{"id":51040,"date":"2016-11-11T14:00:05","date_gmt":"2016-11-11T06:00:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=51040"},"modified":"2016-11-10T21:01:56","modified_gmt":"2016-11-10T13:01:56","slug":"macromolecules%ef%bc%9a%e9%ab%98%e6%80%a7%e8%83%bd%e5%bc%b9%e6%80%a7%e4%bd%93","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=51040","title":{"rendered":"Macromolecules\uff1a\u9ad8\u6027\u80fd\u5f39\u6027\u4f53"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5236\u5907\u5177\u6709\u9ad8\u5f3a\u5ea6\uff0c\u9ad8\u5ef6\u5c55\u6027\u548c\u6320\u66f2\u5f3a\u5ea6\u7684\u5148\u8fdb\u5f39\u6027\u4f53\u81f3\u4eca\u4ecd\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u4e2a\u65b0\u9896\u7684\u5efa\u7acb\u591a\u7f51\u72b6\u7ed3\u6784\u7684\u65b9\u6cd5\uff1a\u901a\u8fc7\u5728\u987a\u5f0f1\uff0c4-\u805a\u5f02\u620a\u4e8c\u70ef\uff08IR\uff09\u7684\u5316\u5b66\u4ea4\u8054\u7f51\u7edc\u7ed3\u6784\u4e2d\u52a0\u5165\u5f31\u7684\u6c22\u952e\u548c\u5f3a\u7684\u950c\u57fa\u5355\u5143\uff0c\u5176\u52a8\u6001\u6027\u8981\u6c42\u7ed3\u5408\u952e\u80fd\u591f\u65ad\u88c2\u548c\u91cd\u7ec4\uff0c\u4ece\u800c\u8fbe\u5230\u9ad8\u7684\u5f39\u6027\u7279\u6027\u3002\u5728\u5916\u90e8\u6324\u538b\u6761\u4ef6\u4e0b\uff0c\u5171\u4ef7\u7f51\u7edc\u4e2d\u7ed3\u5408\u952e\u4f18\u5148\u65ad\u88c2\u80fd\u6709\u6548\u5730\u5206\u6563\u80fd\u91cf\u548c\u4fc3\u8fdb\u94fe\u7684\u53d6\u5411\uff0c\u4ece\u800c\u63d0\u9ad8\u62c9\u4f38\u6a21\u91cf\uff0c\u65ad\u88c2\u97e7\u6027\u548c\u663e\u8457\u5730\u63d0\u9ad8\u6320\u66f2\u5f3a\u5ea6\u3002\u4f5c\u8005\u63d0\u51fa\u7684\u63d0\u9ad8\u6320\u66f2\u5f3a\u5ea6\u7684\u65b9\u6cd5\u8d77\u6e90\u4e8e\u7ed3\u5408\u952e\u7684\u65ad\u88c2\u548c\u91cd\u7ec4\uff0c\u8be5\u8fc7\u7a0b\u80fd\u591f\u5bf9\u80fd\u91cf\u8d77\u5230\u6d88\u6563\u7684\u4f5c\u7528\uff0c\u4e14\u63d0\u4f9b\u4e86\u5e94\u53d8\u8bf1\u5bfc\u7ed3\u6676\u7684\u65b0\u673a\u5236\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u4e2a\u6982\u5ff5\u63d0\u4f9b\u4e86\u72ec\u4e00\u65e0\u4e8c\u7684\u673a\u5236\u6765\u8bbe\u8ba1\u5728\u9759\u6001\u548c\u52a8\u6001\u6761\u4ef6\u4e0b\u90fd\u62e5\u6709\u6770\u51fa\u673a\u68b0\u6027\u80fd\u7684\u9ad8\u5f39\u6027\u4f53\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56db\u5ddd\u5927\u5b66\u9ec4\u5149\u901f\u6559\u6388\u548c\u534e\u5357\u7406\u5de5\u5927\u5b66\u90ed\u5b9d\u6625\u6559\u6388<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>\uff09\u7b49\u4eba\u7814\u5236\u51fa\u4e86\u4e00\u79cd\u5177\u6709\u9ad8\u5f3a\u5ea6\uff0c\u9ad8\u5ef6\u5c55\u6027\u548c\u6770\u51fa\u6320\u66f2\u5f3a\u5ea6\u7684\u6750\u6599\u3002\u5b9e\u73b0\u8fd9\u4e00\u76ee\u7684\u7684\u65b9\u6cd5\u662f\u901a\u8fc7\u5728\u987a\u5f0f1\uff0c4-\u805a\u5f02\u620a\u4e8c\u70ef\u7684\u5316\u5b66\u4ea4\u8054\u7f51\u7edc\u7ed3\u6784\u4e2d\u52a0\u5165\u5f31\u7684\u6c22\u952e\u548c\u5f3a\u7684\u950c\u57fa\u5355\u5143\u3002\u53d7\u529b\u4e0b\u65ad\u88c2\u6c22\u952e\u548c\u950c\u57fa\u5e95\u7ed3\u5408\u952e\u7684\u52a8\u6001\u7279\u6027\u5df2\u7ecf\u88ab\u8bc1\u5b9e\u3002\u5728\u62c9\u4f38\u6761\u4ef6\u4e0b\u952e\u77ac\u95f4\u65ad\u88c2\uff0c\u540c\u65f6\u5728\u52a0\u70ed\u548c\u5378\u538b\u6761\u4ef6\u4e0b\u88ab\u91cd\u65b0\u7ec4\u5408\u3002\u6c22\u952e\u5148\u65ad\u88c2\u7d27\u63a5\u7740\u950c\u57fa\u952e\u7834\u88c2\uff0c\u4ece\u800c\u6709\u6548\u5730\u9a71\u6563\u80fd\u91cf\u548c\u63d0\u9ad8\u5f39\u6027\u6a21\u91cf\u548c\u65ad\u88c2\u5f3a\u5ea6\u3002\u867d\u7136\u6c22\u952e\u88ab\u8ba4\u4e3a\u80fd\u5bfc\u81f4\u6320\u66f2\u5f3a\u5ea6\u7684\u4e0b\u964d\uff0c\u4f46\u662f\u5728\u6df7\u5408\u7f51\u7edc\u7ed3\u6784\u4e2d\u8be5\u7279\u6027\u5374\u88ab\u5927\u5927\u63d0\u5347\u3002\u56e0\u4e3a\u78b3\u5316\u7845\u5728\u5f02\u620a\u4e8c\u70ef\u6a61\u80f6\u5185\u5e76\u6ca1\u6709\u88ab\u6c22\u952e\u6216\u8005\u950c\u57fa\u952e\u6709\u6548\u7684\u4fc3\u8fdb\u3002\u65ad\u88c2\u97e7\u6027\u5927\u90e8\u5206\u7531\u7ed3\u5408\u952e\u65ad\u88c2\u548c\u80fd\u91cf\u7684\u6d88\u6563\u6765\u63d0\u9ad8\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1: \u539f\u7406\u56fe\u89e3<\/strong><\/p>\n

