{"id":55151,"date":"2016-12-12T06:30:18","date_gmt":"2016-12-11T22:30:18","guid":{"rendered":"\/\/m.iemloyee.com\/?p=55151"},"modified":"2016-12-08T22:41:30","modified_gmt":"2016-12-08T14:41:30","slug":"nature%e5%ad%90%e5%88%8a%ef%bc%9a%e7%94%a8%e4%ba%8e%e7%94%b5%e5%82%ac%e5%8c%96%e6%b0%a7%e9%87%8a%e6%94%be%e7%9a%84%e8%b6%85%e8%96%84mof%e7%ba%b3%e7%b1%b3%e7%89%87","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=55151","title":{"rendered":"Nature\u5b50\u520a\uff1a\u7528\u4e8e\u7535\u50ac\u5316\u6c27\u91ca\u653e\u7684\u8d85\u8584MOF\u7eb3\u7c73\u7247"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5728\u7535\u5316\u5b66\u8f6c\u6362\u6280\u672f\u4e2d\uff0c\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u5341\u5206\u91cd\u8981\uff0c\u800c\u88c5\u6362\u4e2d\u6c27\u91ca\u653e\u662f\u6700\u91cd\u8981\u7684\u4e00\u6b65\uff0c\u4e00\u822c\u5e94\u7528\u4e8e\u6c34\u89e3\u79bb\u548c\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u3002\u73b0\u5728\u4f7f\u7528\u7684\u6c27\u91ca\u653e\u50ac\u5316\u5242\u4e00\u822c\u662f\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u4ef7\u683c\u90fd\u5341\u5206\u6602\u8d35\uff1b\u53e6\u5916\uff0c\u7528\u4e8e\u9a71\u52a8\u53cd\u5e94\u7684\u5927\u7684\u8fc7\u7535\u538b\u964d\u4f4e\u4e86\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff0c\u963b\u788d\u4e86\u5668\u4ef6\u5728\u5b9e\u9645\u4e2d\u7684\u5e94\u7528\u3002\u73b0\u5728\u4e00\u76f4\u81f4\u529b\u4e8e\u5236\u9020\u9ad8\u6548\u7387\u7684\u7535\u50ac\u5316\u5242\uff0c\u5206\u4e3a\u5747\u76f8\u548c\u591a\u76f8\u4e24\u79cd\uff0c\u5176\u4e2d\uff0c\u5747\u76f8\u5206\u5b50\u50ac\u5316\u5242\u6709\u9ad8\u6d3b\u6027\uff0c\u6709\u5229\u4e8e\u7ed3\u6784\u7684\u8bbe\u8ba1\u548c\u8c03\u63a7\uff0c\u4f46\u662f\u53cd\u5e94\u7cfb\u7edf\u7684\u53ef\u91cd\u590d\u6027\u6bd4\u8f83\u5dee\uff0c\u963b\u788d\u4e86\u5176\u8fdb\u4e00\u6b65\u5b9e\u9645\u5e94\u7528\uff1b\u76f8\u53cd\uff0c\u591a\u76f8\u50ac\u5316\u5242\u53ef\u5faa\u73af\u6027\u597d\u5e76\u4e14\u5ec9\u4ef7\uff0c\u4f46\u662f\u56fa\u4f53\u50ac\u5316\u5242\u8868\u9762\u7684\u6d3b\u6027\u4e2d\u5fc3\u7684\u6570\u91cf\u548c\u4f4d\u7f6e\u4e0d\u786e\u5b9a\uff0c\u65e0\u6cd5\u63a7\u5236\uff0c\u6240\u4ee5\u5728\u53cd\u5e94\u73af\u5883\u6539\u53d8\u65f6\u7a33\u5b9a\u6027\u548c\u53ef\u91cd\u590d\u6027\u8f83\u5dee\uff0c\u540c\u65f6\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u5341\u5206\u56f0\u96be\u3002<\/p>\n

