{"id":55077,"date":"2016-12-10T06:30:24","date_gmt":"2016-12-09T22:30:24","guid":{"rendered":"\/\/m.iemloyee.com\/?p=55077"},"modified":"2016-12-08T22:15:32","modified_gmt":"2016-12-08T14:15:32","slug":"nano-lett-%e5%8d%8e%e4%b8%ad%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%ef%bc%9a%e8%81%9a%e5%90%88%e7%89%a9%e7%94%b5%e6%9e%81%e7%94%a8%e4%bd%9c%e5%bd%a9%e8%89%b2%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=55077","title":{"rendered":"Nano Lett. \u534e\u4e2d\u79d1\u6280\u5927\u5b66\uff1a\u805a\u5408\u7269\u7535\u6781\u7528\u4f5c\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u8c31\u9009\u62e9\u6027\u6297\u53cd\u5c04\u6d82\u5c42"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6709\u673a\u91d1\u5c5e\u5364\u5316\u9499\u949b\u77ff\u5177\u6709\u76f4\u63a5\u5e26\u9699\uff0c\u5438\u6536\u7cfb\u6570\u5927\uff0c\u6fc0\u5b50\u7ed3\u5408\u80fd\u4f4e\uff0c\u8f7d\u6d41\u5b50\u6269\u6563\u957f\u5ea6\u5927\uff0c\u7535\u8377\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u9ad8\u7b49\u4f18\u5f02\u7684\u5149\u7535\u7279\u6027\uff0c\u5e76\u4e14\u5236\u5907\u7b80\u5355\uff0c\u5728\u8bf8\u5982\u592a\u9633\u80fd\u7535\u6c60\u3001LED\u3001\u6fc0\u5149\u5668\u4ef6\u3001\u5149\u63a2\u6d4b\u5668\u548c\u94c1\u7535\u5668\u4ef6\u7b49\u534a\u5bfc\u4f53\u5668\u4ef6\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5730\u5e94\u7528\u3002\u5c24\u5176\u662f\u6709\u673a\u91d1\u5c5e\u5364\u5316\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff0c\u5176\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u6700\u9ad8\u8fbe22.1%\uff0c\u8d85\u8fc7\u4e86\u591a\u6676\u7845\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u3002\u4f34\u968f\u7740\u592a\u9633\u80fd\u7535\u6c60\u6280\u672f\u7684\u65e5\u76ca\u6210\u719f\uff0c\u592a\u9633\u80fd\u7535\u6c60\u5728\u4e00\u4e9b\u9886\u57df\uff08\u5982\u53ef\u7a7f\u6234\u7535\u5b50\u8bbe\u5907\uff09\u7684\u5e94\u7528\u4f7f\u5f97\u5b83\u4eec\u9700\u8981\u5177\u6709\u4e00\u5b9a\u7684\u5ba1\u7f8e\u7279\u6027\u3002\u7136\u800c\uff0c\u4e3a\u4e86\u6700\u5927\u5316\u6574\u4e2a\u53ef\u89c1\u5149\u57df\u5185\u7684\u5149\u5b66\u5438\u6536\u83b7\u5f97\u9ad8\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff0c\u76ee\u524d\u592a\u9633\u80fd\u7535\u6c60\u5728\u5916\u89c2\u4e0a\u90fd\u9009\u62e9\u505a\u6210\u9ed1\u8272\uff0c\u4f46\u8fd9\u4e5f\u6781\u5927\u5730\u964d\u4f4e\u4e86\u592a\u9633\u80fd\u7535\u6c60\u5728\u5ba1\u7f8e\u5c42\u9762\u4e0a\u7684\u5438\u5f15\u529b\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u79cd\u7b26\u5408\u5ba1\u7f8e\u8981\u6c42\u7684\u9ad8\u6548\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u662f\u975e\u5e38\u91cd\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u6b66\u6c49\u5149\u7535\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5468\u5370\u534e\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7814\u7a76\u56e2\u961f\u5728Nano Letters<\/strong>\u4e0a\u53d1\u8868\u4e00\u7bc7\u9898\u4e3a\u201cEfficient Colorful Perovskite Solar Cells Using a Top Polymer Electrode Simultaneously as Spectrally Selective Antireflection Coating<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u56e2\u961f\u4ee5PEDOT:PSS\u805a\u5408\u7269\u4e3a\u53cd\u5c04\u7535\u6781\uff0c\u5236\u6210\u7ed3\u6784\u4e3aFTO\/c-TiO2<\/sub>\/m-TiO2<\/sub>\/\u9499\u949b\u77ff\u5c42\/HTL\/PEDOT:PSS\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u3002\u56e2\u961f\u7814\u7a76\u4eba\u5458\u5206\u522b\u901a\u8fc7\u65cb\u6d82\u548c\u8f6c\u5370\u6280\u672f\u5236\u5907PEDOT:PSS\u6297\u53cd\u5c04\u7535\u6781\u5c42\uff0c\u5e76\u91c7\u7528\u8c03\u6574\u63a7\u5236\u65cb\u6d82\u53c2\u6570\u4ee5\u53ca\u6539\u53d8\u8f6c\u5370\u8fc7\u7a0b\u4e2d\u6c89\u79ef\u5c42\u6570\u7684\u65b9\u6cd5\u6765\u63a7\u5236PEDOT:PSS\u5c42\u7684\u539a\u5ea6\u3002\u7ecf\u8fc7\u8c03\u8282PEDOT:PSS\u5c42\u539a\u5ea6\u548c\u9009\u62e9\u4e0d\u540cHTL\u5c42\uff0c\u56e2\u961f\u7814\u7a76\u4eba\u5458\u83b7\u5f97\u4e86\u5177\u6709\u5bbd\u8272\u57df\u7684\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff0c\u4e0d\u540c\u989c\u8272\u7535\u6c60\u6548\u7387\u80fd\u8fbe\u523011%\u81f315%\uff0c\u653e\u7f6e\u5728\u60f0\u6027\u6c14\u6c1b\u4e2d30\u5929\u540e\u7535\u6c60PCE\u4ecd\u80fd\u6709\u521d\u59cb\u6548\u7387\u768490%\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1.\u7b80\u5355\u9ad8\u6548\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n

