{"id":5039,"date":"2016-03-30T08:00:10","date_gmt":"2016-03-30T00:00:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=5039"},"modified":"2016-03-29T23:31:28","modified_gmt":"2016-03-29T15:31:28","slug":"%e5%9f%ba%e4%ba%8e%e6%b0%a2%e8%b4%9f%e7%a6%bb%e5%ad%90%e4%bc%a0%e5%af%bc%e7%9a%84%e6%96%b0%e4%b8%80%e4%bb%a3%e6%bd%9c%e5%8a%9b%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=5039","title":{"rendered":"\u57fa\u4e8e\u6c22\u8d1f\u79bb\u5b50\u4f20\u5bfc\u7684\u65b0\u4e00\u4ee3\u6f5c\u529b\u7535\u6c60"},"content":{"rendered":"<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-5194 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72471-23.jpg\" alt=\"\u56fe\u72471-23\" width=\"799\" height=\"480\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72471-23.jpg 799w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72471-23-300x180.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72471-23-768x461.jpg 768w\" sizes=\"(max-width: 799px) 100vw, 799px\" \/><br \/>\nLa2-x-ySrx+yLiH1-x+yO3-y\u7684\u6676\u4f53\u7ed3\u6784\uff08x=0\uff0cy=0\uff0c1\uff0c2\uff09<\/p>\n<p><strong><b>\u6750\u6599\u725b\u6ce8<\/b><\/strong>\uff1a\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u79d1\u5b66\u5bb6\u4e0e\u5176\u65e5\u672c\u540c\u4e8b\u5408\u4f5c\uff0c\u5c55\u793a\u4e86\u7b2c\u4e00\u4e2a\u57fa\u4e8e\u6c27\u5316\u7269\u56fa\u6001\u7535\u6c60\u4e2d\u6c22\u8d1f\u79bb\u5b50\u4f20\u5bfc\u800c\u53d1\u751f\u7684\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u6b64\u4e3e\u6709\u671b\u7528\u4e8e\u4e0b\u4e00\u4ee3\u7535\u6c60\u3002<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u9887\u591a\u5173\u4e8e\u79bb\u5b50\u4f20\u5bfc\u7684\u7814\u7a76\uff0c\u5c24\u5176\u662f\u7528\u4e8e\u80fd\u6e90\u5668\u4ef6\u3002\u5982\u71c3\u6599\u7535\u6c60\uff0c\u4ee5\u53ca\u4f7f\u7528Li+\u3001H+\u3001Ag+\u3001Cu+\u3001F\u2013\u3001O2\u2013\u7b49\u7535\u6c60\u3002\u800c\u6700\u8fd1\u4e00\u9879\u7814\u7a76\u8868\u660e\uff0c\u6c22\u8d1f\u79bb\u5b50\u5bf9\u4e8e\u9ad8\u80fd\u5b58\u50a8\u5143\u4ef6\u6765\u8bf4\u53ef\u80fd\u975e\u5e38\u6709\u7528\u3002<\/p>\n<p>\u4e0d\u8fc7\uff0c\u91d1\u5c5e\u6c22\u5316\u7269\u8d8b\u5411\u5f62\u6210\u56fa\u5b9a\u7684\u70b9\u9635\u7ed3\u6784\uff0c\u8fd9\u4f7f\u5f97\u6c22\u8d1f\u79bb\u5b50\u4f20\u5bfc\u56f0\u96be\uff0c\u56e0\u6b64\u7814\u7a76\u8005\u8f6c\u800c\u7814\u7a76\u6c27\u3001\u6c22\u53ef\u5171\u5b58\u4e8e\u540c\u4e00\u533a\u57df\u7684\u6c27\u6c22\u5316\u7269\uff08\u6c22\u6c27\u5316\u7269\uff09\u3002\u6b64\u5916\uff0c\u6c22\u8d1f\u79bb\u5b50\u6613\u5206\u89e3\u4ea7\u751f\u8d28\u5b50\u548c\u7535\u5b50\uff0c\u5176\u4f9b\u7535\u5b50\u6027\u8d28\u4f18\u5f02\uff0c\u6700\u7ec8\u5bfc\u81f4\u7535\u5b50\u4f20\u5bfc\u800c\u975e\u6c22\u79bb\u5b50\u4f20\u5bfc\u3002<\/p>\n<p>\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66\u51e0\u4f4d\u79d1\u5b66\u5bb6\u56e2\u961f\uff0c\u8054\