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1 \u5149\u50ac\u5316\u6d88\u9664\u73af\u5883\u6c61\u67d3\u7269<\/strong><\/span><\/p>\n

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2 \u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22<\/span><\/strong><\/p>\n

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\u4ece\u50ac\u5316\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u5982\u679c\u80fd\u591f\u901a\u8fc7\u5149\u50ac\u5316\u5242\u8bbe\u8ba1\uff0c\u4f7f\u5f97\u5149\u50ac\u5316\u53cd\u5e94\u52a8\u529b\u5b66\u8fc7\u7a0b\u6539\u53d8\uff0c\u800c\u4e0d\u662f\u4e0a\u6587\u63d0\u53ca\u7684\u76f4\u63a5\u76844\u7535\u5b50\u8fc7\u7a0b\u7684\u8bdd\uff0c\u5c06\u6709\u53ef\u80fd\u63d0\u9ad8\u5149\u50ac\u5316\u5242\u5149\u50ac\u5316\u5206\u89e3\u6c34\u7684\u6027\u80fd\u3002\u8fd9\u91cc\u7ed9\u5927\u5bb6\u63a8\u8350\u4ecb\u7ecd\u82cf\u5dde\u5927\u5b66\u5eb7\u632f\u8f89\u8001\u5e08\u8bfe\u9898\u7ec42015\u5e74\u53d1\u8868\u5728Science\u4e0a\u7684\u4e00\u9879\u5de5\u4f5c[2]\uff0c\u8be5\u5de5\u4f5c\u7ed3\u5408\u4e86\u4e24\u79cd\u78b3\u6750\u6599\u2014\u78b3\u70b9\u548c\u77f3\u58a8\u76f8\u6c2e\u5316\u78b3\u5404\u81ea\u7684\u4f18\u52bf\uff0c\u5b9e\u73b0\u4e86\u50ac\u5316\u53cd\u5e94\u7684\u201c\u5f3a\u5f3a\u8054\u624b\u201d\u3002\u5177\u4f53\u70b9\u8bf4\uff0c\u4ed6\u4eec\u901a\u8fc7\u8bbe\u8ba1\u5408\u6210\u539f\u6599\u4e30\u5bcc\u7684\u78b3\u70b9-\u77f3\u58a8\u76f8\u6c2e\u5316\u78b3(C Dots\u2013C3<\/sub>N4<\/sub>)\u590d\u5408\u50ac\u5316\u5242\u4f53\u7cfb\uff0c\u5176\u4e2dC3<\/sub>N4<\/sub>\u4e3b\u8981\u5b9e\u73b0\u5149\u50ac\u5316\u53cd\u5e94(i) 2H2<\/sub>O \u2192 H2<\/sub>O2<\/sub> + H2<\/sub>\uff0c\u751f\u6210\u7684H2<\/sub>O2<\/sub>\u63a5\u7740\u5728C Dots \u4e0a\u53d1\u751f\u5feb\u901f\u5316\u5b66\u50ac\u5316\u53cd\u5e94(ii) 2H2<\/sub>O2<\/sub> \u2192 2H2<\/sub>O + O2<\/sub>\uff0c\u8fd9\u6837\uff0c\u539f\u6765\u7684\u901f\u63a7\u6b65–4\u7535\u5b50\u8fc7\u7a0b2H2<\/sub>O \u2192 4H+<\/sup> + O2<\/sub> + 4e-\u5c31\u53d8\u6210\u4e86\u53cd\u5e94(i)+(ii)\u76842\u7535\u5b50\/2\u7535\u5b50\u4e24\u6b65\u8fc7\u7a0b\uff0c\u4ece\u800c\u83b7\u5f97\u4e86\u9ad8\u8fbe2.0%\u7684\u592a\u9633\u80fd\u8f6c\u5316\u6548\u7387\u4ee5\u53ca\u5faa\u73af200\u5929\u7684\u8d85\u9ad8\u7a33\u5b9a\u6027(\u56fe2)\uff0c\u5bf9\u8fd9\u7bc7\u6587\u7ae0\u6709\u5174\u8da3\u7684\u8bfb\u8005\u8bf7\u9605\u8bfb\u539f\u6587\u4ee5\u53caSupplementary Materials\uff0c\u5de5\u4f5c\u505a\u5f97\u5f88\u597d\u5f88\u8be6\u7ec6\u3002<\/p>\n

