{"id":59612,"date":"2017-01-02T14:30:02","date_gmt":"2017-01-02T06:30:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=59612"},"modified":"2017-01-01T21:27:19","modified_gmt":"2017-01-01T13:27:19","slug":"adv-energy-mater-%e6%b6%b2%e6%b5%81%e7%94%b5%e6%b1%a0%e6%80%a7%e8%83%bd%e5%9b%a0%e7%94%b5%e8%a7%a3%e6%b6%b2%e5%8d%87%e7%ba%a7%e8%80%8c%e5%be%97%e5%88%b0%e9%a3%9e%e8%b7%83%e6%8f%90%e9%ab%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=59612","title":{"rendered":"Adv.Energy Mater.\u6db2\u6d41\u7535\u6c60\u6027\u80fd\u56e0\u7535\u89e3\u6db2\u5347\u7ea7\u800c\u5f97\u5230\u98de\u8dc3\u63d0\u9ad8"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u6db2\u6d41\u7535\u6c60\uff08RFBs\uff09\u4f5c\u4e3a\u7535\u5316\u5b66\u80fd\u91cf\u5b58\u50a8\u5668\u4ef6\uff0c\u5177\u6709\u5e03\u5c40\u7075\u6d3b\u3001\u5faa\u73af\u5bff\u547d\u957f\u3001\u54cd\u5e94\u65f6\u95f4\u5feb\u548c\u7535\u6781\u53cd\u5e94\u7b80\u5355\u7b49\u4f18\u70b9\uff0c\u76f8\u6bd4\u5339\u914d\u5ea6\u8981\u6c42\u8f83\u9ad8\u7684\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u5b83\u53ef\u4ee5\u8fd0\u7528\u5728\u8026\u5408\u529f\u7387\u80fd\u91cf\u5668\u4ef6\u3002RFBs\u4e2d\u5177\u6709\u9ad8\u6027\u80fd\u79bb\u5b50\u9009\u62e9\u900f\u8fc7\u6027\u7684\u4ea4\u6362\u819c\u4e00\u76f4\u662f\u7814\u7a76\u70ed\u70b9\uff0c\u76ee\u524d\u4f1a\u5b58\u5728\u4ea4\u53c9\u6c61\u67d3\u548c\u79bb\u5b50\u4ea4\u6362\u819c\u4e0a\u7684\u79bb\u5b50\u6e17\u900f\u95ee\u9898\uff0c\u9020\u6210\u81ea\u653e\u7535\u3001\u5e93\u4f26\u6548\u7387\u4f4e\u3001\u80fd\u91cf\u6548\u7387\u4f4e\u7b49\u7f3a\u9677\u3002\u73b0\u5b58\u7684\u591a\u79cd\u89e3\u51b3\u65b9\u6848\u4e2d\uff0c\u5927\u591a\u6570\u6b63\u8d1f\u6781\u91c7\u7528\u4e0d\u540c\u7684\u7535\u89e3\u6db2\u3002\u5982\u679c\u6b63\u8d1f\u6781\u91c7\u7528\u76f8\u540c\u7535\u89e3\u6db2\uff0c\u79bb\u5b50\u4ea4\u53c9\u6c61\u67d3\u7684\u95ee\u9898\u5c31\u53ef\u907f\u514d\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u6765\u81ea\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u7684\u5362\u5584\u5bcc<\/a>\u548c\u76f8\u8273<\/a>\u6559\u6388\u8bfe\u9898\u7ec4\u8fd1\u65e5\u5728Adv.Energy Mater\u4e0a\u53d1\u8868\u4e86\u9898\u4e3aAn Aqueous Redox Flow Battery with a Tungsten\u2013Cobalt Heteropolyacid as the Electrolyte for both the Anode and Cathode\u6587\u7ae0\uff0c\u62a5\u9053\u4e86\u4ed6\u4eec\u5728\u6db2\u6d41\u7535\u6c60\u7535\u89e3\u6db2\u4e0a\u7684\u6700\u65b0\u7a81\u7834\u3002\u4ed6\u4eec\u4f7f\u7528\u94a8\u94b4\u6742\u591a\u9178\u4f5c\u4e3a\u7535\u89e3\u6db2\uff0c\u540c\u65f6\u5728\u6b63\u8d1f\u6781\u4e0a\u5de5\u4f5c\uff0c\u5236\u5f97\u7684\u5668\u4ef6\u6709\u5f88\u9ad8\u7684\u5f00\u8def\u7535\u538b\u3001\u7535\u6d41\u5bc6\u5ea6\u548c\u80fd\u91cf\u6548\u7387\u3002Co\u5728\u6742\u591a\u9178H6<\/sub>[CoW12<\/sub>O40<\/sub>]\u7684\u4e2d\u5fc3\u4f4d\u7f6e\uff0c\u53ef\u4ee5\u540c\u65f6\u5728\u6b63\u8d1f\u6781\u4e4b\u95f4\u4f5c\u4e3a\u80fd\u91cf\u50a8\u5b58\u6750\u6599\u548c\u5728\u8f7d\u6d41\u5b50\u3002\u534a\u7535\u6c60\u7406\u8bba\u5bb9\u91cf\u8fbe\u5230108 A h L\u20131<\/sup>\uff0c\u7528\u77f3\u58a8\u6be1\u505a\u7535\u6781\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a25 mA cm\u20132<\/sup>\uff0c\u4f53\u79ef\u6bd4\u80fd\u91cf15.4 W h L\u20131<\/sup>\u83b7\u5f9799%\u7684\u5e93\u4f26\u6548\u7387\u548c86%\u7684\u80fd\u91cf\u6548\u7387\u3002\u7535\u6d41\u5bc6\u5ea6\u6700\u9ad8\u53ef\u8fbe100mA cm\u20132<\/sup>\uff0c25 mA cm\u22122<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u65f6\u53ef\u4ee5\u5faa\u73af30\u6b21\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u539f\u7406\u56fe<\/strong><\/p>\n