u5408\u65e5\u672c\u5206\u5b50\u79d1\u5b66\u7814\u7a76\u9662\u3001\u65e5\u672c\u79d1\u5b66\u6280\u672f\u603b\u5c40\u3001\u4eac\u90fd\u5927\u5b66\u3001\u65e5\u672c\u9ad8\u80fd\u52a0\u901f\u5668\u7814\u7a76\u7ec4\u7ec7\uff08KEK\uff09\u7b49\u5355\u4f4d\u7684\u540c\u4e8b\uff0c\u5bfb\u627e\u5230\u4e86\u4e00\u79cd\u5177\u6709\u66f4\u597d\u7684\u4f9b\u7535\u6027\u7684\u6b63\u79bb\u5b50\u4f53\u7cfb\uff08\u76f8\u8f83\u4e8e\u5355\u72ec\u7684\u6c22\u8d1f\u79bb\u5b50\uff09\uff0c\u4ece\u800c\u5c55\u5f00\u7814\u7a76\u3002\u968f\u6c27\u6c22\u5316\u5408\u7269\u7684\u6210\u5206\u4e0e\u5408\u6210\u6761\u4ef6\u7684\u6539\u53d8\uff0c\u7814\u7a76\u8005\u68c0\u6d4b\u4e86\u5176\u7ed3\u6784\u7684\u6539\u53d8\u3002\u540c\u65f6\u4ed6\u4eec\u901a\u8fc7\u7814\u7a76\u7535\u5b50\u7ed3\u6784\u7279\u5f81\uff0c\u53d1\u73b0\u5728\u6c27\u6c22\u5316\u5408\u7269\u4e2d\u6709Li-H\u952e\u7684\u5b58\u5728\uff0c\u4e5f\u5c31\u662f\u5728\u6c27\u5316\u7269\u4e2d\u786e\u5b9e\u6709\u6c22\u8d1f\u79bb\u5b50\u7684\u5b58\u5728\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-5195 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72472-12.jpg\" alt=\"\u56fe\u72472-12\" width=\"800\" height=\"480\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72472-12.jpg 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72472-12-300x180.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/03\/\u56fe\u72472-12-768x461.jpg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p style=\"text-align: center;\">\u7eafH-\u4f20\u5bfc\u7684\u6c27\u6c22\u5316\u7269\u6676\u4f53\u7ed3\u6784<\/p>\n<p>\u968f\u540e\uff0c\u7814\u7a76\u8005\u4f7f\u7528\u659c\u65b9\u76f8\u7684La2LiHO3\u4f5c\u4e3a\u7535\u89e3\u8d28\uff0c\u949b\u505a\u9633\u6781\uff0c\u6c22\u5316\u949b\u505a\u9634\u6781\u3002\u7ed3\u679c\u53d1\u73b0\uff0c\u8fde\u7eed\u653e\u7535\u540e\uff0c\u7535\u6781\u53d1\u751f\u53d8\u5316\u4e14Ti-H\u76f8\u4f4d\u56fe\u663e\u793a\u6c22\u8d1f\u79bb\u5b50\u53d1\u751f\u4f20\u5bfc\u3002\u7531\u6b64\u5b66\u8005\u8868\u793a\uff0c\u76ee\u524d\u5728\u5168\u56fa\u6001\u7535\u5316\u5b66\u7535\u6c60\u65b9\u9762\u53d6\u5f97\u7684\u6210\u7ee9\uff0c\u5373\u53d1\u73b0\u6c22\u8d1f\u79bb\u5b50\u4f20\u5bfc\uff0c\u8868\u660e\u5176\u4e0d\u4ec5\u4ec5\u53ef\u5728\u6c22\u6c27\u5316\u7269\u4e2d\u4f5c\u4e3aH\u2013\u56fa\u6001\u7535\u6781\uff0c\u518d\u8005\u53ef\u57fa\u4e8e\u6b64\u5f00\u53d1\u7535\u5316\u5b66\u56fa\u6001\u5143\u4ef6\u3002<\/p>\n<p><strong><b>\u7535\u6c60\u548c\u71c3\u6599\u7535\u6c60<\/b><\/strong><\/p>\n<p>\u7535\u6c60\u548c\u71c3\u6599\u7535\u6c60\u90fd\u5c5e\u4e8e\u7535\u5316\u5b66\u5143\u4ef6\u3002\u4f8b\u5982\u5728\u9502\u7535\u6c60\u4e2d\uff0c\u9502\u79bb\u5b50\u4ece\u9633\u6781\u79fb\u52a8\u5230\u9634\u6781\uff0c\u5145\u7535\u8fc7\u7a0b\u4e2d\u518d\u539f\u8def\u8fd4\u56de\uff0c\u79bb\u5b50\u901a\u8fc7\u7535\u89e3\u8d28\u5728\u7535\u6781\u95f4\u4e0d\u65ad\u4f20\u9