\"2\"
\n\u56fe2 (A) \u5faa\u73af\u5149\u50ac\u5316\u6d3b\u6027\uff1b(B) \u50ac\u5316\u5242\u5728\u4e0d\u540c\u6ce2\u957f\u7684\u91cf\u5b50\u6548\u7387\uff1b(C) \u4e0d\u540c\u78b3\u70b9\u6d53\u5ea6\u4e0b\u50ac\u5316\u5242\u7684\u91cf\u5b50\u6548\u7387\uff1b(D) \u4e0d\u540c\u50ac\u5316\u5242\u7528\u91cf\u4e0b\u50ac\u5316\u5242\u7684\u91cf\u5b50\u6548\u7387[2]<\/p>\n

\u5173\u4e8e\u590d\u5408\u5149\u50ac\u5316\u6750\u6599\u7684\u7814\u7a76\u662f\u8fd1\u5e74\u6765\u7684\u53c8\u4e00\u70ed\u70b9\uff0c\u8fd9\u662f\u56e0\u4e3a\u5355\u4e00\u7ec4\u5206\u50ac\u5316\u5242\u53ef\u5b9e\u73b0\u7684\u6027\u80fd\u8fd8\u4e0d\u4ee4\u4eba\u6ee1\u610f\uff0c\u4ece\u50ac\u5316\u53cd\u5e94\u7684\u673a\u7406\u51fa\u53d1\uff0c\u7ed3\u5408\u5177\u4f53\u6750\u6599\u7684\u6027\u8d28(\u6750\u6599\u7684\u4e3b\u8981\u4f18\u52bf)\uff0c\u901a\u8fc7\u50ac\u5316\u5242\u7684\u201c\u5f3a\u5f3a\u8054\u624b\u201d\u6765\u5b9e\u73b0\u66f4\u597d\u7684\u50ac\u5316\u6027\u80fd\u662f\u4e00\u4e2a\u7406\u60f3\u7684\u9014\u5f84\u3002\u60f3\u4e86\u89e3\u5173\u4e8e\u590d\u5408\u5149\u50ac\u5316\u548c\u5f02\u8d28\u7ed3\u5149\u50ac\u5316\u7684\u8bfb\u8005\u53ef\u4ee5\u9605\u8bfb\u4ee5\u4e0b\u6587\u732e\uff1a\uff08\u89c1\u201c\u63a8\u8350\u6587\u732e\u201d[5]-[8]<\/span>\uff09<\/p>\n

\u53e6\u5916\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u8fd1\u5e74\u6765\u4e8c\u7ef4\u6750\u6599\u7531\u4e8e\u5176\u72ec\u7279\u7684\u5f62\u8c8c\u53ca\u7535\u5b50\u7ed3\u6784\u800c\u6210\u4e3a\u50ac\u5316\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\uff0c\u5176\u4e2d\u5177\u6709\u4ee3\u8868\u6027\u7684\u6750\u6599\u4e3b\u8981\u6709g-C3<\/sub>N4<\/sub>\u3001\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\/\u7852\u5316\u7269(\u5982MoS2<\/sub>\u3001WS2<\/sub>\u3001WSe2<\/sub>\u3001CoSe2<\/sub>\u7b49)\u7b49\uff0c\u6709\u5173g-C3<\/sub>N4<\/sub>\u53ef\u4ee5\u53c2\u8003\u798f\u5dde\u5927\u5b66\u738b\u5fc3\u6668\u6559\u6388\u7684\u7814\u7a76\u5de5\u4f5c(\u8bfe\u9898\u7ec4\u7f51\u5740http:\/\/wanglab.fzu.edu.cn\/)\uff0c\u5bf9\u4e8c\u7ef4\u6750\u6599\u7528\u4e8e\u50ac\u5316\u9886\u57df\u611f\u5174\u8da3\u7684\u8bfb\u8005\u53ef\u4ee5\u9605\u8bfb\u4ee5\u4e0b\u6587\u732e\uff1a\uff08\u89c1\u201c\u63a8\u8350\u6587\u732e\u201d[9]-[12]<\/span>\uff09<\/p>\n

