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1\u3001\u7b80\u4ecb<\/strong><\/p>\n

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\u672c\u6587\u7740\u91cd\u63cf\u8ff0\u4e86\u5728\u5171\u8f6d\u805a\u5408\u7269\u4e2d\u591a\u7ea7\u7535\u5b50\u4f20\u8f93\u7684\u7814\u7a76\uff0c\u4ece\u65e0\u5e8f\u819c\uff0c\u5355\u8f74\u5bf9\u79f0\u819c\u5230\u5355\u6676\u5206\u5b50\u5668\u4ef6\uff08\u56fe1\uff09\u3002\u5176\u4e2d\u5e26\u6709\u786b\u5316\u4e59\u9170\u7aef\u57fa\u7684\u521a\u6027\u6746\u72b6\u5171\u8f6d\u805a\u5408\u7269\u662f\u7814\u7a76\u4eba\u5458\u6700\u521d\u7684\u7814\u7a76\u76ee\u6807\u3002\u539f\u56e0\u5728\u4e8e\u8fd9\u79cd\u7ed3\u6784\u5177\u6709\u826f\u597d\u7684\u4f20\u5bfc\u6027\u548c\u81ea\u7ec4\u88c5\u80fd\u529b\uff08\u56fe1\uff09\u3002TA-PPE\u7684\u7aef\u57fa\u5b98\u80fd\u56e2\u80fd\u5f62\u6210Au-S\u952e\uff0c\u5728\u5206\u5b50\u8bbe\u5907\u4e2d\u8d77\u5230\u91d1\u5c5e\u7535\u6781\u7684\u4f5c\u7528\u3002\u7ecf\u8fc7\u5927\u91cf\u7684\u7814\u7a76\u6211\u4eec\u53d1\u73b0\u63d0\u9ad8TA-PPE\u805a\u5408\u7269\u94fe\u7684\u6709\u5e8f\u5ea6\u53ef\u5927\u5927\u63d0\u9ad8\u7535\u5b50\u4f20\u8f93\u6548\u7387\u3002\u540c\u65f6\u4e5f\u8bc1\u660e\u4e86\u7535\u5b50\u662f\u901a\u8fc7\u5171\u8f6d\u805a\u5408\u7269\u4e3b\u5e72\u4f20\u8f93\u3002\u5bf9\u4e8eTA-PPE\u4ee5\u53ca\u5176\u4ed6\u4e00\u4e9b\u805a\u5408\u7269\u7684\u7535\u5b50\u4f20\u8f93\u673a\u5236\u7684\u7814\u7a76\u7ed9\u4eba\u4eec\u63d0\u4f9b\u4e86\u805a\u5408\u7269\u548c\u5206\u5b50\u8bbe\u5907\u76f8\u7ed3\u5408\u7684\u65b0\u89c6\u89d2\uff0c\u540c\u65f6\u4e5f\u4e3a\u7814\u7a76\u5fae\u7eb3\u5c3a\u5ea6\u7684\u5206\u5b50\u8bbe\u5907\u6253\u5f00\u4e86\u4e00\u6247\u65b0\u7684\u5927\u95e8\u3002<\/p>\n

