{"id":59017,"date":"2017-01-01T06:30:16","date_gmt":"2016-12-31T22:30:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=59017"},"modified":"2017-03-18T22:01:09","modified_gmt":"2017-03-18T14:01:09","slug":"jacs%ef%bc%9aco2%e8%bf%98%e5%8e%9f%e5%85%89%e5%82%ac%e5%8c%96%e5%89%82%e6%8e%ba%e5%85%a5mofs%e5%8f%af%e6%8f%90%e9%ab%98%e5%82%ac%e5%8c%96%e5%89%82%e5%9c%a8%e5%8f%af%e8%a7%81%e5%85%89%e4%b8%8b%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=59017","title":{"rendered":"JACS\uff1aCO2\u8fd8\u539f\u5149\u50ac\u5316\u5242\u63ba\u5165MOFs\u53ef\u63d0\u9ad8\u50ac\u5316\u5242\u5728\u53ef\u89c1\u5149\u4e0b\u7684\u6d3b\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u5168\u7403\u80fd\u6e90\u5b89\u5168\u7684\u538b\u529b\u4e0d\u65ad\u589e\u5927\uff0c\u4ee5\u53ca\u5bf9\u6bd4\u5316\u77f3\u71c3\u6599\u66f4\u4e3a\u6e05\u6d01\u548c\u5b89\u5168\u7684\u66ff\u4ee3\u80fd\u6e90\u9700\u6c42\u91cf\u7684\u589e\u52a0\uff0c\u79d1\u5b66\u5bb6\u4eec\u9010\u6e10\u628a\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u89c6\u4e3a\u4e00\u79cd\u5bcc\u6709\u6f5c\u529b\u7684\u65b0\u80fd\u6e90\u3002\u4ece\u65e0\u673a\u534a\u5bfc\u4f53\u5230\u5206\u5b50\u590d\u5408\u7269\u7684\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u6750\u6599\uff0c\u7279\u522b\u4f5c\u4e3a\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u6750\u6599\u4e2d\u7684\u91cd\u8981\u4e00\u73af\u662fCO2<\/sub>\u8fd8\u539f\u6750\u6599\u5f00\u53d1\u5df2\u7ecf\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u4e3a\u4e86\u63d0\u9ad8\u53ef\u89c1\u5149\u4e0bCO2<\/sub>\u7684\u8fd8\u539f\u5149\u50ac\u5316\u5242\u7684\u6d3b\u6027\uff0c\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u6750\u6599\u7cfb\u6768\u57f9\u4e1c\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u4ee5\u53ca\u5316\u5b66\u7cfbOmar M. Yaghi\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5c06CO2<\/sub>\u8fd8\u539f\u6210CO\u7684\u5149\u50ac\u5316\u5242ReI<\/sup>(CO)3<\/sub>(BPYDC)Cl\u548cBPYDC\uff082,2′-\u8054\u5421\u5576-5,5′-\u4e8c\u7fa7\u9178\u916f\uff09\u5171\u4ef7\u8fde\u63a5\u5230\u4e00\u4e2a\u542bZr\u7684MOF (UiO-67)\u5185\u3002\u901a\u8fc7\u7cfb\u7edf\u5730\u63a7\u5236\u5149\u50ac\u5316\u5242\u5728MOF\u6846\u67b6\u4e2d\u7684\u5bc6\u5ea6\uff08n = 0, 1, 2, 3, 5, 11, 16, \u548c24 \uff0cn\u4e3a\u6bcf\u4e2a\u6846\u67b6\u4e2d\u7684\u590d\u5408\u7269\u4e2a\u6570\uff09\uff0c\u53d1\u73b0Re3<\/sub>-MOF\u5177\u6709\u6700\u9ad8\u5149\u50ac\u5316\u6d3b\u6027\u3002\u5c06\u5177\u6709\u6700\u4f73\u50ac\u5316\u6027\u80fd\u7684Re3<\/sub>-MOF\u6d82\u8986\u5230Ag\u7eb3\u7c73\u7acb\u65b9\u4f53\uff08Ag\u2282Re3<\/sub>-MOF\uff09\u4e0a\u3002\u56e0\u4e3a\u5149\u654f\u4e2d\u5fc3Re\u5728\u7a7a\u95f4\u4e0a\u88ab\u9650\u5236\u5230Ag\u7eb3\u7c73\u7acb\u65b9\u4f53\u8868\u9762\u589e\u5f3a\u7684\u8fd1\u8868\u9762\u7535\u573a\u4e2d\uff0c\u8fd9\u4f7f\u5f97\u5b83\u5728\u53ef\u89c1\u5149\u4e0b\u7684CO2<\/sub>\u5230CO\u7684\u8f6c\u6362\u6548\u7387\u63d0\u9ad8\u4e867\u500d\uff0c\u5e76\u572848\u5c0f\u65f6\u5185\u4fdd\u6301\u957f\u65f6\u95f4\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. Ren<\/sub>-MOF <\/strong>\u548c<\/strong> Ag<\/strong>\u2282<\/strong>Ren<\/sub>-MOF<\/strong>\u7684\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