3 \u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f<\/strong><\/span><\/p>\n

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TiO2<\/sub>\u662f\u8fc4\u4eca\u4e3a\u6b62\u7814\u7a76\u6700\u4e3a\u5e7f\u6cdb\u7684\u5149\u50ac\u5316\u6750\u6599\uff0c\u7136\u800c\u66b4\u9732\u9ad8\u6d3b\u6027{001}\u9762TiO2<\/sub>\u7eb3\u7c73\u6676\u7684\u5408\u6210\u8fd8\u662f\u51e0\u5e74\u524d\u7684\u4e8b[4]\uff0c\u81ea\u6b64\u4ee5\u540e\uff0c\u7814\u7a76\u4eba\u5458\u505a\u4e86\u5927\u91cf\u5173\u4e8e\u66b4\u9732\u9ad8\u6d3b\u6027{001}\u9762\u7eb3\u7c73TiO2<\/sub>\u7684\u5149\u50ac\u5316\u6027\u80fd\u7814\u7a76\uff0c\u53c2\u8003\u6587\u732e\uff1a\uff08\u89c1\u201c\u63a8\u8350\u6587\u732e\u201d[13]-[16]<\/span>\uff09<\/p>\n

\u800c\u5173\u4e8e\u7eb3\u7c73TiO2<\/sub>\u4e0d\u540c\u6676\u9762\u7684\u6d3b\u6027\u8fd8\u4e0d\u662f\u5f88\u6e05\u695a\uff0c\u76f8\u5f53\u90e8\u5206\u7684\u7814\u7a76\u8005\u8ba4\u4e3a\u7eb3\u7c73TiO2<\/sub>{001}\u6676\u9762\u5bf9\u8fd8\u539f\u53cd\u5e94\u7684\u4fc3\u8fdb\u4f5c\u7528\u4e0d\u5982{101}\u9762\uff0c\u5c3d\u7ba1{001}\u6676\u9762\u7684\u80fd\u91cf\u8fdc\u9ad8\u4e8e{101}\u9762\uff0c\u800c\u4f59\u5bb6\u56fd\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u8fd9\u9879\u5de5\u4f5c\u4f3c\u4e4e\u53c8\u5f15\u5165\u4e86\u4e00\u4e2a\u65b0\u7684\u89c6\u89d2–{001}\/{101}\u5904\u4e8e\u4e00\u5b9a\u4e2d\u95f4\u503c\u65f6\u50ac\u5316\u6548\u679c\u6700\u597d\u3002\u7136\u800c\u5fc5\u987b\u8bf4\u660e\u7684\u662f\uff0c\u5c3d\u7ba1\u5927\u91cf\u7684\u7814\u7a76\u5bf9\u6bd4\u4e86\u7eb3\u7c73TiO2<\/sub>\u4e0d\u540c\u6676\u9762\u7684\u6d3b\u6027\uff0c\u4f46\u662f\u7531\u4e8e\u53cd\u5e94\u7c7b\u578b\u3001\u53cd\u5e94\u6761\u4ef6\u3001\u50ac\u5316\u5242\u672c\u8eab\u7684\u5c3a\u5bf8\u3001\u5f62\u72b6\u3001\u4e0d\u540c\u6676\u9762\u6bd4\u4f8b\u7b49\u590d\u6742\u6027\uff0c\u8981\u6e05\u6670\u5730\u8bf4\u660e\u6bcf\u4e2a\u6676\u9762\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u5177\u4f53\u4f5c\u7528\uff0c\u5c24\u5176\u662f\u4f5c\u7528\u673a\u7406\u8fd8\u662f\u5341\u5206\u56f0\u96be\u4e14\u4e0d\u6e05\u695a\u7684\u3002
\n\"3\"\u56fe3 \u4f59\u5bb6\u56fd\u6559\u6388\u8bfe\u9898\u7ec4\u5bf9\u7eb3\u7c73TiO2<\/sub>{001}\/{101}\u8868\u9762\u5f02\u8d28\u7ed3\u7684\u7406\u8bba\u89e3\u91ca[3]<\/p>\n

