{"id":53689,"date":"2016-11-28T14:00:23","date_gmt":"2016-11-28T06:00:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=53689"},"modified":"2017-03-18T22:05:16","modified_gmt":"2017-03-18T14:05:16","slug":"adv-mater-%e4%b8%80%e7%a7%8d%e5%88%b6%e5%a4%87%e9%ab%98%e6%80%a7%e8%83%bd%e4%bf%ae%e9%a5%b0%e4%ba%9a%e5%8d%95%e5%b1%82ru%e7%9a%84%e8%b6%85%e8%96%84pd-nss%e7%9a%84%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=53689","title":{"rendered":"Adv. Mater.: \u4e00\u79cd\u5236\u5907\u9ad8\u6027\u80fd\u4fee\u9970\u4e9a\u5355\u5c42Ru\u7684\u8d85\u8584Pd NSs\u7684\u65b9\u6cd5"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u4e0e\u5757\u72b6\u6750\u6599\u76f8\u6bd4\uff0c\u8d85\u8584\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u7531\u4e8e\u5177\u6709\u72ec\u7279\u7684\u4e8c\u7ef4\u7ed3\u6784\uff0c\u663e\u793a\u51fa\u8bb8\u591a\u72ec\u7279\u7684\u6027\u8d28\u3002\u4f5c\u4e3a\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u7684\u4e00\u79cd\uff0c\u8d85\u8584\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7247\uff08NSs\uff09\u7531\u4e8e\u5177\u6709\u8868\u9762\u79ef-\u4f53\u79ef\u6bd4\u9ad8\u3001\u66b4\u9732\u5728\u8868\u9762\u7684\u4e0d\u9971\u548c\u539f\u5b50\u5bc6\u5ea6\u9ad8\u7b49\u53ef\u4ee5\u589e\u5f3a\u5176\u50ac\u5316\u6d3b\u6027\u7684\u7279\u70b9\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u901a\u5e38\uff0c \u5728\u539f\u5b50\u5c3a\u5ea6\u5bf9\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u8fdb\u884c\u8c03\u6574\u53ef\u4ee5\u6539\u53d8\u5b83\u4eec\u7684\u50ac\u5316\u6027\u80fd\uff0c\u4f8b\u5982\uff0c\u7528\u5176\u5b83\u5355\u5c42\u6216\u5c11\u5c42\u91d1\u5c5e\u539f\u5b50\u4fee\u9970\u5355\u6676\u91d1\u5c5e\u57fa\u6750\u7684\u8868\u9762\u53ef\u4ee5\u8bf1\u5bfc\u53d1\u751f\u5728\u8868\u9762\u53cd\u5e94\u6027\u4e2d\u8d77\u51b3\u5b9a\u6027\u4f5c\u7528\u7684\u6676\u683c\u7578\u53d8\u3002\u53d7\u8fd9\u4e00\u601d\u60f3\u7684\u542f\u53d1\uff0c\u76ee\u524d\u79d1\u5b66\u5bb6\u4eec\u5df2\u7ecf\u5236\u5907\u4e86\u5177\u6709\u539f\u5b50\u7ea7\u8584\u58f3\u7684\u53cc\u91d1\u5c5e\u6838-\u58f3\u7eb3\u7c73\u7ed3\u6784\uff0c\u4ee5\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u7136\u800c\uff0c\u5b8c\u5168\u8986\u76d6\u7684\u5355\u4e00\u539f\u5b50\u5c42\u58f3\u53ef\u80fd\u4f1a\u963b\u65ad\u6838\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5236\u5907\u66b4\u9732\u4e0d\u540c\u91d1\u5c5e\u539f\u5b50\u7684\u53cc\u91d1\u5c5e\u6838-\u58f3\u7eb3\u7c73\u7ed3\u6784\u662f\u63d0\u9ad8\u5176\u50ac\u5316\u6d3b\u6027\u7684\u6709\u6548\u7b56\u7565\u3002\u9274\u4e8e\u8d85\u8584\u4e8c\u7ef4\u7eb3\u7c73\u7247\u548c\u91d1\u5c5e\u539f\u5b50\u5c42\u7684\u72ec\u7279\u6027\u80fd\uff0c\u5f00\u53d1\u4e00\u79cd\u7b80\u5355\u3001\u666e\u904d\u3001\u5b9e\u7528\u7684\u5236\u5907\u8d85\u8584\u4e8c\u7ef4\u91d1\u5c5e\u6838-\u58f3\u7eb3\u7c73\u7247\u7684\u65b9\u6cd5\u662f\u5f88\u6709\u5fc5\u8981\u7684\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u5f20\u534e\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5229\u7528\u79cd\u5b50\u4ecb\u5bfc\u589e\u957f\u6cd5\u5408\u6210\u4fee\u9970\u4e9a\u5355\u5c42Ru\u7684\u8d85\u8584Pd NSs\uff0c\u79f0\u4e3aPd @ Ru