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\u3010<\/b><\/strong>\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

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\"%e5%9b%be%e7%89%871\"<\/p>\n

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\"%e5%9b%be%e7%89%872\"<\/p>\n

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\u56fe<\/b><\/strong>3\uff1a<\/b><\/strong>B<\/b><\/strong>x:MAF-2<\/b><\/strong>(<\/b><\/strong>x=0\u548c<\/b><\/strong>x<\/b><\/strong>=100<\/b><\/strong>\u65f6\u7684\u5355\u6676\u7ed3\u6784<\/b><\/strong>)\u7684\u6676\u4f53\u4f53\u79ef\u3001\u5b54\u9699\u6bd4\u548cO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u7075\u654f\u6027<\/b><\/strong><\/p>\n

\"%e5%9b%be%e7%89%873\"<\/b><\/strong><\/p>\n

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\u56fe<\/b><\/strong>4<\/b><\/strong>\uff1a<\/b><\/strong>M<\/b><\/strong>x:MAF-2<\/b><\/strong>(<\/b><\/strong>x=0\u548c<\/b><\/strong>x<\/b><\/strong>=100<\/b><\/strong>\u65f6\u7684\u5355\u6676\u7ed3\u6784<\/b><\/strong>)\u7684\u6676\u4f53\u4f53\u79ef\u3001\u5b54\u9699\u6bd4\u548cO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u7075\u654f\u6027<\/b><\/strong>\u4ee5\u53ca\u7279\u6b8a\u914d\u6bd4\u4e0b\u5bf9<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u611f\u5e94\u7684\u68c0\u6d4b\u9650\uff0c\u5bf9CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u5438\u9644\u7b49\u6e29\u7ebf<\/b><\/strong><\/p>\n

\"%e5%9b%be%e7%89%874\"<\/p>\n

\u5c06\u914d\u4f53Hdetz\/Hdmtz (Hdetz=3,5-\u4e8c\u4e59\u57fa-1,2,4-\u4e09\u6c2e\u5511\uff1bHdmtz=3,5-\u4e8c\u7532\u57fa-1,2,4-\u4e09\u6c2e\u5511)\u6309\u7167\u4e00\u5b9a\u6bd4\u4f8b\u6df7\u5408\u4e0eCu2<\/sub>O\u7eb3\u7c73\u9897\u7c92\u5728\u6c34\u70ed\u6761\u4ef6\u4e0b\u5f97\u5230[Cu(detz)(100-x)\uff05<\/sub>(dmtz)x<\/sub>%<\/sub>]\uff08\u547d\u540d\u4e3aMx:MAF-2\uff09<\/p>\n

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(b)\u5728\u00a0O2\/N2\u4f53\u7cfb\u4e2dM66:MAF-2\u7684SV\u51fd\u6570\u7ebf\u6027\u62df\u5408\u56fe\u00a0\uff1b<\/p>\n

(c)\u00a0\u5728195K\u4e0bM66:MAF-2, M76:MAF-2, MAF-2 and M100:MAF-2\u7684CO2<\/sub>\u5438\u9644\u7b49\u6e29\u56fe<\/p>\n

\u3010<\/b><\/strong>\u5c55\u671b<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u8be5\u9879\u7814\u7a76\u6210\u679c\u4e3a\u63a7\u5236\u548c\u63d0\u5347MOFs\u7684\u6027\u8d28\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u548c\u7b56\u7565\u3002<\/p>\n

\u3010<\/b><\/strong>\u6587\u732e\u4fe1\u606f<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u6587\u732e\u8fde\u63a5<\/b><\/strong>\uff1aFlexible, Luminescent Metal\u2013Organic Frameworks Showing\u00a0Synergistic Solid-Solution Effects on Porosity and Sensitivity<\/a>\u00a0(Angew. Chem. Int. Ed.<\/i><\/em>2016<\/i><\/em>, DOI: 10.1002\/anie.201608439\u00a0IF=11.709)<\/p>\n

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