{"id":49941,"date":"2016-11-06T14:00:40","date_gmt":"2016-11-06T06:00:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=49941"},"modified":"2016-11-04T21:30:36","modified_gmt":"2016-11-04T13:30:36","slug":"angew-chem-int-ed-%ef%bc%9a%e6%8b%93%e6%89%91%e8%81%9a%e5%90%88%e7%89%a9%e7%9a%84%e8%a1%a8%e9%9d%a2%e7%a7%91%e5%ad%a6-%e7%ba%bf%e6%80%a7%e4%b8%8e%e7%8e%af%e7%8a%b6%e8%81%9a%e5%90%88%e7%89%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=49941","title":{"rendered":"Angew. Chem. Int. Ed.\uff1a\u62d3\u6251\u805a\u5408\u7269\u7684\u8868\u9762\u79d1\u5b66-\u7ebf\u6027\u4e0e\u73af\u72b6\u805a\u5408\u7269\u5237"},"content":{"rendered":"<p>\u3010<strong>\u5f15\u8a00<\/strong>\u3011<\/p>\n<p>\u7279\u6b8a\u7684\u805a\u5408\u7269\u62d3\u6251\u7ed3\u6784\u548c\u7ebf\u6027\u7ed3\u6784\u76f8\u6bd4\uff0c\u5176\u6027\u8d28\u53d1\u751f\u4e86\u660e\u663e\u7684\u53d8\u5316\u3002 \u7279\u522b\u662f\u5bf9\u4e8e\u73af\u72b6\u5927\u5206\u5b50\uff0c\u6ca1\u6709\u94fe\u7aef\u548c\u73af\u5316\u5f15\u5165\u7684\u7a7a\u95f4\u9650\u5236\u5f71\u54cd\u805a\u5408\u7269\u7684\u52a8\u529b\u5b66\u6027\u80fd\u548c\u6269\u6563\u6027\u80fd\u3002 \u52a0\u5165\u73af\u72b6\u5d4c\u6bb5\u5171\u805a\u7269\u5236\u5907\u7684\u81ea\u7ec4\u88c5\u6838 &#8211; \u58f3\u80f6\u675f\uff0c\u76f8\u6bd4\u8f83\u76f8\u540c\u6761\u4ef6\u4e0b\u5236\u5907\u7684\u80f6\u675f\uff0c\u73af\u72b6\u62d3\u6251\u6709\u660e\u663e\u7684\u7ed3\u6784\u6027\u80fd\u6539\u53d8\u3002\u91cd\u8981\u7684\u662f\uff0c\u73af\u72b6\u5171\u805a\u7269\u80f6\u675f\u7684\u80f6\u4f53\u7a33\u5b9a\u6027\uff0c\u7531\u4e8e\u6291\u5236\u81ea\u7531\u94fe\u7aef\u7684\u80f6\u675f\u6865\u63a5\uff0c\u901a\u5e38\u5bfc\u81f4\u5206\u6563\u4f53\u7684\u805a\u96c6\uff0c\u663e\u793a\u4e86\u660e\u663e\u6539\u8fdb\u6e29\u5ea6\u548c\u76d0\u6d53\u5ea6\u7684\u529f\u80fd\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u4e0e\u7ebf\u6027\u805a\u5408\u7269\u76f8\u6bd4\uff0c\u73af\u72b6\u805a\u5408\u7269\u7684\u62d3\u6251\u7ed3\u6784\u80fd\u6539\u53d8\u805a\u5408\u7269\u5237\u5b50\u754c\u9762\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u3002\u6700\u8fd1\uff0c<strong>\u745e\u58eb\u8054\u90a6\u7406\u5de5\u5b66\u9662\u7684Edmondo M. Benetti\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u7528\u805a2-\u4e59\u57fa-2-\u6076\u5511\u5549\uff08PEOXI\uff09\u73af\u72b6\u548c\u7ebf\u6027\u66f2\u7ebf\u56fe\u63a5\u679d\u7ec4\u88c5\u5230\u6c27\u5316\u949b\u8868\u9762\u4e0a\u3002\u76f8\u6bd4\u8f83\u7ebf\u6027\u805a\u5408\u7269\uff0cPEOXI\u8f83\u5c0f\u7684\u6d41\u4f53\u52a8\u529b\u5b66\u534a\u5f84\uff0c\u66f4\u52a0\u6709\u5229\u4e8e\u5f62\u6210\u81f4\u5bc6\u7684\u5237\u5b50\u3002\u8fd9\u79cd\u66f4\u52a0\u81f4\u5bc6\u7684\u5237\u5b50\uff0c\u80fd\u591f\u4ea7\u751f\u8d85\u8fc7\u5178\u578b\u7acb\u4f53\u71b5\u7684\u7acb\u4f53\u969c\u788d\u3002\u8fd9\u79cd\u73b0\u8c61\uff0c\u8f6c\u6362\u4e3a\u5bf9\u6539\u5584\u751f\u7269\u6c61\u67d3\u6297\