(a)Zr6<\/sub>O4<\/sub>(OH)4<\/sub>(\u2212CO2<\/sub>)12<\/sub>\u7684\u4e8c\u6b21\u7ed3\u6784\u5355\u5143\u662f\u7531BPDC\u548cReTC\u7ed3\u5408\u5f62\u6210Ren<\/sub>-MOF\u3002\u56fe\u4e2d\u5c55\u793a\u4e86\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u786e\u5b9a\u7684Re3<\/sub>-MOF\u7ed3\u6784\u300212\u4e2aZr\u57fa\u91d1\u5c5e\u56e2\u7c07\u753121\u4e2aBPDC\u548c3\u4e2aReTC\u94fe\u63a5\u76f8\u4e92\u94fe\u63a5\u5728\u4e00\u4e2a\u9762\u5fc3\u7acb\u65b9\u70b9\u9635\u4e2d\u3002\u539f\u5b50\u6807\u53f7\uff1aC\uff0c\u9ed1\u8272\uff1bO\uff0c\u7ea2\u8272\uff1bZr\uff0c\u84dd\u8272\u591a\u9762\u4f53\uff1bRe\uff0c\u9ec4\u8272\uff1bCl\uff0c\u7eff\u8272\uff1b\u4e3a\u4e86\u7b80\u4fbf\uff0cH\u539f\u5b50\u5ffd\u7565\uff09\uff1b<\/p>\n

(b)Ren<\/sub>-MOF\u6d82\u8986\u5230\u4e00\u4e2aAg\u7eb3\u7c73\u7acb\u65b9\u4f53\u4e0a\uff0c\u4ee5\u63d0\u9ad8CO2<\/sub>\u8f6c\u5316\u7684\u5149\u50ac\u5316\u5242\u6d3b\u6027\u3002<\/p>\n

\u56fe<\/strong>2. Ren<\/sub>-MOFs<\/strong>\u7684\u8868\u5f81\u548c\u5149\u50ac\u5316\u6d3b\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a)ReTCs\u5728Ren<\/sub>-MOFs\u4e2d\u63ba\u5165\u7684\u767e\u5206\u6bd4\uff1b<\/p>\n

(b)Re0<\/sub>-\u548c(c) Re24<\/sub>-MOFs\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1b<\/p>\n

(d) Ren<\/sub>-MOFs\u7684\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\u56fe\u4e0eRe3<\/sub>-MOF\u7684\u6a21\u62df\u56fe\u5bf9\u6bd4\uff1b<\/p>\n

(e)\u53ef\u89c1\u5149\u4e0b(400-700nm)CO2<\/sub>\u8fd8\u539f\u6210CO\u7684\u5149\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u56fe<\/strong>3. Ren<\/sub>-MOFs <\/strong>\u548c<\/strong> H2<\/sub>ReTC<\/strong>\u7684\u7ea2\u5916\u5149\u8c31\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

Ren<\/sub>-MOFs\u7684\u5149\u50ac\u5316\u6d3b\u6027\u5e94\u4e0eReTC\u7684\u914d\u7f6e\u4ee5\u53ca\u5b83\u5468\u56f4\u7684\u73af\u5883\u6709\u5173\u3002<\/p>\n

Ren<\/sub>-MOFs\u4e2dReTC\u7fb0\u57fa\u914d\u4f53(C=O)\u548c\u5206\u5b50H2<\/sub>ReTC\u7684\u4f38\u7f29\u632f\u52a8\u5cf0\u7531\u7ea2\u5916\u5149\u8c31\u6d4b\u5f97\uff08\u5373\u4e0a\u56fe\uff09\u3002\u56fe\u4e2d\uff0c\u6d4b\u5f97\u7684Re1<\/sub>-, Re2<\/sub>-\u548c Re3<\/sub>-MOFs\u7684v(CO)\u952e\u4e0e\u5206\u6563\u5728\u6eb6\u6db2\u4e2d\u7684H2<\/sub>ReTC\u7684\u503c\u4e00\u81f4\uff0c\u4f46\u5bf9\u4e8eRe5<\/sub>-, Re11<\/sub>-, Re16<\/sub>-\u548c Re24<\/sub>-MOFs\uff0c\u4f4d\u4e8e\u4f4e\u6ce2\u957f\u7684v(CO)\u5219\u79fb\u52a8\u5230\u4e86\u8f83\u4f4e\u9891\u7387\u3002\u8fd9\u610f\u5473\u7740\u5b58\u5728\u6765\u81ea\u5176\u4ed6ReTC\u7684Re\u5bf9\u7fb0\u57fa\u914d\u4f53\u7684\u7535\u5b50\u53cd\u9988\uff0c\u4ece\u800c\u51cf\u5f31\u4e86C=O\u7684\u952e\u80fd\u3002\u8fd9\u79cd\u6548\u5e94\u53ef\u80fd\u662f\u7531\u4e8e\u8fde\u7eed\u91cd\u53e0\u7684ReTC\u4e4b\u95f4\u7684\u5f31\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

