{"id":63185,"date":"2017-02-01T06:30:29","date_gmt":"2017-01-31T22:30:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=63185"},"modified":"2017-02-06T12:30:36","modified_gmt":"2017-02-06T04:30:36","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e4%b8%a8%e5%ad%a6%e7%82%b9%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8%e7%9a%84%e7%90%86%e8%ae%ba%e7%9f%a5%e8%af%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=63185","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\u4e28\u5b66\u70b9\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7406\u8bba\u77e5\u8bc6"},"content":{"rendered":"

\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u91cd\u70b9\u5728\u201c\u8d85\u7ea7\u201d\u4e8c\u5b57\uff0c\u5176\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u4e8e\u4f20\u7edf\u7535\u5bb9\u56682~3\u4e2a\u6570\u91cf\u7ea7\uff0c\u529f\u7387\u5bc6\u5ea6\u662f\u7535\u6c60\u768410\u500d\u4ee5\u4e0a\uff0c\u5e7f\u6cdb\u7528\u4e8e\u9ad8\u529f\u7387\u7528\u7535\u9886\u57df\uff0c\u662f\u5f88\u6709\u53d1\u5c55\u6f5c\u529b\u7684\u50a8\u80fd\u5668\u4ef6\u3002But\uff0c\u80fd\u91cf\u5bc6\u5ea6\u5c31\u4e0d\u600e\u4e48\u7406\u60f3\u4e86\uff0c\u8fd9\u5c31\u9650\u5236\u4e86\u5176\u5e94\u7528\u8303\u56f4\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u5927\u591a\u7814\u7a76\u8005\u90fd\u5728\u5bfb\u627e\u6027\u80fd\u4f18\u5f02\u7684\u7535\u6781\u6750\u6599\u3002\u5982\u4f55\u627e\u5230\u6216\u8bbe\u8ba1\u6ee1\u610f\u7684\u9ad8\u6bd4\u7535\u5bb9\u6750\u6599\uff1f\u8fd9\u5c31\u9700\u8981\u4e86\u89e3\u6750\u6599\u7684\u50a8\u80fd\u673a\u7406\u4e86\uff0c\u5f53\u7136\u4e0d\u540c\u7c7b\u578b\u7684\u7535\u5bb9\u5668\u50a8\u80fd\u673a\u7406\u5fc5\u7136\u4e0d\u540c\uff0c\u672c\u6587\u4e3b\u8981\u4ecb\u7ecd\u5e94\u7528\u8f83\u4e3a\u5e7f\u6cdb\u7684\u591a\u5b54\u78b3\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u50a8\u80fd\u673a\u7406\uff0c\u5305\u62ec\u591a\u5b54\u78b3\u53cc\u7535\u5c42\u6a21\u578b\u4ee5\u53ca\u5b54\u7ed3\u6784\u5bf9\u50a8\u80fd\u673a\u7406\u7684\u5f71\u54cd[1]<\/sup>\u3002<\/p>\n

\u9996\u5148\uff0c\u666e\u53ca\u4e00\u4e0b\u57fa\u672c\u77e5\u8bc6\u3002\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u7684\u57fa\u672c\u7ed3\u6784<\/strong>\uff0c\u4e0d\u591a\u8bb2\u4e86\uff0c\u770b\u56fe\uff01<\/p>\n