u6027\u7684\u4e0d\u540c\u86cb\u767d\u8d28\u6df7\u5408\u7269\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u589e\u5f3a\u7a7a\u95f4\u7a33\u5b9a\u6027\u4e0e\u5177\u6709\u5185\u90e8\u7f3a\u9677\u7684\u5faa\u73af\u5237\u5c01\u7aef\u7684\u94fe\u6bb5\u76f8\u7ed3\u5408\uff0c\u5f53\u5b83\u4eec\u76f8\u4e92\u526a\u5207\u65f6\u5177\u6709\u6da6\u6ed1\u7279\u6027\u3002\u8fd9\u4e9b\u7814\u7a76\uff0c\u4e3a\u62d3\u6251\u7ed3\u6784\u7684\u8868\u9762\u5b98\u80fd\u5316\u7684\u5e94\u7528\u94fa\u5e73\u4e86\u9053\u8def\uff0c\u4f7f\u5f97\u7269\u7406\u5316\u5b66\u6027\u8d28\u53ea\u901a\u8fc7\u7ebf\u6027\u79fb\u690d\u8f7b\u5fae\u8c03\u6574\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe1\uff1a\u73af\u72b6\u805a\u5408\u7269\u7684\u5408\u6210\u793a\u610f\u56fe<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50190\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/1_\u526f\u672c.png\" alt=\"1_\u526f\u672c\" width=\"700\" height=\"539\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/1_\u526f\u672c.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/1_\u526f\u672c-300x231.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\uff08a\uff09\u73af\u88c5PEOXA (C-PEOXA-11)\u5438\u9644\u7269\u901a\u8fc7CROP\uff08\u9633\u79bb\u5b50\u5f00\u73af\u805a\u5408\uff09\u5408\u6210\uff0c\u548c\u540e\u671f\u7684\u4fee\u9970\u3002<\/p>\n<p>\uff08b\uff09\u7ebf\u6027PEOXA\u5438\u9644\u7269\uff08L-PEOXA-6\u548cL-PEOXA-11\uff09\u901a\u8fc7CROP\u5408\u6210\uff0c\u63a5\u7740\u8fdb\u884c\u76f8\u4f3c\u7684\u540e\u4fee\u9970\u3002<\/p>\n<p>\uff08c\uff09\u5728\u5ba4\u6e29\u548c\u6d4a\u70b9\u6761\u4ef6\u4e0b\uff0c\u4e0d\u540c\u62d3\u6251\u7ed3\u6784\u7684\u5438\u9644\u7269\u6c89\u79ef\u5728\u949b\u4e0a\uff0c\u901a\u8fc7\u63a5\u679d\u6280\u672f\u6765\u6c89\u79ef\u6c27\u5316\u7269\u886c\u5e95\u3002<\/p>\n<p><strong><b>\u56fe2\uff1a\u4e0d\u540c\u5438\u9644\u7269\u7684\u539f\u4f4d\u8bb0\u5f55<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50191\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/2_\u526f\u672c.png\" alt=\"2_\u526f\u672c\" width=\"700\" height=\"309\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/2_\u526f\u672c.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/2_\u526f\u672c-300x132.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u901a\u8fc7\u539f\u4f4d\u8bb0\u5f55\u6765\u786e\u8ba4\u805a\u5408\u7269\u7ec4\u88c5\u8fc7\u7a0b\u4e2d\u4e09\u79cd\u4e0d\u540c\u7684\u5438\u9644\u7269\u7684\u53d8\u5316\u3002\u84dd\u8272\u7ebf\u4e3aMn=11KDa\u7684\u73af\u72b6PEOXA\uff0c\u7ea2\u8272\u4e3aMn=11KDa\u7684\u7ebf\u72b6\uff0c\u9ec4\u8272\u4e3aMn=6KDa\u7684\u7ebf\u72b6PEOXA\u3002\uff08a\uff09\u5728\u5ba4\u6e29\u4e0b\uff08b\uff09\u5728\u6d4a\u70b9\u4e0b<\/p>\n<p><strong><b>\u56fe3\uff1a\u529b\u5b66\u5206\u6790<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50192\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/3_\u526f\u672c.png\" alt=\"3_\u526f\u672c\" width=\"700\" height=\"303\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/3_\u526f\u672c.