<\/p>\n

\u6c34\u6eb6\u6db2\u4e2dH6<\/sub>[CoW12<\/sub>O40<\/sub>]\u5206\u89e3\u6210[CoW12<\/sub>O40<\/sub>]6\u2013<\/sub>\u548cH+<\/sup>\uff0c\u8d28\u5b50\u4ea4\u6362\u819c\u4f7fH+<\/sup>\u7a7f\u8fc7\u3002\u5145\u7535\u65f6\uff0c[CoW12<\/sub>O40<\/sub>]6\u2013<\/sup>\u4e2d\u7684\u94b4\u5728\u6b63\u6781\u88ab\u53ef\u9006\u6027\u6c27\u5316\uff0c\u94a8\u5728\u8d1f\u6781\u88ab\u8fd8\u539f\uff0c\u653e\u7535\u65f6\u53d1\u751f\u76f8\u53cd\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002<\/p>\n

\u88681.\u4e0d\u540c\u6db2\u6d41\u7535\u6c60\u7684\u6027\u80fd\u5bf9\u6807<\/strong><\/p>\n

<\/p>\n\n\n\n\n
SE\uff1a\u7535\u89e3\u6db2<\/td>\nCE\uff1a\u5e93\u4f26\u6548\u7387<\/td>\nEE\uff1a\u80fd\u91cf\u6548\u7387<\/td>\nJ\uff1a\u7535\u6d41\u5bc6\u5ea6<\/td>\n<\/tr>\n
V:\u7535\u6c60\u7535\u538b<\/td>\nP\uff1a\u80fd\u91cf\u5bc6\u5ea6<\/td>\nC\uff1a\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u6d53\u5ea6<\/td>\nE\uff1a\u80fd\u91cf\u5bc6\u5ea6<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u56fe1.H6<\/sub>[CoW12<\/sub>O40<\/sub>]\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

<\/p>\n

ab) 0.005-m H6[CoW12<\/sub>O40<\/sub>] \u5728 0.5-m H2<\/sub>SO4<\/sub>\u00a0\u6eb6\u6db2\u4e2d\uff0c\u5339\u914d\u73bb\u78b3\u7535\u6781\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf<\/p>\n

c) 0.4-m\u7535\u89e3\u6db2\u572825, 50, 100 mA cm\u20132<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u7535\u538b\u5206\u5e03<\/p>\n

d) 0.4-m\u7535\u89e3\u6db2\u7684\u6db2\u6d41\u7535\u6c60\u572825, 50, 100 and then 25 mA cm\u20132<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

e) Nafion212\u8d28\u5b50\u4ea4\u6362\u819c\u5bf9VO2+<\/sup>\u00a0and [CoW12<\/sub>O40<\/sub>]6\u2013<\/sup>\u6e17\u900f\u6027\u793a\u610f\u56fe<\/p>\n

f) \u9492\u548cH6<\/sub>[CoW12<\/sub>O40<\/sub>]\u4e24\u79cd\u6db2\u6d41\u7535\u6c60\u81ea\u653e\u7535\u6d4b\u8bd5\u56fe<\/p>\n

\u56fe2.H6<\/sub>[CoW12<\/sub>O40<\/sub>]\u6db2\u6d41\u7535\u6c60H6<\/sub>[CoW12<\/sub>O40<\/sub>]\u7535\u89e3\u6db2\u6d53\u5ea6\u548c\u6b63\u8d1f\u6781\u4e4b\u95f4\u4f53\u79ef\u6bd4\u7684\u5f71\u54cd<\/strong><\/p>\n

