{"id":57699,"date":"2016-12-24T06:30:16","date_gmt":"2016-12-23T22:30:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=57699"},"modified":"2017-03-18T21:49:33","modified_gmt":"2017-03-18T13:49:33","slug":"jacs%e5%8f%8d%e5%b8%b8%e9%92%8c%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e9%ab%98%e6%95%88%e7%94%b5%e5%82%ac%e5%8c%96%e6%9e%90%e6%b0%a2%e5%8f%8d%e5%ba%94%e6%b4%bb%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=57699","title":{"rendered":"JACS:\u53cd\u5e38\u948c\u50ac\u5316\u5242\u7684\u9ad8\u6548\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\u6d3b\u6027"},"content":{"rendered":"<p><span style=\"color: #0000ff;\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u76ee\u524d\uff0c\u5927\u591a\u6570\u7814\u7a76\u50ac\u5316\u6790\u6c22\u53cd\u5e94\uff08Hydrogen Evolution Reactions\uff0cHER\uff09\u50ac\u5316\u5242\u7684\u5de5\u4f5c\u90fd\u96c6\u4e2d\u5728\u9178\u6027\u6761\u4ef6\u4e0b\uff0c\u4f46\u78b1\u6027\u73af\u5883\u4e2d\u7684\u7814\u7a76\u9c9c\u6709\u62a5\u9053\u3002\u4e00\u65b9\u9762\uff0c\u53ef\u80fd\u6e90\u4e8e\u50ac\u5316\u5242\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u53cd\u5e94\u901f\u7387\u8f83\u4f4e\uff0c\u53e6\u4e00\u65b9\u9762\uff0c\u9178\u6027\u4ecb\u8d28\u4e2d\u7684\u53cd\u5e94\u8def\u5f84\u8f83\u4e3a\u7b80\u5355\u3002\u4f46\u662f\uff0c\u7814\u7a76\u78b1\u6027\u4ecb\u8d28\u4e2d\u7684HER\u53cd\u5e94\uff0c\u6709\u52a9\u4e8eHER\u548cOER(oxygen evolution reaction\uff0c\u6790\u6c27\u53cd\u5e94)\u53cd\u5e94\u4f53\u7cfb\u7684\u7ed3\u5408\uff0c\u63d0\u9ad8\u6c34\u5206\u89e3\u53cd\u5e94\u4ea7\u7387\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p>11\u670828\u65e5\uff0cJACS\u5728\u7ebf\u53d1\u8868\u9898\u4e3a<strong>\u201c\u53cd\u5e38\u948c\u50ac\u5316\u5242\u7684\u9ad8\u6548\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\u6d3b\u6027<\/strong><strong>\u201d<\/strong>\uff08<a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.6b11291\" target=\"_blank\">High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst<\/a>\uff09\u7684\u7814\u7a76\u8bba\u6587<sup>[1]<\/sup>\uff0c\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66<a href=\"https:\/\/chemeng.adelaide.edu.au\/qiao\/members\/\" target=\"_blank\"><strong><span style=\"color: #0000ff;\">\u4e54\u4e16\u748b<\/span><\/strong><\/a>\u6559\u6388\u4e3a\u901a\u8baf\u4f5c\u8005<strong>\u3002<\/strong><\/p>\n<p><strong>\u672c\u6587\u4eae\u70b9\uff1a<\/strong>\u5728g- C<sub>3<\/sub>N<sub>4<\/sub>\u57fa\u4f53\u4e0a\u7684Ru\u50ac\u5316\u5242\u5b58\u5728\u7684\u5f02\u5e38\u6676\u578b\u53d8\u5316<strong>\uff0c<\/strong>\u8bf1\u5bfc\u4ea7\u751fHER\u9ad8\u6d3b\u6027\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p>\u901a\u5e38Ru\u50ac\u5316\u5242\u7684\u7ed3\u6784\u90fd\u662fhcp\u578b<sup>[2\uff0c3]<\/sup>\uff0c\u8fd9\u91cc\u62a5\u9053\u7684Ru\u50ac\u5316\u5242\u5728g-C<sub>3<\/sub>N<sub>4<\/sub> \u57fa\u4f53\u4e0a\u5b58\u5728fcc\u7ed3\u6784\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>1. Ru<\/strong><strong>\u7eb3\u7c73\u9897\u7c92\u7684<\/strong><strong>HAADF-STEM<\/strong><strong>\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58146 