{"id":64427,"date":"2017-02-12T06:30:37","date_gmt":"2017-02-11T22:30:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=64427"},"modified":"2017-02-09T21:31:04","modified_gmt":"2017-02-09T13:31:04","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e4%b8%a8%e7%9f%b3%e5%a2%a8%e7%83%af%e9%87%8f%e5%ad%90%e7%82%b9%e7%9a%84%e5%88%b6%e5%a4%87%e5%8f%8a%e7%94%9f%e7%89%a9%e5%ba%94%e7%94%a8%e7%ae%80%e4%bb%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=64427","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\u4e28\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\u7684\u5236\u5907\u53ca\u751f\u7269\u5e94\u7528\u7b80\u4ecb"},"content":{"rendered":"<p>\u91cf\u5b50\u70b9\u662f\u5f53\u524d\u7684\u7814\u7a76\u70ed\u70b9\uff0c\u4f46\u76f8\u6bd4\u800c\u8a00\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\uff08GQDs\uff09\u597d\u50cf\u66f4\u53d7\u5ba0\u4e9b\u3002\u96f6\u7ef4\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\u56e0\u5176\u91cf\u5b50\u9650\u57df\u6548\u5e94\u548c\u8fb9\u754c\u6548\u5e94\u800c\u4ea7\u751f\u5e26\u9699\uff0c\u6253\u7834\u4e86\u77f3\u58a8\u70ef\u7279\u6b8a\u7684\u96f6\u5e26\u9699\u7ed3\u6784\uff0c\u53ef\u6fc0\u53d1\u51fa\u7a33\u5b9a\u7684\u8367\u5149\uff0c\u4f7f\u77f3\u58a8\u70ef\u5728\u751f\u7269\u5b66\u9886\u57df\u7684\u5e94\u7528\u6210\u4e3a\u53ef\u80fd\u3002GQDs\u5177\u6709\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\u3001\u4f4e\u6bd2\u6027\u3001\u7a33\u5b9a\u7684\u7684\u8367\u5149\u7279\u6027\u3002\u800c\u5f71\u54cdGQDs\u53d1\u5149\u6027\u80fd\u7684\u56e0\u7d20\u6709\u5f88\u591a\uff0c\u5305\u62ec\u5c3a\u5bf8\u3001\u6fc0\u53d1\u6ce2\u957f\u3001pH\u503c\u3001GQDs\u7684\u6d53\u5ea6\u3001\u6eb6\u5242\u7b49\u3002\u968f\u7740GQDs \u5728\u7ec6\u80de\u6210\u50cf\u3001\u7ec4\u7ec7\u6807\u8bb0\u548c\u836f\u7269\u8f93\u9001\u7b49\u751f\u7269\u533b\u5b66\u9886\u57df\u5e94\u7528\u7684\u4e0d\u65ad\u6df1\u5316\uff0c\u5bf9\u5176\u8367\u5149\u6027\u80fd\u63d0\u51fa\u4e86\u66f4\u9ad8\u7684\u8981\u6c42\u3002\u4e3a\u7cbe\u786e\u63a7\u5236GQDs\u7684\u5f62\u8c8c\u548c\u5c3a\u5bf8\u63d0\u9ad8\u5176\u8367\u5149\u6027\u80fd\uff0c\u5176\u5236\u5907\u8fc7\u7a0b\u3001\u65b9\u6cd5\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u4e0b\u6587\u4e3b\u8981\u4ecb\u7ecd\u76ee\u524dGQDs\u7684\u5236\u5907\u65b9\u6cd5\u4ee5\u53ca\u5728\u4e0d\u540c\u751f\u7269\u9886\u57df\u7684\u5e94\u7528\u4f18\u52bf\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>1. GQDs<\/strong><strong>\u7684\u5236\u5907<\/strong><\/span><\/p>\n<p>\u76ee\u524d\u7528\u6765\u5236\u5907GQDs \u7684\u65b9\u6cd5\u4e00\u822c\u53ef\u4ee5\u5206\u4e3a\u4e24\u7c7b: \u81ea\u4e0a\u800c\u4e0b\u6cd5(Top-down)\u548c\u81ea\u4e0b\u800c\u4e0a\u6cd5(Bottom-up)<sup>[1]<\/sup>\u3002Top-down\u6cd5\u662f\u901a\u8fc7\u5316\u5b66\u3001\u7535\u5316\u5b66\u6216\u7269\u7406\u624b\u6bb5\u5c06\u77f3\u58a8\u70ef\u6750\u6599\u88c2\u89e3\u3001\u7834\u788e\u6210\u5c0f\u5c3a\u5bf8\u91cf\u5b50\u70b9\uff0cBottom-up\u6cd5\u5219\u662f\u4ee5\u5c0f\u7684\u6709\u673a\u5206\u5b50\u4e3a\u524d\u9a71\u4f53, \u901a\u8fc7\u70ed\u89e3\u78b3\u5316\u6216\u4e00\u7cfb\u5217\u5316\u5b66\u53cd\u5e94\u9010\u6b65\u5316\u5408\u5f62\u6210\u5c3a\u5bf8\u8f83\u5927\u7684GQDs\u3002Bottom-up\u6cd5\u53ef\u4ee5\u901a\u8fc7\u63a7\u5236\u53cd\u5e94\u6761\u4ef6\u6765\u8c03\u8282GQDs \u7684\u5f62\u72b6\u548c\u5c3a\u5bf8\uff0c\u5728GQDs \u7684\u751f\u7269\u5e94\u7528\u65b9\u9762\u5177\u6709\u4e0d\u53ef\u5ffd\u7565\u7684\u4f18\u52bf\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>Top-down<\/strong><strong>\u6cd5<\/strong><\/span><\/p>\n<p>\u8fd9\u7c7b\u65b9\u6cd5\u64cd\u4f5c\u6b65\u9aa4\u76f8\u5bf9\u7b80\u5355\u3001\u4ea7\u7387\u8f83\u9ad8\uff0c\u4e5f\u662f\u76ee\u524d\u5e94\u7528\u6700\u591a\u7684\u4e00\u7c7b\u65b9\u6cd5\u3002\u4f46\u662f\u7531\u4e8e\u5176\u7834\u788e\u4f4d\u70b9\u7684\u968f\u673a\u6027\uff0c\u96be\u4ee5\u63a7\u5236GQDs \u7684\u5c3a\u5bf8\u548c\u5f62\u8c8c<sup>[2]<\/sup>\u3002Top-down \u6cd5\u4e3b\u8981\u5305\u62ec\u5f3a\u9178\u6c27\u5316\u6cd5\u3001\u6c34\u70ed\u6cd5\u3001\u6eb6\u5242\u70ed\u6cd5\u548c\u7535\u5316\u5b66\u6cd5\u7b49\u65b9\u6cd5\u3002<\/p>\n<ul>\n<li>\u5f3a\u9178\u6c27\u5316\u6cd5<\/li>\n<\/ul>\n<p>\u8be5\u65b9\u6cd5\u9002\u5408\u4e8e\u4ee5\u4f4e\u6210\u672c\u6613\u83b7\u5f97\u7684\u78b3\u6e90\u4e3a\u524d\u4f53\u5927\u89c4\u6a21\u6eb6\u5242\u5316\u751f\u4ea7\u78b3\u91cf\u5b50\u70b9\u3002\u8be5\u8fc7\u7a0b\u5229\u7528\u5f3a\u9178\u7684\u6c27\u5316\u6027\uff0c\u5c06\u6c27\u5316\u77f3\u58a8\u70ef(GO)\u76f4\u63a5\u5207\u5272\u5f97\u5230GQDs\u3002\u4f46\u4f1a\u5728\u4ea7\u7269\u7684\u8868\u9762\u5f15\u5165\u5927\u91cf\u5e26\u8d1f\u7535\u7684\u542b\u6c27\u5b98\u80fd\u56e2\uff0c\u542b\u6c27\u5b98\u80fd\u56e2\u7684\u5b58\u5728\u4f1a\u7834\u574f\u77f3\u58a8\u70ef\u78b3\u7ed3\u6784\uff0c\u5176\u751f\u7269\u6bd2\u6027\u4e5f\u4f1a\u589e\u5f3a\u3002\u4e14\u8fc7\u91cf\u6c27\u5316\u5242\u5f88\u96be\u53bb\u9664\uff0cGQDs \u4ea7\u7387\u4e5f\u968f\u4e4b\u964d\u4f4e\u3002\u56fe1\u6240\u793a\u9178\u6c27\u5316\u5fae\u6ce2\u8f85\u52a9\u5236\u5907\u91cf\u5b50\u70b9\u8fc7\u7a0b\uff0c\u7ecf\u8fc7\u787c\u6c22\u5316\u94a0\u8fd8\u539f\u540e\u53ef\u5f97\u5230\u7a33\u5b9a\u53d1\u84dd\u5149\u7684\u91cf\u5b50\u70b9\u3002\u4e14\u8fd8\u539f\u8fc7\u7a0b\u53ef\u4f7f\u91cf\u5b50\u4ea7\u7387\u753111.7%\u63d0\u9ad8\u523022.9%<sup>[3]<\/sup>\u3002<\/p>\n<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-64428 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/1-6.jpg\" width=\"496\" height=\"324\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/1-6.jpg 496w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/1-6-300x196.jpg 300w\" sizes=\"(max-width: 496px) 100vw, 496px\" \/>\u56fe<\/strong><strong>1 <\/strong><strong>\u7eff\u8272\u8367\u5149<\/strong><strong>GQDs<\/strong><strong>\u548c\u84dd\u8272\u8367\u5149<\/strong><strong>GQDs<\/strong><strong>\u5236\u5907\u6d41\u7a0b\u56fe<\/strong><strong><sup>[3]<\/sup><\/strong><\/p>\n<ul>\n<li>\u6c34\u70ed\u3001\u6eb6\u5242\u70ed\u6cd5<\/li>\n<\/ul>\n<p>\u6c34\u70ed\u6cd5\u5236\u5907GQDs \u7684\u673a\u7406\u662f\u901a\u8fc7\u5bf9\u77f3\u58a8\u70ef\u8fdb\u884c\u5f3a\u9178\u6c27\u5316\uff0c\u5728\u78b3\u6676\u683c\u4e0a\u5f15\u5165\u73af\u6c27\u57fa\u7b49\u542b\u6c27\u5b98\u80fd\u56e2\uff0c\u5e76\u4e14\u5728\u5ba4\u6e29\u4e0b\u8fdb\u4e00\u6b65\u6c27\u5316\u4e3a\u7fb0\u57fa\u5bf9\u3002\u7531\u4e8e\u7fb0\u57fa\u5bf9\u4e0d\u7a33\u5b9a\uff0c\u5728\u6c34\u70ed\u6761\u4ef6\u4e0b\u53ef\u4ee5\u9664\u53bb\u73af\u6c27\u952e\u4e0a\u7684\u6c27\u539f\u5b50\uff0c\u4ece\u800c\u7834\u788e\u6210GQDs\uff08\u5982\u56fe2\u6240\u793a\uff09\u3002\u6eb6\u5242\u70ed\u6cd5\u7684\u673a\u7406\u4e0e\u6c34\u70ed\u6cd5\u57fa\u672c\u76f8\u540c\uff0c\u5176\u4e3b\u8981\u533a\u522b\u662f\u4f7f\u7528\u4e86\u6709\u4e00\u5b9a\u8fd8\u539f\u6027\u7684\u6709\u673a\u6eb6\u5242\u66ff\u4ee3\u6c34\u4f5c\u4e3a\u6eb6\u5242\uff0c\u5728\u7834\u788eGO\u7684\u540c\u65f6\u5b9e\u73b0\u8fd8\u539f\u3002<\/p>\n<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-64435 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/2-4.jpg\" width=\"517\" height=\"180\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/2-4.jpg 517w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/2-4-300x104.jpg 300w\" sizes=\"(max-width: 517px) 100vw, 517px\" \/>\u56fe<\/strong><strong>2 <\/strong><strong>\u6c34\u70ed\u6cd5\u5207\u5272\u4ea7\u751f<\/strong><strong>GQDs <\/strong><strong>\u7684\u673a\u7406\u793a\u610f\u56fe<\/strong><strong><sup>[4]<\/sup><\/strong><\/p>\n<ul>\n<li>\u7535\u5316\u5b66\u6cd5<\/li>\n<\/ul>\n<p>\u7535\u5316\u5b66\u6cd5\u662f\u901a\u8fc7\u7535\u6781\u65bd\u52a0\u8db3\u591f\u7684\u7535\u4f4d\uff0c\u4f7f\u6c34\u7535\u79bb\u51faOH\u2022\u548cO\u2022\u5c06\u78b3\u6676\u683c\u6c27\u5316\uff0c\u5728\u77f3\u58a8\u70ef\u57fa\u9762\u4e0a\u4ea7\u751f\u5448\u7ebf\u6027\u6392\u5217\u7684\u73af\u6c27\u57fa\u3001\u7fa7\u57fa\u3001\u7f9f\u57fa\u7b49\u542b\u6c27\u57fa\u56e2\uff0c\u50cf\u201c\u526a\u5200\u201d\u4e00\u6837\u5c06\u77f3\u58a8\u70ef\u526a\u788e\u6210GQDs\uff08\u56fe3\uff09\u3002\u8be5\u53cd\u5e94\u8fc7\u7a0b\u4e00\u822c\u4ece\u77f3\u58a8\u70ef\u8fb9\u7f18\u5f00\u59cb\uff0c\u7f3a\u9677\u5904\u53cd\u5e94\u52a0\u5feb\u3002\u7531\u4e8e\u542b\u6c27\u57fa\u56e2\u7684\u5b58\u5728\uff0cGQDs \u5728\u6c34\u6eb6\u6db2\u4e2d\u53ef\u4ee5\u7a33\u5b9a\u5206\u5e03\uff0c\u800c\u4e14\u91cf\u5b50\u70b9\u8868\u9762\u5b98\u80fd\u56e2\u90e8\u5206\u53d6\u51b3\u4e8e\u4f7f\u7528\u7684\u7535\u89e3\u6db2\uff0c\u4e0d\u540c\u6709\u673a\u7535\u89e3\u6db2\u9634\u79bb\u5b50\u7684\u5d4c\u5165\u4e5f\u4f1a\u5f15\u5165\u4e0d\u540c\u7684\u6742\u539f\u5b50\uff0c\u4ece\u800c\u6539\u53d8GQDs\u7684\u5149\u5b66\u7279\u6027\u3002<\/p>\n<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-64430 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/3-1.jpg\" width=\"500\" height=\"280\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/3-1.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/3-1-300x168.