\"1\"<\/p>\n

\uff08a\uff09\u5236\u5907fMAn-g-IR \u548c ATA-Modified MAn-g-IR\u7b80\u56fe\uff08ATA\uff1a3-\u6c28\u57fa1\uff0c2\uff0c4\u4e09\u5511 \u3001MAn\uff1a\u987a\u4e01\u70ef\u4e8c\u9178\u9150\uff09\uff1b<\/p>\n

\uff08b\uff09\u5f02\u620a\u4e8c\u70ef\u6a61\u80f6\u7684\u5047\u60f3\u591a\u7ea7\u7ed3\u6784\u3002<\/p>\n

\u56fe2\uff1a\u4e0d\u540c\u6750\u6599\u5bf9\u4e0d\u540c\u6ce2\u957f\u7684\u5438\u6536\u66f2\u7ebf\u56fe<\/strong><\/p>\n

\"2\"<\/p>\n

IR, MAn-g-IR, \u548c ATA-modified MAn-gIR\u7684FTIR\u5149\u8c31\u56fe\u3002<\/p>\n

\u56fe3\uff1a\u672a\u786b\u5316\u8fc7\u7684ATA-1\u5728\u63d0\u5347\u6e29\u5ea6\u4e0b\u7684FTIR\u5149\u8c31\u56fe<\/strong><\/p>\n

\"3\"<\/p>\n

\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\u7fa7\u9178\u7684\u5438\u6536\u5cf0\u4ece1726cm-1<\/sup>\u8f6c\u79fb\u52301733cm-1<\/sup>\uff0c\u663e\u793a\u51fa\u6c22\u952e\u7684\u9010\u6b65\u65ad\u88c2\u3002\u540c\u65f6\u6c28\u57fa\u7684\u78b3\u6c27\u952e\u4ece1664cm-1<\/sup>\u8f6c\u79fb\u52301658cm-1<\/sup>\uff0c\u4e09\u5511\u4e2dN\u2550CH\u952e\u8f6c\u79fb\u52301584cm-1<\/sup>.\u8fd9\u4e9b\u90fd\u8bc1\u660e\u4e86\u6c22\u952e\u7684\u5f62\u6210\u3002<\/p>\n

\u56fe4\uff1a\u63d0\u9ad8\u950c\u7684\u542b\u91cf\u4e4b\u540eZnATA-x\u7684FTIR\u5149\u8c31\u56fe<\/strong><\/p>\n