2\u3001\u5171\u8f6d\u805a\u5408\u7269\u65e0\u5e8f\u8584\u819c<\/strong><\/p>\n

\u805a\u82ef\u919a\uff08PPEs\uff09\u662f\u5171\u8f6d\u805a\u5408\u7269\u4e2d\u4e00\u4e2a\u91cd\u8981\u7684\u7c7b\u522b\uff0c\u5728PLEDs\u548c\u5316\u5b66\u8367\u5149\u4f20\u611f\u4e2d\u7531\u4e8e\u5176\u53d1\u51b7\u5149\u7684\u6027\u80fd\u6709\u5f88\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u5b83\u4eec\u7406\u60f3\u7684\u521a\u6027\u6746\u72b6\u7ed3\u6784\u4e5f\u6697\u793a\u5176\u6f5c\u5728\u7684\u9ad8\u7535\u5b50\u8f93\u8fd0\u6027\u80fd\u3002\u4f46\u662f\u8fd9\u7c7b\u6750\u6599\u7684\u5149\u7535\u6027\u80fd\u5374\u5f88\u5c11\u88ab\u7814\u7a76\u3002\u7814\u7a76\u4eba\u5458\u9009\u7528PEETs\u548c\u5149\u7535\u8f6c\u6362\u8bbe\u5907\u6765\u6d4b\u8bd5\u5b83\u4eec\u7684\u5149\u7535\u6027\u80fd\u3002\u57fa\u4e8eSi\/SiO2\u57fa\u5e95\uff0c\u65cb\u6d82\u5236\u5907\u7684TA-PPE\u8584\u819c\u548c\u9876\u7aef\u63a5\u89e6PEETs\u9996\u6b21\u4f5c\u4e3a\u6e90\u6781\u548c\u6f0f\u6781\u4f7f\u7528\uff08\u56fe2a\uff09\u3002\u6700\u521d\u7684\u7814\u7a76\u8868\u660eTA-PPE\u6709\u5178\u578b\u7684P\u578b\u573a\u6548\u5e94\u6027\u80fd\uff0c\u4f46\u662f\u5176\u7535\u5b50\u4f20\u8f93\u6027\u4ec5\u670910-6<\/sup>-10-15<\/sup>cmv-1<\/sup>s-1<\/sup>\uff0c\u5149\u7535\u5bfc\u4ec5\u4e3a~2.49\u00a0\u00d710-15<\/sup>S cm-1<\/sup>\uff0c\u57285.76mW cm-2<\/sup>\u5149\u8f90\u7167\u4e0b\u5f00\u5173\u6bd4\u4f8b\u4e3a8-12\uff08\u56fe2c-f\uff09\u3002\u9020\u6210\u8fd9\u79cd\u73b0\u8c61\u7684\u4e3b\u8981\u539f\u56e0\u662f\u805a\u5408\u7269\u94fe\u7684\u6df7\u4e71\u548c\u65cb\u6d82\u805a\u5408\u7269\u8584\u819c\u65f6\u5f15\u5165\u7f3a\u9677\uff08\u56fe2b\uff09\u3002<\/p>\n

\"ar-2016-00368v_0003\"<\/p>\n

\u56fe2<\/strong> TA-PPE\u65e0\u5e8f\u819c\u72b6\u7ed3\u6784\u7684\u6676\u4f53\u7ba1\u548c\u5149\u8f6c\u6362\u5668<\/p>\n

3\u3001\u5171\u8f6d\u805a\u5408\u7269\u7684\u6709\u5e8f\u819c<\/strong><\/p>\n

\u7531\u4e8e\u7535\u5b50\u8fd0\u8f93\u6cbf\u805a\u5408\u7269\u9aa8\u67b6\u7684\u65b9\u5411\uff0c\u805a\u5408\u7269\u5206\u5b50\u5c55\u73b0\u51fa\u5404\u5411\u5f02\u6027\u56e0\u6b64\u94fe\u5185\u7684\u7535\u5b50\u79fb\u52a8\u5728\u5355\u94fe\u4e2d\u5c06\u4f1a\u9ad8\u4e8e\u8584\u819c\u7ed3\u6784\uff0c\u5728\u8584\u819c\u4e2d\u5efa\u7acb\u6700\u4f18\u5316\u7684\u805a\u5408\u7269\u6392\u5217\u6210\u4e3a\u7814\u7a76\u7684\u4e00\u4e2a\u91cd\u8981\u7684\u65b9\u5411\u3002<\/p>\n

