{"id":63542,"date":"2017-02-05T06:30:48","date_gmt":"2017-02-04T22:30:48","guid":{"rendered":"\/\/m.iemloyee.com\/?p=63542"},"modified":"2017-02-06T12:30:18","modified_gmt":"2017-02-06T04:30:18","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%ef%b8%b1%e5%be%ae%e8%83%b6%e5%9b%8a%e8%87%aa%e4%bf%ae%e5%a4%8d%e6%9d%90%e6%96%99%e7%9f%a5%e5%a4%9a%e5%b0%91%ef%bc%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=63542","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\ufe31\u5fae\u80f6\u56ca\u81ea\u4fee\u590d\u6750\u6599\u77e5\u591a\u5c11\uff1f"},"content":{"rendered":"<p><span style=\"color: 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style=\"color: #0000ff;\"><strong>\u4e8c\u3001\u5fae\u80f6\u56ca\u6280\u672f<\/strong><\/span><\/p>\n<p>\u5fae\u56ca\u5316\u5373\u5fae\u80f6\u56ca\u6280\u672f\uff0c\u8be5\u6280\u672f\u662f\u6307\u5c06\u5177\u6709\u7279\u5b9a\u529f\u80fd\u7684\u5355\u4f53\u6216\u8005\u5176\u4ed6\u7269\u8d28\uff0c\u4e0e\u5916\u754c\u7684\u7269\u8d28\u9694\u5f00\uff0c\u5c06\u5176\u4f5c\u4e3a\u82af\u6750\u5305\u8986\u4e8e\u5fae\u5c0f\u7684\u5bb9\u5668\u4e2d\u7684\u65b9\u6cd5\u3002White\u7b49<sup>[1]<\/sup>\u6839\u636e\u88ab\u52a8\u6a21\u5f0f\u7684\u57cb\u690d\u5f0f\u81ea\u4fee\u590d\u4f53\u7cfb\u7684\u6982\u5ff5\uff0c\u9996\u5148\u63d0\u51fa\u5982\u56fe1\u6240\u793a\u7684\u5fae\u80f6\u56ca\u57cb\u690d\u5f0f\u9ad8\u5206\u5b50\u81ea\u4fee\u590d\u6a21\u578b\u3002\u5fae\u80f6\u56ca\u81ea\u4fee\u590d\u6750\u6599\u7684\u4fee\u590d\u8fc7\u7a0b\u4e3a\uff1a\u57fa\u4f53\u4e2d\u7684\u88c2\u7eb9\u6269\u5c55\u4f7f\u5fae\u80f6\u56ca\u7834\u88c2\uff0c\u5fae\u80f6\u56ca\u4e2d\u7684\u4fee\u590d\u5242\u5728\u6bdb\u7ec6\u4f5c\u7528\u4e0b\u6d41\u5230\u88c2\u7eb9\u5904\uff0c\u5728\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\u4fee\u590d\u5242\u53d1\u751f\u805a\u5408\u53cd\u5e94\u4fee\u590d\u88c2\u7eb9\u3002\u4fee\u590d\u53cd\u5e94\u5fc5\u987b\u6ee1\u8db3\u5982\u4e0b\u6761\u4ef6\uff1a\u4fee\u590d\u5242\u4e3a\u4f4e\u7c98\u5ea6\u6db2\u4f53\uff0c\u548c\u65ad\u88c2\u9762\u6709\u826f\u597d\u7684\u6da6\u6e7f\u6027\uff0c\u53ef\u4ee5\u5305\u8986\u5728\u5fae\u80f6\u56ca\u4e2d\uff1b\u805a\u5408\u53cd\u5e94\u7684\u50ac\u5316\u5242(\u56fa\u5316\u5242)\u4e0d\u548c\u57fa\u4f53\u53d1\u751f\u53cd\u5e94\uff0c\u6216\u53ef\u5305\u88f9\u5728\u5fae\u80f6\u56ca\u4e2d\uff1b\u4fee\u590d\u5242\u5728\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u5ba4\u6e29\u53d1\u751f\u805a\u5408\u53cd\u5e94\uff0c\u751f\u6210\u4ea7\u7269\u5177\u6709\u826f\u597d\u7684\u529b\u5b66\u6027\u80fd\u548c\u7c98\u7ed3\u5f3a\u5ea6\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63548\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe1.jpg\" alt=\"\" width=\"500\" height=\"600\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe1.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe1-250x300.jpg 250w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1 \u5fae\u80f6\u56ca\u578b\u81ea\u4fee\u590d\u6750\u6599\u4fee\u590d\u539f\u7406<\/strong><\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u4e09\u3001\u4fee\u590d\u53cd\u5e94<\/strong><\/span><\/p>\n<p><span style=\"color: #ff0000;\"><strong>1 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u65e0\u6807\u9898.png\" alt=\"\" width=\"500\" height=\"247\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u65e0\u6807\u9898.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u65e0\u6807\u9898-300x148.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2 \u5f00\u73af\u6613\u4f4d\u805a\u5408\u7684\u673a\u7406<\/strong><\/p>\n<p>White<sup>[1]<\/sup>\u9996\u6b21\u63d0\u51fa\u4e86\u91c7\u7528\u53cc\u73af\u620a\u4e8c\u70ef(DCPD)\u4f5c\u4e3a\u4fee\u590d\u5242\uff0c\u82ef\u4e9a\u7532\u57fa\u00b7\u4e8c\u6c2f\u00b7\u53cc(\u4e09\u73af\u5df1\u57fa\u81a6)\u5408\u948c(\u7b2c\u4e00\u4ee3Grubbs)\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u6210\u529f\u5236\u5907\u4e86\u57fa\u4e8e\u5fae\u80f6\u56ca\u7684\u81ea\u4fee\u590d\u6750\u6599\uff0c\u4fee\u590d\u53cd\u5e94\u5982\u56fe3\u6240\u793a\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63549\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe3.jpg\" alt=\"\" width=\"294\" height=\"108\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3 