{"id":56718,"date":"2016-12-18T06:30:15","date_gmt":"2016-12-17T22:30:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=56718"},"modified":"2016-12-15T22:26:35","modified_gmt":"2016-12-15T14:26:35","slug":"nature%e5%ad%90%e5%88%8a%ef%bc%9a%e6%b0%a7%e7%a9%ba%e4%bd%8d%e6%8f%90%e9%ab%98%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e6%b0%a7%e5%8c%96%e7%89%a9%e8%b5%9d%e7%94%b5%e5%ae%b9%e6%80%a7%e8%83%bd","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=56718","title":{"rendered":"Nature\u5b50\u520a\uff1a\u6c27\u7a7a\u4f4d\u63d0\u9ad8\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u8d5d\u7535\u5bb9\u6027\u80fd"},"content":{"rendered":"<p><span style=\"color: #ff0000;\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\">\u7535\u5316\u5b66\u50a8\u80fd\u4e00\u76f4\u4ee5\u6765\u90fd\u662f\u7814\u7a76\u4eba\u5458\u5173\u6ce8\u7684\u4e00\u4e2a\u9886\u57df\uff0c\u56e0\u4e3a\u8fd9\u4e9b\u50a8\u80fd\u5668\u4ef6\u5728\u53ef\u79fb\u52a8\u4fbf\u643a\u5f0f\u8bbe\u5907\u3001\u8fd0\u8f93\u7ebf\u8def\u7535\u6c14\u5316\u4e0e\u53ef\u518d\u751f\u80fd\u6e90\u5728\u7535\u7f51\u4e2d\u7684\u8026\u5408\u7b49\u9879\u76ee\u4e0a\u6709\u91cd\u8981\u7684\u5e94\u7528\u3002\u76ee\u524d\u50a8\u80fd\u5668\u4ef6\u4e00\u822c\u5305\u62ec\u7535\u6c60\u4e0e\u7535\u5bb9\uff0c\u4e24\u8005\u90fd\u57fa\u4e8e\u4e0d\u540c\u7684\u7535\u5316\u5b66\u50a8\u80fd\u539f\u7406\uff0c\u4ece\u800c\u9020\u6210\u4e24\u8005\u7684\u7535\u5316\u5b66\u7279\u6027\u4e5f\u4e0d\u76f8\u540c\u3002\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u6bd4\uff0c\u53cc\u7535\u5c42\u7535\u5bb9\u5668\uff08EDLC\uff0c\u4e5f\u88ab\u79f0\u4e3a\u8d85\u7ea7\u7535\u5bb9\uff09\u5177\u6709\u66f4\u77ed\u7684\u5145\u7535\u65f6\u95f4\u3001\u66f4\u9ad8\u7684\u529f\u7387\u548c\u66f4\u957f\u7684\u5faa\u73af\u5bff\u547d\u3002\u4f46\u662f\uff0c\u78b3\u57fa\u7684\u8d85\u7ea7\u7535\u5bb9\u7684\u80fd\u91cf\u5bc6\u5ea6\u5e76\u4e0d\u9ad8\uff0c\u8fd9\u6781\u5927\u5730\u9650\u5236\u4e86\u8d85\u7ea7\u7535\u5bb9\u7684\u53d1\u5c55\u3002\u4e3a\u4e86\u63d0\u9ad8\u8d85\u7ea7\u7535\u5bb9\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u79d1\u7814\u4eba\u5458\u5f00\u59cb\u7814\u7a76\u5176\u4ed6\u7684\u5173\u4e8e\u7535\u5bb9\u80fd\u91cf\u5b58\u50a8\u7684\u673a\u7406\uff0c\u6bd4\u5982\u8d5d\u7535\u5bb9\u73b0\u8c61\u3002\u8d5d\u7535\u5bb9\u4e2d\u7535\u8377\u5b58\u50a8\u8fc7\u7a0b\u5f0f\u901a\u8fc7\u5728\u6216\u8005\u9760\u8fd1\u6750\u6599\u8868\u9762\u7684\u6cd5\u62c9\u7b2c\u7535\u8377\u5b58\u50a8\u6765\u5b9e\u73b0\u7684\uff0c\u5176\u4e2d\u5f15\u4eba\u6ce8\u76ee\u7684\u4e00\u70b9\u662f\u8d5d\u7535\u5bb9\u80fd\u5728\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u524d\u4f53\u4e0b\u4e0d\u5f71\u54cd\u78b3\u57fa\u53cc\u7535\u5c42\u7535\u5bb9\u5668\uff08EDLC\uff09\u7684\u9ad8\u529f\u7387\u548c\u957f\u5faa\u73af\u5bff\u547d\u3002\u8bb8\u591a\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u5728\u6db2\u6001\u6216\u8005\u975e\u6db2\u6001\u7535\u89e3\u8d28\u4e2d\u90fd\u5c55\u793a\u51fa\u4e86\u8d5d\u7535\u5bb9\u6216\u8005\u81f3\u5c11\u4e0e\u8d5d\u7535\u5bb9\u76f8\u4f3c\u7684\u7535\u5316\u5b66\u7279\u5f81\u3002<\/span><\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u3010\u6210\u679c\u7b80<span