<\/p>\n

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\u754c\u9762\u53cc\u7535\u5c42\u7406\u8bba\u6a21\u578b<\/strong>\uff0c\u6700\u65e9\u63cf\u8ff0\u8fd9\u4e00\u8fc7\u7a0b\u7684\u662f\u7ecf\u5178Helmholtz\u53cc\u7535\u5c42\u6a21\u578b\uff08\u56fe2.a\uff09\uff0c\u8be5\u6a21\u578b\u4e2d\u53cc\u7535\u5c42\u4e3a\u7535\u6781\u8868\u9762\u5438\u9644\u7535\u89e3\u6db2\u79bb\u5b50\u7684\u7d27\u5bc6\u5c42\uff0c\u6709\u6548\u539a\u5ea6d\u5728\u7eb3\u7c73\u7ea7\u522b\u3002\u540e\u8003\u8651\u5230\u79bb\u5b50\u6269\u6563\u3001\u6eb6\u5242\u5206\u5b50\u7684\u5076\u6781\u8fd0\u52a8\u7b49\u56e0\u7d20\u53d1\u5c55\u4e86Gouy\u2013Chapman\u6269\u6563\u53cc\u7535\u5c42\u6a21\u578b\uff08\u56fe2.b\uff09\u3002\u5bf9\u4e8e\u6d53\u7535\u89e3\u6db2\u7535\u5bb9\u5668\u4e24\u79cd\u6269\u6563\u6a21\u578b\u5747\u5b58\u5728\uff0c\u540e\u671fStern\u7ed3\u5408\u4e24\u79cd\u53cc\u7535\u5c42\u7406\u8bba\u63d0\u51fa\u4e86\u7b2c\u4e09\u79cd\u6a21\u578b\uff0c\u5373\u7d27\u5bc6\u5c42\u548c\u6269\u6563\u5c42\u4e32\u8054\u6a21\u578b\uff08\u56fe2.c\uff09\u3002\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u7535\u89e3\u6db2\u6d53\u5ea6\u8f83\u9ad8\uff0c\u6269\u6563\u53cc\u7535\u5c42\u5f88\u8584\uff0c\u5f80\u5f80\u8fd9\u90e8\u5206\u7535\u5bb9\u4f1a\u88ab\u76f4\u63a5\u5ffd\u7565\u3002\u5bf9\u4e8e\u591a\u5b54\u78b3\u7535\u6781\u6765\u8bf4\uff0c\u53cc\u7535\u5c42\u50a8\u80fd\u8fc7\u7a0b\u8fdc\u975e\u8fd9\u4e48\u7b80\u5355\uff0c\u4e14\u770b\u4e0b\u6587\u8be6\u89e3\u3002<\/p>\n

<\/p>\n

\u56fe2. (a)Helmholtz\u53cc\u7535\u5c42\u6a21\u578b\uff1b(b)Gouy\u2013Chapman\u53cc\u7535\u5c42\u6a21\u578b\uff1b(c)Stern\u53cc\u7535\u5c42\u6a21\u578b<\/strong>[3]<\/sup><\/strong>\u3002<\/strong><\/p>\n

    \n
  1. \u591a\u5b54\u78b3\u53cc\u7535\u5c42\u6a21\u578b<\/strong><\/li>\n<\/ol>\n

    \u6309\u7167\u4e0a\u8ff0\u7ecf\u5178\u7684\u53cc\u7535\u5c42\u7406\u8bba\u6a21\u578b\u6765\u8bf4\uff0c\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u7684\u7406\u8bba\u6bd4\u7535\u5bb9\u4e0e\u7535\u6781\u6bd4\u8868\u9762\u79ef\u6210\u6b63\u6bd4\u3002\u4f46\u4e8b\u5b9e\u5e76\u975e\u5982\u6b64\uff0c\u5bf9\u4e8e\u591a\u5b54\u78b3\u7535\u6781\u6765\u8bf4\uff0c\u5176\u5b54\u7ed3\u6784\u4e0e\u6bd4\u7535\u5bb9\u6709\u5bc6\u5207\u8054\u7cfb\u3002\u56e0\u6b64\uff0c\u5bf9\u4e8e\u63cf\u8ff0\u771f\u5b9e\u591a\u5b54\u78b3\u7535\u5bb9\u5668\u7684\u53cc\u7535\u5c42\u7ed3\u6784\u4e0a\u8ff0\u4e09\u79cd\u53cc\u7535\u5c42\u6a21\u578b\u5c31\u4e0d\u9002\u7528\u4e86\u3002Huang\u7b49[4]<\/sup>\u5728\u5047\u8bbe\u591a\u5b54\u78b3\u5b54\u4e3a\u5706\u67f1\u5f62\u7684\u524d\u63d0\u4e0b\u63d0\u51fa\u4e86\u5305\u62ec\u5b54\u5f84\u3001\u66f2\u7387\u56e0\u7d20\u7684\u4e24\u79cd\u53cc\u7535\u5c42\u6a21\u578bEDCC\uff08electric double-cylinder capacitors\uff09\u548cEWCC\uff08electric wirein-cylinderca pacitor\uff09\uff0c\u5982\u56fe3\u3002\u5176\u4e2d\u00a0EDCC \u7528\u4e8e\u63cf\u8ff0\u4ecb\u5b54\u7ed3\u6784\u7684\u53cc\u7535\u5c42\uff0c\u7535\u89e3\u6db2\u4e0e\u4ecb\u5b54\u4f5c\u7528\u65f6\u53cd\u79bb\u5b50\u8fdb\u5165\u5b54\u4e2d\uff0c\u6cbf\u5185\u58c1\u6392\u5217\u3002EWCC\u7528\u4e8e\u63cf\u8ff0\u5fae\u5b54\u7ed3\u6784\u7684\u53cc\u7535\u5c42\uff0c\u6eb6\u5242\u5316\u6216\u8005\u53bb\u6eb6\u5242\u5316\u7684\u53cd\u79bb\u5b50\u6cbf\u7740\u5706\u5b54\u4e2d\u8f74\u7ebf\u6392\u5217\u3002\u5bf9\u4e8e\u5927\u5b54\u7ed3\u6784\uff0c\u56e0\u4e3a\u5176\u5b54\u9699\u7684\u66f2\u7387\u5df2\u7ecf\u5f88\u5c0f\u4e86\uff0c\u6240\u4ee5\u53ef\u4ee5\u7528\u5e73\u884c\u677f\u7535\u5bb9\u5668\u6a21\u578b\u8fdb\u884c\u63cf\u8ff0\uff0c\u63a5\u8fd1\u4f20\u7edf\u7684Stern\u6a21\u578b\u3002<\/p>\n

