{"id":49636,"date":"2016-11-02T06:30:10","date_gmt":"2016-11-01T22:30:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=49636"},"modified":"2016-11-05T11:18:05","modified_gmt":"2016-11-05T03:18:05","slug":"adv-mater-%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e6%9c%b1%e5%98%89%e6%95%99%e6%8e%88%ef%bc%9a%e9%ab%98%e6%80%a7%e8%83%bd%e9%94%82%e7%94%b5%e6%b1%a0%e8%b4%9f%e6%9e%81%e7%9a%84%e7%a8%b3%e5%ae%9a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=49636","title":{"rendered":"Adv. Mater. \u5357\u4eac\u5927\u5b66\u6731\u5609\u6559\u6388\uff1a\u9ad8\u6027\u80fd\u9502\u7535\u6c60\u8d1f\u6781\u7684\u7a33\u5b9a\u754c\u9762\u8584\u819c\u2014\u2014\u805a\u4e8c\u7532\u57fa\u7845\u70f7"},"content":{"rendered":"<p><span style=\"color: #ff0000;\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u81ea\u4e0a\u4e16\u7eaa70\u5e74\u4ee3\u4ee5\u6765\uff0c\u9502\u91d1\u5c5e\u5c31\u4f5c\u4e3a\u53ef\u5145\u7535\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u800c\u5f97\u5230\u5e7f\u6cdb\u7814\u7a76\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u7406\u8bba\u5bb9\u91cf\u9ad8\u8fbe3860mAh\u00b7g<sup>-1<\/sup>\uff0c\u5bc6\u5ea6\u53ea\u67090.59g\u00b7cm<sup>-3<\/sup>\uff0c\u5e76\u4e14\u6709\u7740\u6700\u4f4e\u7684\u7535\u6781\u7535\u4f4d\uff08-3.040V\uff0c\u53c2\u6bd4\u7535\u6781\u4e3a\u6807\u51c6\u6c22\u7535\u6781\uff09\u3002\u7136\u800c\uff0c\u5c06\u9502\u91d1\u5c5e\u4f5c\u4e3a\u7535\u6c60\u7684\u8d1f\u6781\u5b58\u5728\u4e00\u4e9b\u96be\u4ee5\u89e3\u51b3\u7684\u95ee\u9898\uff0c\u8fd9\u9650\u5236\u4e86\u9502\u91d1\u5c5e\u7684\u5e94\u7528\u3002\u5176\u4e2d\u6700\u4e3b\u8981\u7684\u95ee\u9898\u662f\u5728\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7535\u6781\u4f53\u79ef\u5b58\u5728\u5de8\u5927\u53d8\u5316\uff0c\u4ee5\u53ca\u7535\u6781\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u819c\u4e0d\u53ef\u63a7\uff0c\u4e24\u8005\u7ed3\u5408\u8d77\u6765\u4f1a\u5bfc\u81f4\u9502\u679d\u6676\u7684\u4ea7\u751f\uff0c\u5e76\u4e14\u964d\u4f4e\u7535\u6c60\u7684\u5e93\u4f26\u6548\u7387\u548c\u5faa\u73af\u5bff\u547d\u3002\u4eba\u4eec\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\u91c7\u53d6\u4e86\u8bb8\u591a\u529e\u6cd5\uff0c\u4f8b\u5982\uff1a\u6539\u53d8\u7535\u89e3\u6db2\u7684\u6210\u5206\uff0c\u91c7\u7528\u591a\u79cd\u7269\u7406\u4fdd\u62a4\u5c42\u6765\u963b\u788d\u9502\u679d\u6676\u7684\u5f62\u6210\u7b49\u3002\u5176\u4e2d\u5f97\u5230\u4e00\u4e2a\u5171\u8bc6\uff1a\u754c\u9762\u5c42\u8584\u819c\u662f\u89e3\u51b3\u9502\u679d\u6676\u95ee\u9898\u7684\u5173\u952e\uff0c\u7406\u60f3\u7684\u754c\u9762\u8584\u819c\u5e94\u5f53\u5177\u6709\u5f88\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u673a\u68b0\u5f3a\u5ea6\uff0c\u4ee5\u53ca\u4e00\u5b9a\u7684\u67d4\u6027\u6765\u5bb9\u7eb3\u9502\u679d\u6676\u9020\u6210\u7684\u4f53\u79ef\u53d8\u5316\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/span><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u5357\u4eac\u5927\u5b66\u6731\u5609\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7684\u8bfe\u9898\u7ec4\u5728<strong>Adv. Mater.