style=\"color: #ff0000;\">\u4ecb<\/span>\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\">\u8fd1\u65e5\uff0c<\/span><strong style=\"color: #000000;\">\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821<\/strong><span style=\"color: #000000;\">\u7684<\/span><span style=\"color: #000000;\"><strong style=\"color: #ff0000;\"><span style=\"color: #000000;\">Sarah H. Tolbert\u6559\u6388<\/span><\/strong><span style=\"color: #000000;\">\u3001<\/span><strong style=\"color: #ff0000;\"><span style=\"color: #000000;\">Vidvuds Ozolins\u6559\u6388<\/span><\/strong><span style=\"color: #000000;\">\u3001<\/span><strong><span style=\"color: #000000;\">B<\/span>ruce Dunn\u6559\u6388<\/strong><\/span><span style=\"color: #000000;\">\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u5408\u4f5c\u5728<\/span><strong style=\"color: #000000;\">Nature Materials<\/strong><span style=\"color: #000000;\">\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a<\/span><strong style=\"color: #000000;\">\u201cOxygen vacancies enhance pseudocapacitive\u00a0charge storage properties of Mo<\/strong><strong style=\"color: #000000;\">O<sub>3-x<\/sub><\/strong><strong style=\"color: #000000;\">\u201d<\/strong><span style=\"color: #000000;\">\u7684\u6587\u7ae0\uff0c\u6587\u7ae0\u4e2d\u9610\u8ff0\u4e86\u4e00\u79cd\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599\u2014\u8d2b\u6c27MoO3\uff08\u03b1-MoO<\/span><sub style=\"color: #000000;\">3-x<\/sub><span style=\"color: #000000;\">\uff09\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8d2b\u6c27\u7684MoO3\uff08\u03b1-MoO<\/span><sub style=\"color: #000000;\">3-x<\/sub><span style=\"color: #000000;\">\uff09\u4fdd\u7559\u4e86\u539f\u59cb\u5c42\u72b6\u6750\u6599\u03b1-MoO<\/span><sub style=\"color: #000000;\">3<\/sub><span style=\"color: #000000;\">\u7684\u6b63\u4ea4\u7ed3\u6784\u3002\u03b1-MoO<\/span><sub style=\"color: #000000;\">3-x<\/sub><span style=\"color: #000000;\">\u662f\u4e00\u79cd\u5177\u6709\u5f88\u9ad8\u7406\u8bba\u5bb9\u91cf\u7684\u5c42\u72b6\u5316\u5408\u7269\uff0c\u5176\u7406\u8bba\u5bb9\u91cf\u8fbe279mAh\u00b7g<\/span><sup style=\"color: #000000;\">-1<\/sup><span style=\"color: #000000;\">\uff081005C\u00b7<\/span>g<sup>-1<\/sup><span style=\"color: #000000;\">\uff09\u3002\u540c\u65f6\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u5c06\u03b1-MoO<sub>3-x<\/sub>\uff08\u8d2b\u6c27\u6001\uff09\u4e0e\u03b1-MoO<sub>3<\/sub>\uff08\u5bcc\u6c27\u6001\uff09\u8fdb\u884c\u4e86\u6bd4\u8f83\uff0c\u4ece\u52a8\u529b\u5b66\u89d2\u5ea6\u8bf4\u660e\u4e86\u6c27\u7a7a<\/span>\u4f4d\u589e\u5f3a\u8d85\u7ea7\u7535\u5bb9\u5668\u80fd\u91cf\u5bc6\u5ea6\u7684\u673a\u7406\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p><strong><span style=\"color: #000000;\">\u56fe1.