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/>\u56fe<\/strong><strong>3 <\/strong><strong>\u7535\u5316\u5b66\u65b9\u6cd5\u5236\u5907<\/strong><strong>GQDs<\/strong><strong>\u53cd\u5e94\u793a\u610f\u56fe<\/strong><strong><sup>[5]<\/sup><\/strong><\/p>\n<ul>\n<li>\u7269\u7406\u6cd5<\/li>\n<\/ul>\n<p><strong>\u8d85\u58f0\u5265\u79bb\u6cd5<\/strong>\u5229\u7528\u8d85\u58f0\u771f\u7a7a\u6c14\u6ce1\u5f62\u6210\u548c\u7834\u788e\u8fc7\u7a0b\u4ea7\u751f\u7684\u9ad8\u901f\u6db2\u4f53\u5c04\u6d41\u63d0\u4f9b\u5f3a\u7684\u6d41\u4f53\u526a\u529b\u4ece\u800c\u5b9e\u73b0\u77f3\u58a8\u70ef\u7684\u7834\u788e\u3002\u4e0e\u4f20\u7edf\u7684\u901a\u8fc7\u6c27\u5316\u53ca\u542b\u6c27\u57fa\u56e2\u7684\u65ad\u88c2\u6765\u7834\u788e\u77f3\u58a8\u70ef\u65b9\u6cd5\u76f8\u6bd4\uff0c\u8d85\u58f0\u5265\u79bb\u6cd5\u56e0\u4e3a\u6574\u4e2a\u8fc7\u7a0b\u4e0d\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u4e0d\u4f1a\u5f15\u5165\u542b\u6c27\u57fa\u56e2\uff0c\u6ca1\u6709\u5316\u5b66\u8fd8\u539f\u7b49\u6b65\u9aa4\uff0c\u6709\u6548\u5730\u907f\u514d\u4e86\u5b98\u80fd\u56e2\u7684\u5f15\u5165\u4ee5\u53ca\u7f3a\u9677\u7684\u4ea7\u751f\u3002<\/p>\n<p><strong>\u7535\u5b50\u675f\u523b\u8680\u6cd5<\/strong>\u662f\u5229\u7528\u7eb3\u7c73\u523b\u8680\u6280\u672f, \u5728\u5927\u5c3a\u5bf8\u77f3\u58a8\u70ef\u7247\u5c42\u4e0a\u8fdb\u884c\u523b\u8680\uff0c\u7cbe\u786e\u5730\u63a7\u5236GQDs \u7684\u5f62\u72b6\u548c\u5c3a\u5bf8\uff0c\u8be5\u65b9\u6cd5\u5236\u5907\u7684GQDs\u6709\u7a33\u5b9a\u7684\u8367\u5149\u6027\u80fd\u3002\u4f46\u7531\u4e8e\u523b\u70db\u6280\u672f\u5206\u8fa8\u7387\u7684\u9650\u5236\uff0c\u8fd9\u79cd\u65b9\u6cd5\u5236\u5907\u51fa\u7684GQDs \u5c3a\u5bf8\u6700\u5c0f\u4e3a10 nm\uff0c\u5e76\u53d7\u5230\u7cbe\u5bc6\u8bbe\u5907\u7684\u9700\u6c42\u4ee5\u53ca\u64cd\u4f5c\u590d\u6742\u7a0b\u5ea6\u7684\u9650\u5236\uff0c\u8be5\u65b9\u6cd5\u5f88\u96be\u5b9e\u73b0GQDs \u7684\u5927\u6279\u91cf\u5236\u5907\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>Bottom-up <\/strong><strong>\u6cd5<\/strong><\/span><\/p>\n<p>Bottom-up \u6cd5\u4e2d\u6700\u5e38\u7528\u7684\u662f\u6eb6\u6db2\u5316\u5b66\u6cd5\u548c\u70ed\u89e3\u70ad\u5316\u6cd5\u3002\u5236\u5907GQDs\u5c3a\u5bf8\u53ef\u63a7\u4f46\u4ea7\u7387\u8f83\u4f4e\uff0c\u5c24\u5176\u662f\u6eb6\u6db2\u5316\u5b66\u6cd5\u4e0d\u53ef\u907f\u514d\u7684\u4f1a\u51fa\u73b0\u56e2\u805a\u3002<\/p>\n<ul>\n<li>\u6eb6\u6db2\u5316\u5b66\u6cd5<\/li>\n<\/ul>\n<p style=\"text-align: left;\">\u6eb6\u6db2\u5316\u5b66\u6cd5\u662fbottom-up\u6cd5\u4e2d\u8f83\u4e3a\u5e38\u7528\u7684\u529e\u6cd5\uff0c\u5c0f\u5206\u5b50\u524d\u4f53\u7ecf\u8fc7\u6c27\u5316\u805a\u5408\u7b49\u4e00\u7cfb\u5217\u5316\u5b66\u53cd\u5e94\u9010\u6b65\u751f\u6210\u5355\u5206\u6563GQDs\u3002\u56fe4\u4e3a\u901a\u8fc7\u5206\u5e03\u6c27\u5316\u805a\u5408\u5f62\u6210\u6811\u679d\u72b6\u805a\u82ef\u6491\u5236\u5907\u542b168\u3001132.170\u4e2a\u78b3\u539f\u5b50\u7684GQDs<sup>[6]<\/sup>\u3002\u4f46\u662f\u968f\u7740\u53cd\u5e94\u7684\u8fdb\u884c, \u805a\u5408\u4ea7\u7269GQDs\u5c3a\u5bf8\u4f1a\u4e0d\u65ad\u589e\u5927,\u800c \u03c0-\u03c0\u952e\u4e4b\u95f4\u7684\u5f15\u529b\u7684\u4e0d\u65ad\u589e\u5f3a\u4f1a\u5bfc\u81f4\u56e2\u805a\u7684\u51fa\u73b0\u3002\u901a\u5e38\u6240\u4f7f\u7528\u7684\u589e\u6eb6\u65b9\u6cd5\u662f\u5728GQDs \u8fb9\u7f18\u5904\u8fde\u63a5\u589e\u6eb6\u57fa\u56e2, \u5f53GQDs \u4e0e\u6eb6\u5242\u4e4b\u95f4\u7684\u5438\u5f15\u529b\u5927\u4e8e\u77f3\u58a8\u70ef\u7247\u5c42\u4e4b\u95f4\u7684\u5438\u5f15\u529b\u65f6, \u6eb6\u89e3\u5ea6\u5c31\u4f1a\u76f8\u5e94\u7684\u589e\u5927\u3002<\/p>\n<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-64436 