{"id":52037,"date":"2016-11-19T06:30:55","date_gmt":"2016-11-18T22:30:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=52037"},"modified":"2016-11-17T22:29:08","modified_gmt":"2016-11-17T14:29:08","slug":"adv-energy-mater-%ef%bc%9a%e6%ba%b6%e6%b6%b2%e6%b3%95%e5%88%b6%e5%a4%87%e5%87%ba%e9%ab%98%e4%bd%93%e7%a7%af%e6%af%94%e7%94%b5%e5%ae%b9%e7%9a%84%e5%85%a8%e5%9b%ba%e6%80%81%e8%b6%85%e7%ba%a7%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=52037","title":{"rendered":"Adv. Energy Mater.\uff1a\u6eb6\u6db2\u6cd5\u5236\u5907\u51fa\u9ad8\u4f53\u79ef\u6bd4\u7535\u5bb9\u7684\u5168\u56fa\u6001\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u67d4\u6027\u50a8\u80fd\u5668\u4ef6\u5728\u73b0\u4ee3\u7535\u5b50\u4ea7\u54c1\u4e2d\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\uff0c\u5982\u79fb\u52a8\u667a\u80fd\u624b\u673a\uff0c\u6237\u5916\u7a7f\u6234\u50a8\u80fd\u8bbe\u5907\u548c\u5176\u4ed6\u80fd\u91cf\u5b58\u50a8\u7cfb\u7edf\u3002\u76ee\u524d\u4e3a\u6b62\u4eba\u4eec\u4e0d\u4f46\u53d1\u660e\u4e86\u8bf8\u5982\u8584\u819c\u7535\u6c60\u3001\u8584\u819c\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u67d4\u6027\u50a8\u80fd\u5668\u4ef6\uff0c\u66f4\u91cd\u8981\u7684\u662f\uff0c\u79d1\u5b66\u5bb6\u4eec\u5229\u7528\u81ea\u7ec4\u88c5\u3001\u5370\u5237\u548c\u539f\u4f4d\u751f\u957f\u7b49\u7eb3\u7c73\u6280\u672f\uff0c\u5236\u5907\u51fa\u4e86\u6982\u5ff5\u578b\u7684\u67d4\u6027\u50a8\u80fd\u5668\u4ef6\u3002\u7136\u800c\uff0c\u5728\u9762\u5bf9\u5546\u4e1a\u5316\u8fd9\u4e00\u91cd\u5927\u8bfe\u9898\u65f6\uff0c\u4e0e\u975e\u67d4\u6027\u5668\u4ef6\u76f8\u6bd4\uff0c\u8868\u73b0\u51fa\u4e86\u8bb8\u591a\u77ed\u677f\uff0c\u4e3b\u8981\u662f\u7531\u4e8e\u6d3b\u6027\u6750\u6599\u3001\u7535\u6781\u548c\u57fa\u5e95\u4eb2\u548c\u6027\u8f83\u5dee\u9020\u6210\u7684\u3002\u5168\u56fa\u6001\u8d85\u7ea7\u7535\u5bb9\u5668\uff08ASSSs\uff09\u4f5c\u4e3a\u73b0\u4ee3\u7535\u5b50\u4ea7\u54c1\u7684\u65b0\u4e00\u4ee3\u7535\u5b50\u50a8\u80fd\u5668\u4ef6\uff0c\u5177\u6709\u5feb\u5145\u5feb\u653e\u548c\u8d85\u957f\u5faa\u73af\u6027\u80fd\u7b49\u4f18\u70b9\uff0c\u4e3b\u8981\u4ea7\u54c1\u6709\u4f20\u7edf\u7684\u5939\u5c42\u5f0f\u56fa\u6001\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u82af\u7247\u4e0a\u7684\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668(MSCs)\u3002\u4eba\u4eec\u5728\u8be5\u9886\u57df\u505a\u4e86\u8bb8\u591a\u5de5\u4f5c\uff0c\u4f46\u4efb\u6709\u8bb8\u591a\u96be\u9898\u7b49\u5f85\u4eba\u4eec\u53bb\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u6765\u81ea\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u51af\u65b0\u4eae\u6559\u6388\u3001\u5e84\u5c0f\u4e1c\u535a\u58eb<\/strong>\u53ca\u957f\u6625\u5e94\u5316\u6240Niu Li\uff08<\/strong>\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/b>\u7b49\u5c55\u793a\u4e86\u9ad8\u6027\u80fd\u67d4\u6027MSCs\u4f5c\u54c1\uff0c\u4ed6\u4eec\u4f7f\u7528\u6eb6\u6db2\u6cd5\u5236\u5907\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u5c42\u7247\uff08Ti3<\/sub>C2<\/sub>Tx <\/sub>\uff09\u548c\u7535\u5316\u5b66\u5265\u843d\u7684\u77f3\u58a8\u70ef\uff08EG\uff09\u7684\u590d\u5408\u7269\uff0c\u4ee5\u5236\u5907\u67d4\u6027\u50a8\u80fd\u5668\u4ef6\u3002\u7ecf\u6d4b\u8bd5\uff0cMSCs\u7684\u8868\u9762\u6bd4\u7535\u5bb9\u9ad8\u8fbe3.26 mF cm\u22122\u00a0 <\/sup>\uff0c2 mV s\u22121<\/sup>\u7684\u6761\u4ef6\u4e0b\u4f53\u79ef\u6bd4\u7535\u5bb9\u9ad8\u8fbe33 F cm\u22123\u00a0 <\/sup>\uff0c\u5728\u5df2\u62a5\u9053\u7684\u6570\u636e\u4e2d\uff0c\u8be5\u6570\u636e\u5df2\u662f\u77f3\u58a8\u70ef\u57fa\u5e95MSCs\u7684\u8d85\u9ad8\u6c34\u5e73\u3002\u67d4\u6027ASSSs\u7684\u8584\u5c42\u7535\u6781\u539a\u5ea6\u4ec5\u67092.5\u5fae\u7c73\uff0c0.1 A cm\u22123<\/sup>\u7684\u6d4b\u8bd5\u6761\u4ef6\u4e0b\u4f53\u79ef\u6bd4\u7535\u5bb9\u9ad8\u8fbe216F cm-3 <\/sup>,\u4f18\u4e8e\u5176\u4ed6\u7535\u6781\u6d3b\u6027\u6750\u6599\u3002\u5728\u590d\u5408\u7535\u6781\u4e2d\uff0c\u77f3\u58a8\u70ef\u5c42\u7684\u5fae\u578b\u8fc7\u6e21\u65cf\u91d1\u5c5e\u9897\u7c92\u4e0d\u4ec5\u662f\u6d3b\u6027\u6750\u6599\u7f13\u51b2\u5c42\uff0c\u8fd8\u6709\u9694\u79bb\u5c42\u7684\u4f5c\u7528\uff0c\u963b\u6b62\u77f3\u58a8\u70ef\u5c42\u7247\u95f4\u5806\u79ef\u8fc7\u91cf\u4e0d\u53ef\u9006\u7684\u03c0\u2013\u03c0\u5efa\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u51c6\u5907\u6750\u6599\u548c\u5236\u9020\u5668\u4ef6<\/strong><\/p>\n