\u6240\u5236\u5907\u7684MoO<sub>3<\/sub>\u7684\u7ed3\u6784\u5206\u6790<\/span><\/strong><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-56724\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f1.jpg\" alt=\"nmat4810-f1\" width=\"600\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f1-300x170.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08a\uff09MoO<sub>3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u7ed3\u6784\u6846\u67b6\u7531\u4e00\u4e2a\u8fb9\u7f18\u5171\u4eab\u7684MoO<sub>6<\/sub>\u516b\u9762\u4f53\uff08\u663e\u793a\u4e3a\u7070\u8272\uff09\u53cc\u5c42\u7f51\u7edc\u7ec4\u6210\uff0c\u53cc\u5c42\u6cbfb\u65b9\u5411\u8fdb\u884c\u5806\u53e0\u5e76\u4e14\u76f8\u90bb\u7684\u4e24\u5c42\u901a\u8fc7\u8303\u5fb7\u534e\u529b\u8fdb\u884c\u7ed3\u5408\u3002\u7ed3\u6784\u4e2d\u5305\u542b\u4e09\u79cd\u7c7b\u578b\u7684\u6c27\u9634\u79bb\u5b50\uff1a\u7b2c\u4e00\u79cd\u8bb0\u4e3a\u201c\u7ec8\u7aef\u6c27\uff08terminal oxygen\uff0cOt\uff09\u201d\uff0c\u5176\u4e3aMo-O\u952e\u65b9\u5411\u4e0e\u8303\u5fb7\u534e\u95f4\u8ddd\u9762\u5782\u76f4\u7684\u7d27\u90bb\u8303\u5fb7\u534e\u95f4\u8ddd\u9762\u7684O\u539f\u5b50\uff1b\u7b2c\u4e8c\u79cd\u8bb0\u4e3a\u201cOa\u201d\uff0c\u4e0e\u4e24\u4e2aMo\u539f\u5b50\u5728a\u65b9\u5411\u4e0a\u5f62\u6210\u4e0d\u5bf9\u79f0\u7684\u952e\uff1b\u7b2c\u4e09\u79cd\u8bb0\u4e3a\u201c\u5bf9\u79f0\u6c27\uff08symmetric oxygen\uff0cOs\uff09\u201d\uff0c\u5b83\u6709\u4e00\u4e2a\u4e09\u91cd\u5bf9\u79f0\u8f74\uff0c\u5bfc\u81f4O\u4e0eMo\u539f\u5b50\u5728[001]\u65b9\u5411\u4e0a\u5f62\u6210\u4e24\u4e2a\u77ed\u952e\uff0c\u5728[010]\u65b9\u5411\u4e0a\u5f62\u6210\u4e00\u4e2a\u957f\u952e<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08b\uff0cc\uff09MoO<sub>3<\/sub>\u7684 \uff08b\uff09\u5185\u5c42 \u548c\uff08c\uff09\u5939\u5c42 \u4e2d\u53ef\u80fd\u7684\u9502\u5d4c\u5165\u4f4d\u70b9\u3002\u5939\u5c42\u4f4d\u70b9\u4f4d\u4e8e\u4e24\u4e2a\u516b\u9762\u4f53\u53cc\u5c42\u4e4b\u95f4\uff0c\u5185\u5c42\u4f4d\u70b9\u4f4d\u4e8e\u516b\u9762\u4f53\u53cc\u5c42\u5185\u90e8\u7684\u4e00\u7ef4\u96a7\u9053\uff08[001]\u65b9\u5411\uff09\u5185\u90e8<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08d\uff09\u00a0R-MoO<sub>3-x<\/sub>(\u7ea2\u7ebf)\u548cF-MoO<sub>3<\/sub>\u00a0(\u9ed1\u7ebf)\u7684XRD\u884d\u5c04\u8c31\u3002\uff08020\uff09\uff0c\uff08040\uff09\uff0c\uff08060\uff09\u6676\u9762\u5904\u7684\u5f3a\u5cf0\u8868\u660e\u6240\u5236\u5907\u7684MoO<sub>3<\/sub>\u7c89\u672b\u4f18\u5148\u5728[0k0]\u65b9\u5411\u4e0a\u751f\u957f<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08e\uff09R-MoO<sub>3-x<\/sub>\u7684TEM\u56fe\u50cf<