012\u3002\u9502\u7535\u6c60\u73b0\u5982\u4eca\u5e7f\u6cdb\u7528\u4e8e\u79fb\u52a8\u8bbe\u5907\uff0c\u540c\u65f6\u4eba\u4eec\u4e5f\u5728\u5c1d\u8bd5\u901a\u8fc7\u6539\u5584\u80fd\u91cf\u5bc6\u5ea6\u3001\u6027\u80fd\u548c\u73af\u4fdd\u6027\u7ee7\u7eed\u6269\u5927\u5176\u4f7f\u7528\u8303\u56f4\uff0c\u8b6c\u5982\u6c7d\u8f66\u3002\u76f8\u6bd4\u6765\u8bf4\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u6bd4\u6db2\u6001\u66f4\u5b89\u5168\u7a33\u5b9a\uff0c\u56e0\u4e3a\u4e0d\u5b58\u5728\u6cc4\u9732\u548c\u77ed\u8def\u7684\u60c5\u51b5\u3002<\/p>\n<p>\u5728\u5176\u4ed6\u7535\u5316\u5b66\u88c5\u7f6e\u4e2d\uff0c\u4e0d\u540c\u7c7b\u578b\u7684\u79bb\u5b50\u4e0d\u65ad\u5730\u5f80\u8fd4\u79fb\u52a8\uff08\u4f8b\u5982\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u6c22\u79bb\u5b50\uff09\uff0c\u6b64\u5916\uff0c\u7535\u8377\u548c\u79bb\u5b50\u7684\u5927\u5c0f\u4e5f\u4f1a\u5f71\u54cd\u8fd0\u52a8\u3002<\/p>\n<p><strong><b>\u6c27\u5316\u8fd8\u539f\u53cd\u5e94<\/b><\/strong><\/p>\n<p>\u79bb\u5b50\u4e00\u822c\u901a\u8fc7\u5916\u5c42\u6216\u4ef7\u7535\u5b50\u8f68\u9053\u4e0a\u7684\u6b63\u8d1f\u79bb\u5b50\u6570\u91cf\u6765\u63cf\u8ff0\u3002\u6c27\u80fd\u591f\u8f7b\u800c\u6613\u4e3e\u548c\u7535\u5b50\u7ed3\u5408\u5f62\u6210O2-\uff0c\u5bfc\u81f4\u79bb\u5b50\u6c27\u5316\u5c06\u5931\u53bb\u7535\u5b50\uff0c\u589e\u52a0\u5176\u6c27\u5316\u6001\u7684\u79ef\u6781\u6027\u3002\u79bb\u5b50\u5438\u6536\u7535\u5b50\u800c\u51cf\u5c11\uff0c\u540c\u65f6\u964d\u4f4e\u5176\u5316\u5408\u4ef7\u3002<\/p>\n<p>\u7535\u6c60\u91cc\u539f\u5b50\u80fd\u591f\u88ab\u6c27\u5316\u5f62\u6210\u6b63\u79bb\u5b50\u5e76\u88ab\u5438\u5f15\u5728\u8d1f\u6781\u51cf\u5c11\uff0c\u53cd\u4e4b\u4ea6\u7136\u3002\u8fd9\u4e9b\u6c27\u5316\u548c\u8fd8\u539f\u53cd\u5e94\u88ab\u63cf\u8ff0\u4e3a\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002<\/p>\n<p><strong><b>\u6c22\u8d1f\u79bb\u5b50<\/b><\/strong><\/p>\n<p>\u5c3d\u7ba1\u6c22\u8d1f\u79bb\u5b50\u4f20\u5bfc\u8fd8\u672a\u88ab\u7528\u4e8e\u7535\u6c60\uff0c\u4f46\u8fd9\u4e9b\u79bb\u5b50\u786e\u6709\u6f5c\u5728\u7684\u4f18\u52bf\u3002\u4ed6\u4eec\u4e0e\u6c2e\u548c\u6c1f\u79bb\u5b50\u5927\u5c0f\u76f8\u4f3c\u5e76\u4e14\u6709\u5f88\u5f3a\u7684\u8fd8\u539f\u80fd\u529b\u3002H-\/H2\u7684\u6807\u51c6\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u4e3a\uff08-2.3v\uff09\u63a5\u8fd1\u4e8eMg\/Mg2+\uff08-2.4v\uff09\uff0c\u540e\u8005\u65e9\u5df2\u5f15\u8d77\u4e86\u7535\u6c60\u884c\u4e1a\u7684\u5174\u8da3\u3002\u56e0\u6b64\uff0c\u6c22\u79bb\u5b50\u5bfc\u4f53\u5f88\u53ef\u80fd\u672a\u6765\u7528\u4e8e\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u5b58\u50a8\u6216\u8005\u8f6c\u6362\u8bbe\u5907\u3002<\/p>\n<p><strong>\u57fa\u4e8e\u6c22\u8d1f\u79bb\u5b50\u4f20\u5bfc\u7684\u6c22\u6c27\u5316\u7269<\/strong><\/p>\n<p>\u4e3a\u4e86\u89e3\u51b3\u59a8\u788d\u6c22\u8d1f\u79bb\u5b50\u4f20\u5bfc\u7684\u56e0\u7d20\u2014