DCPD\u5728Grubbs\u50ac\u5316\u4e0b\u53d1\u751f\u5f00\u73af\u6613\u4f4d\u805a\u5408<\/strong><\/p>\n<p>\u7531\u4e8eGrubbs\u50ac\u5316\u5242\u548c\u57fa\u4f53\u73af\u6c27\u6811\u8102\u4e2d\u7684\u80fa\u7c7b\u56fa\u5316\u5242\u53cd\u5e94\uff0c\u6613\u5931\u53bb\u50ac\u5316\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u65ad\u88c2\u9762\u7684\u50ac\u5316\u5242\u542b\u91cf\u4f4e\u4e8e\u603b\u50ac\u5316\u5242\u542b\u91cf\u3002\u53e6\u4e00\u65b9\u9762\uff0cGrubbs\u50ac\u5316\u5242\u7c92\u5f84\u5927\u3001\u6eb6\u89e3\u901f\u5ea6\u6162\u9020\u6210\u805a\u5408\u53cd\u5e94\u4e0d\u5145\u5206\uff0c\u4fee\u590d\u6548\u7387\u8f83\u4f4e\u3002\u50ac\u5316\u5242\u7684\u7c92\u5f84\u8d8a\u5c0f\uff0c\u6eb6\u89e3\u901f\u5ea6\u8d8a\u5feb\u3002\u4f46\u662f\u7c92\u5f84\u592a\u5c0f\u6613\u548c\u56fa\u5316\u5242\u53cd\u5e94\u5931\u53bb\u50ac\u5316\u6d3b\u6027\uff0c\u56e0\u6b64\u9700\u8981\u7efc\u5408\u8003\u8651\u4e8c\u8005\u5f71\u54cd\u3002<\/p>\n<p>\u867d\u7136Grubbs\u50ac\u5316\u5242\u5bf9\u53cc\u73af\u620a\u4e8c\u70ef\u7684\u50ac\u5316\u6d3b\u6027\u5f88\u9ad8\uff0c\u4e14\u7a33\u5b9a\u6027\u8f83\u597d\uff0c\u4f46\u7531\u4e8e\u5408\u6210\u5de5\u827a\u590d\u6742\u3001 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\u7ed3\u6784\u5982\u56fe4(c)\u6240\u793a\u3002ENB\u7684\u805a\u5408\u4ea7\u7269\u4e3a\u7ebf\u6027\u7ed3\u6784\uff0c \u56e0\u800c\u521a\u5ea6\u548c\u7c98\u7ed3\u5f3a\u5ea6\u8f83\u4f4e\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63550\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe4.png\" alt=\"\" width=\"500\" height=\"173\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe4.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe4-300x104.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4\u5f00\u73af\u805a\u5408\u53cd\u5e94\u5355\u4f53<\/strong><\/p>\n<p>\u5f00\u73af\u6613\u4f4d\u805a\u5408\u7684\u50ac\u5316\u5242\u4e3b\u8981\u5305\u62ec\u4f20\u7edf\u53cc\u7ec4\u4efd\u50ac\u5316\u5242\uff0c\u94bc\u7cfbSchrock\u50ac\u5316\u5242\u4ee5\u53ca\u948c\u7cfbGrubbs\u50ac\u5316\u5242<sup>[4]<\/sup>\u3002\u4f20\u7edf\u53cc\u7ec4\u5206\u50ac\u5316\u5242\u4ef7\u683c\u4f4e\u5ec9\uff0c\u4f46\u5176\u7a33\u5b9a\u6027\u8f83\u5dee\u3002\u948c\u7cfb\u50ac\u5316\u5242\u5305\u62ec\u7b2c\u4e00\u4ee3Grubbs\u3001\u7b2c\u4e8c\u4ee3Grubbs\u3001Hoveyda-Grubbs\u4e09\u79cd\u50ac\u5316\u5242\uff0c\u5176\u7ed3\u6784\u5982\u56fe5\u6240\u793a<sup>[5]<\/sup>\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63551\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe5.png\" alt=\"\" width=\"500\" height=\"544\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe5.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe5-276x300.png 276w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5 \u5f00\u73af\u6613\u4f4d\u805a\u5408\u7684\u4e0d\u540cGrubbs\u50ac\u5316\u5242<\/strong><\/p>\n<p>Wilson\u7684\u7814\u7a76\u7ed3\u679c\u8868\u660e\u8fd9\u4e09\u79cd\u50ac\u5316\u5242\u7684\u4fee\u590d\u6548\u679c\u4e0d\u4ec5\u548c\u805a\u5408\u901f\u5ea6\u6709\u5173\uff0c\u8fd8\u548c\u6eb6\u89e3\u901f\u5ea6\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u6709\u5173<sup>[5]<\/sup>\u3002Grubbs\u50ac\u5316\u5242\u7684\u70ed\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u5728\u8f83\u9ad8\u7684\u6e29\u5ea6\u4e0b\u6613\u5206\u89e3\u3002Hoveyda-Grubbs\u50ac\u5316\u5242\u5728\u5206\u5b50\u4e2d\u5f15\u5165\u8f83\u5927\u4f53\u79ef\u7684\u4eb2\u6838\u6027\u5f02\u4e19\u6c27\u87af\u7edc\u5408\u7269\u914d\u4f53\uff0c\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u70ed\u7a33\u5b9a\u6027\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u7b2c\u4e00\u4ee3Hoveyda-Grubbs\u50ac\u5316\u5242\u7684\u70ed\u7a33\u5b9a\u6027\u660e\u663e\u4f18\u4e8e\u7b2c\u4e00\u4ee3Grubbs\u50ac\u5316\u5242\u548c\u7b2c\u4e8c\u4ee3Grubbs\u50ac\u5316\u5242\u3002\u91c7\u7528ENB\/\u7b2c\u4e00\u4ee3Hoveyda-Grubbs\u50ac\u5316\u5242\u4fee\u590d\u4f53\u7cfb\uff0c\u5728\u4f4e\u6e29(-50\u2103)\u65f6\u4ecd\u5177\u6709\u6781\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\uff0c \u53ef\u5b9e\u73b0\u9ad8\u6e29\u56fa\u5316\u57fa\u4f53\u7684\u4f4e\u6e29\u81ea\u4fee\u590d\u3002<\/p>\n<p>\u50ac\u5316\u5242\u7684\u4e09\u70f7\u57fa\u78f7\u914d\u4f53\u662f\u5f71\u54cd\u53cd\u5e94\u6d3b\u6027\u7684\u91cd\u8981\u56e0\u7d20\u3002\u914d\u4f53\u7684\u7ed9\u7535\u5b50\u6548\u5e94\u8d8a\u5f3a\uff0c\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u8d8a\u5927\uff0c\u914d\u4f53\u8d8a\u5bb9\u6613\u89e3\u79bb\uff0c\u5c31\u8d8a\u5bb9\u6613\u5f62\u6210\u91d1\u5c5e\u56db\u5143\u73af\uff0c\u5176\u53cd\u5e94\u6d3b\u6027\u5c31\u8d8a\u5f3a\u3002Mauldin\u901a\u8fc7\u6539\u53d8\u7b2c\u4e8c\u4ee3Grubbs\u50ac\u5316\u5242\u7684\u4e09\u70f7\u57fa\u78f7\u914d\u4f4d\u4f53\u79cd\u7c7b(\u7528\u4e09\u7532\u57fa\u78f7\u66ff\u4ee3\u4e09\u73af\u5df2\u57fa\u78f7)\u4ee5\u53ca\u6dfb\u52a0\u4e00\u5b9a\u6570\u91cf\u7684\u6e38\u79bb\u6001\u70f7\u57fa\u78f7\u6765\u6291\u5236\u50ac\u5316\u5242\u7684\u914d\u4f53\u89e3\u79bb\uff0c\u8c03\u8282\u50ac\u5316\u6d3b\u6027\uff0c\u4e3a\u4e0b\u4e00\u6b65\u4f18\u5316\u81ea\u4fee\u590d\u4f53\u7cfb\u63d0\u4f9b\u4e86\u57fa\u7840\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>2 \u73af\u6c27\u6811\u8102\u7684\u5f00\u73af\u805a\u5408<\/strong><\/span><\/p>\n<p>\u73af\u6c27\u6811\u8102\u4e2d\u542b\u6709\u4e09\u5143\u73af\u919a\uff0c\u5176\u4e2d\u6c27\u539f\u5b50\u6613\u53d7\u9633\u79bb\u5b50\u7684\u8fdb\u653b\u53d1\u751f\u5f00\u73af\u805a\u5408\uff0c\u6839\u636e\u4e0d\u540c\u7684\u9633\u79bb\u5b50\u5f15\u53d1\u5242\u53ef\u80fd\u751f\u6210\u4e0d\u540c\u4ea7\u7269\u3002\u57fa\u4e8e\u73af\u6c27\u7684\u4fee\u590d\u4f53\u7cfb\u6700\u5927\u7684\u4f18\u52bf\u5728\u4e8e\u539f\u6750\u6599\u4ef7\u683c\u4fbf\u5b9c\uff0c\u4fee\u590d\u5242\u5bf9\u57fa\u4f53\u5177\u6709\u826f\u597d\u7684\u6da6\u6e7f\u6027\u548c\u7c98\u7ed3\u6027(\u57fa\u4f53\u6750\u6599\u4e00\u822c\u4e3a\u73af\u6c27\u6811\u8102)\uff0c\u7528\u4e8e\u5f00\u73af\u805a\u5408\u7684\u56fa\u5316\u5242\u6216\u50ac\u5316\u5242\u79cd\u7c7b\u591a\uff0c\u5e76\u4e14\u73af\u6c27\u6811\u8102\u7684\u5fae\u80f6\u56ca\u5236\u5907\u5de5\u827a\u6210\u719f\uff0c\u56e0\u800c\u53ef\u4f5c\u4e3a\u5fae\u80f6\u56ca\u81ea\u4fee\u590d\u6750\u6599\u7406\u60f3\u7684\u4fee\u590d\u4f53\u7cfb\u3002<\/p>\n<p>\u73af\u6c27\u81ea\u4fee\u590d\u4f53\u7cfb\u6839\u636e\u56fa\u5316\u5242\u5b58\u5728\u7684\u4e0d\u540c\u5f62\u5f0f\uff0c\u5206\u4e3a\u73af\u6c27\u6811\u8102\/\u6f5c\u4f0f\u6027\u56fa\u5316\u5242\u4f53\u7cfb\u548c\u73af\u6c27\u6811\u8102\/\u56fa\u5316\u5242\u53cc\u5fae\u80f6\u56ca\u4f53\u7cfb\u3002\u6f5c\u4f0f\u6027\u56fa\u5316\u5242\u4fee\u590d\u4f53\u7cfb\u91c7\u7528\u4e2d\u6e29\u56fa\u5316\u5242\uff0c\u9700\u8981\u52a0\u70ed\u4fc3\u8fdb\u73af\u6c27\u6811\u8102\u7684\u805a\u5408\u53cd\u5e94\u6765\u4fee\u590d\u88c2\u7eb9\uff0c\u5e76\u4e0d\u5c5e\u4e8e\u771f\u6b63\u610f\u4e49\u7684\u81ea\u4fee\u590d\u4f53\u7cfb\u3002\u53cc\u5fae\u80f6\u56ca\u4fee\u590d\u4f53\u7cfb\u4e00\u822c\u91c7\u7528\u5ba4\u6e29\u56fa\u5316\u5242\uff0c\u53cc\u5fae\u80f6\u56ca\u5728\u88c2\u7eb9\u4f5c\u7528\u4e0b\u540c\u65f6\u7834\u88c2\u8fdb\u800c\u53d1\u751f\u73af\u6c27\u6811\u8102\u805a\u5408\u53cd\u5e94\u3002<\/p>\n<p><strong>2.1 \u6f5c\u4f0f\u6027\u56fa\u5316\u5242<\/strong><\/p>\n<p>\u73af\u6c27\u6811\u8102\u7684\u6f5c\u4f0f\u6027\u56fa\u5316\u5242\u5305\u62ec\u53d4\u80fa\u76d0\u3001\u54aa\u5511\u7b49\uff0c\u56fa\u5316\u6e29\u5ea6\u4e00\u822c\u5728100\u2103\u5de6\u53f3\uff0c\u5747\u9700\u8981\u52a0\u70ed\u624d\u80fd\u50ac\u5316\u53cd\u5e94\u3002Tao<sup>[6]<\/sup>\u91c7\u7528\u54aa\u5511\u91d1\u5c5e\u76d0\u7edc\u5408\u7269CuBr<sub>2<\/sub>(2-MeIm)<sub>4<\/sub>\u4f5c\u4e3a\u6f5c\u4f0f\u56fa\u5316\u5242\u3002\u8be5\u54aa\u5511\u91d1\u5c5e\u76d0\u7edc\u5408\u7269\u5728\u5e38\u6e29\u4e0b\u7a33\u5b9a\uff0c\u52a0\u70ed\u5230120\u2103\u65f6\u53ef\u4ee5\u89e3\u79bb\u54aa\u5511\u7edc\u5408\u7269\uff0c\u4ece\u800c\u548c\u73af\u6c27\u6811\u8102\u53d1\u751f\u56fa\u5316\u53cd\u5e94\u3002\u7c7b\u4f3c\u7684\u54aa\u5511\u91d1\u5c5e\u76d0\u7edc\u5408\u7269CuCl<sub>2<\/sub>(Im)<sub>4<\/sub>\u548c\u73af\u6c27\u6811\u8102\u7684\u53cd\u5e94\u673a\u7406\u5982\u56fe6\u6240\u793a\u3002\u5c06\u73af\u6c27\u6811\u8102\u5fae\u80f6\u56ca\u548c\u6f5c\u4f0f\u6027\u56fa\u5316\u5242CuBr<sub>2<\/sub>(2-MeIm)<sub>4<\/sub>\u6dfb\u52a0\u5230\u57fa\u4f53\u4e2d\uff0c\u5f53\u5fae\u80f6\u56ca\u548c\u6f5c\u4f0f\u6027\u56fa\u5316\u5242\u542b\u91cf\u5206\u522b\u4e3a10%\u548c2%\u65f6\uff0c\u5728130\u2103\u4e0b\u52a0\u70ed1h\uff0c\u4fee\u590d\u6548\u7387\u8fbe\u5230111%\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63552\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe6.jpg\" alt=\"\" width=\"500\" height=\"200\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe6.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe6-300x120.