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/3_\u526f\u672c-300x130.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff09\u7528\u91d1\u6d82\u8986\u7684\u4e8c\u6c27\u5316\u7845\u63a2\u9488\u8bb0\u5f55\u7684C-AFM FS\u5206\u5e03\u5728\u4e0d\u540c\u7684\u62d3\u6251PEOXA\u5237\u4e0a\uff08\u76f4\u5f84colloid = 20mm\uff0c\u6b63\u5e38\u5f39\u7c27\u5e38\u6570= 0.1Nm <sup>-1<\/sup>\uff0c\u538b\u75d5\u901f\u5ea6= 2ums <sup>-1<\/sup>\uff09<\/p>\n<p>b\uff09\u73af\u72b6\u5237\u5b50\u4e2d\u7684\u9ad8\u5206\u5b50\u62d3\u6251\u5b66\u5f71\u54cd\u4e0e\u9ad8\u63a5\u679d\u5bc6\u5ea6\u4e00\u8d77\u4f5c\u7528\uff0c\u4fbf\u5bf9\u63a5\u8fd1\u7684\u63a2\u9488\u4ea7\u751f\u7a7a\u95f4\u6392\u65a5\u529b\uff08\u8d85\u8fc7\u7531\u7ebf\u6027\u5237\u65bd\u52a0\u7684\u71b5\u5c4f\u969c\uff09<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><strong><b>\u56fe4\uff1a\u86cb\u767d\u8d28\u5438\u9644\u56fe<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50193\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/4_\u526f\u672c.png\" alt=\"4_\u526f\u672c\" width=\"700\" height=\"323\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/4_\u526f\u672c.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/4_\u526f\u672c-300x138.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u5355\u4e00\u86cb\u767d\uff08\u7ea4\u7ef4\u86cb\u767d\u539f\uff0c\u767d\u86cb\u767d\u548c\u514d\u75ab\u7403\u86cb\u767dG\uff09\u548c\u5168\u4eba\u8840\u6e05\u5438\u9644\u5728\u4e0d\u540c\u62d3\u6251\u7ed3\u6784\u7684PEOXA\u4e0a\uff08a\uff09\u5ba4\u6e29\u548c\uff08b\uff09\u6d4a\u70b9\u4e0b\u3002 \u7eafTiO <sub>2<\/sub>\u57fa\u5e95\u7528\u4f5c\u9633\u6027\u5bf9\u7167\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><strong><b>\u56fe5 \u8d1f\u8f7d\u6469\u64e6\u548c\u73af\u72b6\u5237\u7684\u7ed3\u6784<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50194\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/5_\u526f\u672c.png\" alt=\"5_\u526f\u672c\" width=\"700\" height=\"516\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/5_\u526f\u672c.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/11\/5_\u526f\u672c-300x221.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff09\u5728C-LFM\uff08\u80f6\u4f53\u63a2\u9488\u6a2a\u5411\u529b\u663e\u5fae\u955c\uff09\u526a\u5207\u4e0b\uff0c\u8bb0\u5f55PEOXA\u5237\u5b98\u80fd\u5316\u80f6\u4f53\u5bf9\u5728\u5e73\u5766\u57fa\u6750\u4e0a\u7684PEOXA\u5237\u5b50\u7684\u6469\u64e6\u529b\u53d8\u5316\u3002<\/p>\n<p>b\uff09\u5728\u76f8\u5bf9\u4f4e\u7684\u65bd\u52a0\u8f7d\u8377\u4e0b\uff0c\u7ebf\u6027- \u7ebf\u6027\u548c\u5faa\u73af-\u5bf9\u6bd4\u5faa\u73af\u5237\u663e\u793a\u4e86\u8f83\u4f4e\u7684\u6469\u64e6;<\/p>\n<p>c\uff09\u9ad8\u4e8e30nN\u65bd\u52a0\u529b\uff0c\u4e24\u4e2a\u7ebf\u6027\u5237\u8f74\u627f\u8868\u9762\u4e4b\u