\u5176\u4e2d\uff0cMOFs\u662f\u7531\u5171\u4ef7\u952e\u8fde\u63a5\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\uff0c\u7531\u4e8e\u5176\u7ed3\u6784\u7684\u7279\u6b8a\u6027\u80fd\uff0c\u53ef\u4ee5\u540c\u65f6\u63d0\u4f9b\u5747\u76f8\u548c\u591a\u76f8\u50ac\u5316\u5242\u4e24\u8005\u7684\u4f18\u70b9\uff0c\u7eb3\u7c73\u591a\u5b54MOFs\u6709\u7740\u5f88\u597d\u7684\u5316\u5b66\u7ed3\u6784\u4e14\u5bb9\u6613\u83b7\u5f97\u6d3b\u6027\u4f4d\u70b9\u3002\u540c\u65f6\uff0cMOFs\u662f\u4e00\u79cd\u9ad8\u7ed3\u6676\u6027\u7684\u56fa\u4f53\u6750\u6599\uff0c\u53ef\u5faa\u73af\u6027\u597d\uff0c\u5728\u7269\u7406\u548c\u5316\u5b66\u53d8\u5316\u4e0b\u7a33\u5b9a\uff0c\u6240\u4ee5\u4ee5MOFs\u4e3a\u57fa\u7684\u8584\u819c\u7535\u6781\u663e\u793a\u51fa\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u5510\u667a\u52c7\u6559\u6388<\/strong>\u8bfe\u9898\u7ec4\u3001\u683c\u91cc\u83f2\u65af\u5927\u5b66Huijun Zhao\u6559\u6388<\/strong>\u3001\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u5218\u7ecd\u7434\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\uff0c\u62a5\u9053\u4e86\u4e00\u79cdNiCo\u53cc\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7eb3\u7c73\u7247\uff08NiCo-UMOFNs\uff09\uff0c\u8fd9\u79cd\u6750\u6599\u5728\u6c27\u91ca\u653e\u8fc7\u7a0b\u4e2d\u663e\u793a\u51fa\u9ad8\u50ac\u5316\u6d3b\u6027\uff0cNiCo-UMOFs\u8d1f\u8f7d\u5728\u94dc\u7b94\u4e0a\u6709\u77401.39V\u4f4e\u7684\u8d77\u59cb\u7535\u538b\uff0c\u5728\u78b1\u6027\u73af\u5883\u4e2d10mA\/cm-2\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fc7\u7535\u538b\u7ea6\u4e3a189mV\uff0c\u5728\u56fa\u5b9a\u76840.25V\u8fc7\u7535\u538b\u4e0b\u53ef\u4ee5\u4fdd\u6301\u7a33\u5b9a\u7684\u7535\u6d41\u5bc6\u5ea6\u6301\u7eed200\u5c0f\u65f6\uff0c\u5bf9\u5e94\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u53ef\u8fbe99.3%\u3002\u53e6\u5916\uff0c\u901a\u8fc7XAS\u5b9e\u9a8c\u6d4b\u8bd5\u548cDFT\u7406\u8bba\u8ba1\u7b97UMOFNs\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u673a\u68b0\u6027\u80fd\u3002<\/p>\n

[<\/strong>\u81f4\u6b49\uff1a\u5f88\u62b1\u6b49\uff0c\u672a\u80fd\u627e\u5230\u901a\u8baf\u4f5c\u8005<\/strong>Huijun Zhao<\/strong>\u6559\u6388<\/strong>\u7684\u786e\u5207\u4e2d\u6587\u540d\u5b57\uff0c\u5c0f\u7f16\u8868\u793a\u8bda\u631a\u7684\u6b49\u610f\uff01<\/strong>]<\/strong><\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a<\/strong>NiCo-UMOFNs<\/strong>\u7684\u7269\u7406\u7279\u5f81<\/strong><\/p>\n