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-002-1.jpg\" alt=\"\" width=\"680\" height=\"1034\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-002-1.jpg 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-002-1-197x300.jpg 197w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-002-1-673x1024.jpg 673w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff0cc\uff0ce\uff09\u8868\u793aRu\u7eb3\u7c73\u9897\u7c92\u7684HAADF-STEM\u56fe\u50cf\uff0ca\uff0cc\uff0ce\u4e2d\u7684\u7ea2\u8272\u548c\u84dd\u8272\u70b9\u6807\u8bb0\u6cbf\u7740\u4e0d\u540c\u6676\u5411\u7684fcc\u548chcp\u7ed3\u6784\u7684\u5178\u578b\u539f\u5b50\u6392\u5217\u3002<\/p>\n<p>\uff08b\uff0cd\uff0cf\uff09STEM\u76f8\u5bf9\u5e94\u7684FFT\u5085\u91cc\u53f6\u53d8\u6362\u56fe\uff08b\uff09fcc\u7ed3\u6784\uff0c\uff08d\uff09fcc \/ hcp\u7ed3\u6784\u6df7\u5408; \u548c\uff08e\uff09hcp\u7ed3\u6784\u3002\u56fed\u4e2d\u7684\u7eff\u8272\u5706\u5708\u8868\u793afcc\u548chcp\u7ed3\u6784\u7684\u5171\u4eab\u884d\u5c04\u56fe\u3002<\/p>\n<p>\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u78b3\u7403\u4e0d\u80fd\u5f15\u8d77\u8868\u9762Ru\u539f\u5b50\u7684\u7c98\u9644\u80fd\u53d8\u5316\uff0c\u800cg- C<sub>3<\/sub>N<sub>4<\/sub>\u4f1a\u4f7f\u5f97\u8868\u9762Ru\u539f\u5b50\u5448hcp\u7ed3\u6784\u65f6\uff0c\u7c98\u9644\u80fd\u76f8\u5bf9\u51cf\u5f31\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>2.<\/strong><strong>\u7c98\u9644\u80fd\u8ba1\u7b97\u7ed3\u679c\u5bf9\u6bd4<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58147 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-003-1.jpg\" alt=\"\" width=\"680\" height=\"474\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-003-1.jpg 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-003-1-300x209.jpg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5177\u6709fcc\u7ed3\u6784\u7684g- C<sub>3<\/sub>N<sub>4<\/sub>\uff082\u00d72\uff09\u548cRu\uff085\u00d75\uff09\u5c42\u7684\u539f\u5b50\u6392\u5e03\uff08\u9876\u90e8\uff09\u548c\u4fa7\u89c6\u56fe\uff08\u5e95\u90e8\uff09\u3002\u6df1\u84dd\u8272\uff0c\u6d45\u84dd\u8272\u548c\u7c89\u7ea2\u8272\u5206\u522b\u8868\u793aRu\u539f\u5b50\u7684\u9876\u5c42\uff0c\u4e2d\u95f4\u5c42\u548c\u5e95\u5c42;\u7eff\u8272\u548c\u9ec4\u8272\u5206\u522b\u8868\u793ag- C<sub>3<\/sub>N<sub>4<\/sub>\u5c42\u4e2d\u7684\u78b3\u548c\u6c2e\u539f\u5b50\u3002<\/p>\n<p>\uff08b\uff09\u5177\u6709fcc\u6216hcp\u7ed3\u6784\u7684\u78b3\/ g- C<sub>3<\/sub>N<sub>4<\/sub>\u548cRu\u5c42\u4e4b\u95f4\u7684\u7c98\u9644\u80fd\u7684\u6bd4\u8f83\u3002<\/p>\n<p>\u901a\u8fc7\u5bf9\u6bd4\u53d1\u73b0\uff0cRu\/C<sub>3<\/sub>N<sub>4<\/sub>\/C\u7684X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u4e2dC\u7684K\u8fb9\u5438\u6536\u6ca1\u6709\u663e\u8457\u53d8\u5316\uff0c\u4f46N\u7684K\u8fb9\u5438\u6536\u4e0eg-C<sub>3<\/sub>N<sub>4<\/sub>\u548c\u6c2e\u63ba\u6742\u78b3\u7403\u76f8\u6bd4\uff0c\u51fa\u73b0\u65b0\u7684N-3C\u952e\uff0c\u8fd9\u6765\u6e90\u4e8eg-C<sub>3<\/sub>N<sub>4<\/sub>\u548cRu\u7684\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>Ru\/C<sub>3<\/sub>N<sub>4<\/sub>\/C<\/strong><strong>\u7684\u5316\u5b66\u7279\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58148 