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6 \u73af\u6c27\u6811\u8102\u548cCuCl<sub>2<\/sub>(Im)<sub>4<\/sub>\u7684\u56fa\u5316\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n<p><strong>2.2\u53cc\u5fae\u80f6\u56ca\u4f53\u7cfb<\/strong><\/p>\n<p>\u76f8\u5bf9\u4e8e\u6f5c\u4f0f\u6027\u56fa\u5316\u5242\u4f53\u7cfb\uff0c\u53cc\u5fae\u80f6\u56ca\u4f53\u7cfb\u6700\u5927\u7684\u4f18\u70b9\u5728\u4e8e\u53ef\u4ee5\u5b9e\u73b0\u5ba4\u6e29\u81ea\u4fee\u590d\u3002\u56e0\u800c\u56fa\u5316\u5242\u4e00\u822c\u9009\u62e9\u5ba4\u6e29\u56fa\u5316\u5242\uff0c\u4f8b\u5982\u8102\u80aa\u65cf\u80fa\u3001\u786b\u9187\u3001\u4e09\u6c1f\u5316\u787c\u7b49\uff0c\u4f46\u662f\u8fd9\u7c7b\u56fa\u5316\u5242\u7684\u5fae\u80f6\u56ca\u5236\u5907\u5f80\u5f80\u6bd4\u8f83\u56f0\u96be\u3002<\/p>\n<p>\u786b\u9187\u5728\u53d4\u80fa\u50ac\u5316\u4e0b\u53ef\u548c\u73af\u6c27\u6811\u8102\u53d1\u751f\u56fa\u5316\u53cd\u5e94\uff0c\u53cd\u5e94\u673a\u7406\u89c1\u56fe7\uff0c\u53d4\u80fa\u50ac\u5316\u5242\u548c\u786b\u9187\u53cd\u5e94\uff0c\u751f\u6210\u786b\u9187\u8d1f\u79bb\u5b50\uff0c\u80fd\u591f\u548c\u73af\u6c27\u5b98\u80fd\u56e2\u53d1\u751f\u5f00\u73af\u53cd\u5e94\u3002\u73af\u6c27\u5b98\u80fd\u56e2\u4e5f\u53ef\u4ee5\u5728\u786b\u9187\u8d1f\u79bb\u5b50\u50ac\u5316\u4e0b\u548c\u53d4\u80fa\u53cd\u5e94\u3002\u5bf9\u4e8e\u73af\u6c27\u6811\u8102\/\u786b\u9187\u4fee\u590d\u4f53\u7cfb\uff0c\u73af\u6c27\u6811\u8102\u7c98\u5ea6\u8d8a\u4f4e\uff0c\u786b\u9187\u805a\u5408\u7269\u7684\u786b\u6c22\u5b98\u80fd\u56e2\u8d8a\u591a\uff0c\u53d4\u80fa\u7684\u78b1\u6027\u8d8a\u5f3a\uff0c\u4fee\u590d\u6548\u7387\u8d8a\u9ad8\u3002\u73af\u6c27\u5355\u4f53\u548c\u786b\u9187\u5fae\u80f6\u56ca\u7c92\u5f84\u5927\u5c0f\u5fc5\u987b\u5339\u914d\u3002\u8f83\u5c0f\u7c92\u5f84\u7684\u5fae\u80f6\u56ca\u53ef\u4f7f\u73af\u6c27\u5355\u4f53\u548c\u56fa\u5316\u5242\u66f4\u597d\u5730\u6269\u6563\u8fdb\u884c\u56fa\u5316\u53cd\u5e94\uff0c\u56e0\u800c\u6548\u7387\u8f83\u9ad8<sup>[7]<\/sup>\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63553\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe7.png\" alt=\"\" width=\"500\" height=\"240\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe7.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe7-300x144.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7\u73af\u6c27\u6811\u8102\u548c\u786b\u9187\u5728\u53d4\u80fa\u50ac\u5316\u4e0b\u7684\u53cd\u5e94\u6d41\u7a0b(a)\u78b1\u50ac\u5316\uff1b(b)\u4eb2\u6838\u50ac\u5316<\/strong><\/p>\n<p><span style=\"color: #ff0000;\"><strong>3 \u57fa\u4e8e\u6eb6\u5242\u7684\u518d\u56fa\u5316<\/strong><\/span><\/p>\n<p>\u57fa\u4e8e\u6eb6\u5242\u7684\u88c2\u7eb9\u4fee\u590d\u6700\u5148\u5e94\u7528\u5728\u70ed\u5851\u6027\u6811\u8102\u4e0a\uff0c\u5229\u7528\u7532\u9187\u3001\u4e59\u9187\u7b49\u6eb6\u5242\u5728\u57fa\u4f53\u4e2d\u6269\u6563\uff0c\u4f7f\u5176\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4f4e\u4e8e\u4fee\u590d\u6e29\u5ea6\uff0c\u88c2\u7eb9\u65ad\u9762\u5206\u5b50\u94fe\u76f8\u4e92\u7f20\u7ed5\u4ece\u800c\u4fee\u590d\u88c2\u7eb9\u3002\u5bf9\u4e8e\u70ed\u56fa\u6027\u6811\u8102\uff0c\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u9ad8\u4e8e\u4fee\u590d\u6e29\u5ea6\uff0c\u56e0\u800c\u4fee\u590d\u673a\u7406\u4e0d\u540c\u4e8e\u70ed\u5851\u6027\u6811\u8102\u3002\u6eb6\u5242\u4fee\u590d\u673a\u7406\u4e3b\u8981\u5305\u62ec\uff1a(1)\u6eb6\u5242\u5728\u57fa\u4f53\u4e2d\u6269\u6563\u4f7f\u5176\u6eb6\u80c0\uff0c\u4fc3\u4f7f\u88c2\u7eb9\u65ad\u9762\u7d27\u5bc6\u63a5\u89e6\uff1b(2)\u6eb6\u5242\u548c\u73af\u6c27\u6811\u8102\u4e2d\u7684\u81ea\u7531\u7f9f\u57fa\u5f62\u6210\u6c22\u952e\u7ed3\u5408\uff1b(3)\u6eb6\u5242\u4fc3\u8fdb\u88c2\u7eb9\u65ad\u9762\u4e2d\u672a\u53c2\u4e0e\u53cd\u5e94\u7684\u56fa\u5316\u5242\u8fdb\u4e00\u6b65\u53d1\u751f\u56fa\u5316\u4ea4\u8054\u53cd\u5e94\u3002\u6eb6\u5242\u81ea\u4fee\u590d\u4f53\u7cfb\u7684\u4f18\u52bf\u5728\u4e8e\u6eb6\u5242\u7c98\u5ea6\u5c0f\uff0c\u4e0d\u9700\u8981\u989d\u5916\u7684\u56fa\u5316\u5242\u3002\u8be5\u81ea\u4fee\u590d\u4f53\u7cfb\u5c5e\u4e8e\u5355\u7ec4\u4efd\u4f53\u7cfb\uff0c\u7b80\u5355\u3001\u9002\u7528\u6027\u5e7f\u3001\u5177\u6709\u5de8\u5927\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p>Blaiszik<sup>[8]<\/sup>\u901a\u8fc7\u8c03\u6574\u82af\u6750\u91cf\u5bf9\u539f\u4f4d\u805a\u5408\u6cd5\u8fdb\u884c\u6539\u8fdb\uff0c\u6210\u529f\u5236\u5907\u4e86\u5305\u8986\u6eb6\u5242\u7684\u5fae\u80f6\u56ca\u3002\u7531\u4e8e\u6eb6\u5242\u5177\u6709\u6325\u53d1\u6027\uff0c\u8981\u6c42\u56ca\u58c1\u66f4\u52a0\u81f4\u5bc6\uff0cCaruso\u63d0\u51fa\u4e86\u805a\u6c28\u916f\/\u8132\u919b\u6811\u8102\u53cc\u58c1\u5fae\u80f6\u56ca\uff0c\u6709\u6548\u63d0\u9ad8\u4e86\u5fae\u80f6\u56ca\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u8010\u4e45\u6027<sup>[9]<\/sup>\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>4 \u70b9\u51fb\u5316\u5b66<\/strong><\/span><\/p>\n<p>\u70b9\u51fb\u5316\u5b66\u4e3b\u8981\u901a\u8fc7\u5c0f\u5355\u5143\u7684\u62fc\u63a5\uff0c\u7b80\u5355\u53ef\u9760\u9ad8\u6548\u5730\u5b8c\u6210\u6709\u673a\u5408\u6210\u53cd\u5e94\uff0c\u5f00\u8f9f\u4e86\u4ee5\u78b3-\u6742\u539f\u5b50\u952e\u5408\u6210\u4e3a\u57fa\u7840\u7684\u7ec4\u5408\u5316\u5b66\u65b0\u65b9\u6cd5\u3002\u5b83\u4e3b\u8981\u6709\u4ee5\u4e0b\u7279\u5f81\uff1a\u539f\u6599\u6613\u5f97\uff0c\u53cd\u5e94\u53ef\u9760\uff0c\u5bf9\u6c27\u6c14\u3001\u6c34\u4e0d\u654f\u611f\uff0c\u4ea7\u7269\u7acb\u4f53\u9009\u62e9\u6027\u597d\u3001\u4ea7\u7387\u9ad8\uff0c\u53cd\u5e94\u526f\u4ea7\u7269\u5bf9\u73af\u5883\u53cb\u597d\u3002\u76ee\u524d\u70b9\u51fb\u5316\u5b66\u4e3b\u8981\u6709\u4ee5\u4e0b\u56db\u79cd\uff1a(1)\u53e0\u6c2e\u5316\u7269-\u7094\u70c3\u53cd\u5e94\uff1b(2)\u70ef\u70c3\u4e4b\u95f4\u7684Diels-Alder\u53cd\u5e94\uff1b(3)\u758f\u57fa-\u70ef\u70c3\u53cd\u5e94\uff1b(4)\u81ea\u7531\u57fa\u5f15\u53d1\u7684\u758f\u57fa-\u7094\u53cd\u5e94\u3002\u76ee\u524d\uff0c\u524d\u4e09\u79cd\u53cd\u5e94\u5747\u5df2\u5e94\u7528\u5728\u5fae\u80f6\u56ca\u81ea\u4fee\u590d\u6750\u6599\u4e0a\u3002<\/p>\n<p><strong>4.1 \u53e0\u6c2e\u5316\u7269-\u7094\u70c3\u53cd\u5e94<\/strong><\/p>\n<p>Gragert<sup>[10]<\/sup>\u901a\u8fc7\u7194\u4f53\u6d41\u52a8\u548c\u6838\u78c1\u5171\u632f\u5b9e\u9a8c\u6d4b\u8bd5\u4e0d\u540c\u53e0\u6c2e\u5316\u7269\u548c\u7094\u70c3\u4f53\u7cfb\u7684\u53cd\u5e94\u901f\u7387\uff0c\u9009\u62e9\u53cd\u5e94\u901f\u7387\u8f83\u5feb\u7684\u4e09\u7094\u4e19\u57fa\u80fa\u3001\u4e09\u81c2\u661f\u578b\u53e0\u6c2e\u9065\u722a\u805a\u5f02\u4e01\u70ef\u548cCuBr(PPh<sub>3<\/sub>)<sub>3<\/sub>\u50ac\u5316\u5242\u4f5c\u4e3a\u4fee\u590d\u4f53\u7cfb\uff0c\u4fee\u590d\u53cd\u5e94\u5982\u56fe8\u6240\u793a\u3002\u5c06\u8d28\u91cf\u5206\u6570\u4e3a10%\u53e0\u6c2e\u5316\u7269\u5fae\u80f6\u56ca\u548c5%\u4e09\u7094\u4e19\u57fa\u80fa\u7684\u5fae\u80f6\u56ca\uff0c2%CuBr(PPh<sub>3<\/sub>)<sub>3<\/sub>\u6dfb\u52a0\u5230\u57fa\u4f53\u805a\u5f02\u4e01\u70ef\u6811\u8102(PIB)\u4e2d\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u81ea\u4fee\u590d\u529f\u80fd\uff0c\u8be5\u6750\u6599\u5728\u5ba4\u6e29\u4e0b\u4fee\u590d5\u5929\u7684\u4fee\u590d\u6548\u7387\u4e3a91%\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63554\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe8.jpg\" alt=\"\" width=\"500\" height=\"169\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe8.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe8-300x101.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe8 \u53e0\u6c2e\u5316\u7269\u548c\u7094\u70c3\u7684\u70b9\u51fb\u53cd\u5e94<\/strong><\/p>\n<p><strong>4.2 Diels-Alder\u53cd\u5e94<\/strong><\/p>\n<p>Diels-Alder\u53cd\u5e94\u662f\u70b9\u51fb\u5316\u5b66\u4e2d\u5e38\u89c1\u7684\u4e00\u79cd\uff0c\u7531\u5171\u8f6d\u4e8c\u70ef\u548c\u4eb2\u4e8c\u70ef\u4f53\u53cd\u5e94\u751f\u6210\u73af\u5df1\u70ef\u3002\u8fd9\u4e2a\u53cd\u5e94\u662f\u70ed\u53ef\u9006\u53cd\u5e94\uff0c\u53ef\u7528\u6765\u5236\u5907\u70ed\u53ef\u9006\u81ea\u4fee\u590d\u6750\u6599\u3002\u5e38\u89c1\u7684Diels-Alder\u4e3a\u544b\u5583\u548c\u9a6c\u6765\u9170\u4e9a\u80fa\u7684\u53cd\u5e94\uff0c\u5982\u56fe9\u6240\u793a\u3002Peterson<sup>[11]<\/sup>\u63d0\u51fa\u5229\u7528Diels-Alder\u53cd\u5e94\u6240\u5f97\u7684\u51dd\u80f6\u4fee\u590d\u70ed\u56fa\u6027\u5851\u6599\u3002Peterson\u5c06\u544b\u5583\u7f29\u6c34\u7518\u6cb9\u919a\u6dfb\u52a0\u5230\u73af\u6c27\u6811\u8102\u4e2d\uff0c\u5236\u5907\u4e86\u5e26\u6709\u544b\u5583\u5b98\u80fd\u56e2\u7684\u73af\u6c27\u6811\u8102\uff0c\u800c\u540e\u624b\u52a8\u6ce8\u5c04\u53cc\u9a6c\u6765\u9170\u4e9a\u80fa\u6eb6\u6db2\u5230\u88c2\u7eb9\u5904\uff0c\u9996\u6b21\u91c7\u7528\u624b\u52a8\u4fee\u590d\u65b9\u6cd5\u9a8c\u8bc1\u4e86Diels-Alder\u53cd\u5e94\u4fee\u590d\u88c2\u7eb9\u7684\u53ef\u884c\u6027\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63555\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe9.jpeg\" alt=\"\" width=\"471\" height=\"108\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe9.jpeg 471w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe9-300x69.jpeg 300w\" sizes=\"(max-width: 471px) 100vw, 471px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe9 \u544b\u5583\u548c\u9a6c\u6765\u9170\u4e9a\u80fa\u7684Diels-Alder\u53cd\u5e94<\/strong><\/p>\n<p><strong>4.3 \u5def\u57fa-\u70ef\u70c3\u53cd\u5e94<\/strong><\/p>\n<p>\u758f\u57fa-\u70ef\u70b9\u51fb\u5316\u5b66\u4e0d\u9700\u8981\u52a0\u5165\u50ac\u5316\u5242\uff0c\u5728\u7d2b\u5916\u5149\u6216\u53ef\u89c1\u5149\u7684\u4f5c\u7528\u4e0b\u53ef\u4ee5\u5feb\u901f\u5730\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u5bf9\u6c27\u6c14\u548c\u6c34\u6c1b\u56f4\u4e0d\u654f\u611f\uff0c\u56e0\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u758f\u57fa-\u70ef\u53cd\u5e94\u673a\u7406\u5982\u56fe10\u6240\u793a\uff0c\u5728\u5149\u7167\u6216\u52a0\u70ed\u5f15\u53d1\u4e0b\uff0c\u758f\u57fa\u8131\u53bb\u4e00\u4e2a\u6c22\u539f\u5b50\u5f62\u6210\u758f\u57fa\u81ea\u7531\u57fa\uff0c\u758f\u57fa\u81ea\u7531\u57fa\u8fdb\u653b\u78b3\u53cc\u952e\u4ea7\u751f\u70f7\u57fa\u81ea\u7531\u57fa\uff0c\u4e0e\u53e6\u4e00\u758f\u57fa\u53d1\u751f\u94fe\u8f6c\u79fb\u53cd\u5e94\u751f\u6210\u6700\u7ec8\u4ea7\u7269\u548c\u758f\u57fa\u81ea\u7531\u57fa<sup>[12]<\/sup>\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63557\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe10-1.png\" alt=\"\" width=\"500\" height=\"241\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe10-1.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe10-1-300x145.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe10 \u758f\u57fa-\u70ef\u7684\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n<p>Dungen<sup>[13]<\/sup>\u63d0\u51fa\u57fa\u4e8e\u5def\u57fa-\u70ef\u53cd\u5e94\u7684\u53cc\u5fae\u80f6\u56ca\u81ea\u4fee\u590d\u4f53\u7cfb\uff0c\u91c7\u7528\u5b63\u620a\u56db\u9187\u56db(3-\u5def\u57fa\u4e19\u9178)\u916f(PETM)\u548c\u4e8c\u4e19\u70ef\u9178\u916f(DiAcrylate)\u6216\u8005\u4e8c\u51b0\u7247\u70ef(DiNorbornene)\u53cd\u5e94\u4f53\u7cfb\uff0c\u5316\u5b66\u7ed3\u6784\u5982\u56fe10\u6240\u793a\u3002\u5b9e\u9a8c\u8868\u660e\uff0cPETM\u548cDiAcrylate\u5728\u7d2b\u5916\u5149\u7167\u5f15\u53d1\u4e0b\u5747\u80fd\u5feb\u901f\u53d1\u751f\u805a\u5408\u53cd\u5e94\uff0cPETM\u548cDiNorbornene\u5728\u65e0\u7d2b\u5916\u5149\u7167\u4e5f\u80fd\u53d1\u751f\u8f83\u5feb\u7684\u805a\u5408\u53cd\u5e94\u3002PETM\u548cDiAcrylate\u4fee\u590d\u4f53\u7cfb\u5177\u6709\u90e8\u5206\u4fee\u590d\u6548\u679c\uff0c\u539f\u56e0\u53ef\u80fd\u662f\u5fae\u80f6\u56ca\u56e2\u805a\uff0c\u5728\u6d82\u5c42\u4e2d\u5206\u5e03\u4e0d\u5747\u5300\uff0c\u5bfc\u81f4\u88c2\u7eb9\u5904\u6ca1\u6709\u8db3\u591f\u7684\u4fee\u590d\u5242\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63544\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe11.png\" alt=\"\" width=\"500\" height=\"196\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe11.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe11-300x118.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe11 \u758f\u57fa\uff0c\u70ef\u70c3\u5316\u5408\u7269\u7684\u7ed3\u6784<\/strong><\/p>\n<p><strong>4.4 \u5def\u57fa-\u6c30\u9178\u8102\u53cd\u5e94<\/strong><\/p>\n<p>\u5def\u57fa-\u6c30\u9178\u8102\u53cd\u5e94\u5bf9\u6c27\u6c14\u548c\u6c34\u6c1b\u56f4\u4e0d\u654f\u611f\uff0c\u5728\u53d4\u80fa\u50ac\u5316\u4e0b\u53ef\u5feb\u901f\u53d1\u751f\u53cd\u5e94\u3002Hillewaere<sup>[14]<\/sup>\u63d0\u51fa\u4e86\u57fa\u4e8e\u5def\u57fa-\u6c30\u9178\u8102\u53cd\u5e94\u7684\u4fee\u590d\u4f53\u7cfb\uff0c\u91c7\u7528PETM\u5def\u57fa\u5316\u5408\u7269\uff0c\u9009\u62e9\u7c98\u7ed3\u5f3a\u5ea6\u6700\u5927\u7684\u516d\u4e9a\u7532\u57fa\u4e8c\u5f02\u6c30\u9178\u916f(HDI)\u4f5c\u4e3a\u6c30\u9178\u916f\u5316\u5408\u7269\u3002\u8003\u8651\u5230\u6bd2\u6027\u5927\uff0c\u6539\u7528\u5176\u4e09\u805a\u4f53(HDI<sub>3<\/sub>)\uff0c\u5176\u7ed3\u6784\u5982\u56fe12\u6240\u793a\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\u57fa\u4f53\u73af\u6c27\u6811\u8102\u4e2d\u542b\u6709\u53d4\u80fa\u5b98\u80fd\u56e2\uff0c\u53ef\u4ee5\u50ac\u5316\u5def\u57fa-\u6c30\u9178\u8102\u53cd\u5e94\u3002\u5f53\u53cc\u5fae\u80f6\u56ca\u6dfb\u52a0\u91cf\u4e3a20%\uff0c\u4fee\u590d\u6548\u7387\u8fbe\u523054%\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63545\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe12.png\" alt=\"\" width=\"500\" height=\"204\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe12.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe12-300x122.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe12 \u516d\u4e9a\u7532\u57fa\u4e8c\u5f02\u6c30\u9178\u916f\u4e09\u805a\u4f53\u7ed3\u6784\u5f0f<\/strong><\/p>\n<p><strong>4.5 \u80fa\u6216\u5def\u57fa-\u9a6c\u6765\u9170\u4e9a\u80fa\u53cd\u5e94<\/strong><\/p>\n<p>\u9a6c\u6765\u9170\u4e9a\u80fa\u548c\u73af\u6c27\u7c7b\u4f3c\uff0c\u53ef\u4ee5\u548c\u80fa\u57fa\u6216\u8005\u758f\u57fa\u5316\u5408\u7269\u53cd\u5e94(\u53cd\u5e94\u5982\u56fe13\u6240\u793a)\uff0c\u4f46\u662f\u9a6c\u6765\u9170\u4e9a\u80fa\u5177\u6709\u66f4\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\u3002\u901a\u8fc7\u4fee\u590d\u5b9e\u9a8c\uff0c\u9009\u53d6\u4e24\u79cd\u4e0d\u540c\u7684\u9a6c\u6765\u9170\u4e9a\u80fa\u5316\u5408\u7269\u9a8c\u8bc1\u4e86\u9a6c\u6765\u9170\u4e9a\u80fa\u548c\u80fa\u6216\u758f\u57fa\u53cd\u5e94\u6765\u4fee\u590d\u88c2\u7eb9\u7684\u53ef\u884c\u6027<sup>[15]<\/sup>\u3002\u4f46\u662f\u76ee\u524d\u4ecd\u6ca1\u6709\u6210\u529f\u5236\u5907\u51fa\u5305\u8986\u9a6c\u6765\u9170\u4e9a\u80fa\u7684\u5fae\u80f6\u56ca\uff0c\u4ec5\u4ec5\u505c\u7559\u5728\u5b9e\u9a8c\u9a8c\u8bc1\u9636\u6bb5\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63546\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe13.png\" alt=\"\" width=\"500\" height=\"285\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe13.