<\/p>\n

a.NiCo-UMOFNs\u7684\u900f\u5c04\u56fe\u50cf\u3002\u63d2\u56fe\u663e\u793a\u4e86NiCo-UMOFNs\u5728\u6eb6\u6db2\u4e2d\u7684\u5ef7\u5fb7\u5c14\u5149\u6563\u5c04\u3002<\/p>\n

b.NiCo-UMOFNs\u7684TEM-EDS mapping\u56fe\u50cf\u3002<\/p>\n

c.NiCo-UMOFNs\uff08200\uff09\u6676\u9762\u7684HAADF-STEM\u56fe\u50cf\uff0c\u663e\u793a\u4e86\u91d1\u5c5e\u539f\u5b50\u7684\u516d\u65b9\u6676\u7cfb\u3002\u7c89\u8272\u4ee3\u8868\u91d1\u5c5e\u539f\u5b50\uff0c\u84dd\u8272\u4ee3\u8868\u5149\u5143\u7d20\uff08\u78b3\u548c\u6c27\uff09\uff0c\u7eff\u8272\u662f\u80cc\u666f\u3002<\/p>\n

d.NiCo-UMOFNs\u7684AFM\u56fe\u50cf\uff0c\u663e\u793a\u51fa\u5355\u4e2a\u7247\u5c42\u7684\u6d4b\u91cf\u7ef4\u5ea6\u3002<\/p>\n

\u4ece\u56fe\u4e2d\u53ef\u4ee5\u770b\u51fa\u5e72\u71e5\u540e\uff0c\u67d4\u6027\u7eb3\u7c73\u7247\u8fb9\u7f18\u81ea\u53d1\u5377\u66f2\uff0c\u800c\u4e14\uff0c\u7531\u4e8e\u5176\u8d85\u8584\u7684\u7ed3\u6784\u53ef\u4ee5\u5f88\u597d\u7684\u5206\u6563\u5728\u6eb6\u6db2\u4e2d\u4fdd\u6301\u51e0\u4e2a\u6708\u3002<\/p>\n

\u56fe\u4e8c\uff1a<\/strong>NiCo-UMOFNs<\/strong>\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

<\/p>\n

a.NiCo-UMOFNs\u7684\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n

b.NiCo-UMOFNs\u7684SAXS\u56fe\u6848\u3002\u63d2\u56fe\u662f\u4e8c\u7ef4\u7684NiCo-UMOFNsSAXS\u56fe\u6848\u3002<\/p>\n

c.\u6709\u7740\u4e30\u5bcc\u914d\u4f4d\u7684\u4e0d\u9971\u548c\u4f4d\u70b9UMOFNs\u8868\u9762\u7684\uff08200\uff09\u6676\u683c\u9762\u7684\u6a21\u62df\u56fe\u6848\u3002<\/p>\n

d.NiCo-UMOFNs\uff08200\uff09\u6676\u9762\u7684\u7406\u8bba\u6676\u683c\u53c2\u6570\u3002<\/p>\n

e.\u56db\u91d1\u5c5e\u914d\u4f4d\u5c42\u7684NiCo-UMOFNs\u7684\u7406\u8bba\u539a\u5ea6\u3002<\/p>\n

\u4eceSAXS\u56fe\u663e\u793a\u4e86\u56db\u79cd\u53cd\u5c04\uff0c\u5206\u522b\u5c5e\u4e8e\uff08200\uff09\uff0c\uff08001\uff09\uff0c\uff08201\uff09\uff0c\uff08201\uff09\u6676\u9762\uff0c\u6a21\u62df\u7684\u56db\u4e2a\u53cd\u5c04\u548c\u5b9e\u9a8c\u7ed3\u679c\u76f8\u5339\u914d\uff1b\u4e5f\u53ef\u4ee5\u770b\u51faNiCo-UMOFNs\u7684\u6700\u5927\u66b4\u9732\u6676\u9762\u662f\u91d1\u5c5e\u539f\u5b50\u5bc6\u5806\u79ef\u7684\uff08200\uff09\u6676\u9762\u3002<\/p>\n