\u2014\u6c22\u8d1f\u79bb\u5b50\u5728\u6c27\u5316\u7269\u6676\u4f53\u6676\u683c\u4e2d\u4f20\u64ad\u4e14\u9ad8\u80fd\u6c22\u8d1f\u79bb\u5b50\u6613\u5206\u89e3\u6210\u7535\u5b50\u548c\u539f\u5b50\u6838\u2014\u2014\u7814\u7a76\u8005\u4eec\u5bf9\u6c22\u6c27\u5316\u5408\u7269\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u7ed3\u679c\u53d1\u73b0\u5176\u7ed3\u6784\u7c7b\u4f3c\u4e8eK2NiF4\uff0c\u6b64\u7c7b\u6c22\u6c27\u5316\u7269\u5305\u62ecLa2LiHO3 (x = y = 0), Sr2LiH3O (x = 0, y = 2), La2-xSrxLiH1-xO3 (0 \u2264 x \u2264 1, y = 0), \u4ee5\u53caLa1-xSr1+xLiH2-xO2 (0 \u2264 x \u2264 1, y = 1)\u7b49\u3002<\/p>\n<p>\u4ed6\u4eec\u53d1\u73b0La2LiHO3\u6709\u4e24\u79cd\u5316\u5b66\u72b6\u6001\uff0c\u5206\u522b\u662f\u659c\u65b9\u6676\u7cfb\u548c\u6b63\u65b9\u6676\u7cfb\uff0c\u4e8c\u8005\u5f62\u6210\u533a\u522b\u5728\u4e8e\u53cd\u5e94\u7269\u7684\u6bd4\u4f8b\u548c\u53cd\u5e94\u6761\u4ef6\u3002\u5bf9\u5316\u5408\u7269\u7684\u7814\u7a76\u53d1\u73b0\uff0c\u5176\u7ec4\u6210\u5bfc\u81f4\u7684\u7a7a\u9699\u4f1a\u8ba9\u6df7\u5408\u7269\u66f4\u5177\u5bfc\u7535\u6027\uff0c\u4ece\u800c\u4e5f\u89e3\u91ca\u4e86\u7c92\u5b50\u7a7a\u9699\u548c\u7c92\u5b50\u6269\u6563\u7684\u5173\u7cfb\u3002\u4ed6\u4eec\u4e5f\u8868\u660e\u53ef\u901a\u8fc7\u589e\u52a0\u7c92\u5b50\u95f4\u7684\u7a7a\u9699\u6765\u63d0\u9ad8\u5bfc\u7535\u6027\u3002<\/p>\n<p>\u539f\u6587\u53c2\u8003\u5730\u5740:\u00a0<a href=\"http:\/\/Researchers demonstrate hydride-ion conduction for potential next-gen batteries\" target=\"_blank\">Researchers demonstrate hydride-ion conduction for potential next-gen batteries<\/a><\/p>\n<p>\u7d20\u6750\uff1a\u738b\u5b87 \u00a0\u7ffb\u8bd1\uff1a\u738b\u65d7<\/p>\n","protected":false},"excerpt":{"rendered":"<p>La2-x-ySrx+yLiH1-x+yO3-y\u7684\u6676\u4f53\u7ed3\u6784\uff08x=0\uff0cy=0\uff0c1\uff0c2\uff09 \u6750\u6599\u725b\u6ce8\uff1a\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u79d1\u5b66\u5bb6\u4e0e\u5176\u65e5\u672c\u540c\u4e8b\u5408\u4f5c\uff0c\u5c55\u793a\u4e86\u7b2c\u4e00\u4e2a\u57fa\u4e8e\u6c27\u5316\u7269\u56fa\u6001&#8230;<\/p>\n","protected":false},"author":230,"featured_media":5044,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[27],"class_list":["post-5039","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-cell"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/5039"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=5039"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/5039\/revisions"}],"predecessor-version":[{"id":5196,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/5039\/revisions\/5196"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/5044"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=5039"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=5039"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=5039"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}