{"id":59280,"date":"2017-01-01T14:00:00","date_gmt":"2017-01-01T06:00:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=59280"},"modified":"2017-01-05T10:37:56","modified_gmt":"2017-01-05T02:37:56","slug":"adv-science-mater-%e9%94%82%e7%a1%ab%e7%94%b5%e6%b1%a0-%e7%ae%80%e5%8d%95%e7%9a%84%e4%b8%80%e6%ad%a5%e6%93%8d%e4%bd%9c%e4%bb%8e%e6%99%ae%e9%b2%81%e5%a3%ab%e8%93%9d%e4%b8%ad%e8%8e%b7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=59280","title":{"rendered":"Adv. Energy Mater.\u9502\u786b\u7535\u6c60\u2014\u2014\u7b80\u5355\u7684\u4e00\u6b65\u64cd\u4f5c\u4ece\u666e\u9c81\u58eb\u84dd\u4e2d\u83b7\u5f97\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef-\u78b3\u7eb3\u7c73\u7ba1"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u9502\u786b\u7535\u6c60\u7406\u8bba\u5bb9\u91cf\uff081673 mA h g-1<\/sup>\uff09\u548c\u80fd\u91cf\u5bc6\u5ea6\uff082600W h kg-1<\/sup>\uff09\u5f88\u9ad8\uff0c\u5b9e\u9645\u8fd0\u7528\u4e2d\u80fd\u8fbe\u5230\u76ee\u524d\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4e94\u500d\u4ee5\u4e0a\u3002\u9664\u6b64\u786b\u8fd8\u6709\u50a8\u91cf\u4e30\u5bcc\uff0c\u4ef7\u683c\u4f4e\uff0c\u73af\u5883\u53cb\u597d\u7684\u4f18\u70b9\u3002\u5c3d\u7ba1\u7814\u7a76\u56e2\u961f\u9488\u5bf9\u5b83\u5c55\u5f00\u4e86\u8bfe\u9898\uff0c\u8ddd\u79bb\u5b9e\u9645\u8fd0\u7528\u8fd8\u6709\u8bb8\u591a\u95ee\u9898\u4e9f\u5f85\u89e3\u51b3\uff0c\u5982\u786b\u662f\u4e2a\u7edd\u7f18\u4f53\uff0c\u4e0e\u7535\u6781\u6750\u6599\u95f4\u7684\u7535\u5316\u5b66\u53cd\u5e94\u8fdf\u949d\uff1b\u4e2d\u95f4\u591a\u786b\u5316\u7269\u7684\u4ea7\u751f\u4f1a\u5728\u7535\u89e3\u6db2\u4e2d\u6eb6\u89e3\uff0c\u5728\u6b63\u8d1f\u6781\u4e4b\u95f4\u7a7f\u68ad\uff0c\u9020\u6210\u786b\u7684\u4e0d\u53ef\u9006\u635f\u5931\uff0c\u4e25\u91cd\u5f71\u54cd\u5e93\u4f26\u6548\u7387\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u3001\u589e\u5927\u4e86\u7535\u6c60\u5185\u963b\uff1bLi2<\/sub>S\uff081.66g cm-3<\/sup>\uff09\u4e0eS\uff082.03g cm-3<\/sup>\uff09\u5bc6\u5ea6\u76f8\u5dee\u8f83\u5927\uff0c\u4ea7\u751f\u7684\u4f53\u79ef\u81a8\u80c0\u4f1a\u4f7f\u7535\u6c60\u5bb9\u91cf\u8fc5\u901f\u8870\u51cf\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u6765\u81ea\u6089\u5c3c\u79d1\u6280\u5927\u5b66\u6e05\u6d01\u80fd\u6e90\u79d1\u5b66\u6280\u672f\u5b66\u9662\u7684\u6c6a\u56fd\u79c0\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bfe\u9898\u7ec4\u8fd1\u65e5\u5728Adv. Energy Mater.\u4e0a\u53d1\u8868\u4e86\u9898\u4e3aFabrication of N-doped Graphene\u2013Carbon Nanotube Hybrids from Prussian Blue for Lithium\u2013Sulfur Batteries\u7684\u6587\u7ae0\uff0c\u62a5\u9053\u4e86\u5728\u9502\u786b\u7535\u6c60\u4e0a\u7684\u65b0\u7a81\u7834\u3002\u8be5\u56e2\u961f\u6210\u5458\u4ece\u666e\u9c81\u58eb\u84dd\u8fd9\u79cd\u4ef7\u683c\u4f4e\u5ec9\u7684\u539f\u6750\u6599\u4e2d\uff0c\u4f7f\u7528\u4e00\u6b65\u7b80\u5355\u7684\u64cd\u4f5c\u83b7\u5f97\u4e86Fe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269\u3002\u751f\u957f\u754c\u9762\u4e0a\u77f3\u58a8\u70ef\u548cCNTs\u65e0\u7f1d\u7ed3\u5408\uff0c\u5f62\u62103D\u7684\u5fae\u578b\u6846\u67b6\uff0c\u4ee5\u5bb9\u7eb3\u9502\u786b\u7535\u6c60\u4e2d\u7684\u786b\uff0c\u83b7\u5f97\u4e861221mA h g-1<\/sup>\u7684\u53ef\u9006\u5bb9\u91cf\uff0c5\u2103\u4e0b10C\u653e\u7535\u5faa\u73af1000\u6b21\uff0c\u8870\u9000\u7387\u5206\u522b\u4e3a0.015%\u548c0.025%. \u5f53\u6709\u954d\u63ba\u6742\u65f6\u5219\u4f1a\u589e\u52a0\u6846\u67b6\u4e0a\u7684\u7f3a\u9677\u548c\u6d3b\u6027\u4f4d\u70b9\uff0c\u628a\u9502\u7684\u591a\u786b\u5316\u7269\u9650\u5236\u5728\u6b63\u6781\u4e2d\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe1.\u5408\u6210\u53ca\u8868\u5f81\u793a\u610f\u56fe<\/strong><\/p>\n