    <\/p>\n

    \u56fe<\/strong>3. Huang\u7b49\u63d0\u51fa\u7684(a)EDCC<\/strong>\u53cc\u7535\u5c42\u6a21\u578b\uff1b<\/strong>(b)EWCC <\/strong>\u53cc\u7535\u5c42\u6a21\u578b<\/strong>\u3002<\/strong><\/p>\n

    HUANG \u7b49\u5bf9\u6587\u732e\u4e2d\u4e0d\u540c\u79cd\u7c7b\u78b3\u6750\u6599\u5728\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u5bb9\u503c\u8fdb\u884c\u62df\u5408\uff0c\u62df\u5408\u7ed3\u679c\uff08\u66f2\u7ebf\u00a0D\u548c\u533a\u57df\u00a0III \u4e2d\u7684\u77ed\u865a\u7ebf\uff09\u548c\u5b9e\u9a8c\u6570\u636e\u8d8b\u52bf\u4e00\u81f4\uff08\u56fe4.\uff09\uff0c\u7531\u6b64\u53ef\u89c1EDCC \u548c\u00a0EWCC\u6a21\u578b\u5177\u6709\u4e00\u5b9a\u7684\u9002\u7528\u6027\u3002\u4f46\u4f5c\u8005\u5206\u6790\u7531\u4e8e\u591a\u5b54\u7ed3\u6784\u5706\u67f1\u5f62\u5047\u8bbe\u524d\u63d0\u4ee5\u53ca\u5ffd\u7565\u7535\u89e3\u6db2\u56e0\u7d20\u7684\u5f71\u54cd\uff0c\u8be5\u6a21\u578b\u4efb\u7136\u5b58\u5728\u4e00\u5b9a\u5c40\u9650\u6027\u3002<\/p>\n

    <\/p>\n

    \u56fe<\/strong>4. <\/strong>\u91c7\u7528<\/strong>EWCC<\/strong>\u548c<\/strong>EDCC<\/strong>\u6a21\u578b\u5bf9\u6587\u732e\u6570\u636e\u62df\u5408\u7684\u7ed3\u679c<\/strong>[4]<\/sup><\/strong>\u3002<\/strong><\/p>\n