<\/strong> \u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u5728\u4e4b\u524d\u7684\u7814\u7a76\u4e2d\uff0c\u8bf8\u5982\u201c\u5728\u9502\u91d1\u5c5e\u8d1f\u6781\u8868\u9762\u5305\u8986\u91d1\u521a\u77f3\u6837\u78b3\u8584\u819c\u3001\u8bbe\u8ba1\u4e92\u8054\u7684\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u5fae\u7403\u6291\u5236\u9502\u679d\u6676\u5f62\u6210\u201d\u7b49\u65b9\u6cd5\u90fd\u786e\u5b9e\u6539\u5584\u4e86\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u6027\u80fd\uff0c\u4f46\u662f\u8fd9\u4e9b\u5305\u8986\u6750\u6599\u3001\u7eb3\u7c73\u7ed3\u6784\u7684\u5236\u5907\u8fc7\u7a0b\u6781\u5176\u590d\u6742\u3002\u9488\u5bf9\u8fd9\u4e00\u95ee\u9898\uff0c\u8be5\u8bfe\u9898\u7ec4\u8bbe\u8ba1\u4e86\u4e00\u79cd\u6539\u8fdb\u7684\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7\uff08PDMS\uff09\u7eb3\u7c73\u5b54\u8584\u819c\uff0c\u8fd9\u79cd\u8584\u819c\u6750\u6599\u80fd\u591f\u901a\u8fc7\u65cb\u6d82\u6cd5\u548c\u6c22\u6c1f\u9178\uff08HF\uff09\u523b\u8680\u8fdb\u884c\u5236\u5907\u3002\u540c\u65f6PDMS\u8584\u819c\u4e2d\u5177\u6709\u7eb3\u7c73\u5b54\u7ed3\u6784\uff0c\u53ef\u4ee5\u4e3a\u9502\u79bb\u5b50\u63d0\u4f9b\u6709\u6548\u7684\u4f20\u8f93\u901a\u9053\uff1b\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u8be5PDMS\u8584\u819c\u80fd\u4fdd\u6301\u826f\u597d\u7684\u673a\u68b0\u3001\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u4ece\u800c\u80fd\u591f\u6709\u6548\u5730\u6291\u5236\u9502\u679d\u6676\u7684\u5f62\u6210\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u8be5PDMS\u8584\u819c\u80fd\u591f\u4e0e\u4e0d\u540c\u7684\u7535\u6781\u6750\u6599\u517c\u5bb9\u3002\u603b\u4f53\u800c\u8a00\uff0c\u8be5\u8bfe\u9898\u7ec4\u62a5\u9053\u7684PDMS\u8584\u819c\u6750\u6599\u7684\u5e94\u7528\u6709\u6548\u5730\u63d0\u9ad8\u5e76\u4e86\u7535\u6c60\u7684\u5e93\u4f26\u6548\u7387\uff0c\u5728\u957f\u671f\u5faa\u73af\u540e\u5e93\u4f26\u6548\u7387\u4ecd\u80fd\u4fdd\u6301\u572895%\u4ee5\u4e0a\uff0c\u8fd9\u5bf9\u4e8e\u5f53\u524d\u9502\u7535\u6c60\u5faa\u73af\u5bff\u547d\u7684\u63d0\u9ad8\u662f\u5341\u5206\u6709\u610f\u4e49\u7684\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\"><strong>\u56fe1.\u9502\u6c89\u79ef\u793a\u610f\u56fe<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-49654\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0001-m.jpg\" alt=\"adma201603755-fig-0001-m\" width=\"600\" height=\"458\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0001-m.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0001-m-300x229.