{"id":47912,"date":"2016-10-25T06:30:30","date_gmt":"2016-10-24T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=47912"},"modified":"2016-10-23T22:15:53","modified_gmt":"2016-10-23T14:15:53","slug":"science%ef%bc%9a%e9%80%9a%e8%bf%87%e4%bc%98%e5%8c%96%e5%b8%a6%e9%9a%99%e7%9a%84%e9%92%99%e9%92%9b%e7%9f%bf-%e9%92%99%e9%92%9b%e7%9f%bf%e5%8f%a0%e5%b1%82%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=47912","title":{"rendered":"Science\uff1a\u901a\u8fc7\u4f18\u5316\u5e26\u9699\u7684\u9499\u949b\u77ff-\u9499\u949b\u77ff\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\uff08ABX<sub>3<\/sub>\uff0c\u5178\u578b\u7684A\u4e3aCs\u3001MA\u3001FA\uff0cB\u4e3aPb\u3001Sn\uff0cX\u4e3aI\u3001Br\u3001Cl\uff09\u4ee5\u5176\u5feb\u901f\u63d0\u9ad8\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u548c\u4f4e\u5ec9\u7684\u5236\u5907\u6210\u672c\uff0c\u5df2\u7ecf\u6210\u4e3a\u6781\u5177\u524d\u666f\u7684\u5149\u4f0f\u6280\u672f\u3002\u5355\u7ed3\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7684\u8ba4\u8bc1\u6548\u7387\u4e3a22%\uff0c\u4f46\u662f\u9499\u949b\u77ff\u7535\u6c60\u7684\u5546\u4e1a\u5316\u5c06\u53ef\u80fd\u4f5c\u4e3a\u7845\u592a\u9633\u80fd\u7535\u6c60\u7684\u201c\u8865\u5145\u201d\u3002\u5728\u53e0\u5c42\u6784\u9020\u4e2d\uff0c\u5e26\u9699\u4e3a1.75eV\u7684\u9499\u949b\u77ff\u80fd\u591f\u63d0\u9ad8\u7845\u7535\u6c60\u7684\u6548\u7387\uff0c\u6240\u6709\u7684\u53e0\u5c42\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u66f4\u4f4e\u7684\u5236\u5907\u6210\u672c\uff0c\u4f46\u662f\u5408\u9002\u7684\u6750\u6599\u5e26\u9699\u5339\u914d\u8fd8\u672a\u80fd\u5b9e\u73b0\u3002\u6700\u9ad8\u6548\u7684\u53e0\u5c42\u5668\u4ef6\u8981\u6c42\u80cc\u7535\u6c60\u7684\u5e26\u9699\u4e3a0.9-1.2eV\uff0c\u524d\u7535\u6c60\u7684\u5e26\u9699\u4e3a1.7-1.9eV\u3002\u867d\u7136\u50cfFA<sub>0.83<\/sub>Cs <sub>0.17<\/sub>Pb(I<sub>x<\/sub>Br<sub>1-x<\/sub>)<sub>3<\/sub>\u7b49\u6750\u6599\u7684\u5e26\u9699\u80fd\u591f\u6ee1\u8db3\u524d\u7535\u6c60\u7684\u8981\u6c42\uff0c\u4f46\u662f\u94c5\u57fa\u6750\u6599\u7684\u5e26\u9699\u65e0\u6cd5\u8c03\u8282\u5230\u6ee1\u8db3\u80cc\u7535\u6c60\u8981\u6c42\u76841.48eV\u4ee5\u4e0b\u3002\u7528Sn\u5b8c\u5168\u53d6\u4ee3Pb\u540e\u7684\u5e26\u9699\u80fd\u591f\u8fbe\u52301.3eV\uff0c\u7136\u800c\u9521\u57fa\u6750\u6599\u5bf9\u7a7a\u6c14\u6781\u5ea6\u654f\u611f\u800c\u4e14\u5236\u5907\u56f0\u96be\uff0c\u6240\u4ee5\u8fd9\u7c7b\u5668\u4ef6\u7684\u6548\u7387\u88ab\u9650\u5236\u57286%\u5de6\u53f3\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u901a\u8fc7\u4f18\u5316\u5e26\u9699\u5339\u914d\uff0c\u65e2\u80fd\u5206\u522b\u6ee1\u8db3\u524d\u7535\u6c60\u548c\u80cc\u7535\u6c60\u7684\u5e26\u9699\u8981\u6c42\u53c8\u53ef\u4ee5\u7a33\u5b9a\u5b58\u5728\uff0c\u4fbf\u6210\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684\u5173\u952e\u6240\u5728\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u5728\u672c\u7bc7\u62a5\u9053\u4e2d\uff0c<strong>\u82f1\u56fd\u725b\u6d25\u5927\u5b66\u7684Henry J. Snaith\u548c\u7f8e\u56fd\u65af\u5766\u798f\u5927\u5b66\u7684Michael D. McGehee\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7684\u56e2\u961f\u4ee5\u7406\u60f3\u7684\u5339\u914d\u5e26\u9699\uff0c\u5236\u5907\u51fa\u4e86\u56db\u7aef\u548c\u4e24\u7aef\u9499\u949b\u77ff-\u9499\u949b\u77ff\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u3002\u8be5\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u4e2a\u80fd\u591f\u5438\u6536\u7ea2\u5916\u5149\u3001\u5e26\u9699\u4e3a1.2eV\u7684\u9499\u949b\u77ff\u6750\u6599FA<sub>0.75<\/sub>Cs<sub>0.25<\/sub>Sn<sub>0.5<\/sub>Pb<sub>0.5<\/sub>I<sub>3<\/sub>\uff0c