\"1\"<\/p>\n

a\u7535\u5316\u5b66\u5265\u843d\u6cd5\u5236\u9020\u77f3\u58a8\u70ef\u53ca\u7a33\u5b9a\u7684IPA\u77f3\u58a8\u70ef\u5206\u6563\u6db2<\/p>\n

b\u8fc7\u6e21\u65cf\u91d1\u5c5e\u7eb3\u7c73\u5c42\u7247\u7684\u5236\u9020\u53ca\u5176\u7a33\u5b9a\u7684\u5206\u6563\u6db2<\/p>\n

c EGMX1:3\u7eb3\u7c73\u6df7\u5408\u6db2\u7684\u5236\u9020\u8fc7\u7a0b<\/p>\n

\u6ce8\uff1aa,b,c\u4e2d\u7684\u6570\u7801\u7167\u7247\u662f\u5149\u8def\u5206\u522b\u5728EG, Mxene\u548c EGMX1:3\u6eb6\u6db2\u4e2d\u6563\u5c04\u7684\u7ed3\u679c<\/p>\n

d,e \u5177\u6709\u67d4\u6027\u7684EGMX1:3 \u5c42\u5355\u72ec\u7684\u7167\u7247\uff0c\u53ca\u5176\u5bf9\u5e94\u7684ASSS<\/p>\n

\u56fe<\/strong>2 EG, Mxene<\/strong>\u548c<\/strong> EGMX1:3 <\/strong>\u7b26\u5408\u5c42\u7684\u5fae\u89c2\u5f62\u6001\u7167\u7247<\/strong><\/p>\n