    \u968f\u7740\u5bf9\u591a\u5b54\u78b3\u50a8\u80fd\u673a\u7406\u7814\u7a76\u7684\u6df1\u5165\uff0c\u4e0d\u5c11\u7814\u7a76\u53d1\u73b0\u5728\u6ca1\u6709\u5916\u52a0\u7535\u538b\u65f6\uff0c\u591a\u5b54\u78b3\u7684\u5b54\u9699\u5185\u4e5f\u4f1a\u5438\u9644\u6b63\u8d1f\u79bb\u5b50\u3002\u8fd9\u53c8\u5f15\u5165\u4e86\u53e6\u5916\u4e00\u79cd\u5f71\u54cd\u6bd4\u7535\u5bb9\u7684\u79bb\u5b50\u5206\u5e03\u6a21\u578b\uff0c\u5982\u56fe5\u6240\u793a\u3002\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u5145\u7535\u8fc7\u7a0b\u5c06\u4f1a\u5b58\u5728\u4e09\u79cd\u79bb\u5b50\u4f5c\u7528\u8fc7\u7a0b\uff1a\u5f02\u6027\u79bb\u5b50\u5438\u9644\u3001\u540c\u6027\u79bb\u5b50\u8131\u9644\u548c\u79bb\u5b50\u4e92\u6362\u4e09\u79cd\u4f5c\u7528\u65b9\u5f0f[5]<\/sup>\u3002\u5373\u5f53\u5b54\u9699\u5185\u5b58\u5728\u540c\u79cd\u7535\u6027\u79bb\u5b50\u65f6\uff0c\u5145\u7535\u8fc7\u7a0b\u4e2d\u591a\u5b54\u78b3\u6bd4\u7535\u5bb9\u4f1a\u88ab\u62b5\u6d88\u3002\u56e0\u6b64\uff0c\u82e5\u8981\u8bbe\u8ba1\u5177\u6709\u9ad8\u6bd4\u7535\u5bb9\u7684\u591a\u5b54\u78b3\u6750\u6599\uff0c\u5e94\u8be5\u662f\u8ba9\u5b54\u9699\u4e2d\u4e0d\u5b58\u5728\u6216\u5c3d\u53ef\u80fd\u5c11\u5b58\u5728\u540c\u6027\u79bb\u5b50\u3002<\/p>\n

    <\/p>\n

    \u56fe<\/strong>5. <\/strong>\u65e0\u5de5\u4f5c\u7535\u538b\u548c\u6709\u5de5\u4f5c\u7535\u538b\u4e0b\u7a7a\u9699\u4e2d\u79bb\u5b50\u72b6\u6001<\/strong>[5]<\/sup><\/strong>\u3002<\/strong><\/p>\n

     <\/p>\n

      \n
    1. <\/b>\u591a\u5b54\u78b3\u7ed3\u6784\u5bf9\u7535\u5bb9\u6027\u80fd\u5f71\u54cd<\/strong><\/li>\n<\/ol>\n

      \u53cc\u7535\u5c42\u6a21\u578b\u53ea\u80fd\u5728\u7406\u8bba\u4e0a\u8bf4\u660e\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u5206\u5e03\u8fc7\u7a0b\uff0c\u771f\u5b9e\u60c5\u51b5\u4e0b\u591a\u5b54\u78b3\u6750\u6599\u7684\u5b54\u9699\u7ed3\u6784\u5f88\u5927\u7a0b\u5ea6\u4e0a\u51b3\u5b9a\u4e86\u6750\u6599\u7535\u5bb9\u6027\u80fd\u4ee5\u53ca\u7535\u89e3\u6db2\u79bb\u5b50\u50a8\u80fd\u673a\u7406\u3002\u5b54\u7ed3\u6784\u5bf9\u7535\u5bb9\u6027\u80fd\u5f71\u54cd\u5206\u4e3a\u4ee5\u4e0b\u51e0\u79cd\u60c5\u51b5\uff1a<\/p>\n

      1)\u00a0<\/b>\u79bb\u5b50\u7b5b\u9009\u6548\u5e94 <\/strong><\/p>\n

      \u5f53\u6d3b\u6027\u70ad\u7684\u5b54\u9699\u5e73\u5747\u5c3a\u5bf8\u4e0e\u7535\u89e3\u6db2\u4e2d\u79bb\u5b50\u5927\u5c0f\u76f8\u9002\u5e94\u65f6\uff0c\u7535\u89e3\u6db2\u79bb\u5b50\u624d\u6709\u53ef\u80fd\u88ab\u6d3b\u6027\u70ad\u5438\u9644\u3002\u9664\u5b54\u5f84\u5c3a\u5bf8\u5916\u79bb\u5b50\u7684\u7a7a\u95f4\u51e0\u4f55\u6548\u5e94\u4e5f\u662f\u4ea7\u751f\u79bb\u5b50\u7b5b\u9009\u6548\u5e94\u7684\u539f\u56e0\u4e4b\u4e00\u3002\u6709\u7814\u7a76\u53d1\u73b0\u72ed\u7f1d\u578b\u5b54\u7ed3\u6784\u80fd\u5bb9\u7eb3\u5e73\u9762\u5f62\u72b6\u79bb\u5b50SO3<\/sub>\u2212<\/sup>\uff0c\u4f46\u4f1a\u6392\u9664\u7403\u5f62\u79bb\u5b50 Cl\u2212<\/sup>[6]<\/sup>\u3002<\/p>\n