\u56fe\u4e09\uff1a<\/strong>NiCo-UMOFNs<\/strong>\u7684\u6c27\u91ca\u653e\u7535\u5316\u5b66\u6d3b\u6027<\/strong><\/p>\n

<\/p>\n

a.NiCo-UMOFNs\u3001Ni-UMOFNs\u3001Co-UMOFNs\u3001RuO2<\/sub>\u548c\u5757\u4f53NiCo-MOFs\u5206\u522b\u57285mV\/s\u626b\u901f\u4e0b\uff0c 1M KOH\u9971\u548c\u6c27\u6eb6\u6db2\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\u3002\u56fe\u4e2d\u5782\u76f4\u7684\u865a\u7ebf\u6807\u660e\u4e8610mA\/cm2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

b.NiCo-UMOFNs\u3001Ni-UMOFNs\u3001Co-UMOFNs\u3001RuO2<\/sub>\u548c\u5757\u4f53NiCo-MOFs\u5206\u522b\u57281M KOH\u9971\u548c\u6c27\u6eb6\u6db2\u4e2d\u7684Tafel\u66f2\u7ebf\u3002<\/p>\n

c.\u57281500r.p.m.\u8f6c\u901f\u4e0b\uff0c 1M KOH\u9971\u548c\u6c27\u6eb6\u6db2\u4e2dNiCo-UMOFNs\u7684RRDE\u6d4b\u8bd5\u3002<\/p>\n

d.1M KOH\u9971\u548c\u6c2e\u6c14\u6eb6\u6db2\u4e2d\u5229\u7528RRDE\u6d4b\u8bd5\u51fa\u7684NiCo-UMOFNs\u6cd5\u62c9\u7b2c\u6548\u7387\u3002\u4e2d\u95f4\u7684\u63d2\u56fe\u663e\u793a\u4e86\u6cd5\u62c9\u7b2c\u6548\u7387\u7684\u6d4b\u8bd5\u673a\u7406\uff0c\u8fb9\u4e0a\u7684\u9ed1\u8272\u680f\u8868\u793a\u94c2\u73af\u5f62\u7535\u6781\u3002\u94c2\u73af\u5f62\u7535\u6781\u548c\u73bb\u7483\u78b3\u7535\u6781\u4e2d\u95f4\u88ab\u4e00\u4e2a\u4e0d\u5bfc\u7535\u7684PTFE\u5c42\uff08\u767d\u8272\u680f\uff09\u5206\u5f00\u3002\u5f53\u7ed9\u76d8\u578b\u7535\u6781\u52a0\u4e0a\u4e00\u4e2a\u6052\u5b9a\u7535\u6d41\uff08300mA\uff09\u6c27\u4ee320s\uff0c\u6c27\u91ca\u653e\u4ea7\u751f\u7684\u7ea6\u4e3a59.6mA\u7684\u73af\u5f62\u7535\u6d41\u53ef\u4ee5\u7acb\u5373\u68c0\u6d4b\u5230\u3002<\/p>\n

\u56fe\u56db\uff1a<\/strong>NiCo-UMOFNs<\/strong>\u4e2d<\/strong>Ni\/Co<\/strong>\u539f\u5b50\u914d\u4f4d\u7684\u975e\u539f\u4f4d<\/strong>XAS<\/strong>\u8868\u5f81<\/strong><\/p>\n

<\/p>\n

a.NiCo-UMOFNs\u548c\u5757\u4f53NiCo-MOFs\u5728R-\u4f4d\u7684\u975e\u539f\u4f4dEXAFS\u6570\u636e\uff08\u9ed1\u7ebf\uff09\u548c\u6700\u4f18\u7ed3\u679c\uff08\u7ea2\u7ebf\uff09\u3002<\/p>\n

b.\u5728UMOFNs\u8868\u9762\u91d1\u5c5e\u7684\u5b8c\u5168\u4e0d\u9971\u548c\u6a21\u578b\u548c\u90e8\u5206\u9971\u548c\u6a21\u578b\u3002<\/p>\n

c.NiCo-UMOFNs\u3001\u5757\u4f53NiCo-MOFs\u548c\u7406\u8bba\u7ed3\u6784\u6a21\u578b\u7684\u5b9e\u9a8c\u548c\u7406\u8bbaNi K-\u8fb9\u754cXANES\u5149\u8c31\u7684\u5bf9\u6bd4\u3002<\/p>\n

