{"id":52184,"date":"2016-11-20T06:30:50","date_gmt":"2016-11-19T22:30:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=52184"},"modified":"2017-03-18T21:47:51","modified_gmt":"2017-03-18T13:47:51","slug":"adv-energy-mater-%ef%bc%9a%e5%a4%8d%e6%97%a6%e5%bd%ad%e6%85%a7%e8%83%9c-%e7%94%a8%e4%ba%8e%e9%ab%98%e5%ba%a6%e6%8b%89%e4%bc%b8%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8%e7%9a%84%e8%8a%af%e9%9e%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=52184","title":{"rendered":"Adv. Energy Mater. \uff1a\u590d\u65e6\u5f6d\u6167\u80dc-\u7528\u4e8e\u9ad8\u5ea6\u62c9\u4f38\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u82af\u9798\u5c42\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\u9635\u5217"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u8d85\u7ea7\u7535\u5bb9\u5668\u4e3b\u8981\u5efa\u7acb\u5728\u4e00\u79cd\u53cc\u7535\u5c42\u7406\u8bba\u7684\u57fa\u7840\u4e0a\uff0c\u4e0e\u53ef\u5145\u7535\u7535\u6c60\u76f8\u6bd4\uff0c\u53ef\u8fdb\u884c\u4e0d\u9650\u6d41\u5145\u7535\uff0c\u4e14\u5145\u7535\u6b21\u6570\u53ef\u8fbe10^6\u6b21\u4ee5\u4e0a\uff0c\u56e0\u6b64\u53cc\u7535\u5c42\u7535\u5bb9\u4e0d\u4f46\u5177\u6709\u7535\u5bb9\u7684\u7279\u6027\uff0c\u540c\u65f6\u4e5f\u5177\u6709\u7535\u6c60\u7279\u6027\uff0c\u662f\u4e00\u79cd\u4ecb\u4e8e\u7535\u6c60\u548c\u7535\u5bb9\u4e4b\u95f4\u7684\u65b0\u578b\u7279\u6b8a\u5143\u5668\u4ef6\u3002\u8fc7\u53bb\u8d85\u7ea7\u7535\u5bb9\u5668\u4e3b\u8981\u5e94\u7528\u5728\u5907\u7528\u7535\u6e90\u7cfb\u7edf\u3001\u7535\u52a8\u6c7d\u8f66\u4e0a\uff0c\u968f\u7740\u6280\u672f\u53d1\u5c55\u76ee\u524d\u5e0c\u671b\u8d85\u7ea7\u7535\u5bb9\u5668\u80fd\u591f\u5177\u6709\u53ef\u62c9\u4f38\u3001\u67d4\u6027\u7684\u6027\u8d28\uff0c\u4ece\u800c\u80fd\u591f\u5e94\u7528\u5728\u4e00\u4e9b\u65b0\u5174\u6280\u672f\u573a\u5408\uff0c\u4f8b\u5982\uff1a\u4fbf\u643a\u5f0f\u8bbe\u5907\u3001\u96c6\u6210\u7535\u8def\u7535\u5b50\u8bbe\u5907\u3001\u7535\u5b50\u76ae\u80a4\u548c\u53ef\u7a7f\u6234\u7ec7\u7269\u7b49\u3002\u4f46\u662f\uff0c\u76ee\u524d\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd\u3001\u53ef\u62c9\u4f38\u6027\u8fdc\u672a\u8fbe\u5230\u8981\u6c42\u3002\u5982\u679c\u80fd\u591f\u9002\u5f53\u8c03\u6574\u7535\u6781\u6750\u6599\u4e2d\u7ec4\u6210\u6210\u5206\u548c\u6750\u6599\u7684\u7ed3\u6784\uff0c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6027\u80fd\u4ece\u800c\u6ee1\u8db3\u6280\u672f\u4e0a\u7684\u8981\u6c42\u3002<\/span><\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u590d\u65e6\u5927\u5b66\u5f6d\u6167\u80dc\u6559\u6388<\/span>(\u901a\u8baf\u4f5c\u8005)<\/strong>\u8bfe\u9898\u7ec4\u5728Advanced Energy Materials<\/strong><\/span>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cNitrogen-Doped Core-Sheath Carbon Nanotube Array for\u00a0Highly Stretchable Supercapacitor\u201d<\/strong><\/span>\u7684\u6587\u7ae0\u3002\u8be5\u8bfe\u9898\u7ec4\u901a\u8fc7\u5236\u5907\u51fa\u82af\u9798\u5c42\u6c2e\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u7ba1(NCNT)\u9635\u5217\uff0c\u5c06\u5176\u4e0e\u805a\u6c28\u916f(PU)\u7ed3\u5408\u5728\u4e00\u8d77\uff0c\u4ece\u800c\u5236\u5907\u51fa\u4e86\u4e00\u79cd\u53ef\u62c9\u4f38\u7684\u5f39\u6027\u7535\u6781\u3002\u5728\u4e24\u5c42\u5f39\u6027NCNT\/PU\u7535\u6781\u4e2d\u95f4\u5939\u4e00\u5c42\u805a\u4e59\u70ef\u9187(PVA)\u51dd\u80f6\u7535\u89e3\u8d28\uff0c\u5f62\u6210\u4e00\u79cd\u4e09\u660e\u6cbb\u7684\u7ed3\u6784\uff0c\u4ece\u800c\u5f97\u5230\u4e86\u60f3\u8981\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u3002\u6240\u5f97\u5230\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u6bd4\u7535\u5bb9\u53ef\u8fbe31.1mF\u00b7cm-2<\/sup>\uff0c\u5c06\u5176\u5728\u62c9\u5e94\u529b\u4e0b\u53d8\u5f62400%\u540e\u6bd4\u7535\u5bb9\u4ecd\u80fd\u7ef4\u6301\u539f\u6765\u768498.9%\uff0c\u5728\u62c9\u4f38\u53d8\u5f62200%\u3001\u5faa\u73af1000\u6b21\u540e\u6bd4\u7535\u5bb9\u4ecd\u80fd\u7ef4<\/span>\u630196%\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe1. \u5f39\u6027NCNT\/PU\u8584\u819c\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/span><\/p>\n