      2)\u00a0<\/b>\u79bb\u5b50\u53bb\u6eb6\u5242\u5316\u6548\u5e94 <\/strong><\/p>\n

      \u7531\u4e0a\u6240\u8ff0\uff0c\u7531\u4e8e\u5b58\u5728\u79bb\u5b50\u7b5b\u9009\u6548\u5e94\uff0c\u591a\u5b54\u78b3\u4e0d\u53ef\u80fd\u5438\u9644\u8d85\u8fc7\u5176\u5e73\u5747\u5b54\u5f84\u7684\u6eb6\u5242\u5316\u79bb\u5b50\uff0c\u4f46\u6709\u7814\u7a76\u8868\u660e\u7535\u89e3\u6db2\u4e2d\u7684\u79bb\u5b50\u80fd\u591f\u53bb\u6eb6\u5242\u5316\u540e\u50a8\u5b58\u4e8e\u5fae\u5b54\u6216\u8d85\u5fae\u5b54\u4e2d\u3002VIX-GUTER \u7b49[7]<\/sup>\u7814\u7a76\u53d1\u73b0\u5fae\u5b54\u5b54\u5bb9\u4e0e\u591a\u5b54\u78b3\u8d28\u91cf\u6bd4\u7535\u5bb9\u5448\u6b63\u76f8\u5173\uff0c\u5982\u56fe6.\u3002TEA+\u548c BF4\u2212\u7684\u6eb6\u5242\u5316\u79bb\u5b50\u76f4\u5f84\u5206\u522b\u4e3a 1.30nm\u548c1.61nm\uff0c\u800c\u8be5\u5b9e\u9a8c\u4e2d\u591a\u5b54\u78b3\u7684\u5fae\u5b54\u4ec5\u67090.7nm\u8fdc\u5c0f\u4e8e\u6eb6\u5242\u5316\u79bb\u5b50\u5c3a\u5bf8\uff0c\u56e0\u6b64\uff0cVIX-GUTER \u7b49\u63a8\u6d4b\u79bb\u5b50\u5728\u8fdb\u5165\u5fae\u5b54\u524d\uff0c\u5728\u7535\u573a\u6781\u5316\u4f5c\u7528\u4e0b\u53bb\u9664\u4e86\u6eb6\u5242\u5316\u5916\u58f3\u3002<\/p>\n

      <\/p>\n

      \u56fe6. \u5728\u6c34\u57fa\u7535\u89e3\u6db2\uff081 mol\/L H2SO4\uff09\u548c\u6709\u673a\u7535\u89e3\u6db2\uff081 mol\/L TEA-BF4\u4e59\u8148\u6eb6\u5242\uff09\u4e2d\u591a\u5b54\u78b3\u7684\u6bd4\u7535\u5bb9\u4e0e\u5fae\u5b54\u5b54\u5bb9\u5173\u7cfb<\/strong>[7]<\/sup><\/strong>\u3002<\/strong><\/p>\n