\u73b0\u884c\u6709\u5f88\u591a\u6280\u672f\u80fd\u591f\u5e94\u7528\u4e8e\u6750\u6599\u7684\u6392\u5217\uff0c\u4f8b\u5982\uff1a\u201c\u6469\u64e6\u8f6c\u79fb\u6280\u672f\u201d\u5c31\u662f\u4e00\u79cd\u80fd\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6821\u51c6\u4e0d\u540c\u6750\u6599\u6392\u5217\u7684\u9ad8\u6548\u6280\u672f\u3002\u7136\u800cPPEs\u94fe\u72b6\u805a\u5408\u7269\u548c\u4e00\u4e9b\u7cbe\u7ec6\u7684\u7ed3\u6784\u9886\u57df\u5374\u672a\u6d89\u53ca\u3002\u4e3a\u4e86\u80fd\u6df1\u5165\u7684\u4e86\u89e3TA-PPE\u94fe\u7684\u81ea\u7ec4\u88c5\u3002\u7814\u7a76\u4eba\u5458\u5c06\u7ed3\u5408\u6d47\u7b51\u81ea\u7ec4\u88c5\u548c\u6469\u64e6\u8f6c\u6362\u6280\u672f\u6765\u8fbe\u5230\u8fd9\u4e00\u76ee\u7684\u3002\u5728PTFE\u57fa\u5e95\u7684\u5236\u5907\u4e2d\u91c7\u7528\u7684\u65b9\u6cd5\u662f\u4ee5\u4e00\u4e2a\u6301\u7eed\u7684\u538b\u529b\u6469\u64e6\u57fa\u5e95\uff0c\u5728\u6469\u64e6\u7684\u65b9\u5411\u5219\u4f1a\u6392\u5217\u51fa\u94fe\u72b6PTFE\uff0c\u7136\u540e\u901a\u8fc7\u5728\u4f4e\u84b8\u53d1\u7684\u7f50\u5b50\u5185\u6ef4\u6ce8\u5165TA-PPE\u56db\u6c22\u544b\u5583\u6eb6\u6db2\u5230\u4e00\u5b9a\u53d6\u5411\u7684PTFE\u5c42\u4e0a\uff08\u56fe3b\uff09\u6765\u83b7\u5f97\u4e00\u5b9a\u53d6\u5411\u7684TA-PPE\u8584\u819c\u3002\u8fd9\u6837TA-PPE\u94fe\u5c31\u80fd\u6cbfPTFE\u6ed1\u79fb\u7684\u65b9\u5411\u5f62\u6210\u3002\u901a\u8fc7AFM\u548cUV-vis\u5438\u6536\u548c\u5149\u5b66\u5fae\u89c2\u56fe\uff08\u56fe3c-f\uff09\u53ef\u8bc1\u5b9e\u4ea7\u7269\u7ed3\u6784\u3002<\/p>\n

\"ar-2016-00368v_0004\"<\/p>\n

\u56fe3<\/strong> \u6709\u5e8f\u819c\u7ed3\u6784\u7684\u5f62\u6210\u548c\u8868\u5f81<\/p>\n

PFET\u53ef\u8fdb\u4e00\u6b65\u901a\u8fc7\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u4e09\u6c2f\u7845\u70f7\uff08OTS\uff09\u4fee\u9970\u7684\u5355\u5206\u5b50\u57fa\u5e95\u4e0a\u6709\u5e8fTA-PPE\u819c\u6765\u5236\u5907\uff08\u56fe4a\uff09\u3002\u5728\u6d3b\u6cfc\u5c42\uff0c\u805a\u5408\u7269\u4ee5\u5782\u76f4\u57fa\u5e95\u8fb9\u754c\u7684\u65b9\u5411\u6392\u5217\u3002\u8fd9\u6837\u80fd\u663e\u8457\u63d0\u9ad8\u805a\u5408\u7269\u8584\u819c\u4e8c\u7ef4\u65b9\u5411\u4e0a\u7684\u7535\u5b50\u4f20\u8f93\uff08\u56fe4b\uff09\u3002\u8fd9\u79cdPFETs\u5177\u6709~4.3\u00d710-3<\/sup>cm2<\/sup>v-1<\/sup>s-1<\/sup>\u7684\u7535\u5b50\u4f20\u8f93\u6548\u7387\uff0c3.8×104<\/sup>\u7684\u5f00\u5173\u6bd4\u7387\u548c-28v\u7684\u9608\u503c\u7535\u538b\u3002\u8fd9\u4e9b\u660e\u786e\u7684\u8868\u660e\u4e86\u7ecf\u8fc7\u4f18\u5316\u540e\u7684TA-PPE\u8584\u819c\u7535\u5b50\u4f20\u8f93\u6027\u80fd\u7684\u663e\u8457\u63d0\u9ad8\u3002<\/p>\n