\"nl-2016-04019n_0001\"<\/p>\n

 <\/p>\n

(a)\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u9876\u7aef\u7535\u6781\u662f\u7531\u8f6c\u5370\u6280\u672f\u5236\u6210\u7684PEDOT:PSS\u5bfc\u7535\u805a\u5408\u7269<\/p>\n

(b)\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7167\u7247\uff0c\u7167\u7247\u4e2d\u591a\u7247\u5c3a\u5bf8\u4e3a5\u00d75 mm2<\/sup>\u7684\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7ec4\u88c5\u6210\u5f69\u8272\u5b57\u6bcd\u201cH\u201d<\/p>\n

\u56fe2.\u6298\u5c04\u7387(n)\u548c\u6d88\u5149\u7cfb\u6570(k)\u8c31\u53ca\u7535\u6c60\u53cd\u5c04\u7387\u8c31<\/strong><\/p>\n

\"nl-2016-04019n_0002\"<\/p>\n

(a)\u9499\u949b\u77ff\u819c\u7684\u6298\u5c04\u7387\u548c\u6d88\u5149\u7cfb\u6570\u8c31<\/p>\n

(b)PEDOT:PSS\u819c\u7684\u6298\u5c04\u7387\u548c\u6d88\u5149\u7cfb\u6570\u8c31<\/p>\n

(c)\u63ba\u6742Spiro-OMeTAD\u819c\u7684\u6298\u5c04\u7387\u548c\u6d88\u5149\u7cfb\u6570\u8c31<\/p>\n

(d)\u63ba\u6742P3HT\u819c\u7684\u6298\u5c04\u7387\u548c\u6d88\u5149\u7cfb\u6570\u8c31<\/p>\n

(e f)\u7a7a\u7a74\u4f20\u8f93\u5c42\u5206\u522b\u4e3a\u63ba\u6742Spiro-OMeTAD\u548c\u63ba\u6742P3HT\u65f6\u7535\u6c60\u53cd\u5c04\u7387\u4e0ePEDOT:PSS\u7535\u6781\u539a\u5ea6\u4e4b\u95f4\u7684\u51fd\u6570\u5173\u7cfb\u8c31\u56fe\uff0c\u5176\u4e2d\u7535\u6c60\u7ed3\u6784\u4e3aFTO\/c-TiO2<\/sub>\/m-TiO2<\/sub>\/\u9499\u949b\u77ff\u5c42\/HTL\/PEDOT:PSS<\/p>\n

\u56fe3.\u7535\u6c60\u7167\u7247\u53ca\u5149\u5b66\u7279\u6027<\/strong><\/p>\n

\"nl-2016-04019n_0003\"<\/p>\n

(a)\u9499\u949b\u77ff\u7535\u6c60\u7684\u7167\u7247\uff0c\u7535\u6c60\u7ed3\u6784\u4e3aFTO\/c-TiO2<\/sub>\/m-TiO2<\/sub>\/\u9499\u949b\u77ff\u5c42\/HTL\/PEDOT:PSS\uff0cHTL\u5206\u522b\u4e3a\u63ba\u6742Spiro-OMeTAD\u548c\u63ba\u6742P3HT\uff0cPEDOT:PSS\u539a\u5ea6\u4e3a40-160 nm\u6216\u4e0d\u540c\u5c42\u6570\uff081-4\u5c42\uff09\u7684PEDOT:PSS\u819c<\/p>\n

