bb\uff0c\u8be5\u533a\u901a\u5e38\u5728\u9633\u79bb\u5b50\u5468\u56f4\uff1b\u76f8\u53cd\u84dd\u8272\u533a\u57df\u7535\u8377\u5bc6\u5ea6\u4e3a\u6b63\uff0c\u767d\u8272\u533a\u57df\u4e3a\u96f6\u7535\u52bf\u533a\uff09<\/p>\n

(b)DoDS\u4e0eDoC\u7ebf\u6027\u76f8\u5173\u56fe\uff1b<\/p>\n

(c)\u5728-0.6V\u4e0b\u4e09\u4e2a\u78b3\u7535\u6781\u4e2d\u7684\u9633\u79bb\u5b50\u91ca\u653e\u51fa\u53bb\u6eb6\u5242\u5316\u7684\u6c34\u5206\u5b50\u6570\u76f4\u65b9\u56fe\uff0c\u7bad\u5934\u5904\u8868\u793a\u91ca\u653e\u7684\u6c34\u5206\u5b50\u7684\u5e73\u5747\u6570\u91cf\u3002<\/p>\n

(d)\u4f4d\u4e8e\u5177\u6709\u8f83\u5927DoC\u4f4d\u70b9\u4e0a\u7684\u9633\u79bb\u5b50\u6216\u9634\u79bb\u5b50\u7684\u5c40\u90e8\u7535\u6781\u7535\u8377\u7684\u5927\u5c0f\uff1b<\/p>\n

(e)\u5e73\u5747DoC\u659c\u7387\u4e0e\u5fae\u5b54\u4f53\u79ef\u6807\u51c6\u5316\u540e\u5b9e\u9a8c\u6d4b\u5f97\u7684\u7535\u5bb9\u503c\u7ebf\u6027\u76f8\u5173\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4f5c\u8005\u6210\u529f\u6784\u5efa\u4e86\u6a21\u62df\u79bb\u5b50\u5728\u7eb3\u7c73\u5b54\u7ed3\u6784\u4e2d\u7535\u5438\u9644\u8fc7\u7a0b\u7684\u7efc\u5408\u6a21\u578b\uff0c\u8be5\u6a21\u578b\u80fd\u66f4\u597d\u5730\u9884\u6d4b\u7eb3\u7c73\u591a\u5b54\u78b3\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u7684\u7535\u5bb9\u6027\u80fd\u3002\u8fd9\u4e00\u6210\u679c\u5bf9\u53cc\u7535\u5c42\u7535\u5bb9\u76f8\u5173\u73b0\u8c61\u7684\u89e3\u91ca\u4ece\u5b9e\u9a8c\u6d4b\u8bd5\u4e0a\u5347\u5230\u7406\u8bba\u6a21\u62df\u5c42\u9762\u3002\u8be5\u6a21\u578b\u5c06\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u7814\u7a76\u4ee5\u53ca\u7535\u5316\u5b66\u6c34\u5904\u7406\u7b49\u9886\u57df\u5f97\u5230\u5f88\u597d\u7684\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Quantification of ion confinement and desolvation in nanoporous carbon supercapacitors with modelling and in situ <\/em>X-ray scattering<\/a> (Nature Energy, 2017, DOI: 10.1038\/nenergy.2016.215 )<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 Starkle\u00a0\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4\u00a0422065952\u201d\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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