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/4-1.jpg\" width=\"507\" height=\"590\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/4-1.jpg 507w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/4-1-258x300.jpg 258w\" sizes=\"(max-width: 507px) 100vw, 507px\" \/>\u56fe4 <\/strong><strong>\u5206\u6b65\u6c27\u5316\u805a\u5408\u7531<\/strong><strong>3-<\/strong><strong>\u7898<\/strong><strong>-4-<\/strong><strong>\u6eb4\u82ef\u80fa\u5408\u6210<\/strong><strong>GQD<\/strong><strong>\u7684\u8fc7\u7a0b<\/strong><strong><sup>[6]<\/sup><\/strong><\/p>\n<ul>\n<li>\u70ed\u89e3\u78b3\u5316\u6cd5<\/li>\n<\/ul>\n<p>\u70ed\u89e3\u70ad\u5316\u6cd5\u7684\u4e3b\u8981\u539f\u7406\u662f\u5c06\u6709\u673a\u76d0\u7b49\u6709\u673a\u5c0f\u5206\u5b50\u524d\u4f53\u52a0\u70ed\u81f3\u5176\u7194\u70b9\u4ee5\u4e0a\uff0c\u7136\u540e\u51b7\u51dd\u96c6\u7ed3\u5f62\u6838\u957f\u5927\uff0c\u6700\u7ec8\u5f62\u6210\u4e00\u5b9a\u5c3a\u5bf8\u548c\u5f62\u72b6\u7684GQDs\u3002\u6240\u7528\u7684\u524d\u4f53\u5305\u62ec\u6709\u673a\u76d0\uff08\u4f8b\u5982\uff0c\u5341\u516b\u70f7\u57fa\u67e0\u6aac\u9178\u94f5\u6216\u4e8c\u7518\u9187\u94f5\u67e0\u6aac\u9178\u76d0\uff09\u3001\u7518\u6cb9\u3001 L-\u8c37\u6c28\u9178\u9178\u3001\u6297\u574f\u8840\u9178\u3001\u67e0\u6aac\u9178\u3001\u4e59\u4e8c\u80fa\u56db\u4e59\u9178\u9178\u4e8c\u94a0\u76d0\u7b49\u3002\u56fe5\u4e3aChi \u7b49<sup>[7]<\/sup>\u901a\u8fc7\u5bf9\u67e0\u6aac\u9178\u8fdb\u884c\u70ad\u5316\u5236\u5907\u51fa15 nm\u7684GQDs\uff0c\u4e14\u5176\u91cf\u5b50\u4ea7\u7387\u76f8\u5bf9\u8f83\u9ad8\u3002<\/p>\n<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-64432 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/5.jpg\" width=\"429\" height=\"409\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/5.jpg 429w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/5-300x286.jpg 300w\" sizes=\"(max-width: 429px) 100vw, 429px\" \/>\u56fe<\/strong><strong>5 <\/strong><strong>\u67e0\u6aac\u9178\u78b3\u5316\u5f62\u6210<\/strong><strong>GQDs <\/strong><strong>\u548c<\/strong><strong>GO <\/strong><strong>\u7684\u793a\u610f\u56fe<\/strong><strong><sup>[7]<\/sup><\/strong><\/p>\n<p><span style=\"color: #ff0000;\"><strong>GQDs<\/strong><strong>\u7684\u529f\u80fd\u5316<\/strong><\/span><\/p>\n<p>GQDs\u7684\u8367\u5149\u6027\u80fd\u5f88\u5927\u7a0b\u5ea6\u4e0a\u7531\u5176\u5927\u5c0f\u751a\u81f3\u5f62\u72b6\u6240\u51b3\u5b9a\uff0c\u800c\u8868\u9762\u7f3a\u9677\u53d1\u5149\u5219\u4f9d\u8d56\u4e8e\u91cf\u5b50\u70b9\u8868\u9762\u5b98\u80fd\u56e2\u7684\u6027\u8d28\uff0c\u56e0\u6b64\u901a\u8fc7\u5f62\u8c8c\u8c03\u63a7\u3001\u5316\u5b66\u4fee\u9970\u7b49\u65b9\u6cd5\u53ef\u63d0\u9ad8GQDs\u7684\u8367\u5149\u91cf\u5b50\u6548\u7387\u5b9e\u73b0\u8367\u5149\u8c03\u63a7\u3002<\/p>\n<p>C60 \u5f00\u7b3c\u6cd5\u662f\u6709\u6548\u63a7\u5236GQDs\u5f62\u72b6\u548c\u5c3a\u5bf8\u7684\u65b9\u6cd5\uff0c\u901a\u8fc7\u63a7\u5236\u9000\u706b\u6e29\u5ea6\u548c\u78b3\u7c07\u805a\u5408\u7684\u5bc6\u5ea6\u53ef\u5236\u5907\u4e09\u89d2\u5f62\u3001\u5e73\u884c\u56db\u8fb9\u5f62\u3001\u68af\u5f62\u5f62\u72b6\u3001\u516d\u89d2\u5f62\u548c\u8611\u83c7\u5f62\u7684GQDs\u3002\u5982\u56fe6\u6240\u793a\uff0c\u9000\u706b\u6e29\u5ea6\u4e3a725K \u65f6\uff0cGODs \u5448\u4e09\u89d2\u5f62\u6216\u516d\u89d2\u8611\u83c7\u72b6\u548c\u82b1\u6735\u72b6\uff1b\u5728825 K \u4e0b\u9000\u706b\u65f6\uff0c\u5c0f\u5c3a\u5bf8GQDs \u805a\u5408\u6210\u4e3a\u5c3a\u5bf8\u8f83\u5927\u7684\u516d\u8fb9\u5f62GQDs<sup>[8]<\/sup>\u3002\u901a\u8fc7\u6a21\u677f\u805a\u5408\u3001\u5408\u6210\u524d\u9884\u5206\u79bb\u6280\u672f\u7b49\u4e5f\u53ef\u5b9e\u73b0\u5bf9GQDs\u5c3a\u5bf8\u7684\u8c03\u63a7\u3002<\/p>\n<p>\u901a\u8fc7\u8c03\u5242pH\u3001\u8fd8\u539f\u5242\u8fd8\u539f\u7b49\u65b9\u6cd5\u8fdb\u884c\u6c27\u5316\u7a0b\u5ea6\u63a7\u5236\u6216\u5229\u7528\u6709\u673a\u7269\u8868\u9762\u949d\u5316\uff08\u5e38\u901a\u8fc7\u9170\u80fa\u5316\u53cd\u5e94\u5b9e\u73b0\uff09\u3001\u6742\u539f\u5b50\u63ba\u6742\u7684\u65b9\u6cd5\u53ef\u5b9e\u73b0\u53d1\u5149\u7684\u591a\u8272\u8c03\u63a7\u3002<\/p>\n<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-64433 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/6.jpg\" width=\"471\" height=\"703\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/6.jpg 471w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/6-201x300.jpg 201w\" sizes=\"(max-width: 471px) 100vw, 471px\" \/>\u56fe<\/strong><strong>6 C60 <\/strong><strong>\u5f00\u7b3c\u6cd5\u5236\u5907<\/strong><strong>GQDs <\/strong><strong>\u793a\u610f\u56fe<\/strong><strong><sup>[8]<\/sup><\/strong><\/p>\n<p><span style=\"color: #0000ff;\"><strong>2. GQDs<\/strong><strong>\u5728\u751f\u7269\u9886\u57df\u5e94\u7528<\/strong><\/span><\/p>\n<p>GQDs \u5177\u6709\u66ff\u4ee3\u91cd\u91d1\u5c5e\u91cf\u5b50\u70b9\u6210\u4e3a\u73af\u5883\u53cb\u597d\u91cf\u5b50\u70b9\u7684\u6f5c\u529b\uff0c\u79d1\u5b66\u5bb6\u4eec\u5229\u7528\u5176\u53ef\u8c03\u8282\u7684\u5149\u81f4\u53d1\u5149\u6027\u3001\u4f4e\u7ec6\u80de\u6bd2\u6027\u548c\u9ad8\u7684\u751f\u7269\u76f8\u5bb9\u6027\u5df2\u6210\u529f\u5f00\u5c55\u4e86GQDs\u5728\u7ec6\u80de\u6210\u50cf\u3001\u751f\u7269\u4f20\u611f\u548c\u836f\u7269\u8f93\u8fd0\u7b49\u9886\u57df\u7684\u5e94\u7528\u7814\u7a76\u5de5\u4f5c\uff0c\u4e3a\u5176\u5728\u751f\u547d\u3001\u73af\u5883\u9886\u57df\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n<ul>\n<li>\u8367\u5149\u6210\u50cf<\/li>\n<\/ul>\n<p>\u76f8\u5bf9\u4e8e\u76ee\u524d\u4f7f\u7528\u7684\u7684\u6709\u673a\u3001\u65e0\u673a\u7684\u91cf\u5b50\u70b9\u548c\u8367\u5149\u5242\uff0cGODs \u5177\u6709\u7a81\u51fa\u7684\u5206\u8fa8\u7387\u3001\u8367\u5149\u7a33\u5b9a\u6027\u548c\u8f83\u4f4e\u7684\u7ec6\u80de\u6bd2\u6027\u548c\u8f83\u9ad8\u7684\u751f\u7269\u76f8\u5bb9\u6027<sup>[5]<\/sup>\uff0c\u6240\u4ee5\u53ef\u4ee5\u7528\u4e8e\u7ec6\u80de\u548c\u751f\u7269\u6210\u50cf\u3002<\/p>\n<ul>\n<li>\u751f\u7269\u4f20\u611f\u5668<\/li>\n<\/ul>\n<p>GQDs\u7684\u8367\u5149\u548c\u7535\u5316\u5b66\u6027\u8d28\u5bf9\u5fae\u5c0f\u7684\u6270\u52a8\u5f88\u654f\u611f\uff0c\u4e14\u5176\u5c3a\u5bf8\u5c0f\u53ef\u4e0e\u751f\u7269\u5206\u5b50\u901a\u8fc7\u80fd\u91cf\u5171\u632f\u8f6c\u79fb\u7b49\u53d1\u751f\u5bc6\u5207\u76f8\u4e92\u4f5c\u7528\uff0c\u56e0\u6b64\u5177\u6709\u5f88\u5927\u7684\u4f20\u611f\u5e94\u7528\u6f5c\u529b\u3002\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\u4e0e\u65e0\u673a\u6216\u6709\u673a\u7269\u53d1\u751f\u76f8\u4e92\u4f5c\u7528\u65f6\u53ef\u80fd\u5bfc\u81f4GQDs \u7684\u8367\u5149\u731d\u706d\uff0c\u6839\u636e\u8fd9\u4e9b\u7279\u6027, \u53ef\u4ee5\u5236\u4f5c\u6210\u751f\u7269\u4f20\u611f\u5668\u4f7f\u4f20\u611f\u7075\u654f\u5ea6\u3001\u9009\u62e9\u6027\u5f97\u5230\u6539\u5584\u3002<\/p>\n<ul>\n<li>\u836f\u7269\u8f93\u8fd0<\/li>\n<\/ul>\n<p>GQDs \u5177\u6709\u5927\u7684\u6bd4\u8868\u9762\u79ef\u53ef\u4ee5\u4e0e\u591a\u79cd\u5206\u5b50\u901a\u8fc7\u03c0-\u03c0\u952e\u3001\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u3001\u7269\u7406\u5438\u9644\u7b49\u76f8\u4e92\u4f5c\u7528\u529b\u7ed3\u5408\uff0c\u540c\u65f6\u5b83\u8fd8\u6709\u5f88\u597d\u5730\u7ec6\u80de\u76f8\u5bb9\u6027\u53ef\u4f7f\u7ec6\u80de\u6bd2\u6027\u6700\u5c0f\u5316\uff0c\u6240\u4ee5GQDs \u662f\u8fd0\u8f7d\u836f\u7269\u7684\u8f83\u4e3a\u5b89\u5168\u7684\u4f18\u826f\u8f7d\u4f53\u3002<\/p>\n<ul>\n<li>\u5149\u52a8\u529b\u6cbb\u7597<\/li>\n<\/ul>\n<p>\u5df2\u7ecf\u53d1\u73b0\u7531\u4e8eGQDs\u8868\u9762\u5b58\u5728\u7684\u7f3a\u9677\uff0c\u5728\u84dd\u5149\u7167\u5c04\u4e0b\u53ef\u4ee5\u4ea7\u751f\u6d3b\u6027\u6c27\u81ea\u7531\u57fa(ROS)\u4ee5\u53ca\u5355\u7ebf\u6001\u6c27\uff0c\u7ec6\u80de\u6444\u53d6GQDs\u540eROS\u589e\u52a0<sup>[9]<\/sup>\u3002\u800c\u6d3b\u6027\u6c27\u81ea\u7531\u57fa\u53ef\u4ee5\u5bfc\u81f4\u7ec6\u80de\u7684\u51cb\u4ea1\uff0c\u56e0\u6b64GQDs 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\u751f\u7269\u6bd2\u6027\u7684\u7814\u7a76\u5927\u591a\u90fd\u5ffd\u7565\u4e86GQDs\u5728\u5149\u7167\u4e0b\u6f5c\u5728\u7684\u5149\u654f\u6bd2\u6027\uff0cGQDs \u5728\u5149\u7684\u6fc0\u53d1\u4e0b\u4f1a\u4ea7\u751f\u6d3b\u6027\u6c27\u81ea\u7531\u57fa\uff0c\u4f1a\u964d\u4f4e\u7ec6\u80de\u6d3b\u6027\u3002\u968f\u7740\u7814\u7a76\u7684\u4e0d\u65ad\u6df1\u5165\uff0cGQDs\u7684\u5e94\u7528\u5c06\u6539\u53d8\u751f\u7269\u533b\u5b66\u7814\u7a76\uff0c\u540c\u65f6GQDs\u5c06\u5728\u80fd\u91cf\u5b58\u50a8\u8f6c\u5316\u3001\u5149\u50ac\u5316\u7b49\u65b0\u578b\u9886\u57df\u5d2d\u9732\u5934\u89d2\u6210\u4e3a\u771f\u6b63\u7684\u201cbig small things\u201d\u3002<\/p>\n<p><strong>\u53c2\u8003\u6587\u732e<\/strong><\/p>\n<p>[1]\u00a0\u00a0 Zheng X T, Ananthanarayanan A, Luo K Q, et al. Glowing graphene quantum dots and carbon dots: properties, syntheses, and biological applications [J]. Small, 2015, 11(14): 1620-1636.<\/p>\n<p>[2]\u00a0\u00a0 Hao Y, Liu Z Q, Sun X D. Preparation of Graphene Quantum Dots and Their Biological Applications [J]. Journal Of Inorganic Materials, 2016, 31(4): 337.<\/p>\n<p>[3] Li L, Ji J, Feu R, et al. A facile microwave avenue to electrochemiluminescent two-color graphene quantum dots [J]. Adv. Funct.Mater., 2012, 22(14): 2971\u20132979.<\/p>\n<p>[4] Pan D, Zhang J, Li Z, et al. Hydrothermal route for cutting graphene sheets into blue-Luminescent graphene quantum dots [J]. Adv. Mater. 2010, 22(6): 734\u2013738.