95f4\u7684\u4ea4\u53c9\u5bfc\u81f4\u6469\u64e6\u7684\u7a33\u5b9a\u589e\u52a0\uff0c\u800c\u5faa\u73af\u5237\u56e0\u5b58\u5728\u94fe\u7aef\u800c\u4fdd\u6301\u4f4e\u6469\u64e6\u3002<\/p>\n<p><strong><b>\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n<p>\u603b\u7684\u6765\u8bf4\uff0c\u7531\u73af\u72b6\u9ad8\u5206\u5b50\u7ed3\u6784\u63d0\u4f9b\u7684\u62d3\u6251\u7ed3\u6784\u589e\u5f3a\u4e86\u5237\u7684\u673a\u68b0\u6027\u80fd\uff0c\u4f8b\u5982\u7a7a\u95f4\u7a33\u5b9a\u5316\u7684\u8868\u9762\uff0c\u9632\u6c61\u548c\u987a\u6ed1\u6027\u80fd\u3002\u8fd9\u4e9b\u6027\u8d28\u57fa\u672c\u662f\u53ef\u8c03\u7684\uff0c\u4f8b\u5982\uff0c\u901a\u8fc7\u6539\u53d8\u63a5\u679d\u7269\u7684\u5c3a\u5bf8\uff0c\u63a5\u679d\u7269\u7684\u5316\u5b66\u7ec4\u6210\u548c\u5b83\u4eec\u7684\u63a5\u679d\u5bc6\u5ea6\u3002\u73af\u72b6\u5237\u7684\u754c\u9762\u62d3\u6251\u7ed3\u6784\u7684\u8c03\u5236\u56e0\u6b64\u53ef\u4ee5\u786e\u4fdd\u5b83\u4eec\u4e0d\u540c\u79cd\u7684\u9ad8\u5206\u5b50\u914d\u65b9\uff0c\u4f8b\u5982\u7a33\u5b9a\u5242\u5bf9\u7eb3\u7c73\u9897\u7c92\u7684\u5f71\u54cd\u6216\u8005\u62d3\u6251\u7ed3\u8f6c\u81f3\u5171\u805a\u7269\u8868\u9762\u6027\u80fd\u7684\u6539\u6027\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><u><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201610385\/full\" target=\"_blank\">Topological Polymer Chemistry Enters Surface Science: Linear versus Cyclic Polymer Brushes<\/a>\u00a0<\/u>(Angew. Chem. Int. Ed., 2016, DOI: 10.1002\/anie.201607309\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u5b66\u4e60\u5c0f\u7ec4\u5c0f\u9ea6\u5b50\u63d0\u4f9b\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u4eba<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u7279\u6b8a\u7684\u805a\u5408\u7269\u62d3\u6251\u7ed3\u6784\u548c\u7ebf\u6027\u7ed3\u6784\u76f8\u6bd4\uff0c\u5176\u6027\u8d28\u53d1\u751f\u4e86\u660e\u663e\u7684\u53d8\u5316\u3002 \u7279\u522b\u662f\u5bf9\u4e8e\u73af\u72b6\u5927\u5206\u5b50\uff0c\u6ca1\u6709\u94fe\u7aef\u548c\u73af\u5316\u5f15\u5165\u7684\u7a7a\u95f4\u9650\u5236\u5f71\u54cd\u805a\u5408\u7269\u7684\u52a8\u529b\u5b66\u6027\u80fd\u548c\u6269\u6563\u6027\u80fd\u3002 \u52a0&#8230;<\/p>\n","protected":false},"author":395,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-49941","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/49941"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/395"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=49941"}],"version-history":[{"count":11,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/49941\/revisions"}],"predecessor-version":[{"id":50229,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/49941\/revisions\/50229"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=49941"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=49941"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=49941"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}