\"aenm201601814-fig-0001\"<\/p>\n

\u56fe2. CNT\u548cNCNTs\u7684\u8868\u5f81<\/span><\/strong><\/p>\n

\"c389-tmp-0002\"<\/p>\n

(a-d) NCNTs\u7684SEM\u56fe\u50cf\uff0cNCNT\u7684\u518d\u751f\u957f\u65f6\u95f4\u5206\u522b\u4e3a(a)10min,(b)15min,(c)20min,(d)40min<\/p>\n

(e-h) NCNTs\u7684TEM\u56fe\u50cf\uff0cNCNT\u7684\u518d\u751f\u957f\u65f6\u95f4\u5206\u522b\u4e3a(e)10min,(f)15min,(g)20min,(h)40min<\/p>\n

(i) NCNT\u518d\u751f\u957f\u65f6\u95f4\u4e3a20min\u65f6\u7684TEM\u56fe\u50cf<\/p>\n

(j) NCNT\u518d\u751f\u957f\u65f6\u95f4\u4e3a40min\u65f6\u7684TEM\u56fe\u50cf<\/p>\n

(k,l) \u56fe(j)\u4e2dNCNT\u9635\u5217\u7684EDX\u56fe\uff0c\u5176\u4e2d\u56fe(k)\u663e\u793aC\u5143\u7d20\u5206\u5e03\uff0c\u56fe(l)\u663e\u793aN\u5143\u7d20\u5206\u5e03<\/p>\n

(m) CNT\u548cNCNT\u518d\u751f\u957f\u65f6\u95f4\u4e3a20min\u65f6\u7684\u62c9\u66fc\u56fe\u8c31\uff0c\u5f3a\u5ea6\u5cf0\u7684\u6bd4\u503c\u8868\u793a\u78b3\u7cfb\u7edf\u4e2d\u6df7\u4e71\u5ea6\u548c\u7f3a\u9677\u7a0b\u5ea6<\/p>\n

(n) NCNT\u7684N 1s XPS\u56fe\u8c31\uff0c\u663e\u793a\u4e86NCNT\u4e2d\u542bN\u5143\u7d20\u76f8\u67094\u79cd\u5b58\u5728\u5f62\u5f0f<\/p>\n

\u56fe3. NCNT\/PU\u62c9\u4f38\u6027\u80fd\u7684\u793a\u610f\u56fe\u548c\u5b9e\u9a8c\u6d4b\u8bd5<\/strong><\/p>\n

\"2nv88pb0bwk3nnmfwouu-0003\"<\/p>\n

(a) NCNT\/PU\u819c\u7684\u62c9\u4f38\u6027\u80fd\u7684\u793a\u610f\u56fe<\/p>\n

(b) NCNT\/PU\u819c\u5728\u62c9\u4f38\u91cf\u4ece0%\u589e\u52a0\u81f3500%\u8fc7\u7a0b\u4e2d\u7684\u7167\u7247<\/p>\n

\u56fe4. \u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u53ca\u5bf9\u6bd4<\/strong><\/p>\n

\"bir6okzk7wvawu9kdm-0004\"<\/p>\n

(a)\u4e0d\u540c\u518d\u751f\u957f\u65f6\u95f4\u4e0b\u7684\u9ad8\u5ea6\u62c9\u4f38\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u6d4b\u91cf\u65f6\u7684\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1mA\u00b7cm-2<\/sup><\/p>\n