(d,e).\u5b9e\u9a8c\u548c\u6a21\u62df\u7684\u524d\u8fb9\u754c\u5cf0\u7684\u653e\u5927\u56fe\u3002<\/p>\n

\u7814\u7a76\u8005\u4eec\u7684\u5de5\u4f5c\u901a\u8fc7\u8ba1\u7b97\u548c\u5b9e\u9a8c\u5757\u4f53\u548c\u8d85\u8584\u7684NiCo-MOFs\u7684\u524d\u8fb9\u754c\u5cf0\u7b2c\u4e00\u6b21\u5f97\u5230\u8bc1\u5b9e\u3002<\/p>\n

\u56fe\u4e94\uff1a<\/strong>NiCo-UMOFNs<\/strong>\u7684\u539f\u4f4d<\/strong> XAS<\/strong>\u8868\u5f81<\/strong><\/p>\n

<\/p>\n

a.\u9884\u5148\u51c6\u5907\u7684NiCo-UMOFNs\u548c\u4e0d\u540c\u7535\u538b\u4e0b\u6052\u7535\u4f4d\u6c27\u91ca\u653e\u5b9e\u9a8c\u7684Ni K-\u8fb9\u754cXANES\u6570\u636e\u7684\u5bf9\u6bd4\u3002\u4e2d\u95f4\u7684\u63d2\u56fe\u663e\u793a\u4e86\u76f8\u5bf9\u80fd\u91cf\u53d8\u5316\u3002<\/p>\n

b.\u9884\u5148\u51c6\u5907\u7684NiCo-UMOFNs\u548c\u4e0d\u540c\u7535\u538b\u4e0b\u6052\u7535\u4f4d\u6c27\u91ca\u653e\u5b9e\u9a8c\u50ac\u5316\u72b6\u6001\u4e0b\u7684R-\u4f4dNi K-\u8fb9\u754cXANES\u6570\u636e\u7684\u5bf9\u6bd4\u3002<\/p>\n

\u4e3a\u4e86\u66f4\u597d\u5730\u8bf4\u660e\u6d3b\u6027\u4f4d\u70b9\u7684\u5316\u5b66\u6027\u8d28\uff0c\u7814\u7a76\u8005\u4eec\u4f5c\u4e86\u4ee5\u4e0a\u5b9e\u9a8c\uff0c\u9884\u5148\u51c6\u5907\u7684NiCo-UMOFNs\u548c\u5757\u4f53NiCo-MOFs\u7684\u4e3b\u8981Ni K-\u8fb9\u754c\u57288349.7eV\uff0c\u5728\u52a0\u4e86\u7535\u538b\u4e4b\u540e\uff0c\u5cf0\u5411\u9ad8\u80fd\u91cf\u4f4d\u7f6e\u79fb\u52a8\uff0c\u53ef\u80fd\u662f\u7531\u4e8eNi\u4f4d\u70b9\u7684\u6c27\u5316\u3002<\/p>\n

\u56fe\u516d\uff1a<\/strong>NiCo-UMOFNs<\/strong>\u5728\u6c27\u91ca\u653e\u8fc7\u7a0b\u4e2d\u7684<\/strong>DFT<\/strong>\u8ba1\u7b97<\/strong><\/p>\n

\u3010\u6ce8\u3011<\/strong>DFT<\/strong>\uff1a\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba<\/strong><\/p>\n