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe13-300x171.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe13 \u9a6c\u6765\u9170\u4e9a\u80fa\u548c(a)\u80fa\u3001(b)\u5def\u57fa\u7684\u53cd\u5e94<\/strong><\/p>\n<p><span style=\"color: #ff0000;\"><strong>5 \u5176\u4ed6<\/strong><\/span><\/p>\n<p>Keller<sup>[16]<\/sup>\u5229\u7528\u4e59\u70ef\u529f\u80fd\u5316\u7684\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7(PDMS)\u5fae\u80f6\u56ca\u4fee\u590dPDMS\u5f39\u6027\u4f53\u3002\u8be5\u81ea\u4fee\u590d\u4f53\u7cfb\u4f7f\u7528\u4e24\u79cd\u5fae\u80f6\u56ca\uff0c\u5176\u4e2d\u4e00\u79cd\u5fae\u80f6\u56ca\u5305\u88f9\u4e59\u70ef\u57faPDMS\u548c\u94c2\u50ac\u5316\u5242\uff0c\u53e6\u5916\u4e00\u79cd\u5fae\u80f6\u56ca\u5305\u88f9\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7\u5171\u805a\u4f53\uff0c\u5728\u94c2\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u4e8c\u8005\u53d1\u751f\u805a\u5408\u53cd\u5e94(\u5982\u56fe14\u6240\u793a)\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-63547\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe14.png\" alt=\"\" width=\"500\" height=\"113\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe14.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/02\/\u56fe14-300x68.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe14 \u94c2\u50ac\u5316\u4e59\u70ef\u57faPDMS\u548c\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7\u5171\u805a\u4f53\u4ea4\u8054\u53cd\u5e94<\/strong><\/p>\n<p>Cho<sup>[17]<\/sup>\u5229\u7528\u7f9f\u57fa\u529f\u80fd\u5316\u7684\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7(HOPDMS)\u548c\u805a\u4e8c\u4e59\u6c27\u57fa\u7845\u70f7(PDES)\u6db2\u6ef4\u5206\u6563\u5230\u4e59\u70ef\u57fa\u916f\u6811\u8102\u96c6\u4f53\u4e2d\uff0c\u5728\u5fae\u80f6\u56ca\u5305\u88f9\u7684\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\u7684\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\uff0c\u53ef\u5b9e\u73b0\u81ea\u4fee\u590d\u53cd\u5e94\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u56db\u3001\u7ed3\u8bba\u4e0e\u5c55\u671b<\/strong><\/span><\/p>\n<p>\u76ee\u524d\uff0c\u5fae\u80f6\u56ca\u4fee\u590d\u6750\u6599\u7684\u4fee\u590d\u53cd\u5e94\u79cd\u7c7b\u5f88\u591a\uff0c\u901a\u8fc7\u5bf9\u4f53\u7cfb\u4f18\u5316\u5b9e\u73b0\u4e86\u8f83\u9ad8\u7684\u4fee\u590d\u6548\u7387\uff0c\u4f46\u662f\u4e5f\u5b58\u5728\u7740\u6210\u672c\u8f83\u9ad8\uff0c\u4fee\u590d\u901f\u7387\u6162\uff0c\u5fae\u80f6\u56ca\u5236\u5907\u5de5\u827a\u56f0\u96be\u7b49\u95ee\u9898\u3002\u81ea\u4fee\u590d\u53cd\u5e94\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\u53ef\u5f52\u7eb3\u4e3a\uff1a(1)\u91c7\u7528\u9ad8\u6d3b\u6027\u7684\u50ac\u5316\u5242\u63d0\u9ad8\u81ea\u4fee\u590d\u6548\u7387\uff0c\u4f8b\u5982\u7a00\u571f\u4e09\u6c1f\u7532\u78fa\u9178\u916f\u3001SbF<sub>5<\/sub>\u7b49\u3002(2)\u53d1\u5c55\u65b0\u7684\u5fae\u80f6\u56ca\u5236\u5907\u5de5\u827a\uff0c\u4f8b\u5982\u91c7\u7528\u6e17\u5165\u6cd5\u5c06\u4e2d\u7a7a\u5fae\u80f6\u56ca\u3001\u73bb\u7483\u7403\uff0c\u7eb3\u7c73\u7ba1\u4f5c\u4e3a\u8f7d\u4f53\u6765\u5236\u5907\u9ad8\u6d3b\u6027\u7684\u50ac\u5316\u5242\u5fae\u80f6\u56ca\u3002(3)\u70b9\u51fb\u5316\u5b66\u4ee5\u5176\u5feb\u901f\uff0c\u7b80\u5355\u7684\u7279\u70b9\uff0c\u6210\u4e3a\u81ea\u4fee\u590d\u6750\u6599\u8bbe\u8ba1\u548c\u5f00\u53d1\u7684\u7814\u7a76\u5de5\u5177\u3002\u5176\u4e2d\uff0c\u758f\u57fa\u7531\u4e8e\u5177\u6709\u5f88\u9ad8\u7684\u5316\u5b66\u6d3b\u6027\uff0c\u53ef\u4ee5\u548c\u73af\u6c27\u3001\u70ef\u70c3\u3001\u6c30\u9178\u916f\u4ee5\u53ca\u9a6c\u6765\u9170\u4e9a\u80fa\u7b49\u5728\u5ba4\u6e29\u4e0b\u5feb\u901f\u53cd\u5e94\uff0c\u5728\u81ea\u4fee\u590d\u53cd\u5e94\u4e2d\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002\u4f46\u662f\u758f\u57fa\u5316\u5408\u7269\u4e0d\u7a33\u5b9a\uff0c\u6c61\u67d3\u73af\u5883\uff0c\u9650\u5236\u4e86\u5176\u53d1\u5c55\u3002\u5c06\u6765\uff0c\u6211\u4eec\u9700\u8981\u62d3\u5bbd\u70b9\u51fb\u5316\u5b66\u5728\u81ea\u4fee\u590d\u6750\u6599\u4e2d\u7684\u5e94\u7528\uff0c\u5f00\u53d1\u66f4\u52a0\u7eff\u8272\u73af\u4fdd\u7a33\u5b9a\u7684\u4fee\u590d\u5242\uff0c\u5feb\u901f\u9ad8\u6548\u5730\u5b9e\u73b0\u6750\u6599\u7684\u81ea\u4fee\u590d\u529f\u80fd\u3002<\/p>\n<p><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n<p>[1] White S R, Sottos N R, Geubelle P H, et al. Autonomic healing of polymer composites[J]. Nature, 2001, 409(6822): 794-797.