<\/p>\n

a.\u5408\u6210Fe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269\u7684\u8fc7\u7a0b\u793a\u610f\u56fe<\/p>\n

b.\u5546\u4e1a\u5316Na4<\/sub>Fe(CN)6<\/sub>\u00b710H2<\/sub>O\u7684XRD\u884d\u5c04\u56fe\uff08Rietveld\u7cbe\u4fee\u6a21\u5f0f\uff09<\/p>\n

c.\u65e0\u6c34\u7684Na4<\/sub>Fe(CN)6<\/sub><\/p>\n

d.Fe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269<\/p>\n

\u6240\u89c2\u5bdf\u5230\u548c\u8ba1\u7b97\u51fa\u7684\u5f3a\u5ea6\u5206\u522b\u7531\u7531\u7ea2\u8272\u5706\u5708\u548c\u84dd\u8272\u5b9e\u7ebf\u8868\u793a\uff0c\u5e95\u90e8\u7684\u7d2b\u8272\u7ebf\u8868\u793a\u62df\u5408\u6b8b\u5dee\uff0c\u6d45\u7eff\u8272\u7684\u8bb0\u53f7\u8868\u793a\u5e03\u62c9\u683c\u4f4d\u70b9\u3002<\/p>\n

e.Fe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269\u7684FESEM\u56fe\u50cf<\/p>\n

f.\u56fe\u89e3\u77f3\u58a8\u70ef\u4e0a\u751f\u957f\u78b3\u7eb3\u7c73\u7ba1<\/p>\n

\u56fe2.\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u548cFe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269\u7684\u8868\u5f81\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

<\/p>\n

a.\u77f3\u58a8\u70ef\u7684TEM\u7167\u7247<\/p>\n

b.\u77f3\u58a8\u70ef\u7684HRTEM\u7167\u7247<\/p>\n

c.\u539a\u5ea6\u5206\u5e03\u6d4b\u91cf<\/p>\n

d.\u78b3\u7eb3\u7c73\u7ba1TEM\u7167\u7247<\/p>\n

e.Fe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269\u7684HRTEM\u7167\u7247\uff0c\u56fe\u4e2d\u5c55\u793a\u4e86Fe3<\/sub>C\u3001\u78b3\u7eb3\u7c73\u7ba1\u548c\u77f3\u58a8\u70ef\u4e4b\u95f4\u7684\u94fe\u63a5<\/p>\n

f.\u78b3\u7eb3\u7c73\u7ba1\u5728\u77f3\u58a8\u70ef\u4e0a\u751f\u957f\u7684\u6839\u533a\u90e8\u4f4d\u7684TEM\u7167\u7247<\/p>\n

g.\u5178\u578b\u7684\u78b3\u7eb3\u7c73\u7ba1\u7684TEM\u7167\u7247<\/p>\n

h.\u78b3\u7eb3\u7c73\u7ba1\u7684HRTEM\u7167\u7247\uff0c\u63d2\u56fe\u662f\u78b3\u7eb3\u7c73\u7ba1\u58c1\u539a\u5206\u5e03<\/p>\n

i-l.Fe3<\/sub>C@N-GE\u2013CNTs\u751f\u957f\u6f14\u53d8\u539f\u7406\u793a\u610f\u56fe<\/p>\n