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-004-1.jpg\" alt=\"\" width=\"680\" height=\"514\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-004-1.jpg 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-004-1-300x227.jpg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a)C\u7684K\u8fb9\u5438\u6536\u8c31\uff0c<\/p>\n<p>\uff08b)N\u7684K\u8fb9\u5438\u6536\u8c31.<\/p>\n<p>\u78b1\u6027\u6eb6\u6db2\u4e2d\uff0cRu\/C &lt; Pt\/C &lt; Ru\/C<sub>3<\/sub>N<sub>4<\/sub>\/C\uff0c\u5176\u4e2dRu\u50ac\u5316\u5242\u4ea7\u6c22\u6bd4\u7387\u662fPt\u76842.5\u500d\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>4. <\/strong><strong>\u7535\u50ac\u5316\u6d3b\u6027\u548c<\/strong><strong>TOF<\/strong><strong>\u5206\u6790\u6bd4\u8f83<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58149 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-005-1.jpg\" alt=\"\" width=\"680\" height=\"920\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-005-1.jpg 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-005-1-222x300.jpg 222w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5728N2\u9971\u548c\u76840.1M KOH\u6eb6\u6db2\u4e2d\u8bb0\u5f55\u7684Ru \/ C<sub>3<\/sub>N<sub>4<\/sub> \/ C\uff0c\u5e38\u89c4Ru \/ C\u548c\u5546\u4e1aPt \/ C\u7535\u50ac\u5316\u5242\u7684HER\u6781\u5316\u66f2\u7ebf\u3002\u56fea\u4e2d\uff0c\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u4f4e\u7535\u52bf\u6c22\u5438\u9644\u6548\u5e94\u4ee5\u53ca\u7eb3\u7c73\u78b3\u7684\u7535\u5bb9\u6548\u5e94\u4f7f\u5f97\u7535\u6d41\u8d77\u59cb\u70b9\u4e0d\u4e3a\u96f6\u3002<\/p>\n<p>\uff08b\uff09\u76f8\u5e94\u7684Tafel\u56fe\u3002\u9762\u677f\u4e2d\u7684\u865a\u7ebf\u662f\u901a\u8fc7Tafel\u56fe\u7684\u7ebf\u6027\u62df\u5408\u8ba1\u7b97j<sub>0<\/sub>\u3002<\/p>\n<p>\uff08c\uff09\u5728\u78b3\u8f7d\u4f53\u4e0a\u7684\u5404\u79cd\u7eb3\u7c73\u7ed3\u6784\u7684\u8d35\u91d1\u5c5e\u7535\u50ac\u5316\u5242\uff0c\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\uff0c100 mV\u8d85\u7535\u52bf\u4e0b\uff0c\u5b9e\u73b010mA cm <sup>-2<\/sup>\u9634\u6781\u7535\u6d41\u5bc6\u5ea6\u6240\u9700\u7684\u8d85\u7535\u52bf\u503c\u3002<\/p>\n<p>\uff08d\uff09TOF\u503c\u7684\u6bd4\u8f83\u3002<\/p>\n<p>\uff08e\uff09TOF\u548cRu \/ C<sub>3<\/sub>N<sub>4<\/sub> \/ C\u548c\u5546\u4e1aPt \/ C\u7535\u50ac\u5316\u5242\u57280.1M KOH\u6eb6\u6db2\u4e2d\u7684\u6d4b\u91cf\u7535\u4f4d\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u5546\u4e1aNi-Mo\u5408\u91d1\u4e3a\u57fa\u51c6\u3002<\/p>\n<p>\uff08f\uff09Ru \/ C<sub>3<\/sub>N<sub>4<\/sub> \/ C\u7535\u50ac\u5316\u5242\u572850 mV\u8d85\u7535\u52bf\u4e0b\u7684\u7535\u6d41-\u65f6\u95f4\uff08i-t\uff09\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\u3002\u63d2\u56fe\u8868\u793a\u57280.1M KOH\u6eb6\u6db2\u4e2d\u57281000\u6b21\u626b\u63cf\uff08\u7535\u4f4d\u5728+0.2 V vs RHE\u81f3-0.6 V vs RHE\u4e4b\u95f4\uff09\u4e4b\u524d\u548c\u4e4b\u540e\u8bb0\u5f55\u7684HER\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>5.