\u5171\u8f6d\u805a\u5408\u7269\u6709\u5e8f\u8584\u819c\u4e0d\u5149\u6709\u5229\u4e8e\u7535\u5b50\u4f20\u8f93\uff0c\u540c\u6837\u8fd8\u80fd\u63d0\u9ad8\u7535\u5b50\u7684\u6fc0\u53d1\u3002\u4e3a\u4e86\u8bc1\u660e\u8fd9\u4e00\u70b9\uff0c\u7814\u7a76\u4eba\u5458\u6d4b\u91cf\u4e86\u57fa\u4e8e\u6392\u5217\u597d\u7684TA-PPE\u8584\u819c\u57fa\u5e95\u7684\u5149\u7535\u8bbe\u5907\u7684\u5149\u7535\u7075\u654f\u5ea6\uff0c\u7ed3\u679c\u663e\u793a\u5728\u56fe4e\u3002\u4ece\u4e2d\u80fd\u5f88\u660e\u663e\u7684\u770b\u51fa\u8fd9\u79cd\u5149\u7535\u8bbe\u5907\u5de5\u4f5c\u72b6\u51b5\u826f\u597d\uff0c\u57285.76mW cm-2<\/sup>\u4ece\u5149\u7167\u4e0b\uff0c\u5177\u6709\u6709\u5e8f\u5206\u5b50\u6392\u5217\u7ed3\u6784\u7684\u8bbe\u5907\u7535\u6d41\u548c\u7535\u538b\u8fbe\u5230\u4e862.65nA\u548c20V\u3002\u8fd9\u6bd4\u540c\u6761\u4ef6\u7684\u8bbe\u5907\u9ad8\u51fa\u4e86\u5f88\u591a\uff08\u56fe2e\uff09\u3002\u53e6\u4e00\u65b9\u9762\u5f53\u5de5\u4f5c\u5728\u5149\u4ece\u6709\u5230\u65e0\u7684\u8f6c\u53d8\u6761\u4ef6\u4e0b\uff0c\u8bbe\u5907\u5c06\u5904\u4e8e\u9ad8-\u4f4e\u7535\u6d41\u4ea4\u66ff\u7684\u5de5\u4f5c\u6761\u4ef6\uff0c\u8f6c\u6362\u80fd\u529b\u8fbe\u5230\u4e86330-400\uff0c\u6bd4\u65e0\u5e8f\u819c\u9ad8\u51fa\u4e86\u51e0\u5341\u500d\uff08\u56fe2f\uff09<\/p>\n

\"ar-2016-00368v_0005\"<\/p>\n

\u56fe4<\/strong> PFET\u6a21\u578b\u53ca\u76f8\u5173\u6027\u8d28\u6d4b\u8bd5<\/p>\n

4\u3001\u5fae\u89c2\u548c\u7eb3\u7c73\u5c3a\u5bf8\u4e0b\u7684\u5355\u6676<\/strong><\/p>\n

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\"ar-2016-00368v_0006\"<\/p>\n

\u56fe5<\/strong> TA-PPE\u7eb3\u7c73\u7ebf\u8868\u5f81\u53ca\u76f8\u5173\u6027\u80fd\u6d4b\u8bd5<\/p>\n

5\u3001\u5355\u5c42\u5171\u8f6d\u805a\u5408\u7269<\/strong><\/p>\n

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\"ar-2016-00368v_0007\"<\/p>\n

\u56fe6<\/strong> TTF-PPE\u7ed3\u6784\u56fe\u53ca\u76f8\u5173\u6027\u80fd\u6d4b\u8bd5<\/p>\n

6\u3001\u5171\u8f6d\u805a\u5408\u7269\u7684\u5206\u5b50\u8bbe\u5907<\/strong><\/p>\n