\"2\"<\/p>\n

a,c \u00a0EG\u548cEGMX1:3\u7eb3\u7c73\u590d\u5408\u5c42\u7684TEM\u7167\u7247<\/p>\n

b,d \u8fc7\u6e21\u65cf\u91d1\u5c5e\u7eb3\u7c73\u5c42\u548cEGMX1:3\u590d\u5408\u5c42\u7684SEM\u7167\u7247<\/p>\n

a,b,c\u4e2d\u7684\u63d2\u56fe\u5206\u522b\u5bf9\u5e94EG,Mxene\u548cEGMX1:3\u7684\u9009\u533a\u7535\u5b50\u884d\u5c04\u82b1\u6837<\/p>\n

d\u4e2d\u7684\u63d2\u56fe\u662fEGMX1:3\u65ad\u9762\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n

\u56fe<\/strong>3 ASSSs<\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u56fe<\/strong><\/p>\n

\"3\"<\/p>\n

a \u626b\u63cf\u901f\u7387\u572820mV s-1<\/sup>\u6761\u4ef6\u4e0b\uff0cASSSs\u5206\u522b\u5728EG, MXene \u548c EGMXx:y ( x:y = 1:3, 3:1, 1:9\u548c 9:1)\u57fa\u5e95\u4e0aCV\u66f2\u7ebf\u7684\u6bd4\u8f83\u56fe<\/p>\n

b ASSSs\u5206\u522b\u5728EG, MXene \u548c EGMXx:y ( x:y = 1:3, 3:1, 1:9\u548c 9:1)\u57fa\u5e95\u4e0aGCD\u66f2\u7ebf\u7684\u6bd4\u8f83\u56fe<\/p>\n

c \u57280.2Acm-3<\/sup>\u6761\u4ef6\u4e0bASSSs\u5206\u522b\u5728EG, Mxene\uff0cEGMXx:y \u4ee5\u53carGOMX1:3\u57fa\u5e95\u4e0a\u4f53\u79ef\u6bd4\u5bb9\u91cf\u7684\u5bf9\u6bd4\u56fe<\/p>\n

d\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u7684\u6761\u4ef6\u4e0bASSSs\u5206\u522b\u5728EG, Mxene\uff0cEGMXx:y \u4ee5\u53carGOMX1:3\u57fa\u5e95\u4e0a\u4f53\u79ef\u6bd4\u5bb9\u91cf\u7684\u5bf9\u6bd4\u56fe<\/p>\n

e ASSSs\u4e2dEGMX1:3\u5206\u522b\u572810\uff0c20\uff0c50\uff0c100\u548c200mV s-1 <\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\u56fe<\/p>\n

f ASSSs\u4e2dEGMX1:3\u5206\u522b\u57280.1\uff0c0.2\uff0c0.5\uff0c1\u548c2 Acm-3 <\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684GCD\u66f2\u7ebf\u56fe<\/p>\n

g \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u6761\u4ef6\u4e0b\u5e93\u4f26\u6548\u7387\u548c\u4f53\u79ef\u6bd4\u5bb9\u91cf\u7684\u7edf\u8ba1\u56fe<\/p>\n

h 1A cm-3<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af2500\u6b21\u540eASSS\u4e2dEGMX1:3\u7684\u80fd\u91cf\u4fdd\u7559\u60c5\u51b5<\/p>\n

i \u4e0e\u5176\u4ed6\u6587\u732e\u4e2d\u62a5\u9053\u8fc7\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6bd4\u8f83\u56fe<\/p>\n

\u56fe<\/strong>4 ASSSs<\/strong>\u7684\u67d4\u6027\u548c\u7535\u538b\u7a97\u53e3\u6d4b\u8bd5\u56fe<\/strong><\/p>\n

\"4\"<\/p>\n

a 20mV s-1\u6761\u4ef6\u4e0b\uff0cASSSs\u5206\u522b\u5f2f\u66f230\u00b0\uff0c90\u00b0\uff0c180\u00b0\u65f6\uff0cEGMX1:3\u7684CV\u66f2\u7ebf<\/p>\n

b \u4e0d\u540c\u5f2f\u66f2\u89d2\u5ea6\u4e0b\u7684\u6570\u7801\u7167\u7247<\/p>\n

c 200mV s-1\u6761\u4ef6\u4e0b\uff0c\u4e0d\u540c\u7535\u538b\u7a97\u53e3\u4e0bASSS\u7684CV\u66f2\u7ebf\u56fe<\/p>\n