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08f\uff09R-MoO<sub>3-x<\/sub>\u7684SEM\u56fe\u50cf<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08g\uff09\u622a\u9009\u7684R-MoO<sub>3-x<\/sub> \uff08\u7ea2\u7ebf\uff09\u548cF-MoO<sub>3<\/sub>\u00a0\uff08\u9ed1\u7ebf\uff09\u7684\uff08020\uff09\uff0c\uff08040\uff09\uff0c\uff08060\uff09\u884d\u5c04\u5cf0\u7684\u5bf9\u6bd4\u56fe\uff0c\u5cf0\u4f4d\u7f6e\u8f6c\u79fb\u81f3\u4f4e\u89d2\u5ea6\u8868\u660e\u8d2b\u6c27MoO<sub>3<\/sub>\u7684\u8303\u5fb7\u534e\u95f4\u8ddd\u53d8\u5927<\/span><\/p>\n<p><strong><span style=\"color: #000000;\">\u56fe2. MoO3\u4e2d\u6c27\u7a7a\u4f4d\u7684\u8868\u5f81<\/span><\/strong><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-56735\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f2.jpg\" alt=\"nmat4810-f2\" width=\"600\" height=\"150\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f2-300x75.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08a\uff0cb\uff09\u6240\u5408\u6210\u7684R-MoO<sub>3-x<\/sub>\u57283d\u533a\u57df\u7684\u9ad8\u5206\u8fa8XPS\u5149\u8c31\u56fe\uff0c\u5206\u522b\u8868\u793a\u6c29\u7b49\u79bb\u5b50\u4f53\u523b\u8680 \uff08a\uff09\u524d\uff0c \uff08b\uff09\u540e<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08c\uff09\u7531DFT\u8ba1\u7b97\u5f97\u51fa\u7684R-MoO<sub>3-x<\/sub>\u4e2d\u6700\u7a33\u5b9a\u7684\u6c27\u7a7a\u4f4d\u4f4d\u7f6e\u548c\u6781\u5316\u5b50\u7684\u5f62\u6210<\/span><\/p>\n<p><strong><span style=\"color: #000000;\">\u56fe3.\u00a0MoO<sub>3<\/sub>\u8584\u819c\u7535\u6781\u7684\u7535\u5316\u5b66\u5206\u6790<\/span><\/strong><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-56737\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f3.jpg\" alt=\"nmat4810-f3\" width=\"600\" height=\"301\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f3-300x151.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08a\uff09\u00a0R-MoO<sub>3-x<\/sub>\u548cF-MoO<sub>3<\/sub>\u572810mV\u00b7<\/span>s<sup>-1<\/sup>\u901f\u7387\u4e0b\u7684\u4f0f\u5b89\u626b\u63cf\uff08\u7b2c\u5341\u6b21\u5faa\u73af\uff09<\/p>\n<p><span style=\"color: #000000;\">\uff08b\uff09\u4ee5\u6bd4\u5bb9\u91cf\u4f5c\u626b\u63cf\u901f\u7387\u7684\u51fd\u6570\u5f97\u5230\u7684\u66f2\u7ebf\uff0c\u626b\u63cf\u901f\u7387\u8303\u56f4\u4e3a1-100mV\u00b7s<sup>-1<\/sup>\uff0cR-MoO<sub>3-x<\/sub>\u548cF-MoO<sub>3<\/sub>\u6837\u54c1\u5728\u6d4b\u8bd5\u524d\u9884\u5148\u5faa\u73af\u4e8610\u5708\uff0c\u626b\u63cf\u901f\u7387\u4e3a10mV\u00b7s<sup>-1<\/sup><\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08c\uff09\u4ee5R-MoO<sub>3-x<\/sub>\u548cF-MoO<sub>3<\/sub>\u6bd4\u5bb9\u91cf\u7684\u53d8\u5316\u4f5c10mV\u00b7s<sup>-1<\/sup>\u4e0b\u5faa\u73af\u6b21\u6570\u7684\u51fd\u6570\u5f97\u5230\u7684\u66f2\u7ebf<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08d\uff092.4V\u4e0b\u9634\u6781\u7535\u6d41\