<\/p>\n

a.UMOFNs\u8868\u9762\u6c27\u91ca\u653e\u8fc7\u7a0b\u7684\u539f\u59cb\u6b65\u9aa4\u3002\u4e0d\u540c\u989c\u8272\u4ee3\u8868\u7684\u5316\u5b66\u5143\u7d20\uff1a\u7eff\u8272\u4ee3\u8868\u91d1\u5c5eS1\uff08Ni\/Co\uff09\uff0c\u7ea2\u8272\u4ee3\u8868O\uff0c\u7070\u8272\u4ee3\u8868C\uff0c\u767d\u8272\u4ee3\u8868H\u3002\u7f57\u9a6c\u6570\u5b57\u7684\u610f\u4e49\uff1a\uff08\u2170\uff09\u4ee3\u8868\u6c27\u91ca\u653e\u8fc7\u7a0b\u7684\u5438\u9644\u6b65\u9aa4\uff0c\uff08\u2171\uff09\uff08\u2172\uff09\u4ee3\u8868\u6c27\u91ca\u653e\u8fc7\u7a0b\u7684\u5206\u79bb\u6b65\u9aa4\uff0c\uff08\u2173\uff09\u4ee3\u8868\u6c27\u91ca\u653e\u8fc7\u7a0b\u7684\u89e3\u79bb\u6b65\u9aa4\u3002<\/p>\n

b.UMOFNs\u8868\u9762\u6c27\u91ca\u653e\u8fc7\u7a0b\u7684\u6807\u51c6\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n

c.UMOFNs\u4e2dCo\u548cNi\u7535\u5b50\u8026\u5408\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5728\u8fd9\u7bc7\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u8005\u4eec\u5728\u5ba4\u6e29\u4e0b\u901a\u8fc7\u7b80\u5355\u7684\u8d85\u58f0\u6cd5\u5236\u5907\u51fa\u4e00\u7cfb\u5217\u4e0d\u9971\u548c\u91d1\u5c5e\u914d\u4f4d\u7684UMOFNs\u6750\u6599\u5e76\u5c06\u5176\u5728\u78b1\u6027\u73af\u5883\u4e2d\u4f5c\u4e3a\u6c27\u91ca\u653e\u8fc7\u7a0b\u7684\u7535\u50ac\u5316\u5242\u3002\u5176\u4e2d\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cNiCo-UMOFNs\u50ac\u5316\u5242\u663e\u793a\u51fa\u9ad8\u7684\u7535\u50ac\u5316\u6d3b\u6027\u548c\u957f\u65f6\u95f4\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u3002NiCo-UMOFNs\u786e\u5b9a\u7684\u539f\u5b50\u7ed3\u6784\u5141\u8bb8\u7814\u7a76\u8005\u4eec\u63a2\u7d22\u5176\u9ad8\u7535\u50ac\u5316\u6d3b\u6027\u7684\u539f\u56e0\uff1a\u4e0d\u9971\u548c\u914d\u4f4d\u7684\u91d1\u5c5e\u539f\u5b50\u662f\u6c27\u91ca\u653e\u8fc7\u7a0b\u4e2d\u7684\u4e3b\u8981\u6d3b\u6027\u4e2d\u5fc3\uff0c\u800c\u4e14Ni\u548cCo\u7684\u7535\u5b50\u8026\u5408\u6548\u5e94\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86\u7535\u50ac\u5316\u6c27\u91ca\u653e\u6d3b\u6027\u3002\u6211\u4eec\u76f8\u4fe1\u4e86\u8d85\u8584MOF\u8bbe\u8ba1\u662f\u4e00\u79cd\u6709\u6548\u7684\u7b56\u7565\u5728\u539f\u5b50\u7ea7\u522b\u4e0a\u5236\u5907\u6d3b\u6027\u591a\u76f8\u50ac\u5316\u5242\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ultrathin metal\u2013organic framework nanosheets for electrocatalytic oxygen evolution.<\/a>\u00a0(Nature Energy\u00a0, 2016, doi:10.1038\/nenergy.2016.184)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4Jane915126<\/strong>\u6574\u7406\u7f16\u8bd1\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d,\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n

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