\"ma-2016-01576r_0004\"<\/p>\n

\u56fe\u4e2d\u6e05\u695a\u7684\u663e\u793a\u4e86\u6c22\u952e\u548c\u950c\u952e\u5f88\u597d\u7684\u5728\u5f02\u620a\u4e8c\u70ef\u805a\u5408\u7269\u4e2d\u7684\u5408\u5e76\u3002<\/p>\n

\u56fe5\uff1a\u5728300%\u5f20\u529b\u6761\u4ef6\u4e0b\u6d4b\u5f97\u7684\u5faa\u73af\u538b\u529b\u6d4b\u8bd5\u56fe<\/strong><\/p>\n

\"ma-2016-01576r_0005\"<\/p>\n

\u56fea\u548cb\u4e3aIR\u548cATA-1\u7684\u5faa\u73af\u5f20\u529b\u66f2\u7ebf\uff0cATA-\u6a61\u80f6\u4e2d\u76842\/1\u548c\u0394\u53d6\u51b3\u4e8eATA\u548cMan\u7684\u6469\u5c14\u6bd4\u4f8b\u3002\u5176\u4e2d\u56fec\u4e2d\u7684\u9ed1\u7ebf\u548c\u7ea2\u7ebf\u5206\u522b\u4ee3\u8868\u4e86IR\u4e2d\u76842\/1\u548c\u0394\u3002<\/p>\n

\u56fe6\uff1aZnATA\u7684\u5178\u578b\u5faa\u73af\u538b\u529b\u8bd5\u9a8c<\/strong><\/p>\n

\"ma-2016-01576r_0006\"<\/p>\n

\uff08a\uff09 ZnATA-0.2\u7684\u5faa\u73af\u538b\u529b\u8bd5\u9a8c\u3002<\/p>\n

\uff08b\uff09 ZnATA-\u4e2d\u4e0d\u540cZn2+<\/sup>\/ATA\u6bd4\u4f8b\u4e0b\u76842\/1\u548c\u0394\u3002<\/p>\n

\uff08c\uff09 ZnATA-0 \u548c ZnATA-0.2\u4e2d\u6807\u51c6\u5316\u7684\u6b8b\u4f59\u5e94\u53d8\u548c\u7b49\u5f85\u65f6\u95f4\u4e4b\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n

\u56fe7\uff1a6.28 rad\/s\u56fa\u5b9a\u9891\u7387\u4e0b\u7684\u5f20\u529b\u6d88\u9664\u6d4b\u8bd5<\/strong><\/p>\n

\"ma-2016-01576r_0007\"<\/p>\n

\u5728\u4e0d\u540c\u7684\u5f20\u529b\u4e0b\u6d4b\u8bd5\u50a8\u5b58\u6a21\u91cf\u548c\u5931\u53bb\u6a21\u91cf\u53ef\u4ee5\u5f97\u5230\u6d41\u53d8\u6d4b\u8bd5\u7ed3\u679c\u3002<\/p>\n

\u56fe8\uff1aIR, ZnATA-0\u548cZnATA-0.2\u5728100%\u5f20\u529b\u4e0b\u7684\u5e94\u53d8\u677e\u5f1b<\/strong><\/p>\n

\"ma-2016-01576r_0008\"<\/p>\n

\u901a\u8fc7\u8fdb\u4e00\u6b65\u8bf4\u660e\u6c22\u952e\u548c\u950c\u57fa\u5355\u5143\u52a8\u6001\u4e0b\u7684\u7ed3\u5408\u529b\uff0c\u572825\u2103\u4e0b\u6d4b\u8bd5\u4e86\u5176\u5e94\u529b\u677e\u5f1b\u66f2\u7ebf\u3002<\/p>\n

\u56fe9\uff1aATA-\u4f53\u7cfb\u4e2dE\u2032 (a) \u548ctan \u03b4 (b)\u4e0e\u6e29\u5ea6\u7684\u4f9d\u8d56\u7279\u6027<\/strong><\/p>\n

\"9\"<\/p>\n

\u4e3a\u4e86\u7b2c\u4e00\u6b65\u8ba8\u8bba\u727a\u7272\u65ad\u88c2\u952e\u7684\u70ed\u884c\u4e3a\uff0c\u56fe\u4e2d\u4e3a\u5b9e\u9a8c\u6240\u505a\u7684\u50a8\u5b58\u6a21\u91cfE\u2032\u548c\u6297\u6e7f\u6ed1\u6027tan \u03b4\u4e0e\u6e29\u5ea6\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n

\u56fe10\uff1a\u4e0d\u540c\u586b\u5145\u6750\u6599\u7684\u6297\u88c2\u6027<\/strong><\/p>\n

