{"id":62491,"date":"2017-01-24T06:30:07","date_gmt":"2017-01-23T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=62491"},"modified":"2017-01-23T22:34:57","modified_gmt":"2017-01-23T14:34:57","slug":"nano-letters%ef%bc%9a-%e5%9c%a8na%e2%88%92sn%e7%94%b5%e6%b1%a0%e7%9a%84%e9%92%a0%e5%8c%96%e8%bf%87%e7%a8%8b%e4%b8%adzintl%e7%a6%bb%e5%ad%90%e5%8f%8a%e5%85%b6%e7%9a%84%e6%9e%84%e5%9e%8b%e5%8f%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=62491","title":{"rendered":"Nano Lett.\uff1a\u5728Na\u2212Sn\u7535\u6c60\u7684\u94a0\u5316\u8fc7\u7a0b\u4e2dZintl\u79bb\u5b50\u53ca\u5176\u7684\u6784\u578b\u53d8\u5316"},"content":{"rendered":"
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\u5728\u6a21\u578b\u7c92\u5b50\u4e2d\u4f7f\u7528\u989c\u8272\u4ee5\u533a\u5206\u7531\u4e24\u76f8\u5206\u79bb\u7684\u79fb\u52a8\u76f8\u8fb9\u754c\u7684\u4f4d\u7f6e\uff0c\u5373\uff0c\u03b1-Na0.2Sn\uff08\u4ee5\u6a59\u8272\uff09\u548c\u03b1-NaSn\uff08\u4ee5\u84dd\u8272\uff09\u3002<\/p>\n \u56fe\u4e94\uff1aZintl\u79bb\u5b50\u7684\u7ed3\u6784<\/strong><\/span><\/p>\n \uff08a\uff09\u03b2-NaSn\u6676\u4f53\u7684\u8d85\u6676\u80de\u7ed3\u6784\uff0c\u5176\u5b8c\u5168\u5177\u6709\u7406\u60f3\u7684Zintl\u76f8\u3002 \u5355\u8f74\u548c\u53cc\u8f74\u5e94\u529b\u5bf9\uff08b\uff09Zintl\u79bb\u5b50\u7684\u7ed3\u6784\uff08|\u0394l|\uff09\u548c\uff08c\uff09\u5e26\u9699\uff08Eg\uff09\u7684\u53d8\u5316\u7684\u5f71\u54cd\u3002<\/p>\n \u3010\u603b\u7ed3\u3011<\/strong><\/span><\/p>\n Na-Sn\u7535\u6c60\u7cfb\u7edf\u7684\u539f\u4f4d\u94a0\u79bb\u5b50\u5b9e\u9a8c\u8868\u660e\uff0cNa\u7684\u8fde\u7eed\u548c\u81ea\u53d1\u5d4c\u5165\u53d1\u751f\u5728\u4e09\u4e2a\u7279\u5f81\u9636\u6bb5\u3002\u901a\u8fc7\u5728\u8868\u9762\u4e0a\u5f62\u6210\u8584\u7684a-NaSn\u5c42\u5f00\u59cb\u94a0\u5316\u3002\u968f\u7740\u65f6\u95f4\u7684\u63a8\u79fb\uff0ca-NaSn\u5c42\u751f\u957f\u5f97\u66f4\u539a\uff0c\u5728\u5185\u90e8\u5f62\u6210\u65b0\u7684\u03b1-Na0.2Sn\u76f8\uff0c\u5f62\u6210\u6838-\u58f3\u7ed3\u6784\u3002\u8fdb\u4e00\u6b65\u7684\u94a0\u5316\u5c06\u03b1-NaSn\u76f8\u8f6c\u53d8\u4e3a\u03b1-Na3.75Sn\u76f8\uff0c\u8fd9\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\u5728\u9897\u7c92\u8868\u9762\u4e0a\u5f15\u8d77\u88c2\u7eb9\u3002\u5bf9\u4e8e\u6bcf\u4e2a\u9636\u6bb5\u7684\u94a0\u79bb\u5b50\u6240\u89c2\u5bdf\u5230\u7684\u76f8\u53d8\u5bfc\u81f4\u7535\u963b\u7387\u589e\u52a0\uff0c\u4f7f\u5f97\u5728\u5b8c\u5168\u94a0\u5316\u4e4b\u540e\uff0c\u88ab\u70e7\u7ed3\u7684Sn\u7684\u7535\u963b\u7387\u6bd4\u539f\u59cbSn\u7684\u7535\u963b\u7387\u9ad88\u4e2a\u6570\u91cf\u7ea7\u3002\u8be5\u589e\u91cf\u4e3b\u8981\u5f52\u56e0\u4e8e\u5728\u7b2c\u4e00\u9636\u6bb5\u548c\u7b2c\u4e8c\u9636\u6bb5\u4e2d\u5f62\u6210\u4e8eSn\u8d1f\u6781\u8868\u9762\u7684a-NaSn\u76f8\uff08Zintl\u79bb\u5b50\uff09\u3002\u7136\u800c\uff0c\u5728\u7b2c\u4e8c\u9636\u6bb5\uff0c\u7535\u963b\u7387\u7684\u589e\u91cf\u66f4\u52a0\u660e\u663e\uff0c\u5728\u7b2c\u4e8c\u9636\u6bb5\u671f\u95f4\u5f62\u6210\u03b1-NaSn \/ a-Na0.2Sn\u6838-\u58f3\u7ed3\u6784\u3002\u6838-\u58f3\u7ed3\u6784\u4f7f\u5728\u88ab\u94a0\u5316\u7684Sn\u9897\u7c92\u7684\u8868\u9762\u6b8b\u4f59\u5e94\u529b\u5904\u663e\u7740\u6c34\u5e73\uff08\u301c2GPa\uff09\u3002\u8be5\u5e94\u529b\u8fdb\u800c\u8bf1\u5bfcZintl\u79bb\u5b50\u4ece\u5176\u7406\u60f3\u7ed3\u6784\u7684\u53d8\u5f62\uff0c\u5bfc\u81f4\u5e26\u9699\u7ed3\u6784\u7684\u53d8\u5316\uff0c\u4ece\u800c\u5bfc\u81f4\u88ab\u94a0\u5316\u7684Sn\u7684\u7535\u963b\u7387\u589e\u52a0\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/span>Formation of Zintl Ions and Their Configurational Change during Sodiation in Na\u2212Sn Battery<\/a><\/strong>\uff08Nano Lett.<\/strong>\uff0c2016<\/strong>\uff0cDOI: 10.1021\/acs.nanolett.6b03690<\/strong>\uff09<\/strong><\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4 \u80cc\u9006\u65f6\u5149 \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n 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