\u56fe3.\u62c9\u66fc\u5149\u8c31\u3001\u7b49\u6e29\u5206\u6790\u3001XPS\u3001EDS\u5206\u6790<\/strong><\/p>\n

<\/p>\n

a.\u62c9\u66fc\u5149\u8c31\u5206\u6790<\/p>\n

b.\u7b49\u6e29\u5206\u6790\uff08\u63d2\u56fe\u663e\u793a\u5b54\u5f84\u5206\u5e03\uff09<\/p>\n

c.C 1s\u7684XPS\u6d4b\u8bd5\u56fe<\/p>\n

d.N 1s\u7684XPS\u6d4b\u8bd5\u56fe<\/p>\n

e.N\u63ba\u6742\u77f3\u58a8\u70ef\u7684\u539f\u7406\u793a\u610f\u56fe<\/p>\n

f.EDS\u5149\u8c31\u5206\u6790\u65e0\u6c34Na4<\/sub>Fe(CN)6<\/sub>, Fe3<\/sub>C@N-GE\u2013CNTs \u590d\u5408\u7269, S@Fe3<\/sub>C@N-GE\u2013CNTs \u590d\u5408\u7269,\u548c S@RGO\u2013CNTs \u590d\u5408\u7269<\/p>\n

\u56fe4.Fe3C@N-GE\u2013CNTs\u590d\u5408\u7269\u5404\u5143\u7d20\u5206\u5e03\u7684\u8868\u5f81<\/strong><\/p>\n

<\/p>\n

a.Fe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269\u8d1f\u8f7dS\u7684FESEM\u7167\u7247<\/p>\n

b.EDS\u80fd\u8c31\u56fe<\/p>\n

c.C\u5143\u7d20\u5747\u5300\u5206\u5e03<\/p>\n

d.S\u5143\u7d20\u7684\u5206\u5e03<\/p>\n

e.\u94c1\u5143\u7d20\u7684\u5206\u5e03<\/p>\n

\u56fe5.\u4e00\u4e9b\u5143\u7d20\u7684XPS\u5206\u6790<\/strong><\/p>\n

<\/p>\n

a.S@Fex<\/sub>S@N-GE\u2013CNTs \u590d\u5408\u7269\u590d\u5408\u793a\u610f\u56fe<\/p>\n

b.XRD\u884d\u5c04<\/p>\n

c.S@Fex<\/sub>S@N-GE\u2013CNTs \u590d\u5408\u7269\uff0c\u7eaf\u51c0S\u4ee5\u53caFe3<\/sub>C@N-GE\u2013CNTs\u590d\u5408\u7269\u7684\u62c9\u66fc\u5149\u8c31\u6d4b\u8bd5\u56fe<\/p>\n

d.Fe3<\/sub>C@N-GE\u2013CNTs \u548c Fex<\/sub>S@N-GE\u2013CNTs \u590d\u5408\u7269\u4e2d2P\u94c1\u5143\u7d20\u7684XPS\u6d4b\u8bd5\u56fe<\/p>\n

e.Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u4e2d2P\u786b\u5143\u7d20\u6d4b\u8bd5\u56fe<\/p>\n

f.S@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u7684TAG\u66f2\u7ebf\uff0c\u63d2\u56fe\u662f\u6e29\u5ea6\u4e0e\u65f6\u95f4\u5bf9\u5e94\u7684\u4e00\u9636\u5bfc\u6570<\/p>\n

\u56fe6.S@FexS@N-GE\u2013CNTs\u590d\u5408\u7269\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u56fe\uff081\uff09<\/strong><\/p>\n

<\/p>\n

a.\u626b\u63cf\u901f\u5ea60.1v m-1<\/sup>\u65f6S@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u524d\u4e09\u6b21\u7684CV\u66f2\u7ebf<\/p>\n

b.0.2C\u6761\u4ef6\u4e0b\uff0cS@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u5faa\u73af1st, 20th, 40th, 60th, 80th, and 100th\u7684\u5178\u578b\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

c.0.2C\u548c0.5C\u65f6S@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u5145\u653e\u7535\u6027\u80fd\u548c\u5e93\u4f26\u6548\u7387\u6d4b\u8bd5\u56fe<\/p>\n

d.0.5, 1, 2, 5, \u548c 10 C\u500d\u7387\u4e0bS@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u9996\u6b21\u5145\u653e\u7535\u6d4b\u8bd5\u56fe<\/p>\n