\u5355\u5c42\u819c\u805a\u5408\u7269\u63d0\u4f9b\u4e86\u4e00\u4e2a\u7814\u7a76\u5176\u7535\u5b50\u4f20\u8f93\u7684\u673a\u5236\u3002\u7136\u800c\u805a\u5408\u7269\u94fe\u4e0a\u7684\u7535\u5b50\u4f20\u8f93\u4f9d\u7136\u5f88\u4e0d\u660e\u6717\u3002Hoofman\u901a\u8fc7\u7a00\u6eb6\u5242\u8109\u51b2\u8f90\u89e3\u548c\u65f6\u95f4\u5206\u8fa8\u7684\u5fae\u6ce2\u4f20\u5bfc\uff08TRMC\uff09\u6280\u672f\u7814\u7a76\u4e86\u5b64\u7acb\u534a\u5bfc\u4f53\u805a\u5408\u7269\u94fe\u7684\u7535\u5b50\u4f20\u8f93\uff0c\u53d1\u73b0\u6cbf\u805a\u5408\u7269\u94fe\u4e0a\u7535\u5b50\u4f20\u8f93\u6bd4\u5e73\u9762\u4f20\u8f93\u9ad84\u4e2a\u91cf\u7ea7\u3002Terao\u62a5\u9053\u4e86\u4e00\u4e2a\u5728\u5206\u5b50\u7ed3\u6784\u4e2d\u7535\u5b50\u4f20\u8f93\u7684\u9ad8\u6548\u9014\u5f84\u3002\u901a\u8fc7TRMC\u6d4b\u91cf\uff0c\u53d1\u73b0\u4ece\u5206\u5b50\u8bbe\u8ba1\u89d2\u5ea6\u4e0a\u6765\u8bf4\uff0c\u6301\u7eed\u63a7\u5236\u94fe\u4e2d\u70ed\u8fd0\u52a8\u7684\u6563\u5c04\uff0c\u805a\u5408\u7269\u03c0\u5171\u8f6d\u8f68\u9053\u53ea\u5728\u4f4e\u6e29\u4e0b\u4f1a\u5f15\u8d77\u9891\u6ce2\u4f20\u5bfc\uff0c\u4ece\u800c\u8fbe\u52308.5cm2<\/sup>v-1<\/sup>s-1<\/sup>\u7684\u9ad8\u8fc1\u79fb\u7387\u3002\u4e3a\u4e86\u4e86\u89e3\u5b9e\u9645\u7eb3\u7c73\u5c3a\u5bf8\u4e2d\u7535\u8377\u6cbf\u94fe\u4f20\u9012\u7684\u65b9\u5f0f\uff0c\u524d\u63d0\u662f\u5c06\u94fe\u56fa\u5b9a\u5728\u4e24\u5c42\u5f88\u7a84\u7684\u7535\u6781\u4e2d\u3002\u5176\u4e2d\u5b58\u5728\u4e24\u4e2a\u6311\u6218\uff1a\u4e00\u662f\u5982\u4f55\u5236\u5907\u5339\u914d\u7684\u7eb3\u7c73\u7535\u6781\uff0c\u53e6\u5916\u5219\u662f\u5982\u4f55\u5c06\u94fe\u56fa\u5b9a\u5728\u4e24\u6781\u4e4b\u95f4\u3002\u4e3a\u4e86\u8fbe\u5230\u8fd9\u4e00\u76ee\u7684\uff0c\u6709\u51e0\u79cd\u65b9\u6cd5\u6765\u5236\u5907\u8fd9\u79cd\u5c0f\u7f1d\u9699\u7ed3\u6784\u3002\u5148\u53ef\u901a\u8fc7\u7535\u5b50\u663e\u5fae\u6280\u672f\u5728\u4e9a\u5fae\u7c73\u7684\u7535\u6781\u6c9f\u9053\u4e2d\u7535\u9540\u4e0a\u5bbd\u5ea6\u4e3a20~100nm\u7684\u91d1\u7535\u6781\uff0c\u8fd8\u53ef\u4ee5\u5229\u7528\u7eb3\u7c73\u7ebf\u6676\u4f53\u4f5c\u4e3a\u6a21\u5177\u6765\u5f97\u52309nm\u7684\u91d1\u7535\u6781\uff0c\u53e6\u5916\u8fd8\u80fd\u5229\u7528\u7eb3\u7c73\u7ebf\u6676\u4f53\u4f5c\u4e3a\u6a21\u5177\u6765\u5f97\u52309nm\u7684\u91d1\u7535\u6781\uff0c\u6216\u8005\u53ef\u4ee5\u901a\u8fc7\u6253\u7834\u6676\u754c\u8fde\u63a5\u5f97\u52301-2nm\u7684\u7535\u6781\u7f1d\u9699\u3002\u8fd9\u4e9b\u7eb3\u7c73\u7535\u6781\u63d0\u4f9b\u4e86\u7814\u7a76\u4eba\u5458\u4e00\u4e2a\u5f88\u597d\u7684\u5e73\u53f0\u6765\u6df1\u5165\u7814\u7a76\u7eb3\u7c73\u5c3a\u5ea6\u7684\u5206\u5b50\u8bbe\u5907\u3002\u4f8b\u5982\u57fa\u4e8e\u5e73\u9762\u7eb3\u7c73\u7535\u6781\uff0c\u7814\u7a76\u4eba\u5458\u572870-TA-PPE\u5206\u5b50\u4e0a\u5236\u5907\u4e86\u4ee5\u4f20\u7edf\u94fe\u7ed3\u5408\u7ea640nm\u7684TA-PPE\u7535\u6781\u3002TA-PPE\u7eb3\u7c73\u8bbe\u5907\u7ecf\u6d4b\u8bd5\u5448\u73b0\u51fa\u660e\u663e\u7684\u975e\u7ebf\u6027\uff0c\u8bc1\u660e\u7535\u5b50\u6ce8\u5165\u662f\u901a\u8fc7\u96a7\u9053\u6548\u5e94\u3002\u7531\u4e8e\u5176\u5728\u5149\u7167\u4e0b\u7535\u5b50\u80fd\u6709\u8db3\u591f\u7684\u80fd\u91cf\u7a7f\u8fc7\u91d1\u786b\u7684\u5e26\u9699\u96a7\u9053\uff08\u56fe7\uff09\uff0c\u8fd9\u4e9b\u7eb3\u7c73\u8bbe\u5907\u540c\u65f6\u4e5f\u8868\u73b0\u51fa\u5149\u63a7\u6548\u5e94\uff0c\u4ece\u800c\u53ef\u4ee5\u4f5c\u4e3a\u5149\u7535\u8f6c\u6362\u8bbe\u5907\u3002<\/p>\n