      \u7efc\u5408\u5927\u91cf\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u76f8\u5173\u7814\u7a76\u7ed3\u679c\uff0c\u5fae\u5b54\u53d1\u8fbe\u4e14\u6bd4\u8868\u9762\u79ef\u9ad8\u7684\u6750\u6599\u5bf9\u5e94\u8d28\u91cf\u6bd4\u7535\u5bb9\u76f8\u5bf9\u8f83\u9ad8\u3002\u800c\u5f53\u5b54\u5f84\u5927\u4e8e1 nm \u65f6\uff0c\u6bd4\u7535\u5bb9\u5f00\u59cb\u4e0b\u964d\u3002\u5c24\u5176\u5f53\u5b54\u5f84\u5927\u4e8e2 nm \u540e\uff0c\u5373\u4f7f\u6bd4\u8868\u9762\u79ef\u5df2\u7ecf\u8fbe\u5230 2000\uff5e2500m2<\/sup>\/g\uff0c\u6750\u6599\u6bd4\u7535\u5bb9\u4e5f\u53ea\u6709100\uff5e150 F\/g\uff0c\u8fdc\u4f4e\u4e8e\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u6d3b\u6027\u70ad\u7684\u5e73\u503c200 F\/g[8]<\/sup>\u3002\u8bc1\u660e\u76f8\u6bd4\u4e8e\u6bd4\u8868\u9762\u79ef\u800c\u8a00\uff0c\u5fae\u5b54\u5bf9\u4e8e\u8d28\u91cf\u6bd4\u7535\u5bb9\u7684\u5f71\u54cd\u66f4\u5927\u3002<\/p>\n

      3)\u00a0<\/b>\u4ecb\u5b54\u7ed3\u6784\u7684\u5f71\u54cd <\/strong><\/p>\n

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      <\/p>\n

      \u56fe<\/strong>7.<\/strong>\u6ca1\u6709\u4ecb\u5b54\uff08<\/strong>a<\/strong>\uff09\u548c\u6709\u4ecb\u5b54\u7ed3\u6784\uff08<\/strong>b<\/strong>\uff09\u65f6\u7684\u6d3b\u6027\u70ad\u5185\u90e8\u79bb\u5b50\u4f20\u8f93\u901a\u9053\u793a\u610f\u56fe<\/strong>[9]<\/sup><\/strong>\u3002<\/strong><\/p>\n

      \u7531\u6b64\u53ef\u89c1\u8bbe\u8ba1\u65b0\u578b\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u7684\u7535\u6781\u6750\u6599\u65f6\uff0c\u8981\u7efc\u5408\u8003\u8651\u5fae\u5b54\u548c\u4ecb\u5b54\u76f8\u4e92\u4f5c\u7528\u7684\u5f71\u54cd\uff0c\u4e0d\u80fd\u5355\u7eaf\u63d0\u9ad8\u591a\u5b54\u78b3\u4e2d\u5fae\u5b54\u5b54\u5bb9\u3002\u4f46\u662f\uff0c\u5173\u4e8e\u4ecb\u5b54\u548c\u5fae\u5b54\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4ee5\u53ca\u5982\u4f55\u786e\u5b9a\u6700\u4f73\u4ecb\u5b54\u5fae\u5b54\u5b54\u5bb9\u6bd4\uff0c\u76ee\u524d\u8fd8\u7f3a\u4e4f\u6df1\u5165\u7406\u89e3\uff0c\u8fd8\u9700\u8981\u7ee7\u7eed\u6df1\u5165\u7814\u7a76\u3002<\/p>\n

      4)\u00a0<\/b>\u9971\u548c\u6548\u5e94 <\/strong><\/p>\n

      \u591a\u5b54\u78b3\u79bb\u5b50\u50a8\u80fd\u5b58\u5728\u9971\u548c\u6548\u5e94\uff1a\u5373\u5f53\u5145\u7535\u7535\u538b\u8d85\u8fc7\u67d0\u4e00\u503c\u540e\uff0c\u5c31\u4e0d\u80fd\u7ee7\u7eed\u50a8\u5b58\u7535\u8377\u3002\u9971\u548c\u6548\u5e94\u4e0e\u5fae\u5b54\u7c92\u5f84\u5206\u5e03\u5bc6\u5207\u76f8\u5173\u7684\uff0c\u5f53\u7535\u538b\u8fbe\u5230\u4e00\u5b9a\u503c\u65f6\uff0c\u5b54\u7ed3\u6784\u5904\u4e8e\u9971\u548c\u72b6\u6001\uff0c\u5bfc\u81f4\u7535\u538b\u7ee7\u7eed\u589e\u5927\u65f6\u7535\u5bb9\u7535\u6d41\u6025\u5267\u4e0b\u964d\u3002MYSYK \u7b49[10]<\/sup>\u7684\u7814\u7a76\u8868\u660e\u591a\u5b54\u78b3\u9971\u548c\u6548\u5e94\u4ea7\u751f\u7684\u6839\u672c\u539f\u56e0\u662f\u5728\u5de5\u4f5c\u7535\u538b\u8303\u56f4\u5185\uff0c\u6b63\u8d1f\u6781\u7535\u8377\u50a8\u5b58\u80fd\u529b\u4e0d\u76f8\u5f53\u3002\u6839\u672c\u539f\u56e0\u662f\u6b63\u8d1f\u6781\u5438\u9644\u79bb\u5b50\u7684\u6709\u6548\u6bd4\u8868\u9762\u79ef\u4e0d\u540c\u3002\u56e0\u6b64\uff0c\u771f\u6b63\u610f\u4e49\u4e0a\u7684\u201c\u5bf9\u79f0\u201d\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u7684\u4e0d\u4ec5\u4ec5\u662f\u6b63\u8d1f\u6781\u6750\u6599\u76f8\u540c\uff0c\u4e24\u6781\u8fd8\u5e94\u5177\u6709\u76f8\u5f53\u7684\u7535\u8377\u50a8\u5b58\u80fd\u529b\u3002<\/p>\n