\u8fd9\u80fd\u591f\u83b7\u5f9714.8%\u7684\u6548\u7387\u3002\u5c06\u8be5\u6750\u6599\u4e0e\u5bbd\u5e26\u9699\u7684FA<sub>0.83<\/sub>Cs<sub>0.17<\/sub>Pb(I<sub>0.5<\/sub>Br<sub>0.5<\/sub>)<sub>3<\/sub>\u6750\u6599\u76f8\u7ed3\u5408\uff0c\u5355\u7247\u4e24\u7aef\u53e0\u5c42\u6548\u7387\u8fbe\u5230\u4e8617%\uff0c\u8d85\u8fc71.65V\u7684\u5f00\u8def\u7535\u538b\u3002\u540c\u65f6\u4ed6\u4eec\u4e5f\u673a\u68b0\u5730\u5806\u53e0\u4e86\u56db\u7aef\u53e0\u5c42\u7535\u6c60\uff0c\u5e76\u83b7\u5f9720.3%\u7684\u6548\u7387\u3002\u81f3\u5173\u91cd\u8981\u7684\u662f\u4ed6\u4eec\u53d1\u73b0\uff0c\u4ed6\u4eec\u5f00\u53d1\u7684\u5438\u6536\u7ea2\u5916\u7684\u9499\u949b\u77ff\u7535\u6c60\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u7a7a\u6c14\u7a33\u5b9a\u6027\u3002\u5728\u957f\u65f6\u95f4\u548c\u4f4e\u5236\u5907\u6210\u672c\u4e0b\uff0c\u8fd9\u4e2a\u5668\u4ef6\u7ed3\u6784\u548c\u6750\u6599\u8bbe\u7f6e\u5c06\u4f1a\u4f7f\u5f97\u201c\u6240\u6709\u7684\u9499\u949b\u77ff\u201d\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u8fbe\u5230\u6700\u9ad8\u7684\u6548\u7387\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1\u3001Sn-Pb\u5408\u91d1<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-47913\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F1.large_-2.jpg\" alt=\"F1.large\" width=\"700\" height=\"947\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F1.large_-2.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F1.large_-2-222x300.jpg 222w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-47914\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F2.large_-1.jpg\" alt=\"F2.large\" width=\"700\" height=\"367\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F2.large_-1.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F2.large_-1-300x157.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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0.5, 1)\u4ee5\u53ca \u00a0FA<sub>75<\/sub>Cs<sub>0.25<\/sub>Sn<sub>0.5<\/sub>Pb<sub>0.5<\/sub>I<sub>3<\/sub>\u00a0\u7535\u6c60\u5728\u7a7a\u6c14\u4e2d\u3001AM1.5G\u7167\u5c04\u3001\u6700\u5927\u529f\u7387\u70b9\u4e0b\u6d4b\u91cf\uff0c\u5f97\u5230PCE\u7684\u65f6\u95f4\u51fd\u6570\u3002<\/p>\n<p>f,FASn<sub>5<\/sub>Pb<sub>0.5<\/sub>I<sub>3<\/sub>\u548cFA<sub>0.75<\/sub>Cs<sub>0.25<\/sub>Sn<sub>0.5<\/sub>Pb<sub>0.5<\/sub>I<sub>3<\/sub>\u819c\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u8fd9\u901a\u8fc7\u5728100\u00b0C\u52a0\u70ed\u6837\u54c1\uff0c\u5e76\u76d1\u6d4b\u5176\u5728900 nm\u5904\u7684\u5438\u6536\u7684\u65f6\u95f4\u51fd\u6570\u3002<\/p>\n<p><strong>\u56fe3\u3001\u9499\u949b\u77ff-\u9499\u949b\u77ff\u7684\u53e0\u5c42<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-47915\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F3.large_.jpg\" alt=\"F3.large\" width=\"700\" height=\"1118\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F3.large_.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F3.large_-188x300.jpg 188w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/F3.large_-641x1024.jpg 641w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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href=\"http:\/\/science.sciencemag.org\/content\/early\/2016\/10\/19\/science.aaf9717\" target=\"_blank\">Perovskite-perovskite tandem photovoltaics with optimized bandgaps<\/a>\uff08Science\uff0c2016\uff0cDOI: 10.1126\/science.aaf9717\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7535\u5b50\u7535\u5de5\u5b66\u672f\u7ec4lyh_wv\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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