\"ar-2016-00368v_0008\"<\/p>\n

\u56fe7<\/strong> TA-PPE\u7eb3\u7c73\u8bbe\u5907\u539f\u7406\u53ca\u76f8\u5173\u6027\u80fd\u6d4b\u8bd5\u56fe<\/p>\n

\u5229\u7528\u886c\u5e95Si\u505a\u4e3a\u7535\u6781\uff0c\u6574\u4e2a\u8bbe\u5907\u8f6c\u6362\u4e3a\u4e00\u4e2a\u5177\u6709\u5178\u578bP\u4f20\u8f93\u7279\u6027\u7684\u7eb3\u7c73\u6676\u4f53\u7ba1\uff0c\u5e76\u4e14\u62e5\u6709\u9ad8\u7684\u9707\u8361\u5f00\u542f\u7535\u538b\u3002\u6d3b\u6cfc\u7684\u5171\u8f6dTA-PPE\u5c42\u5c31\u50cf\u91cf\u5b50\u70b9\u8bbe\u5907\u4e2d\u7684\u91cf\u5b50\uff0c\u786b\u7aef\u57fa\u72b9\u5982\u4e24\u4e2a\u96a7\u9053\u7684\u8fb9\u963b\u3002\u4e3a\u4e86\u80fd\u66f4\u597d\u7684\u63a2\u6d4bTA-PPE\u5206\u5b50\u5c3a\u5bf8\u8bbe\u5907\u7684\u6027\u80fd\uff0c \u7814\u7a76\u4eba\u5458\u5c06TA-PPE\u7f29\u5c0f\u523024-TA-PPE\u7684\u4f4e\u805a\u7269\uff0818.3nm\u957f\uff09\uff0c\u5e76\u4ee5\u5927\u7ea618nm\u7684\u7535\u6781\u7f1d\u9699\u6765\u5339\u914d\u3002\u57fa\u4e8e\u8fd9\u79cd\u5206\u5b50\u5668\u4ef6\uff0c\u5728\u5ba4\u6e29\u4e0b\u7814\u7a76\u4eba\u5458\u89c2\u5bdf\u5230\u4e86\u975e\u5e38\u6709\u8da3\u7684I-V\u7279\u6027\uff08\u56fe8b\uff0cc\uff09\u3002\uff081\uff09\u9ad8\u7684\u5468\u671f\u6027\u548c\u53ef\u91cd\u590d\u7684\u6e10\u53d8\u6027\u3002\uff082\uff09\u76f8\u90bb\u7ea7\u522b\u7684\u5206\u79bb\u7535\u538b\u7ea6\u4e3a0.23-0.26v\u3002\uff083\uff09\u7535\u538b\u53cd\u8f6c\u540eI-V\u66f2\u7ebf\u7684\u4e0d\u5bf9\u79f0\u6027\u3002I-V\u66f2\u7ebf\u6700\u597d\u7684\u7ea7\u522b\u4e0d\u662f\u7531\u4e8e\u7535\u5bfc\u7684\u91cf\u5316\uff0c\u56e0\u4e3a\u6700\u9ad8\u7ea7\u522b\u6bd4\u91cf\u5316\u6a21\u5f0f\u4f4e\u51e0\u4e2a\u91cf\u7ea7\u3002\u539f\u56e0\u4e0d\u80fd\u5f52\u7ed3\u5230\u90a3\u4e9b\u4f1a\u5f71\u54cd\u7ed3\u6784\u7684\u5206\u5b50\u5f62\u53d8\u6216\u7f3a\u9677\u3002\u867d\u7136\u805a\u5408\u7269\u5206\u5b50\u662f\u901a\u8fc