      5)\u00a0<\/b>\u79bb\u5b50\u53d8\u5f62\u3001\u79bb\u5b50\u5d4c\u5165\/\u8131\u51fa <\/strong><\/p>\n

      \u5f53\u5fae\u5b54\u5c3a\u5bf8\u8fdb\u4e00\u6b65\u7f29\u5c0f\uff0c\u5e73\u5747\u5b54\u5f84\u57280.58 nm\u65f6\uff0c\u591a\u5b54\u78b3\u4ecd\u6709\u50a8\u80fd\u80fd\u529b\uff0c\u800c\u7406\u8bba\u4e0a\u53bb\u6eb6\u5242\u5316\u9633\u79bb\u5b50\u76f4\u5f84\u5927\u4e8e\u5fae\u5b54\u5b54\u5f84\uff0c\u8be5\u6750\u6599\u4e0d\u5177\u6709\u50a8\u80fd\u80fd\u529b\uff0c\u56e0\u6b64 ANIA \u7b49\u89e3\u91ca\u5728\u7535\u573a\u4f5c\u7528\u4e0b\uff0c\u53bb\u6eb6\u5242\u5316\u9633\u79bb\u5b50\u4ea7\u751f\u53d8\u5f62\uff0c\u8fdb\u800c\u88ab\u5438\u9644[11]<\/sup>\u3002\u4e5f\u6709\u7814\u7a76\u8005\u8bc1\u5b9e\u4e86\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u53ef\u80fd\u5b58\u5728\u79bb\u5b50\u7684\u5d4c\u5165\/\u8131\u51fa\u8fc7\u7a0b\uff0c\u540c\u65f6\u4e5f\u8ba4\u4e3a\u79bb\u5b50\u5d4c\u5165\/\u8131\u51fa\u9020\u6210\u7684\u4f53\u79ef\u53d8\u5316\u662f\u5f71\u54cd\u78b3\u6750\u6599\u7535\u6781\u5faa\u73af\u5bff\u547d\u7684\u4e3b\u8981\u56e0\u7d20[12]<\/sup>\u3002<\/p>\n