(b)\u9ad8\u5ea6\u62c9\u4f38\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u518d\u751f\u957f\u65f6\u95f4\u4e3a20min\u524d\u540e\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff0c\u626b\u63cf\u901f\u7387\u4e3a200mV\u00b7s-1<\/sup><\/p>\n

(c)\u589e\u52a0\u7535\u6d41\u5bc6\u5ea6\u540e\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

(d)\u589e\u52a0\u626b\u63cf\u901f\u7387\u540e\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n

(e)\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1mA\u00b7cm-2<\/sup>\u4e0b\u7684\u5faa\u73af\u6bd4\u7535\u5bb9\u56fe<\/p>\n

(f)\u6bd4\u7535\u5bb9\u4e0e\u53d8\u5f62\u91cf\u7684\u5173\u7cfb\u56fe<\/p>\n

(g)\u6bd4\u7535\u5bb9\u4e0e\u62c9\u4f38\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb\u56fe<\/p>\n

(h)\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u62c9\u4f38\u548c\u6536\u7f29\u901f\u7387\u4e3a5mm\u00b7s-1<\/sup>\u65f6\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1mA\u00b7cm-2<\/sup><\/p>\n

(i)\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6bd4\u7535\u5bb9\u4e0e\u62c9\u4f38\u548c\u6536\u7f29\u6b21\u6570\u7684\u5173\u7cfb\u56fe\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a2mA\u00b7cm-2<\/sup><\/p>\n

(C<\/i><\/em>0<\/i><\/sub><\/em>\u548cC<\/em>\u5206\u522b\u8868\u793a\u62c9\u4f38\u524d\u3001\u540e\u7684\u6bd4\u7535\u5bb9)<\/p>\n

\u56fe5. \u4e24\u79cd\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd\u96f7\u8fbe\u56fe\u7684\u5bf9\u6bd4<\/strong><\/p>\n

\"a0wbp81o2zzw5iwx-0005\"<\/p>\n

\u6b64\u9ad8\u5ea6\u53ef\u62c9\u4f38\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0e\u62a5\u9053\u8fc7\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u62c9\u4f38\u6027\u80fd\u548c\u62c9\u4f38\u5faa\u73af\u7a33\u5b9a\u6027\u4e0a\u7684\u5bf9\u6bd4\uff0cC<\/i><\/em>0<\/i><\/sub><\/em>\u548cC<\/em>\u5206\u522b\u8868\u793a\u62c9\u4f38\u524d\u3001\u540e\u7684\u6bd4\u7535\u5bb9\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

\u8be5\u8bfe\u9898\u7ec4\u901a\u8fc7\u4f7f\u7528\u6c2e\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u7ba1\u9635\u5217\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\uff0c\u6240\u5236\u5f97\u5f97\u8d85\u7ea7\u7535\u5bb9\u5668\u5177\u5907\u826f\u597d\u7684\u62c9\u4f38\u6027\u80fd\u3002\u5176\u5faa\u73af\u53d8\u5f62\u91cf\u53ef\u8fbe200%\uff0c\u800c\u5927\u591a\u6570\u6750\u6599\u8fd9\u4e00\u503c\u5728100%\u4ee5\u4e0b\uff1b\u5176\u6700\u5927\u53d8\u5f62\u91cf\u53ef\u63a5\u8fd1400%\uff0c\u800c\u5176\u4ed6\u6750\u6599\u540c\u6837\u5728100%\u4ee5\u4e0b\uff1b\u6b64\u5916\uff0c\u5728\u6700\u5927\u5e94\u529b\u5faa\u73af\u3001\u957f\u671f\u5faa\u73af\u4e0b\uff0c\u5176\u5bb9\u91cf\u4fdd\u6709\u7387\u53ef\u8fbe95%\u4ee5\u4e0a\uff0c\u957f\u5faa\u73af\u4e0b\u53ef\u5faa\u73af1000\u6b21\u3002\u5728\u6750\u6599\u5236\u5907\u65b9\u9762\uff0c\u8be5\u8bfe\u9898\u7ec4\u6240\u62a5\u9053\u7684\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1(NCNT)\u9635\u5217\u5236\u5907\u65b9\u6cd5\u4e5f\u8f83\u7b80\u5355\uff0c\u4e3b\u8981\u901a\u8fc7CVD\u8fdb\u884cCNT\u53caNCNT\u7684\u5408\u6210\u3002\u603b\u4f53\u800c\u8a00\uff0c\u8be5\u8bfe\u9898\u7ec4\u6210\u529f\u7814\u7a76\u51fa\u4e86\u4e00\u79cd\u67d4\u6027\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u5177\u6709\u826f\u597d\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/strong><\/span> Nitrogen-Doped Core-Sheath Carbon Nanotube Array for Highly Stretchable Supercapacitor<\/u><\/a><\/p>\n

(Adv.Energy Mater. , 2016, DOI:10.1002\/aenm.201601814)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 charles \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

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