7\u5316\u5b66\u952e\u5c06\u7aef\u57fa\u548c\u91d1\u7535\u6781\u76f8\u8fde\u3002\u5171\u8f6d\u805a\u5408\u7269\u7684\u03c0\u8f68\u9053\u5e76\u4e0d\u80fd\u5f71\u54cd\u5230\u7535\u6781\u3002\u81ea\u7ec4\u88c5\u7684\u7eb3\u7c73\u70b9\u53ef\u80fd\u4e0e\u91cf\u5b50\u70b9\u76f8\u4f3c\u3002\u5171\u8f6d\u805a\u5408\u7269\u4f5c\u4e3a\u91cf\u5b50\u70b9\uff0c\u7aef\u57fa\u786b\u539f\u5b50\u626e\u6f14\u96a7\u9053\u963b\u788d\u3002\u8fd9\u6837\u7b80\u4fbf\u7684\u673a\u5236\u53ef\u80fd\u4e0e\u7535\u5b50\u96a7\u9053\u7684\u5171\u632f\u6709\u5173\u3002\u66f2\u7ebf\u4e2d\u6bcf\u4e2a\u9636\u68af\u6240\u5bf9\u5e94\u7684\u72b6\u6001\u53ef\u80fd\u4e3a\u805a\u5408\u7269\u5206\u5b50\u5bfc\u7535\u7535\u8def\u7684\u5f00\u542f\u72b6\u6001\uff0c24\u805a\u5408\u7269\u7684I-V\u7279\u6027\u5728\u56fe8b\uff0cc\u4e2d\u663e\u793a\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c\u7406\u8bba\u548c\u5b9e\u8df5\u7ed3\u5408\u7684\u975e\u5e38\u597d\u300224\u805a\u5408\u7269\u4e2d\u5f88\u597d\u5206\u9694\u5f00\u7684\u5206\u5b50\u8f68\u9053\u662f\u9636\u68af\u5f62I-V\u66f2\u7ebf\u5f62\u6210\u7684\u539f\u56e0\u3002\u4e0d\u540c\u7684\u9636\u6bb5\u5bf9\u5e94\u4e0d\u540c\u7684\u5f00\u542f\u7535\u538b\u3002\u901a\u8fc7\u8ba1\u7b97\u5f97\u5230\u4e0d\u540c\u9636\u6bb5\u7684\u5f00\u542f\u7535\u538b\u5927\u7ea6\u4e3a0.26V\u5de6\u53f3\uff0c\u4e0e\u5b9e\u9a8c\u5f97\u5230\u76840.23-0.26V\u5341\u5206\u543b\u5408\uff0c\u53ef\u4ee5\u53d1\u73b018nm\u573a\u7684TA-PPE\u7684\u7535\u5b50\u7ed3\u6784\u4ecd\u5177\u6709\u91cf\u5b50\u7279\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\u57282.5V\u4ee5\u4e0b\u7684\u5b9e\u9a8c\u6570\u636e\u548c\u8ba1\u7b97\u5f97\u5230\u7684\u6709\u6240\u4e0d\u540c\uff0c\u5176\u539f\u56e0\u53ef\u80fd\u662f\u6a21\u578b\u4e2d\u6ca1\u6709\u8003\u8651\u8d39\u7c73\u80fd\u7ea7\u548c\u5355\u7535\u5b50\u6548\u5e94\u3002<\/p>\n

