{"id":48313,"date":"2016-10-26T14:00:26","date_gmt":"2016-10-26T06:00:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=48313"},"modified":"2016-10-26T12:21:24","modified_gmt":"2016-10-26T04:21:24","slug":"nature-chemistry%ef%bc%9araft%e6%b4%bb%e6%80%a7%e8%81%9a%e5%90%88%e8%8e%b7%e9%87%8d%e8%a6%81%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=48313","title":{"rendered":"Nature Chemistry\uff1aRAFT\u6d3b\u6027\u805a\u5408\u83b7\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u6750\u6599\u725b\u6ce8<\/strong>\uff1a\u8fd9\u4e5f\u8bb8\u662f\u4eca\u5e74\u6700\u6f02\u4eae\u7684\u9ad8\u5206\u5b50\u5316\u5b66\u5408\u6210\u7814\u7a76\u3002<br \/>\n\u82f1\u56fd\u534e\u5a01\u5927\u5b66\u5316\u5b66\u7cfb\u7684\u6559\u6388David Haddleton\u8fd1\u65e5\u5728Nature chemistry\u53d1\u5e03\u62a5\u544a\u4ecb\u7ecd\u4e86\u4e00\u79cd\u5feb\u901f\u53ef\u5b9a\u91cf\u63a7\u5236\u7684\u6709\u5e8f\u591a\u5d4c\u6bb5RAFT\u805a\u5408\u53cd\u5e94\uff0c\u79f0\u80fd\u591f\u5c06\u4eba\u4eec\u5bf9\u4e8e\u4ea7\u54c1\u7684\u5177\u4f53\u9700\u6c42\uff0c\u8f6c\u5316\u4e3a\u57fa\u672c\u7684\u5206\u5b50\u7ed3\u6784\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-48669 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/betterstrong-1.jpg\" alt=\"betterstrong\" width=\"740\" height=\"444\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/betterstrong-1.jpg 740w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/betterstrong-1-300x180.jpg 300w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><strong>RAFT\u662f\u4ec0\u4e48\uff1f<\/strong><br \/>\nRAFT\u805a\u5408\u5168\u79f0\u662f\u53ef\u9006\u52a0\u6210-\u65ad\u88c2\u94fe\u8f6c\u79fb\u805a\u5408(Reversible Addition-Fragmentation Chain Transfer Polymerization)\uff0c\u662f\u6d3b\u6027\/\u53ef\u63a7\u81ea\u7531\u57fa\u805a\u5408(CRP)\u7684\u4e00\u79cd\u3002\u4ece1998\u5e74\u5de6\u53f3\u8d77\uff0c\u4eba\u4eec\u5bf9RAFT\u805a\u5408\u7684\u7814\u7a76\u5c31\u5df2\u7ecf\u5f00\u5c55\u4e86\uff0c\u4f46\u662f\u5176\u5de5\u4e1a\u5316\u751f\u4ea7\u53ca\u7528\u9014\u4e00\u76f4\u53d7\u9650\u5236\u3002\u9996\u5148\u662f\u56e0\u4e3a\u5176\u6d3b\u6027\u805a\u5408\u64cd\u4f5c\u76f8\u5bf9\u4e0d\u6613\uff0c\u53e6\u5916RAFT\u805a\u5408\u7684\u4f20\u7edf\u65b9\u6cd5\u6709\u4e24\u79cd\uff1a\u4e00\u662f\u4f7f\u7528\u6709\u673a\u786b\u94fe\u8f6c\u79fb\u5242\uff0c\u4e0d\u4ec5\u6709\u6bd2\u800c\u4e14\u6c14\u5473\u96be\u95fb\uff1b\u4e8c\u662f\u4f7f\u7528\u91cd\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u4f1a\u589e\u52a0\u6210\u672c\u548c\u526f\u53cd\u5e94\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-48315\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/nchem_2634-f4.jpg\" alt=\"nchem_2634-f4\" width=\"740\" height=\"560\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/nchem_2634-f4.jpg 946w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/nchem_2634-f4-300x227.