d \u5355\u4e2aASSS\uff0c\u4e24\u4e2aASSSs\u5e76\u8054\uff0c\u4e32\u8054\u548c\u4e09\u4e2aASSSs\u4e32\u8054\u7684GCD\u66f2\u7ebf\uff0c\u63d2\u56fe\u662f\u4e32\u5e76\u8054\u7684\u793a\u610f\u56fe<\/p>\n

e,f \u4e09\u4e2a\u5e76\u8054ASSSs\u7ec4\u5bf9LED\u706f\u7684\u53d1\u5149\u6548\u679c\uff0c\u63d2\u56fe\u662f\u4e09\u4e2aASSSs\u7ec4\u53d1\u51498\u5206\u949f\u540e\u7684\u6548\u679c<\/p>\n

\u56fe<\/strong>5 MSCs<\/strong>\u7535\u5316\u5b66\u548c\u67d4\u6027\u7684\u7814\u7a76<\/strong><\/p>\n

\"5\"<\/p>\n

a \u4ee5PET\u4e3a\u886c\u5e95\uff0cMSC\u88c5\u9970\u5728EGMX1:3\u5916\u5c42\u6240\u7ec4\u6210\u5668\u4ef6\u7684\u67d4\u6027\u7167\u7247<\/p>\n

b EGMX1:3\u4e0aMSC\u572810\uff0c20\uff0c50\uff0c100\u548c200mV s-1\u6761\u4ef6\u4e0b\u7684CV\u66f2\u7ebf<\/p>\n

c EGMX1:3\u7eb3\u7c73\u590d\u5408\u5c42\u4e0aMSC\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684\u9762\u79ef\u6bd4\u5bb9\u91cf\u548c\u4f53\u79ef\u6bd4\u5bb9\u91cf<\/p>\n

d 200mV s-1\u6761\u4ef6\u4e0b\uff0c\u5206\u522b\u5728\u5e73\u94fa\u548c\u5f2f\u66f2\u6761\u4ef6\u4e0b\u5faa\u73af2500\u6b21\u540e\u7684\u5bb9\u91cf\u4fdd\u7559\u60c5\u51b5\uff0c\u63d2\u56fe\u8868\u793a\u5fae\u578b\u5668\u4ef6\u5e73\u94fa\u548c\u5f2f\u66f2\u65f6\u7684\u7167\u7247<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4f5c\u8005\u901a\u8fc7\u6eb6\u6db2\u6cd5\u5904\u7406Mxene\u548cEG\u5236\u5907\u51fa\u8584\u819c\u7535\u6781\uff0c\u5e94\u7528\u4e8e\u5168\u56fa\u6001\u548c\u5fae\u578b\u5e73\u9762\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c5 mV s\u22121\u6761\u4ef6\u4e0b\u83b7\u5f97\u4e86\u9762\u79ef\u6bd4\u5bb9\u91cf3.26 mF cm\u22122\uff0c\u4f53\u79ef\u6bd4\u5bb9\u91cf33 F cm\u22123\u4f18\u5f02\u6027\u80fd\uff0c\u9664\u6b64\u4ee5\u5916\u5f97\u76ca\u4e8e\u8d28\u91cf\u8f7b\u3001\u5c42\u95f4\u8ddd\u5927\u3001\u5bfc\u7535\u6027\u597d\u3001\u590d\u5408\u5c42\u72b6\u7535\u6781\u5b8c\u6574\u6027\u597d\u7684\u7279\u70b9\uff0c0.1 mV s\u22121\u6761\u4ef6\u4e0b\uff0cASSS\u6837\u54c1\u53d6\u5f97\u4e86216 mF cm\u22122\u7684\u8d85\u9ad8\u6548\u7387\u3002\u76f8\u4fe1\u6eb6\u6db2\u6cd5\u5236\u5907ASSSs\u548cMSCs\u5c06\u4f1a\u4e3a\u7535\u5bb9\u5668\u6311\u6218\u66f4\u9ad8\u6027\u80fd\u63d0\u4f9b\u6377\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aFlexible All-Solid-State Supercapacitors with High Volumetric Capacitances Boosted by Solution Processable MXene and Electrochemically Exfoliated Graphene<\/a> (Adv. Energy Mater. ,2016, DOI: 10.1002\/aenm.201601847)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4 YueZhou \u6574\u7406\u7f16\u8bd1\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

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