NSs\u3002\u5728\u8be5\u65b9\u6cd5\u4e2d\u6b20\u7535\u4f4d\u6c89\u79ef\u662f\u5f62\u6210Pd @ Ru NSs\u7684\u9a71\u52a8\u529b\u3002\u5177\u4f53\u7684\u5236\u5907\u65b9\u6cd5\u662f\uff1a\u9996\u5148\u9ad8\u6548\u5408\u6210\u7c92\u5f84\u4e3a7.2\u00b10.8nm\uff0c\u539a\u5ea6\u7ea6\u4e3a1.5nm\u7684\u8d85\u8584Pd NSs\uff1b\u518d\u5c06\u5408\u6210\u7684Pd NSs\u7684\u60ac\u6d6e\u6db2\u4e0e\u6eb6\u89e350mg\u805a\u4e59\u70ef\u5421\u54af\u70f7\u916e\uff08PVP, Mw = 29000\uff09\u548c50mg\u6297\u574f\u8840\u9178\uff08AA\uff09\u76845mL\u4e59\u4e8c\u9187\uff08EG\uff09\u6eb6\u6db2\u6df7\u5408\uff0c\u5267\u70c8\u6405\u62cc\u6df7\u5408\u7269\u5e76\u5728\u6cb9\u6d74\u4e2d\u52a0\u70ed\u81f3160\u2103\uff0c\u5728\u5267\u70c8\u6405\u62cc\u4e0b\uff0c\u5c06\u4e59\u9170\u4e19\u916e\u948c\uff08III\uff09\uff08Ru(acac)<sub>3<\/sub>\uff09\u7684EG\u6eb6\u6db2\uff080.8mg mL<sup>-1<\/sup>, 5mL\uff09\u4ee55mLh<sup>-1<\/sup>\u7684\u901f\u7387\u6ce8\u5c04\u5230\u4e0a\u8ff0\u6df7\u5408\u7269\u4e2d\uff1b\u6eb6\u6db2\u4fdd\u6301\u5267\u70c8\u6405\u62cc\u5e76\u5728160\u2103\u4e0b\u4fdd\u63011\u5c0f\u65f6\uff0c\u81ea\u7136\u51b7\u5374\u81f3\u5ba4\u6e29\uff0c\u5373\u53ef\u5f97\u5230Pd @ Ru NSs\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0c\u4e0e\u7eaf\u8d85\u8584Pd NSs\u548cRu NSs\u76f8\u6bd4\uff0c\u6240\u83b7\u5f97\u7684Pd @ Ru NSs\u5bf94-\u785d\u57fa\u82ef\u915a\u7684\u8fd8\u539f\u548c1-\u8f9b\u7094\u7684\u534a\u6c22\u5316\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u00a0\u56fe1: Pd @ Ru NSs\u7684\u50ac\u5316\u53cd\u5e94\u793a\u610f\u56fe<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-gra-0001-m.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-53707 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-gra-0001-m.png\" alt=\"adma201604829-gra-0001-m\" width=\"433\" height=\"314\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-gra-0001-m.png 433w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-gra-0001-m-300x218.png 300w\" sizes=\"(max-width: 433px) 100vw, 433px\" \/><\/a><\/p>\n<p>\u56fe1\u662f\u5bf9Pd @ Ru NSs\u5bf94-\u785d\u57fa\u82ef\u915a\u7684\u8fd8\u539f\u548c1-\u8f9b\u7094\u7684\u534a\u6c22\u5316\u53cd\u5e94\u7684\u50ac\u5316\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u56fe 2 :<\/strong> <strong>\u6837\u54c1\u5f62\u8c8c\u3001\u7ed3\u6784\u53ca\u5143\u7d20\u5206\u6790<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0001.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-53704\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0001.png\" alt=\"adma201604829-fig-0001\" width=\"600\" height=\"507\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0001.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0001-300x254.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>\uff08a\uff09\u6837\u54c1TEM\u56fe\uff1b<\/p>\n<p>\uff08b\uff09\u6837\u54c1\u7c92\u5f84\u7edf\u8ba1\u56fe\uff0c\u4ece\u56fe\u4e2d\u53ef\u4ee5\u770b\u51faPd @ Ru NSs\u7684\u7c92\u5f84\u7ea6\u4e3a7.8\u00b10.7nm\u3002<\/p>\n<p>\uff08c-e\uff09\u6837\u54c1STEM\u9ad8\u89d2\u73af\u5f62\u6697\u573a\u56fe\u50cf\uff1b<\/p>\n<p>\uff08f\uff09\u6837\u54c1\u5143\u7d20\u5206\u6790\u56fe\uff0c\u53ef\u4ee5\u89c2\u5bdf\u5230Pd\u548cRu\u5143\u7d20\u5728\u7cfb\u7edf\u4e2d\u5747\u5300\u5206\u5e03\uff0c\u8bc1\u5b9e\u4e86Pd @ Ru NSs\u7684\u5f62\u6210\uff1b<\/p>\n<p>\uff08g\uff09Pd @ Ru NSs\u5408\u6210\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u56fe 3 : Pd @ Ru NSs\u7684\u5143\u7d20\u4ef7\u6001\u5206\u6790<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0002.