<\/strong> <strong>\u4e0d\u540c\u6676\u4f53\u7ed3\u6784\u7535\u50ac\u5316\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58151 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-006-1.jpg\" alt=\"\" width=\"680\" height=\"654\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-006-1.jpg 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-006-1-300x289.jpg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff0cb\uff09TOF\u503c\u4e0eRu \/ C<sub>3<\/sub>N<sub>4<\/sub> \/ C\u548c\u5e38\u89c4Ru \/ C\u7535\u50ac\u5316\u5242\u5728\u5404\u79cd\u6761\u4ef6\u4e0b\u6d4b\u91cf\u7684\u7535\u4f4d\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n<p>\uff08c\uff09\u6781\u5316\u66f2\u7ebf\u548c\uff08d\uff09TOF\u503c\u4e0e\u5728\u5404\u79cd\u6761\u4ef6\u4e0bRu \/ C<sub>3<\/sub>N<sub>4<\/sub>\/ C\u548cPt \/ C\u7535\u50ac\u5316\u5242\u7684\u6d4b\u91cf\u7535\u4f4d\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n<p>\u901a\u8fc7\u7ecf\u5178\u5fae\u52a8\u529b\u5b66\u6a21\u578b\uff08\u5e94\u7528\u0394G<sub>H*<\/sub>\u4f5c\u4e3a\u6709\u6548\u52bf\uff09\u4e0e\u65b0\u8fd1\u8003\u8651\u7684\u8fc7\u6e21\u6001\u7406\u8bba\uff08\u5e94\u7528\u0394G<sub>B<\/sub>\u4f5c\u4e3a\u6709\u6548\u52bf\u80fd\uff09\u7684\u8054\u5408\u4f7f\u7528\uff0c\u6587\u7ae0\u7ed9\u51fa\u4e86\u78b1\u6027\u6eb6\u6db2\u4e2d\uff0cPt \/ C\u7535\u50ac\u5316\u5242\u6c22\u6790\u7684\u52a8\u529b\u5b66\u8fdf\u7f13\u7684\u5b9a\u6027\u5206\u6790\uff0c\u66f4\u91cd\u8981\u7684\u662f\uff0c\u89e3\u91ca\u4e86Ru<sub>fcc<\/sub>\u7ed3\u6784\u5728Ru \/C<sub>3<\/sub>N<sub>4<\/sub> \/ C\u7535\u50ac\u5316\u5242\u4e0a\u663e\u793a\u66f4\u597d\u7684\u50ac\u5316\u6d3b\u6027\u7684\u57fa\u672c\u673a\u5236\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>6.<\/strong> <strong>Ru \/ C<sub>3<\/sub>N<sub>4<\/sub> \/ C\u6d3b\u6027\u589e\u5f3a\u7684\u8d77\u6e90<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58152 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-007-1.jpg\" alt=\"\" width=\"680\" height=\"360\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-007-1.jpg 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/master.img-007-1-300x159.jpg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09HER\u5728\u4e0d\u540c\u8868\u9762\u4e0a\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe\uff0c\u5305\u62ec\u53cd\u5e94\u7269\u521d\u59cb\u72b6\u6001\uff0c\u4e2d\u95f4\u72b6\u6001\uff0c\u6c34\u89e3\u79bb\u8fc7\u6e21\u72b6\u6001\u548c\u6700\u7ec8\u72b6\u6001\u3002\u0394G<sub>H*<\/sub>\u8868\u793a\u6c22\u5438\u9644\u81ea\u7531\u80fd\uff0c\u0394G<sub>B<\/sub>\u8868\u793a\u6c34\u89e3\u79bb\u81ea\u7531\u80fd\u52bf\u5792\u3002<\/p>\n<p>\uff08b\uff09\u8ba1\u7