7\u3001\u603b\u7ed3\u548c\u5c55\u671b<\/strong><\/p>\n

\u7531\u4e8e\u81ea\u7136\u754c\u4e2d\u5b58\u5728\u56fa\u4f53\u57fa\u805a\u5408\u7269\u4f53\u7cfb\u7684\u65e0\u5e8f\u6027\uff0c\u805a\u5408\u7269\u7535\u5b50\u4f20\u8f93\u673a\u5236\u7684\u7814\u7a76\u4f9d\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u672c\u6587\u4e2d\u4ee5TA-PPE\u5171\u8f6d\u805a\u5408\u7269\u4e3a\u4f8b\uff0c\u4f9d\u636e\u805a\u5408\u7269\u7684\u4f20\u8f93\u7279\u6027\u5f15\u5165\u4e86\u591a\u7ea7\u7814\u7a76\u6a21\u578b\uff0c\u4ece\u65e0\u5e8f\u819c\uff0c\u6709\u5e8f\u819c\uff0c\u5fae\u7eb3\u5c3a\u5ea6\u5355\u6676\u6709\u4ee5\u4e0b\u7684\u53d1\u73b0\u3002<\/p>\n

1. \u5728\u56fa\u4f53\u6750\u6599\u4e2d\u63d0\u9ad8\u805a\u5408\u7269\u7684\u6709\u5e8f\u5ea6\u80fd\u663e\u8457\u63d0\u9ad8\u5176\u6027\u80fd\u3002\u539f\u56e0\u5728\u4e8e\u51cf\u5c11\u4e86\u6676\u754c\u548c\u7535\u8377\u4f20\u8f93\u7f3a\u9677\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8\u94fe\u95f4\u7535\u5b50\u4f20\u8f93\u7684\u6027\u80fd\u3002<\/p>\n

2. \u5171\u8f6d\u805a\u5408\u7269\u5177\u6709\u4e00\u5b9a\u7684\u521a\u6027\u3002\u4f8b\u5982\u5728TA-PPE\u4e2d\u03c0-\u03c0\u952e\u5728\u7eb3\u7c73\u5355\u6676\u4e2d\u7684\u5806\u79ef\u65b9\u5411\u662f\u4e0e\u7eb3\u7c73\u7ebf\u7684\u957f\u8f74\u76f8\u5782\u76f4\u3002\u4e3b\u94fe\u662f\u4e0e\u957f\u8f74\u76f8\u5e73\u884c\uff0c\u8fd9\u662f\u4e0e\u4e4b\u524d\u9884\u60f3\u6240\u4e0d\u540c\u7684\u3002\u5728P3HT\u7eb3\u7c73\u6676\u4f53\u4e2d\u957f\u94fe\u662f\u4e0e\u957f\u8f74\u65b9\u5411\u5782\u76f4\u3002\u8fd9\u79cd\u65b0\u9896\u7684\u5806\u79ef\u65b9\u6cd5\u6709\u5229\u4e8e\u7814\u7a76\u805a\u5408\u7269\u94fe\u4e0a\u7684\u4f20\u8f93\u673a\u5236\u3002<\/p>\n

3. \u901a\u8fc7\u964d\u4f4e\u5206\u5b50\u5c3a\u5bf8\uff0c\u6709\u5f88\u591a\u65b0\u73b0\u8c61\u88ab\u89c2\u5bdf\u5230\u3002\u4f8b\u598218nm\u957fTA-PPE\u7684\u5927\u91cf\u91cf\u5b50\u5316\u7ed3\u6784\u3002TTF\u5355\u5143\u6c27\u5316\u8fd8\u539f\u4e2d\u5fc3\u7684\u8fc1\u79fb\uff0c\u8fd9\u4e5f\u4e3a\u5171\u8f6d\u805a\u5408\u7269\u5728\u7eb3\u7c73\u91cf\u5b50\u8bbe\u5907\u4e2d\u7684\u5e94\u7528\u5f00\u8f9f\u4e86\u4e00\u6247\u5927\u95e8\u3002<\/p>\n

4. \u5bf9\u591a\u7ea7\u5171\u8f6d\u805a\u5408\u7269\u591a\u7ea7\u7ed3\u6784\u7684\u7406\u89e3\u7ed9\u805a\u5408\u7269\u4e2d\u7535\u5b50\u4f20\u8f93\u673a\u5236\u7684\u63cf\u7ed8\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u7684\u9014\u5f84\uff0c\u4e5f\u5bf9\u5171\u8f6d\u805a\u5408\u7269\u673a\u5236\u7814\u7a76\u63d0\u51fa\u4e00\u4e2a\u957f\u671f\u6311\u6218\uff0c\u4e0e\u6b64\u540c\u65f6\u4e5f\u63d0\u4f9b\u4e86\u5f88\u591a\u5171\u8f6d\u805a\u5408\u7269\u7ed3\u5408\u7684\u65b0\u65b9\u5411\u3002\u5e76\u786e\u4fdd\u5176\u5728\u4e0b\u4e00\u4ee3\u7535\u5b50\u8bbe\u5907\u4e2d\u7684\u5e94\u7528\u7684\u53ef\u80fd\u3002<\/p>\n

\"ar-2016-00368v_0009\"<\/p>\n

\u56fe8<\/strong> TA-PPE\u5206\u5b50\u7ed3\u539f\u7406\u53ca\u5b9e\u9a8c\u548c\u7406\u8bba\u6027\u80fd\u5bf9\u6bd4\u56fe<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong> Multilevel Investigation of Charge Transport in Conjugated Polymers<\/a>\uff08Acc. Chem. Res., 2016, DOI:10.1021\/acs.accounts.6b00368\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u7ec4Aaron\u63d0\u4f9b\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002\uff08\u6587\u732e\u5168\u6587\u5df2\u4e0a\u4f20\u81f3\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4298064863\uff09<\/p>\n

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