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)\u9502\u6c89\u79ef\u5728\u88f8\u9732\u94dc\u7b94\u4e0a\uff0c\u82d4\u85d3\u72b6\u9502\u548c\u679d\u6676\u5728\u7ecf\u8fc7\u591a\u6b21\u5faa\u73af\u540e\u624d\u751f\u957f\u51fa<\/p>\n<p>(b)\u9502\u6c89\u79ef\u5728\u8986\u6709PDMS\u8584\u819c\u7684\u94dc\u7b94\u4e0a\uff0c\u5728\u591a\u6b21\u5faa\u73af\u540e\u6291\u5236\u9502\u679d\u6676\u751f\u957f<\/p>\n<p>(c)PDMS\u8584\u819c\u6a2a\u622a\u9762\u7684SEM\u56fe\u50cf<\/p>\n<p>(d)\u7ecf\u8fc7HF\u9178\u6d17\u540e\u7684PDMS\u8584\u819c\u4fef\u89c6SEM\u56fe\u50cf<\/p>\n<p><strong>\u56fe2.\u9502\u6c89\u79ef\u5728\u88f8\u9732\u94dc\u7b94\u53ca\u6539\u6027\u540e\u94dc\u7b94\u4e0a\u7684SEM\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-49661\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0002.jpg\" alt=\"adma201603755-fig-0002\" width=\"600\" height=\"350\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0002.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0002-300x175.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a,b)\u9502\u521d\u59cb\u6c89\u79ef\u5728\u88f8\u9732\u94dc\u7b94\u4e0a\u7684\u6a2a\u622a\u9762\u3001\u4fef\u89c6SEM\u56fe\u50cf<\/p>\n<p>(c)\u5265\u79bb\u6c89\u79ef\u7684\u9502\u540e\u7684\u88f8\u9732\u94dc\u7b94\u7684\u4fef\u89c6SEM\u56fe\u50cf<\/p>\n<p>\u9502\u521d\u59cb\u6c89\u79ef\u5728\u5177\u6709PDMS\u8584\u819c\u4fdd\u62a4\u7684\u7535\u6781\u4e0a\u7684(d)\u6a2a\u622a\u9762\u3001(e)\u4fef\u89c6 SEM\u56fe\u50cf\uff0c\u767d\u8272\u7bad\u5934\uff1aPDMS\u8584\u819c<\/p>\n<p>(f)\u5265\u79bb\u6c89\u79ef\u7684\u9502\u540e\u7684\u6539\u6027\u7535\u6781\u7684\u4fef\u89c6SEM\u56fe\u50cf<\/p>\n<p><strong>\u56fe3.\u88f8\u9732\u94dc\u7b94\u53ca\u5305\u8986\u6709PDMS\u94dc\u7b94\u7684XRD\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-49662\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0003-m.jpg\" alt=\"adma201603755-fig-0003-m\" width=\"600\" height=\"995\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0003-m.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0003-m-181x300.jpg 181w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)\u7b2c\u4e00\u6b21\u5faa\u73af\u540e\u7684\u88f8\u9732\u94dc\u7b94\u7684XRD\u5149\u8c31<\/p>\n<p>(b)\u7b2c\u4e00\u6b21\u5faa\u73af\u524d\u3001\u540e\u7684\u6539\u6027\u7535\u6781\u7684XRD\u5149\u8c31<\/p>\n<p><strong>\u56fe4.\u88f8\u9732\u94dc\u7b94\u3001\u6539\u6027\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-49664\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0004.jpg\" alt=\"adma201603755-fig-0004\" width=\"600\" height=\"895\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0004.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0004-201x300.jpg 201w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)\u88f8\u9732\u94dc\u7b94\u3001\u6539\u6027\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5e93\u4f26\u6548\u7387\u66f2\u7ebf\u5bf9\u6bd4<\/p>\n<p>(b)\u88f8\u9732\u94dc\u7b94\u7535\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5mA\u00b7cm<sup>-2<\/sup>\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u4e0b\u7684\u7535\u538b\u5206\u5e03\u66f2\u7ebf<\/p>\n<p>(c)\u5177\u6709PDMS\u8584\u819c\u7684\u6539\u6027\u7535\