<\/p>\n<p>[5] Zhang M, Bai L, Shang W, et al<em>. <\/em>Facile synthesis of watersoluble, highly fluorescent graphene quantum dots as a robust biological label for stem cells [J]. J. Mater. Chem., 2012, 22(15): 7461\u20137467.<\/p>\n<p>[6] Xin Yan, Xiao Cui, and Liang-shi Li. Synthesis of large, stable colloidal graphene quantum dots with tunable size [J]. Journal of the American Chemical Society, 2010, 132: 5944\u20135945.<\/p>\n<p>[7] Dong Y, Shao J, Chen C, et al. Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid [J]. Carbon, 2012, 50(12): 4738\u20134743.<\/p>\n<p>[8] Lu J, Yeo P S, Gan C K, et al. Transforming C60 molecules into graphene quantum dots [J]. Nat. Nanotechnol., 2011, 6(4): 247\u2013252.<\/p>\n<p>[9] Markovic Z M , Ristic B Z , Arsikin K M, et al. Graphene quantum dots as autophagy-inducing photodynamic agents[J]. Biomaterials.2012, 33(29): 7084\u20137092.<\/p>\n<p>[10] Jiang F, Chen D, Li R, et al. Eco-friendly synthesis of size-controllableamine-functionalized\u00a0graphene\u00a0quantum dotswith antimycoplasma properties [J]. Nanoscale, 2013, 5: 1137-1142.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4Starkle\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u5411\u5404\u5927\u56e2\u961f\u8bda\u5fc3\u7ea6\u7a3f\uff0c\u8bfe\u9898\u7ec4\u6700\u65b0\u6210\u679c\u3001\u65b9\u5411\u603b\u7ed3\u3001\u56e2\u961f\u8bbf\u8c08\u3001\u5b9e\u9a8c\u6280\u80fd\u7b49\u7686\u53ef\u6295\u7a3f\uff0c\u4f18\u79c0\u7a3f\u4ef6\u4e00\u7ecf\u5f55\u7528\uff0c\u6211\u4eec\u4f1a\u5949\u4e0a\u7a3f\u916c\uff0c\u8bf7\u8054\u7cfb\uff1a\u90ae\u7bb1tougao@cailiaoren.com \u6216 QQ\uff1a97482208\u3002<\/p>\n<p>\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<a href=\"http:\/\/www.cailiaoren.com\/\" target=\"_blank\">\u6750\u6599\u4eba<\/a>\u3001\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u91cf\u5b50\u70b9\u662f\u5f53\u524d\u7684\u7814\u7a76\u70ed\u70b9\uff0c\u4f46\u76f8\u6bd4\u800c\u8a00\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\uff08GQDs\uff09\u597d\u50cf\u66f4\u53d7\u5ba0\u4e9b\u3002\u96f6\u7ef4\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\u56e0\u5176\u91cf\u5b50\u9650\u57df\u6548\u5e94\u548c\u8fb9\u754c\u6548\u5e94\u800c\u4ea7\u751f\u5e26\u9699\uff0c\u6253\u7834\u4e86\u77f3\u58a8\u70ef\u7279\u6b8a\u7684\u96f6\u5e26\u9699\u7ed3\u6784\uff0c\u53ef\u6fc0&#8230;<\/p>\n","protected":false},"author":1797,"featured_media":64430,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-64427","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/64427"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1797"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=64427"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/64427\/revisions"}],"predecessor-version":[{"id":64579,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/64427\/revisions\/64579"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/64430"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=64427"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=64427"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=64427"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}