b97\u7684\u0394G<sub>H*<\/sub>\u6216\u0394G<sub>B<\/sub>\u503c\u4e0e\u5728\u5404\u79cd\u91d1\u5c5e\u8868\u9762\u4e0a\u6d4b\u91cf\u7684j<sub>0<\/sub>\u503c\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n<p>\uff08c\uff09Ru<sub>fcc<\/sub>\u8868\u9762\u4e0a\u7684\u6c34\u89e3\u79bb\u6b65\u9aa4\u7684\u539f\u5b50\u6784\u578b\u3002\u6df1\u84dd\u8272\uff0c\u6d45\u84dd\u8272\u548c\u7c89\u7ea2\u8272\u4ee3\u8868Ru\u7684\u9876\u5c42\uff0c\u4e2d\u95f4\u5c42\u548c\u5e95\u5c42\u3002\u7ea2\u8272\u548c\u767d\u8272\u4ee3\u8868\u5355\u4e2a\u6c34\u5206\u5b50\u4e2d\u7684\u6c27\u548c\u6c22\u539f\u5b50\u3002\u9ec4\u8272\u4ee3\u8868\u5438\u9644\u5728\u91d1\u5c5e\u8868\u9762\u4e0a\u7684\u79bb\u89e3\u7684H\u539f\u5b50\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u5c55\u671b\u3011<\/strong><\/span><\/p>\n<p>\u8fd9\u9879\u5de5\u4f5c\u7814\u7a76\u4e86\u4f4e\u6210\u672c\u4f46\u50ac\u5316\u6027\u80fd\u597d\u7684Ru\u7535\u50ac\u5316\u5242\u5728\u6790\u6c22\u53cd\u5e94\u4e2d\uff0c\u8868\u73b0\u51fa\u9ad8\u50ac\u5316\u6d3b\u6027\u4e0e\u5176\u5f02\u5e38\u6676\u4f53\u7ed3\u6784\u548c\u56fa\u6709\u53cd\u5e94\u80fd\u91cf\u7684\u76f8\u4e92\u5173\u7cfb\u3002\u901a\u8fc7\u7ecf\u5178\u5fae\u52a8\u529b\u5b66\u6a21\u578b\u4e0e\u8fc7\u6e21\u6001\u7406\u8bba\u7684\u8054\u5408\u4f7f\u7528\uff0c\u9610\u660e\u4e86\u5728\u78b1\u6027\u4ecb\u8d28\u4e2dPt\/c\u53cd\u5e94\u6d3b\u6027\u4f4e\u7684\u539f\u56e0\u3002\u5b9e\u9a8c\u6570\u636e\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u7279\u6b8a\u7c7b\u578b\u7684\u78b3\u57fa\u6750\u6599\uff08\u4f8b\u5982g-C<sub>3<\/sub>N<sub>4<\/sub>\uff09\u53ef\u4ee5\u8bf1\u5bfc\u5f62\u6210\u5177\u6709\u975e\u5e38\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u7684\u8fc7\u6e21\u91d1\u5c5e\uff08\u4f8b\u5982Ru\uff09\u7684\u5f02\u5e38\u6676\u4f53\u7ed3\u6784\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u7814\u7a76\u4e3a\u66f4\u5e7f\u6cdb\u7684\u5f02\u76f8\u50ac\u5316\u548c\u7535\u50ac\u5316\u6240\u5e94\u7528\u7684\u5404\u79cd\u56fa\u4f53\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\uff0c\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.6b11291\" target=\"_blank\"><strong>High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst<\/strong><\/a>(J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b11291)<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong>\u3011<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-57701 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/shizhang_qiao.jpg\" width=\"150\" height=\"186\" \/><\/p>\n<p><strong>\u4e54\u4e16\u748b<\/strong>\u6559\u6388\u5728\u5929\u6d25\u5927\u5b66\u5316\u5de5\u7cfb\u83b7\u5f97\u5b66\u58eb\u548c\u7855\u58eb\u5b66\u4f4d\u540e\u7559\u6821\u4efb\u8bb2\u5e08\uff0c1996\u5e74\u521d\u8d74\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\u30022000\u5e74\u5b66\u6210\u540e\u8d74\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u4efb\u7814\u7a76\u5458\uff0c2001\u5e74\u8d74\u6fb3\u5927\u5229\u4e9a\uff0c\u5728\u6606\u58eb\u