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5mA\u00b7cm<sup>-2<\/sup>\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u4e0b\u7684\u7535\u538b\u5206\u5e03\u66f2\u7ebf<\/p>\n<p>(d)\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5mA\u00b7cm<sup>-2<\/sup>\u4e0b\uff0c\u9502\u5728\u4e0d\u540c\u7535\u6781\u7684\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u4e2d\u7535\u538b\u6ede\u73af\u7684\u6bd4\u8f83<\/p>\n<p>(e)\u957f\u671f\u5faa\u73af\u4e0b\u7684PDMS\u6539\u6027\u7535\u6781\u7684\u5e93\u4f26\u6548\u7387\u66f2\u7ebf\u7684\u53d8\u5316\uff08\u63d2\u56fe\u662f\u8be5\u7535\u6c60\u7684\u7535\u538b-\u65f6\u95f4\u66f2\u7ebf\uff09<\/p>\n<p><strong>\u56fe5.\u7535\u6781\u4e0e\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-49677\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0005.jpg\" alt=\"adma201603755-fig-0005\" width=\"600\" height=\"213\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0005.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/adma201603755-fig-0005-300x107.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)PDMS\u8584\u819c\u6539\u6027\u94dc\u7b94\u57281mA\u00b7cm<sup>-2<\/sup>\u4e0bLiTFSI\u7535\u89e3\u8d28\u4e2d\u7684\u5e93\u4f26\u6548\u7387\u66f2\u7ebf<\/p>\n<p>(b)\u4ee5LiFePO4\u4e3a\u6b63\u6781\u7684\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u66f2\u7ebf<\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/span><\/p>\n<p>\u4e0e\u4e4b\u524d\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u91c7\u7528\u7684\u4fdd\u62a4\u3001\u6539\u8fdb\u65b9\u6cd5\u76f8\u6bd4\uff0c\u8be5\u8bfe\u9898\u7ec4\u63d0\u51fa\u7684\u805a\u4e8c\u7532\u57fa\u7845\u70f7\u8584\u819c\u6750\u6599\u4ec5\u9700\u901a\u8fc7\u65cb\u6d82\u6cd5\u4ee5\u53ca\u6c22\u6c1f\u9178\u7684\u523b\u8680\u8fdb\u884c\u5236\u5907\uff0c\u5176\u5236\u5907\u5de5\u827a\u7b80\u5355\uff0c\u5e76\u4e14\u7ecf\u8be5PDMS\u8584\u819c\u6539\u6027\u540e\u7684\u9502\u91d1\u5c5e\u7535\u6781\u6bd4\u5176\u4ed6\u65b9\u6cd5\u6539\u8fdb\u540e\u7684\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u66f4\u597d\u3002\u591a\u5b54PDMS\u8584\u819c\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u4fdd\u62a4\uff0c\u7ed3\u5408\u5e38\u89c4\u7684\u78b3\u9178\u76d0\u7535\u6781\u6750\u6599\uff0c\u7535\u6c60\u7684\u5e93\u4f26\u6548\u7387\u5728\u5faa\u73af\u8d85\u8fc7200\u6b21\u4ee5\u540e\u53ef\u4ee5\u7a33\u5b9a\u572895%\u5de6\u53f3\u3002\u901a\u8fc7\u53d1\u5c55\u65b0\u7684\u7535\u89e3\u8d28\u4e0ePDMS\u4fdd\u62a4\u819c\u534f\u540c\u5de5\u4f5c\uff0c\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u6709\u671b\u5f97\u5230\u8fdb\u4e00\u6b65\u7684\u63d0\u9ad8\u3002\u603b\u4e4b\uff0c\u8be5\u8bfe\u9898\u7ec4\u5728\u9502\u91d1\u5c5e\u8d1f\u6781\u4fdd\u62a4\u6750\u6599\u65b9\u9762\u63d0\u51fa\u4e86\u4e00\u4e2a\u53ef\u62d3\u5c55\u7684\u65b9\u6cd5\uff0c\u4e3a\u53d1\u5c55\u9ad8\u6027\u80fd\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a 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