<\/p>\n

ab) \u7535\u6d41\u5bc6\u5ea6\u572825 mA cm\u20132<\/sup>\u65f6\uff0c\u4e0d\u540cH6<\/sub>[CoW12<\/sub>O40<\/sub>]\u6d53\u5ea6\u4e0b\u6db2\u6d41\u7535\u6c60\u7535\u538b\u5206\u5e03\u548c\u7535\u6c60\u6548\u7387\u6d4b\u8bd5\u56fe<\/p>\n

cd) \u7535\u6d41\u5bc6\u5ea6\u572825 mA cm\u20132<\/sup>\u65f6\uff0c\u6b63\u8d1f\u6781\u4e0d\u540c\u4f53\u79ef\u6bd4\u6761\u4ef6\u4e0b\u6db2\u6d41\u7535\u6c60\u6bd4\u5bb9\u91cf\u3001\u6bd4\u80fd\u91cf\u6027\u80fd\u6d4b\u8bd5\u56fe<\/p>\n

\u56fe3.\u7535\u89e3\u6db2\u6d53\u5ea60.8 M\uff0c\u6b63\u8d1f\u7535\u89e3\u6db2\u4f53\u79ef\u6bd4\u4e3a4:1\u7684\u975e\u5bf9\u79f0\u6027all-H6<\/sub>[CoW12<\/sub>O40<\/sub>]\u6db2\u6d41\u7535\u6c60\u7535\u6c60\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

<\/p>\n

a) \u7535\u6d41\u5bc6\u5ea625 mA cm\u20132<\/sup>\u65f6\u7684\u7535\u538b\u5206\u5e03<\/p>\n

b) \u7535\u6d41\u5bc6\u5ea6\u572825 \u5230 100 mA cm\u20132<\/sup>\u8303\u56f4\u5185\u5e93\u4f26\u6548\u7387\u3001\u80fd\u91cf\u6548\u7387\u6d4b\u8bd5\u56fe<\/p>\n

c) \u7535\u6d41\u5bc6\u5ea625 mA cm\u20132<\/sup>\u65f6\u7535\u6c60\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5\u56fe<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/span><\/strong><\/p>\n

\u8be5\u8bfe\u9898\u7ec4\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u94b4\u2013\u94a8\u6742\u591a\u9178\u7535\u89e3\u8d28\u5e94\u7528\u5728\u6db2\u6d41\u7535\u6c60\u4e2d\uff0c\u5b83\u53ef\u4ee5\u4e0d\u6dfb\u52a0\u4efb\u4f55\u7535\u89e3\u8d28\u6761\u4ef6\u4e0b\u540c\u65f6\u5728\u6b63\u8d1f\u6781\u4e4b\u95f4\u5de5\u4f5c\uff0c\u6bd4\u5bb9\u91cf\u548c\u6bd4\u80fd\u91cf\u53d7\u6b63\u8d1f\u6781\u4f53\u79ef\u6bd4\u548c\u7535\u89e3\u6db2\u6d53\u5ea6\u6240\u5f71\u54cd\uff0c\u6b63\u8d1f\u7535\u6781\u4f53\u79ef\u6bd4\u4e3a4:1\u65f6\u83b7\u5f97\u4e86\u6700\u597d\u7684\u7535\u6c60\u6027\u80fd\uff0c\u7136\u800c\u8fd9\u79cd\u5f88\u6709\u524d\u666f\u7684\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u503c\u5f97\u7ee7\u7eed\u6df1\u5165\u7814\u7a76\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/strong>An Aqueous Redox Flow Battery with a Tungsten\u2013Cobalt Heteropolyacid as the Electrolyte for both the Anode and Cathode<\/a>\u00a0\uff08Adv. Energy Mater.\uff0c2017\uff0cDOI: 10.1002\/aenm.201601224\uff09<\/u><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 YueZhou \u4f9b\u7a3f\u3002\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n

\"\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u6db2\u6d41\u7535\u6c60\uff08RFBs\uff09\u4f5c\u4e3a\u7535\u5316\u5b66\u80fd\u91cf\u5b58\u50a8\u5668\u4ef6\uff0c\u5177\u6709\u5e03\u5c40\u7075\u6d3b\u3001\u5faa\u73af\u5bff\u547d\u957f\u3001\u54cd\u5e94\u65f6\u95f4\u5feb\u548c\u7535\u6781\u53cd\u5e94\u7b80\u5355\u7b49\u4f18\u70b9\uff0c\u76f8\u6bd4\u5339\u914d\u5ea6\u8981\u6c42\u8f83\u9ad8\u7684\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u5b83\u53ef\u4ee5\u8fd0\u7528\u5728\u8026\u5408…<\/p>\n","protected":false},"author":1203,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-59612","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/59612"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1203"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=59612"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/59612\/revisions"}],"predecessor-version":[{"id":59694,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/59612\/revisions\/59694"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=59612"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=59612"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=59612"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}