u4e0e\u626b\u63cf\u901f\u7387\u7684\u5bf9\u6570\u4f5c\u5f97\u7684\u66f2\u7ebf\uff0c\u66f2\u7ebf\u7684\u659c\u7387\u4e3ab\uff0c\u8be5\u503c\u8868\u660e\u5728\u63a5\u8fd11\u65f6\u4e3aR-MoO<sub>3-x<\/sub>\uff0c\u5728\u63a5\u8fd10.7\u65f6\u4e3aF-MoO<sub>3<\/sub>\uff0c\u626b\u63cf\u901f\u7387\u8303\u56f4\u4e3a0.1-20mV\u00b7s<sup>-1<\/sup><\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08e\uff09R-MoO<sub>3-x<\/sub> \u548c \uff08f\uff09F-MoO<sub>3<\/sub>\u00a0 \u7684K1\uff0cK2\u5206\u6790\uff08\u65b9\u7a0b3\uff09\uff0c\u626b\u63cf\u901f\u7387\u4e3a1mV\u00b7s<sup>-1<\/sup>\uff0c10\u5708\u540e\u626b\u63cf\u901f\u7387\u4e3a10<\/span><span style=\"color: #000000;\">mV\u00b7s<sup>-1<\/sup><\/span><\/p>\n<p><strong><span style=\"color: #000000;\">\u56fe4.\u00a0F-MoO<sub>3<\/sub>\u548cR-MoO<sub>3-x<\/sub>x\u7684\u7ed3\u6784\u8868\u5f81\uff0c\u7ed3\u5408\u7535\u5316\u5b66\u5faa\u73af\u6d4b\u8bd5<\/span><\/strong><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-56738\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f4.jpg\" alt=\"nmat4810-f4\" width=\"600\" height=\"495\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f4-300x248.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08a\uff09\u00a0F-MoO<sub>3<\/sub>\u00a0\u548c \uff08b\uff09R-MoO<sub>3-x<\/sub> 10mV\u00b7s<sup>-1<\/sup>\u901f\u7387\u4e0b\u9996\u4e2a\u4e09\u6b21\u5faa\u73af\u7684\u4f0f\u5b89\u66f2\u7ebf\u548c\u6052\u6d41\u653e\u7535\u66f2\u7ebf\uff08\u63d2\u56fe\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a10mA\u00b7g<sup>-1<\/sup>\uff09<\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08c\uff09\u00a0F-MoO<sub>3<\/sub>\u00a0\u548c \uff08d\uff09R-MoO<sub>3-x<\/sub> \u5728\u9502\u5316\uff081.5V\uff09\u548c\u8131\u9502\uff083.5V\uff09\u72b6\u6001\u4e0b\u7684\u975e\u539f\u4f4dXRD\u8c31\u56fe\uff0c\u6570\u636e\u8868\u660eF-MoO<sub>3<\/sub>\u5728\u9502\u79bb\u5b50\u7684\u5d4c\u5165\u8fc7\u7a0b\u4e2d\u53d1\u751f\u4e86\u76f8\u53d8\uff0c\u4f46\u5728R-MoO<sub>3-x<\/sub>\u4e2d\u76f8\u53d8\u53d7\u5230\u6291\u5236<\/span><\/p>\n<p><strong><span style=\"color: #000000;\">\u56fe5.\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5728Mo<sup>4+<\/sup>\u548cMo<sup>5+<\/sup>\u5b58\u5728\u4e0b\u6c27\u7a7a\u4f4d\u7684\u5f71\u54cd<\/span><\/strong><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-56742\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f5-1.jpg\" alt=\"nmat4810-f5\" width=\"600\" height=\"319\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f5-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/nmat4810-f5-1-300x160.