\"10\"<\/p>\n

\u4e3a\u4e86\u7814\u7a76\u65ad\u88c2\u7f51\u7edc\u5bf9\u4e8e\u6a61\u80f6\u75b2\u52b3\u6027\u7684\u5f71\u54cd\uff0c\u56fe\u4e2d\u4e3a\u586b\u5145\u4e86\u70ad\u9ed1\u4e4b\u540e\u4e0d\u540c\u6750\u6599\u7684\u6320\u66f2\u5f00\u88c2\u6d4b\u8bd5\u3002<\/p>\n

\u56fe11\uff1a\u5728\u7279\u6027\u5f20\u529b\u4e0b\u7684\u4e0d\u540c\u6750\u6599\u7684XRD\u56fe\u8c31<\/strong><\/p>\n

\"11\"<\/p>\n

\u4e3a\u4e86\u63a2\u7d22\u6750\u6599\u6297\u75b2\u52b3\u5f3a\u5ea6\u663e\u8457\u63d0\u9ad8\u7684\u539f\u56e0\u4e0eSiC\u7f51\u7edc\u4e2d\u727a\u7272\u952e\u8d77\u5230\u7684\u4f5c\u7528\uff0c\u56fe\u4e2d\u4e3a\u4e0d\u540c\u6750\u6599\u7684XRD\u7684\u7ebf\u6027\u884d\u5c04\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u901a\u8fc7\u52a0\u5165\u6c22\u952e\u548c\u7528ZnATA-0\u586b\u5145\uff0c\u53ef\u4ee5\u8ba4\u4e3a\u662f\u5f15\u5165\u4e86\u66f4\u591a\u7684\u7a7a\u8154\uff0c\u7531\u4e8e\u6c22\u952e\u7684\u65ad\u88c2\u5728\u4ea4\u53d8\u8f7d\u8377\u4e0b\u7684\u88c2\u7eb9\u5c16\u7aef\u9644\u8fd1\u3002\u901a\u8fc7\u6320\u66f2\u6d4b\u8bd5\u663e\u793a\u7a7a\u8154\u819c\u88ab\u6495\u88c2\uff0c\u5bfc\u81f4\u7a7a\u6d1e\u5408\u5e76\uff0c\u6467\u6bc1\u4e86\u88c2\u7eb9\u5c16\u7aef\u548c\u963b\u6b62\u4e86\u5782\u76f4\u53d7\u529b\u65b9\u5411\u7834\u88c2\u7684\u4f20\u64ad\u3002\u7531\u4e8e\u950c\u57fa\u56e2\u8f83\u5f3a\u7684\u5f3a\u5ea6\uff0c\u63ba\u5165\u4ee5\u950c\u4e3a\u57fa\u7840\u7684\u5355\u4f4d\u76f8\u5f53\u4e8e\u589e\u52a0\u4e86\u5fc5\u8981\u7684\u80fd\u91cf\uff0c\u6253\u7834\u4e86\u88c2\u7eb9\u5c16\u7aef\u7684\u952e\u7ed3\u5408\u3002\u5728\u6320\u66f2\u5f00\u88c2\u6d4b\u8bd5\u4e2d\uff0c\u6c22\u952e\u4f18\u5148\u65ad\u88c2\uff0c\u7d27\u63a5\u7740\u950c\u57fa\u5355\u5143\u7834\u88c2\uff0c\u8fd9\u4e9b\u65ad\u88c2\u6d88\u6563\u4e86\u4f53\u7cfb\u4e2d\u7684\u80fd\u91cf\u3002\u53e6\u5916\u7531\u4e8e\u52a8\u6001\u5b66\u7684\u539f\u56e0\uff0c\u65ad\u88c2\u952e\u53ef\u80fd\u4f1a\u8fc5\u901f\u5730\u7ed3\u5408\u5728\u4e00\u8d77\u963b\u6b62\u4e86\u7a7a\u6d1e\u819c\u7684\u6495\u88c2\u3002\u56e0\u6b64\u4e5f\u5927\u5927\u63d0\u9ad8\u4e86\u6320\u66f2\u5f00\u88c2\u5f3a\u5ea6\u3002\u5176\u4e2d\u51c6\u786e\u7684\u7269\u7406\u56fe\u50cf\u5728\u672a\u6765\u6709\u5f85\u4e8e\u8fdb\u4e00\u6b65\u7684\u53d1\u73b0\u3002\u7136\u800c\u4f5c\u8005\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u63d0\u9ad8\u6750\u6599\u6297\u75b2\u52b3\u5f3a\u5ea6\u7684\u4e00\u4e2a\u91cd\u8981\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Bioinspired Engineering of Two Different Types of Sacrificial Bonds into Chemically Cross-Linked cis-1,4-Polyisoprene toward a High-Performance Elastomer <\/a>\uff08Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b01576\uff09<\/p>\n

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