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-53705\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0002.png\" alt=\"adma201604829-fig-0002\" width=\"600\" height=\"520\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0002.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0002-300x260.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>\uff08a\uff09Pd NSs\u4e2dPd 3d\u80fd\u7ea7\u7684X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff1b<\/p>\n<p>\uff08b-d\uff09Pd@Ru NSs \u4e2dPd 3d \u3001 Ru 3d \u3001Ru 3p \u80fd\u7ea7\u7684X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0Ru\u4e9a\u539f\u5b50\u5c42\u7684\u4fee\u9970\u4f1a\u6539\u53d8Pd 3d \u80fd\u7ea7\u7684\u7535\u5b50\u72b6\u6001\uff0c\u8fd9\u8bc1\u5b9e\u4e86Pd@Ru NSs\u7684\u5f62\u6210\u3002<\/p>\n<p><strong>\u56fe 4 : \u6837\u54c1\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0003.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-53706\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0003.png\" alt=\"adma201604829-fig-0003\" width=\"600\" height=\"707\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0003.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/adma201604829-fig-0003-255x300.png 255w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>\uff08a-b\uff09Pd@Ru NSs\u548cPd NSs\u5bf94-\u785d\u57fa\u82ef\u915a\u8fd8\u539f\u53cd\u5e94\u50ac\u5316\u6027\u80fd\u7684\u6bd4\u8f83\uff1b<\/p>\n<p>\uff08c-d\uff09Pd@Ru NSs\u548cPd NSs\u5bf94-\u785d\u57fa\u82ef\u915a\u8fd8\u539f\u53cd\u5e94\u50ac\u5316\u50ac\u5316\u6548\u7387\u5bf9\u6bd4\u56fe\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0Pd@Ru NSs\u5bf94-\u785d\u57fa\u82ef\u915a\u8fd8\u539f\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff1b<\/p>\n<p>\uff08e-f\uff09Pd@Ru NSs\u548cPd NSs\u5bf91-\u8f9b\u7094\u534a\u6c22\u5316\u53cd\u5e94\u50ac\u5316\u6027\u80fd\u7684\u6bd4\u8f83\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u9996\u6b21\u901a\u8fc7\u79cd\u5b50\u4ecb\u5bfc\u589e\u957f\u6cd5\u5b9e\u73b0\u4e86Pd@Ru NSs\u7684\u5408\u6210\u3002\u4e0e\u7eafPd NSs\u548cRu NSs\u76f8\u6bd4\uff0c\u6240\u5408\u6210\u7684\u65b0\u578b\u53cc\u91d1\u5c5ePd@Ru NSs\u5bf94-\u785d\u57fa\u82ef\u915a\u7684\u8fd8\u539f\u548c1-\u8f9b\u7094\u7684\u534a\u6c22\u5316\u5177\u6709\u66f4\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u540c\u65f6\uff0c\u8be5\u7814\u7a76\u6240\u91c7\u7528\u7684\u5408\u6210Pd@Ru NSs\u7684\u7b56\u7565\u53ef\u4e3a\u5408\u6210\u5176\u4ed6\u5177\u6709\u7c7b\u4f3c\u7eb3\u7c73\u7ed3\u6784\u7684\u9ad8\u6027\u80fd\u50ac\u5316\u5242\u63d0\u4f9b\u7406\u8bba\u548c\u5b9e\u8df5\u6307\u5bfc\u3002<\/p>\n<p><strong>\u00a0\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201604829\/full\" target=\"_blank\">Submonolayered Ru Deposited on Ultrathin Pd Nanosheets used for Enhanced Catalytic Applications <\/a>(Adv. 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