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">\uff08a\uff09R-MoO<sub>3-x<\/sub> \u548c \uff08b\uff09\u00a0F-MoO<sub>3<\/sub>\u00a0\u57285mV\u00b7s<sup>-1<\/sup>\u4e0b\u7684\u4f0f\u5b89\u626b\u63cf\uff0c\u6837\u54c1\u5728\u6d4b\u91cf\u524d\u572810mV\u00b7s<sup>-1<\/sup>\u4e0b\u9884\u5faa\u73af5\u5708<\/span><\/p>\n<p><span style=\"color: #000000;\">\u00a0R-MoO<sub>3-x<\/sub>\u5728 \uff08c\uff09\u5d4c\u9502 \u548c\uff08d\uff09\u8131\u9502\uff0c\u548cF-MoO<sub>3<\/sub>\u5728\uff08e\uff09\u5d4c\u9502 \u548c\uff08f\uff09\u8131\u9502 \u6001\u65f6Mo\u539f\u5b50\u76843d\u80fd\u7ea7\u7684\u9ad8\u5206\u8fa8XPS\u8c31\u56fe<\/span><\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\">\u8be5\u8bfe\u9898\u7ec4\u901a\u8fc7\u5bf9\u6bd4\u5177\u6709\u6c27\u7a7a\u4f4d\u7684\u03b1-MoO<sub>3-x<\/sub>\u4e0e\u5168\u6c27\u5316\u6001\u7684\u03b1-MoO<sub>3<\/sub>\u7684\u6027\u80fd\uff0c\u53d1\u73b0\u6c27\u7a7a\u4f4d\u7684\u5f15\u5165\u589e\u5927\u4e86MoO<sub>3<\/sub>\u5c42\u72b6\u7ed3\u6784\u7684\u5c42\u95f4\u8ddd\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86\u7535\u8377\u5feb\u901f\u5b58\u50a8\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u540c\u65f6\uff0c\u8fd8\u53d1\u73b0\u5728\u5d4c\u9502\u4e0e\u8131\u9502\u8fc7\u7a0b\u4e2d\uff0c\u5373\u4f7f\u662f\u5177\u6709\u6c27\u7a7a\u4f4d\u7684\u03b1-MoO<sub>3-x<\/sub>\u6750\u6599\u7684\u7ed3\u6784\u4e5f\u4f9d\u7136\u53ef\u4ee5\u4ee5\u03b1-MoO<sub>3<\/sub>\u7684\u7ed3\u6784\u5f62\u5f0f\u7a33\u5b9a\u5b58\u5728\u3002\u53e6\u5916\uff0c\u8fd8\u63d0\u51fa\u4e86R-MoO<sub>3-x<\/sub>\u7684\u9ad8\u5bb9\u91cf\u662f\u7531\u4e8e\u5728\u7535\u6781\u9502\u5316\u540e\u6709\u5927\u91cf\u7684Mo<sup>4+<\/sup>\u79bb\u5b50\u53ef\u9006\u5730\u5f62\u6210\u3002\u8fd9\u9879\u5de5\u4f5c\u5f3a\u8c03\u4e86\u5728\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u5f97\u5230\u6c27\u7a7a\u4f4d\u4ece\u800c\u63d0\u9ad8\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u7684\u7535\u8377\u5b58\u50a8\u52a8\u529b\u5b66\u7684\u6f5c\u5728\u91cd\u8981\u6027\u3002<\/span><\/p>\n<p><span style=\"color: #000000;\"><strong><span style=\"color: #ff0000;\">\u6587\u732e\u94fe\u63a5\uff1a<\/span><\/strong><a href=\"http:\/\/www.nature.com\/nmat\/journal\/vaop\/ncurrent\/full\/nmat4810.html\" target=\"_blank\">Oxygen vacancies enhance pseudocapacitive\u00a0charge storage properties of MoO<sub>3-x<\/sub><\/a>\uff08Nature Materials\uff0c2016\uff0cDOI: 10.1038\/NMAT4810\uff09<\/span><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 charles 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/\u65b0\u80fd\u6e90\u524d\u7ebf-1-1.jpg\" alt=\"%e6%96%b0%e8%83%bd%e6%ba%90%e5%89%8d%e7%ba%bf-1\" width=\"340\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/\u65b0\u80fd\u6e90\u524d\u7ebf-1-1.jpg 340w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/\u65b0\u80fd\u6e90\u524d\u7ebf-1-1-150x150.jpg 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/12\/\u65b0\u80fd\u6e90\u524d\u7ebf-1-1-300x300.jpg 300w\" sizes=\"(max-width: 340px) 100vw, 340px\" \/><\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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