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/nchem_2634-f4-768x581.jpg 768w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><strong>\u91cd\u5927\u7a81\u7834<\/strong><br \/>\nDavid Haddleton\u6559\u6388\u7684\u8fd9\u9879\u7814\u7a76\u662f\u5728\u4e73\u6db2\u73af\u5883\u4e2d\u8fdb\u884c\u7684\uff0c\u901a\u8fc7\u6dfb\u52a0\u7279\u6b8a\u7684\u5927\u5206\u5b50\u5355\u4f53\uff0c\u53cd\u5e94\u4e2d\u672a\u4f7f\u7528\u4efb\u4f55\u4f20\u7edf\u7684\u6709\u673a\u786b\u94fe\u8f6c\u79fb\u5242\u6216\u91cd\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6240\u4ee5\u5236\u5907\u7684\u805a\u5408\u7269\u66f4\u52a0\u201c\u7eff\u8272\u201d\uff0c\u89e3\u51b3\u4e86\u957f\u4e45\u4ee5\u6765\u7684\u70e6\u607c\u3002\u590d\u6742\u7684\u805a\u5408\u7269\u53ef\u4ee5\u901a\u8fc7\u7c7b\u4f3c\u4e8e\u751f\u4ea7\u4e73\u80f6\u6f06\u548c\u80f6\u6c34\u7684\u8fc7\u7a0b\u88ab\u5b9a\u5236\uff0c\u800c\u751f\u4ea7\u5546\u7f16\u901a\u8fc7\u5199\u9ad8\u5206\u5b50\u7684DNA\u7a0b\u5e8f\uff0c\u5c31\u80fd\u63a7\u5236\u6700\u7ec8\u4ea7\u54c1\u7684\u786e\u5207\u6027\u8d28(\u91cd\u91cf\u3001\u5f3a\u5ea6\u3001\u5f62\u72b6\u3001\u5927\u5c0f\u7b49)\u3002\u73b0\u5728\u5728\u5df2\u6709\u7684\u57fa\u7840\u8bbe\u65bd\u4e0a\u505a\u7b80\u5355\u7684\u4fee\u6539\uff0c\u5c31\u80fd\u591f\u6bd4\u4ee5\u5f80\u66f4\u597d\u5730\u63a7\u5236\u4ea7\u54c1\u7684\u8bbe\u8ba1\u4e86\u3002\u8fd9\u9879\u7a81\u7834\u5c06\u4f1a\u5e26\u6765\u8bb8\u591a\u5546\u4e1a\u7528\u9014\uff0c\u6709\u671b\u5728\u7eb3\u7c73\u533b\u836f\u548c\u6d82\u6599\u7b49\u9886\u57df\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/phys.org\/news\/2016-10-stronger-polymer-breakthrough-everyday.html\" target=\"_blank\">Better, stronger: Polymer breakthrough to improve things we use everyday<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/www.nature.com\/nchem\/journal\/vaop\/ncurrent\/full\/nchem.2634.html\" target=\"_blank\">Nikolaos G. Engelis et al, Sequence-controlled methacrylic multiblock copolymers via sulfur-free RAFT emulsion polymerization, Nature Chemistry (2016).<\/a><\/p>\n<p>\u672c\u6587\u7531\u7f16\u8f91\u90e8\u6768\u6811\u63d0\u4f9b\u7d20\u6750\uff0c\u5b5f\u4ee4\u6653\u7f16\u8bd1\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6750\u6599\u725b\u6ce8\uff1a\u8fd9\u4e5f\u8bb8\u662f\u4eca\u5e74\u6700\u6f02\u4eae\u7684\u9ad8\u5206\u5b50\u5316\u5b66\u5408\u6210\u7814\u7a76\u3002 \u82f1\u56fd\u534e\u5a01\u5927\u5b66\u5316\u5b66\u7cfb\u7684\u6559\u6388David Haddleton\u8fd1\u65e5\u5728Nature chemistry\u53d1\u5e03\u62a5\u544a\u4ecb\u7ecd\u4e86\u4e00&#8230;<\/p>\n","protected":false},"author":608,"featured_media":48314,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[293,42],"class_list":["post-48313","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-nature","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/48313"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/608"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=48313"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/48313\/revisions"}],"predecessor-version":[{"id":48670,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/48313\/revisions\/48670"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/48314"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=48313"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=48313"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=48313"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}