      \u8fd1\u5e74\uff0c\u7814\u7a76\u8005\u4eec\u63d0\u51fa\u7684\u591a\u79cd\u591a\u5b54\u78b3\u53cc\u7535\u5c42\u7535\u5bb9\u50a8\u80fd\u673a\u7406\u6a21\u578b\u4e3a\u7406\u89e3\u53cc\u7535\u5c42\u50a8\u80fd\u673a\u7406\u3001\u63d0\u9ad8\u591a\u5b54\u78b3\u7684\u50a8\u80fd\u6027\u80fd\u5f00\u8f9f\u4e86\u65b0\u601d\u8def\u3002\u7814\u7a76\u5df2\u8bc1\u5b9e\u6750\u6599\u5b54\u7ed3\u6784\u662f\u51b3\u5b9a\u7535\u5bb9\u50a8\u80fd\u673a\u7406\u7684\u5173\u952e\u56e0\u7d20\uff0c\u5355\u7eaf\u589e\u5927\u6bd4\u8868\u9762\u79ef\u4e0d\u5229\u4e8e\u63d0\u9ad8\u591a\u5b54\u78b3\u7535\u5bb9\uff0c\u53cd\u800c\u5bfc\u81f4\u4f4e\u80fd\u91cf\u5bc6\u5ea6\u3002\u5f53\u5b54\u5f84\u4e0e\u53bb\u6eb6\u5242\u5316\uff08\u6216\u53d8\u5f62\uff09\u540e\u7684\u79bb\u5b50\u76f4\u5f84\u76f8\u5f53\u65f6\uff0c\u591a\u5b54\u78b3\u6bd4\u7535\u5bb9\u4f1a\u663e\u8457\u63d0\u9ad8\uff0c\u4e14\u5f53\u591a\u5b54\u78b3\u4e2d\u8fd8\u5b58\u5728\u5408\u9002\u6bd4\u4f8b\u7684\u4ecb\u5b54\u65f6\u53ef\u63d0\u9ad8\u7535\u89e3\u6db2\u79bb\u5b50\u5411\u6750\u6599\u672c\u4f53\u4f20\u8f93\u7684\u80fd\u529b\u4ece\u800c\u66f4\u5927\u9650\u5ea6\u5730\u53d1\u6325\u5fae\u5b54\u7684\u7535\u8377\u50a8\u5b58\u80fd\u529b\u3002<\/p>\n

      \u76f8\u5173\u6587\u732e<\/strong><\/p>\n

      [1] Xiang Y, Cao G, . A review on the mechanism of the energy storage about the electrochemical double-layer capacitors [J]. Energy Storage Science and Technology, 2016, 5(6): 816-827.<\/p>\n

      [2] Zhai Y, Dou Y, Zhao D, et al. Carbon materials for chemical capacitive energy storage [J]. Advanced Materials, 2011, 23(42): 4828-4850.<\/p>\n

      [3] Zhang L L, Zhao X S. Carbon-based materials as supercapacitor electrodes [J]. Chemical Society Reviews, 2009, 38(9): 2520-2531.<\/p>\n

      [4] Huang J S, Sumpter B G, Meunier V. A universal model for nanoporous carbon supercapacitors applicable to diverse pore regimes, carbon materials, and electrolytes [J]. Chemistry-a European Journal, 2008, 14(22): 6614-6626.<\/p>\n

      [5] Forse A C, Merlet C, Griffin J M, et al. New Perspectives on the Charging Mechanisms of Supercapacitors [J]. Journal Of The American Chemical Society, 2016, 138(18): 5731-5744.<\/p>\n

      [6] Noked M, Avraham E, Soffer A, et al. The Rate-Determining Step of Electroadsorption Processes into Nanoporous Carbon Electrodes Related to Water Desalination [J]. Journal Of Physical Chemistry C, 2009, 113(51): 21319-21327.<\/p>\n

      [7] Vix-Guterl C, Frackowiak E, Jurewicz K, et al. Electrochemical energy storage in ordered porous carbon materials [J]. Carbon, 2005, 43(6): 1293-1302.<\/p>\n

      [8] Ghosh A, Lee Y H. Carbon-Based Electrochemical Capacitors [J]. ChemSusChem, 2012, 5(3): 480-499.<\/p>\n

      [9] Zheng X Y, Luo J Y, Lv W, et al. Two-Dimensional Porous Carbon: Synthesis and Ion-Transport Properties [J]. Advanced Materials, 2015, 27(36): 5388-5395.<\/p>\n

      [10] Mysyk R, Raymundo-Pinero E, Pernak J, et al. Confinement of Symmetric Tetraalkylammonium Ions in Nanoporous Carbon Electrodes of Electric Double-Layer Capacitors [J]. Journal Of Physical Chemistry C, 2009, 113(30): 13443-13449.<\/p>\n

      [11] Ania C O, Pernak J, Stefaniak F, et al. Polarization-induced distortion of ions in the pores of carbon electrodes for electrochemical capacitors [J]. Carbon, 2009, 47(14): 3158-3166.<\/p>\n

      [12] Hahn M, Barbieri O, Campana F P, et al. Carbon based double layer capacitors with aprotic electrolyte solutions: the possible role of intercalation\/insertion processes [J]. Applied Physics A-materials Science & Processing, 2006, 82(4): 633-638.<\/p>\n

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      \u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

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