\u56fe7.S@FexS@N-GE\u2013CNTs\u590d\u5408\u7269\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u56fe\uff082\uff09<\/strong><\/p>\n

<\/p>\n

a.1\uff0c2\uff0c5C\u6761\u4ef6\u4e0bS@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4f26\u6548\u7387\u6d4b\u8bd5\u56fe\uff0c\u9996\u6b21\u5faa\u73af\u662f\u57280.5C<\/p>\n

b.10C\u6761\u4ef6\u4e0bS@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4f26\u6548\u7387\u6d4b\u8bd5\u56fe\uff0c\u9996\u6b21\u5faa\u73af\u662f\u57280.5C<\/p>\n

c.\u4e0d\u540c\u5e93\u4f26\u6548\u7387\u4e0b\uff080.2, 0.5, 2, 4, 5, \u548c 10 C\uff09S@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5\u56fe<\/p>\n

\u56fe8.\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u5143\u7d20\u68c0\u6d4b<\/strong><\/p>\n

<\/p>\n

a.S@Fex<\/sub>S@N-GE\u2013CNTs\u590d\u5408\u7269\u548c\u7535\u6781\u57281C\u6761\u4ef6\u4e0b\u653e\u7535\u81f32.0V\u4ee5\u4e0b\u5faa\u73af1000\u6b21\u7684\u62c9\u66fc\u5149\u8c31\u6d4b\u8bd5<\/p>\n

b.\u653e\u7535\u81f32.0V\u4e00\u4e0b\u7535\u6781\u4e2dLi 1s\u7684XPS\u68c0\u6d4b<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/span><\/strong><\/p>\n

\u672c\u6587\u4f5c\u8005\u4f7f\u7528\u7b80\u5355\u7684\u4e00\u4e2a\u6b65\u9aa4\u4ece\u4ef7\u683c\u4f4e\u5ec9\u7684\u666e\u9c81\u58eb\u84dd\u4e2d\u5408\u6210\u4e86Fe3<\/sub>C@NGE\u2013CNTs\u7ed3\u6784\uff0c\u5927\u7535\u6d41\u5145\u653e\u7535\u4ee5\u53ca\u957f\u65f6\u95f4\u5faa\u73af\u540e\uff0c\u53ef\u9006\u5bb9\u91cf\u4ecd\u80fd\u4fdd\u63011221 mA h g\u22121<\/sup>\u3002\u589e\u5f3a\u7684\u7535\u5316\u5b66\u6027\u80fd\u53ef\u4ee5\u5f52\u56e0\u4e8e\u7ed3\u5408\u4e8c\u7ef4\u77f3\u58a8\u70ef\u548c\u4e00\u7ef4\u78b3\u7eb3\u7c73\u7ba1\u72ec\u7279\u7684\u67b6\u6784\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u5b50\u5bfc\u7535\u6027\uff0c\u9632\u6b62\u591a\u786b\u5316\u7269\u7684\u6eb6\u89e3\uff0c\u5e76\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u4e86\u7a7f\u68ad\u6548\u5e94\u7684\u5f71\u54cd\uff0c\u540c\u65f6\u4e09\u7ef4\u4e92\u8fde\u7684\u591a\u5b54\u7a7a\u95f4\u4e5f\u4fc3\u8fdb\u7535\u89e3\u8d28\u7684\u6e17\u900f\u548c\u6269\u6563\u3002\u6b64\u5916\uff0c\u63ba\u6c2e\u4f7f\u78b3\u6846\u67b6\u5f15\u5165\u4e86\u66f4\u591a\u7f3a\u9677\u548c\u6d3b\u6027\u4f4d\u70b9\uff0c\u4f7f\u591a\u786b\u5316\u7269\u9650\u5236\u5728\u4e86\u6b63\u6781\u4e2d\u3002\u8fd9\u4e00\u7b56\u7565\u5c06\u4e3a\u5f00\u53d1\u9ad8\u6027\u80fd\u9502\u7535\u6c60\u5f00\u8f9f\u4e00\u6761\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/strong>Fabrication of N-doped Graphene\u2013Carbon Nanotube Hybrids from Prussian Blue for Lithium\u2013Sulfur Batteries<\/a>\uff08Adv. Energy Mater. 2017,DOI: 10.1002\/aenm.201602014\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 YueZhou \u4f9b\u7a3f\u3002\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002<\/p>\n

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\"\"<\/p>\n","protected":false},"excerpt":{"rendered":"

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