\u56fe<\/strong>4. Ag<\/strong>\u2282<\/strong>Re3<\/sub>-MOF<\/strong>\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a)Ag\u2282Re3<\/sub>-MOF\u7684TEM\u56fe\u663e\u793a\u4e86\u518dAg\u7eb3\u7c73\u7acb\u65b9\u4f53\u8868\u9762\u5f62\u6210\u7684Re3<\/sub>-MOF\uff1b<\/p>\n

(b) Re3<\/sub>-MOF \u7684\u653e\u5927\u56fe\uff1b<\/p>\n

(c) Re3<\/sub>-MOF\u3001Ag\u7eb3\u7c73\u7acb\u65b9\u4f53\u548cAg\u2282Re3<\/sub>-MOF\u7684\u7d2b\u5916\u53ef\u89c1\u5149\u5149\u8c31\uff1b<\/p>\n

(d) Ren<\/sub>-MOFs\uff08\u84dd\u7ebf\uff09\u3001Ag\u2282Re0<\/sub>-MOF\u3001Cu\u2282Re2<\/sub>-MOF\u3001\u548cAg\u2282Re3<\/sub>-MOFs \u7684CO2<\/sub>\u8fd8\u539f\u6210CO\u7684\u5149\u50ac\u5316\u6d3b\u6027\uff1b<\/p>\n

(e) Ag\u2282Re3<\/sub>-MOFs \u548cH2<\/sub>ReTC\u7684\u7a33\u5b9a\u6027\u5bf9\u6bd4\u3002<\/p>\n

\u3010\u7ed3\u8bba\u3011<\/strong><\/p>\n

\u5149\u654f\u5242ReI<\/sup>(CO)3<\/sub>(BPYDC)Cl\u548cBPYDC\uff082,2′-\u8054\u5421\u5576-5,5′-\u4e8c\u7fa7\u9178\u916f\uff09\u5171\u4ef7\u8fde\u63a5\u5230\u4e00\u4e2a\u542bZr\u7684MOF (UiO-67)\u540e\uff0c\u968fReTC\u5bc6\u5ea6\u800c\u6539\u53d8\u7684MOFs\u5185\u7684\u5206\u5b50\u73af\u5883\u5bf9\u6574\u4f53\u7684\u6d3b\u6027\u6709\u91cd\u8981\u5f71\u54cd\uff0c\u5f53n\u4e3a3\u65f6\uff0c\u53ef\u83b7\u5f97\u6700\u5927\u6d3b\u6027\u3002\u5c06Re3-MOF\u6d82\u8986\u5230Ag\u7eb3\u7c73\u7acb\u65b9\u4f53\uff0c\u53ef\u4ee5\u5c06\u5176\u5728\u53ef\u89c1\u5149\u4e0b\u7684\u50ac\u5316\u6d3b\u6027\u63d0\u9ad87\u500d\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Plasmon-Enhanced Photocatalytic CO2 Conversion within Metal\u2212Organic Frameworks under Visible Light<\/a>\u00a0(J. Am. Chem. Soc., 2016,DOI: 10.1021\/jacs.6b11027)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8MOF\u7ec4Joanna\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\uff01\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/u><\/a>\u3002\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/b><\/strong>\u4e0a<\/b><\/strong>\u6d4b\u8bd5\u8c37<\/b><\/u><\/strong><\/a>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u968f\u7740\u5168\u7403\u80fd\u6e90\u5b89\u5168\u7684\u538b\u529b\u4e0d\u65ad\u589e\u5927\uff0c\u4ee5\u53ca\u5bf9\u6bd4\u5316\u77f3\u71c3\u6599\u66f4\u4e3a\u6e05\u6d01\u548c\u5b89\u5168\u7684\u66ff\u4ee3\u80fd\u6e90\u9700\u6c42\u91cf\u7684\u589e\u52a0\uff0c\u79d1\u5b66\u5bb6\u4eec\u9010\u6e10\u628a\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u89c6\u4e3a\u4e00\u79cd\u5bcc\u6709\u6f5c\u529b\u7684\u65b0\u80fd\u6e90\u3002\u4ece\u65e0\u673a\u534a\u5bfc\u4f53…<\/p>\n","protected":false},"author":611,"featured_media":59019,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1300],"class_list":["post-59017","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-omar-m-yaghi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/59017"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/611"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=59017"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/59017\/revisions"}],"predecessor-version":[{"id":59174,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/59017\/revisions\/59174"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/59019"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=59017"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=59017"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=59017"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}