<\/p>\n<p>[2] Bielawski C W, Grubbs R H. Living ring-opening metathesis polymerization[J]. Progress in Polymer Science, 2007, 32(1): 1-29.<\/p>\n<p>[3] Liu X, Lee J K, Yoon S H, et al. Characterization of diene monomers as healing agents for autonomic damage repair[J]. Journal of applied polymer science, 2006, 101(3): 1266-1272.<\/p>\n<p>[4] Trnka T M, Grubbs R H. The development of L2X2Ru CHR olefin metathesis catalysts: an organometallic success story[J]. Accounts of Chemical Research, 2001, 34(1): 18-29.<\/p>\n<p>[5] Wilson G O, Caruso M M, Reimer N T, et al. Evaluation of ruthenium catalysts for ring-opening metathesis polymerization-based self-healing applications[J]. Chemistry of Materials, 2008, 20(10): 3288-3297.<\/p>\n<p>[6] Yin T, Rong M Z, Zhang M Q, et al. Self-healing epoxy composites\u2013preparation and effect of the healant consisting of microencapsulated epoxy and latent curing agent[J]. Composites Science and Technology, 2007, 67(2): 201-212.<\/p>\n<p>[7] Yuan Y C, Rong M Z, Zhang M Q, et al. Self-healing polymeric materials using epoxy\/mercaptan as the healant[J]. Macromolecules, 2008, 41(14): 5197-5202.<\/p>\n<p>[8] Blaiszik B J, Caruso M M, McIlroy D A, et al. Microcapsules filled with reactive solutions for self-healing materials[J]. Polymer, 2009, 50(4): 990-997.<\/p>\n<p>[9] Caruso M M, Blaiszik B J, Jin H, et al. Robust, double-walled microcapsules for self-healing polymeric materials[J]. ACS applied materials &amp; interfaces, 2010, 2(4): 1195-1199.<\/p>\n<p>[10] Gragert M, Schunack M, Binder W H. Azide\/Alkyne\u2010\u201cClick\u201d\u2010Reactions of Encapsulated Reagents: Toward Self\u2010Healing Materials[J]. Macromolecular rapid communications, 2011, 32(5): 419-425.<\/p>\n<p>[11] Peterson A M, Jensen R E, Palmese G R. Reversibly cross-linked polymer gels as healing agents for epoxy\u2212 amine thermosets[J]. 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Self\u2010healing polymer coatings[J]. Advanced Materials, 2009, 21(6): 645-649.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4watermelon\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u5411\u5404\u5927\u56e2\u961f\u8bda\u5fc3\u7ea6\u7a3f\uff0c\u8bfe\u9898\u7ec4\u6700\u65b0\u6210\u679c\u3001\u65b9\u5411\u603b\u7ed3\u3001\u56e2\u961f\u8bbf\u8c08\u3001\u5b9e\u9a8c\u6280\u80fd\u7b49\u7686\u53ef\u6295\u7a3f\uff0c\u4f18\u79c0\u7a3f\u4ef6\u4e00\u7ecf\u5f55\u7528\uff0c\u6211\u4eec\u4f1a\u5949\u4e0a\u7a3f\u916c\uff0c\u8bf7\u8054\u7cfb\uff1a\u90ae\u7bb1tougao@cailiaoren.com \u6216 QQ\uff1a97482208\u3002<\/p>\n<p>\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<a href=\"http:\/\/www.cailiaoren.com\/\" target=\"_blank\">\u6750\u6599\u4eba<\/a>\u3001\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5f15\u8a00 \u805a\u5408\u7269\u6750\u6599\u56e0\u5176\u4ef7\u683c\u4f4e\u3001\u6613\u6210\u578b\u3001\u7edd\u7f18\u6027\u597d\u3001\u5bc6\u5ea6\u5c0f\u3001\u6bd4\u5f3a\u5ea6\u9ad8\u7b49\u7279\u6027\u800c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5efa\u7b51\u3001\u901a\u8baf\u3001\u4ea4\u901a\u3001\u56fd\u9632\u3001\u533b\u7597\u548c\u65e5\u7528\u54c1\u7b49\u9886\u57df\u3002\u4f46\u662f\u805a\u5408\u7269\u6750\u6599\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e&#8230;<\/p>\n","protected":false},"author":393,"featured_media":63548,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[42],"class_list":["post-63542","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/63542"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/393"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=63542"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/63542\/revisions"}],"predecessor-version":[{"id":63714,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/63542\/revisions\/63714"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/63548"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=63542"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=63542"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=63542"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}