(b)\u7535\u6c60\u7684\u5b9e\u9a8c\u6d4b\u91cf\u53cd\u5c04\u7387\u548c\u6a21\u62df\u6d4b\u91cf\u53cd\u5c04\u7387\uff0cHTL\u4e3aSpiro-OMeTAD<\/p>\n

(c)CIE 1931\u8272\u5f69\u7a7a\u95f4\u4e2d\u7535\u6c60\u7684\u989c\u8272\uff0cHTL\u5206\u522b\u4e3aSpiro-OMeTAD\u548cP3HT<\/p>\n

\u56fe4.\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd<\/strong><\/p>\n

\"nl-2016-04019n_0004\"<\/p>\n

(a b)\u5149\u7167\u9762\u5206\u522b\u4e3aFTO\u9762\u548cPEDOT:PSS\u65f6\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5404\u81ea\u7684J-V\u66f2\u7ebf\uff0c\u7535\u6c60\u7ed3\u6784\u4e3aFTO\/c-TiO2<\/sub>\/m-TiO2<\/sub>\/\u9499\u949b\u77ff\u5c42\/Spiro-OMeTAD\/PEDOT:PSS\uff0cPEDOT:PSS\u7535\u6781\u539a\u5ea6\u4e3a48 nm\u300195 nm\u548c160 nm\uff0c\u63d2\u56fe\u662f95 nm\u539aPEDOT:PSS\u5c42\u5f69\u8272\u7535\u6c60\u5728\u6700\u5927\u529f\u7387\u70b9(Vmpp<\/sub>=0.88 V)\u5904\u7684\u7a33\u6001\u5149\u7535\u6d41\u548cPCE<\/p>\n

(c d)\u5149\u7167\u9762\u5206\u522b\u4e3aFTO\u9762\u548cPEDOT:PSS\u65f6\u5f69\u8272\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5404\u81ea\u7684EQE\u8c31\uff0cPEDOT:PSS\u7535\u6781\u539a\u5ea6\u4e3a48 nm\u300195 nm\u548c160 nm<\/p>\n

\u3010\u5c0f\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

\u7528\u4e0d\u540c\u539a\u5ea6\u7684PEDOT:PSS\u805a\u5408\u7269\u5bfc\u7535\u819c\u53d6\u4ee3\u4f20\u7edf\u7684\u91d1\u5c5e\u7535\u6781\uff0c\u518d\u501f\u4ee5\u5b58\u5728\u4e8ePEDOT:PSS\u7535\u6781\u3001HTL\u548c\u9499\u949b\u77ff\u5c42\u4e4b\u95f4\u7684\u53cd\u5c04\u548c\u53d1\u5c04\u7535\u78c1\u573a\u4f5c\u7528\uff0c\u4f7f\u5f97\u5236\u5907\u5f62\u6210\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5728\u5916\u89c2\u4e0a\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u989c\u8272\uff0c\u540c\u65f6\u7535\u6c60PCE\u4e5f\u80fd\u8fbe\u5230\u4e00\u4e2a\u4e0d\u9519\u7684\u6c34\u5e73\u3002\u50cf\u8fd9\u79cd\u5728\u5927\u6298\u5c04\u7387\u819c\u548c\u5c0f\u6298\u5c04\u7387\u819c\u4e4b\u95f4\u5929\u7136\u5b58\u5728\u7684\u5e72\u6d89\u6548\u5e94\u4e5f\u53ef\u4ee5\u5e94\u7528\u4e8e\u5176\u5b83\u7c7b\u578b\u7684\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\uff0c\u540c\u65f6\u4e5f\u80fd\u6709\u529b\u5730\u63a8\u52a8\u5f69\u8272\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u5728\u591a\u79cd\u9886\u57df\u7684\u5e94\u7528\uff0c\u5982\u5efa\u7b51\u7528\u6750\u3001\u7535\u52a8\u8f66\u548c\u53ef\u7a7f\u6234\u7535\u5b50\u8bbe\u5907\u7b49\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Efficient Colorful Perovskite Solar Cells Using a Top Polymer Electrode Simultaneously as Spectrally Selective Antireflection Coating<\/a>(Nano Letters, 2016, DOI:10.1021\/acs.nanolett.6b04019)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Jon\u4f9b\u7a3f\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

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