5170\u5927\u5b66\u5148\u540e\u4efb\u535a\u58eb\u540e\u3001\u7814\u7a76\u5458\u3001\u9ad8\u7ea7\u7814\u7a76\u5458\u53ca\u526f\u6559\u6388\u30022012\u5e74\u8d77\u5728\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u5316\u5de5\u5b66\u9662\u4efb\u7eb3\u7c73\u6280\u672f\u9996\u5e2d\u6559\u6388\u3002<\/p>\n<p>\u4e54\u4e16\u748b\u6559\u6388\u5728\u7845\u3001\u78b3\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u5b54\u6750\u6599\u3001\u6c27\u5316\u7269\u5355\u6676\u5408\u6210\u53ca\u5176\u5728\u751f\u7269\u5438\u9644\u3001\u5206\u79bb\u3001\u50ac\u5316\u3001\u71c3\u6599\u7535\u6c60\u3001\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u9886\u57df\u53d6\u5f97\u4e86\u4ee4\u4eba\u77a9\u76ee\u7684\u6210\u7ee9\u3002\u4f5c\u4e3a\u901a\u8baf\u8054\u7cfb\u4eba\uff0c\u5728\u300a\u81ea\u7136\u300b\u3001\u300a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\u300b\u3001\u300a\u5fb7\u56fd\u5e94\u7528\u5316\u5b66\u300b\u3001\u300a\u5148\u8fdb\u6750\u6599\u300b\u3001\u300a\u6750\u6599\u5316\u5b66\u300b\u3001\u300a\u5316\u5b66\u901a\u8baf\u300b\u3001\u300a\u7269\u7406\u5316\u5b66\u300b\u7b49\u671f\u520a\u53d1\u8868\u8d85\u8fc7250\u7bc7\u8bba\u6587\uff0c\u5f15\u7528\u8d85\u8fc718000\u6b21\uff0ch\u6307\u6570\u4e3a73\u3002\u4ed6\u5f00\u53d1\u7684\u6c27\u5316\u949b\u5355\u6676\u6280\u672f\u5438\u5f15\u4e86\u4e00\u767e\u4e07\u6fb3\u5143\u7684\u98ce\u9669\u6295\u8d44\uff0c\u5b9e\u73b0\u4e13\u5229\u6280\u672f\u7684\u4ea7\u4e1a\u5316\u3002\u8fd1\u4e94\u5e74\uff0c\u5176\u7814\u7a76\u83b7\u5f97\u6fb3\u5927\u5229\u4e9a\u7814\u7a76\u7406\u4e8b\u4f1a\u53ca\u6606\u5927\u4e09\u767e\u4e94\u5341\u591a\u4e07\u6fb3\u5143\u7684\u8d44\u52a9\uff0c\u4ed6\u5148\u540e\u88ab\u6388\u4e88\u6606\u58eb\u5170\u5927\u5b66\u7814\u7a76\u6700\u9ad8\u5956\uff08Foundation Research Excellence Award\uff09\uff0c\u6fb3\u5927\u5229\u4e9a\u7814\u7a76\u7406\u4e8b\u4f1a\u7814\u7a76\u5458\u5956\u548c\u6606\u58eb\u5170\u5927\u5b66\u4e2d\u9752\u5e74\u7814\u7a76\u5458\u5956\u30022013\u5e74\u83b7\u7f8e\u56fd\u5316\u5b66\u4f1a\u80fd\u6e90\u5206\u4f1a\u5b66\u672f\u65b0\u661f\u5956\uff08Emerging Researcher Award\uff09\u3002\u5728\u6b64\u4e4b\u524d\uff0c\u4ed6\u88ab\u6388\u4e88\u6fb3\u5927\u5229\u4e9a\u7814\u7a76\u59d4\u5458\u4f1a\u6770\u51fa\u7814\u7a76\u5956\uff08Outstanding Researcher Award\uff09\uff0c\u66fe\u88ab\u6fb3\u5927\u5229\u4e9a\u7814\u7a76\u59d4\u5458\u4f1a\u9074\u9009\u4e3a\u6fb3\u5927\u5229\u4e9a\u653f\u5e9c\u535a\u58eb\u540e\u7814\u7a76\u5458\uff08ARC APD Fellowship\uff09\u3001\u7814\u7a76\u5458\uff08ARC ARF Fellowship\uff09\u3002\u73b0\u4efb\u56fd\u9645\u520a\u7269\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u6742\u5fd7Journal of Materials Chemistry A\u526f\u4e3b\u7f16, \u6fb3\u5927\u5229\u4e9a\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\uff0c\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\u30022010\u5e74\u83b7\u5f97\u56fd\u5bb6\u6d77\u5916\u53ca\u6e2f\u6fb3\u5408\u4f5c\u57fa\u91d1, \u5165\u9009\u5929\u6d25\u5e02\u5343\u4eba\u8ba1\u5212\u3002\u73b0\u4e3a\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u5316\u5de5\u5b66\u9662\u7eb3\u7c73\u6280\u672f\u9996\u5e2d\u6559\u6388\uff0c\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u5927\u5b66\u8363\u8a89\u6559\u6388\u3002\u4e3b\u8981\u4ece\u4e8b\u9ad8\u6548\u50a8\u80fd\u6750\u6599\u3001\u7535\u50ac\u5316\u65b0\u6750\u6599\u3001\u7eb3\u7c73\u591a\u5b54\u6750\u6599\u7684\u5236\u5907\u3001\u7ed3\u6784\u8868\u5f81\u53ca\u5176\u5728\u836f\u7269\u4f20\u8f93\u548c\u7535\u5316\u5b66\u50a8\u80fd\u7b49\u9886\u57df\u7684\u7814\u7a76\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u53c2\u8003\u6587\u732e\u3011<\/strong><\/span><\/p>\n<p>[1]. Zheng Y, Jiao Y, Zhu Y, Li LH, Han Y, Chen Y, et al. High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst. Journal of the American Chemical Society 2016, 138(49): 16174-16181.<br \/>\n[2]. Feibelman PJ. Partial Dissociation of Water on Ru(0001). Science 2002, 295(5552): 99-102.<br \/>\n[3]. Kusada K, Kobayashi H, Yamamoto T, Matsumura S, Sumi N, Sato K, et al. Discovery of Face-Centered-Cubic Ruthenium Nanoparticles: Facile Size-Controlled Synthesis Using the Chemical Reduction Method. Journal of the American Chemical Society 2013, 135(15): 5493-5496.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u5c0f\u7ec4pamperhey\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a><strong>\uff01<\/strong><\/p>\n<p>\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-57709 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-3.png\" alt=\"\" width=\"327\" height=\"326\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-3.png 327w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-3-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-3-300x300.png 300w\" sizes=\"(max-width: 327px) 100vw, 327px\" \/><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u76ee\u524d\uff0c\u5927\u591a\u6570\u7814\u7a76\u50ac\u5316\u6790\u6c22\u53cd\u5e94\uff08Hydrogen Evolution Reactions\uff0cHER\uff09\u50ac\u5316\u5242\u7684\u5de5\u4f5c\u90fd\u96c6\u4e2d\u5728\u9178\u6027\u6761\u4ef6\u4e0b\uff0c\u4f46\u78b1\u6027\u73af\u5883\u4e2d\u7684\u7814\u7a76\u9c9c\u6709&#8230;<\/p>\n","protected":false},"author":1311,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[474,1414],"class_list":["post-57699","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-jacs","tag-qiaoshizhang"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/57699"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1311"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=57699"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/57699\/revisions"}],"predecessor-version":[{"id":58298,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/57699\/revisions\/58298"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=57699"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=57699"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=57699"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}