\u5149\u50ac\u5316\u6c34\u5206\u89e3\u4e0eCO2<\/sub>\u8fd8\u539f\u5728\u76ee\u524d\u662f\u6d3b\u8dc3\u7684\u7814\u7a76\u9886\u57df\uff0c\u8fd1\u5e74\u6765\u5173\u4e8e\u8fd9\u4e24\u4e2a\u8fc7\u7a0b\u7684\u7ed3\u5408–\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u4e5f\u5907\u53d7\u5173\u6ce8\uff0c\u6750\u6599\u725b\u5728\u6b64\u524d\u5df2\u7ecf\u505a\u4e86\u4ecb\u7ecd\uff0c\u8bf7\u53c2\u770b\u5982\u4e0b\u6587\u7ae0<\/p>\n

\u5b66\u672f\u5e72\u8d27 | \u4ee5\u6768\u57f9\u4e1c\u6559\u6388\u5de5\u4f5c\u4e3a\u4f8b\u2014\u89e3\u6790\u4eba\u5de5\u5149\u5408\u4f5c\u7528<\/a><\/span><\/p>\n

\u6709\u5174\u8da3\u7684\u8bfb\u8005\u53ef\u4ee5\u53c2\u8003\u6768\u57f9\u4e1c\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u6709\u5173\u5de5\u4f5c\uff1ahttp:\/\/nanowires.berkeley.edu\/<\/a>\u3002<\/span><\/p>\n

4 \u5149\u50ac\u5316\u6709\u673a\u53cd\u5e94<\/span><\/strong><\/p>\n

\u8bf4\u5230\u6709\u673a\u53cd\u5e94\uff0c\u5c0f\u7f16\u662f\u5b66\u65e0\u673a\u51fa\u751f\u7684\uff0c\u6ca1\u6709\u5b66\u8fc7\u6709\u673a\u5316\u5b66\uff0c\u60f3\u8bb2\u6df1\u5165\u70b9\u4e5f\u662f\u65e0\u80fd\u4e3a\u529b\uff0c\u4e0d\u8fc7\u975e\u5e38\u613f\u610f\u4ece\u5176\u4ed6\u7684\u89d2\u5ea6\u6765\u770b\u5f85\u8fd9\u4e2a\u95ee\u9898\uff0c\u5206\u4eab\u4e00\u4e9b\u6587\u732e\u3002\u6211\u4eec\u77e5\u9053\uff0c\u8bb8\u591a\u6709\u673a\u53cd\u5e94\u90fd\u9700\u8981\u50ac\u5316\u5242\uff0c\u4f8b\u5982\u5de5\u4e1a\u4e0a\u7684\u805a\u5408\u7269\u53ef\u63a7\u5408\u6210\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u805a\u5408\u7269\u7684\u50ac\u5316\u53cd\u5e94\u9700\u8981\u7528\u5230\u7684\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u5c06\u6c61\u67d3\u4ea7\u7269\u3002\u8fd9\u91cc\u7ed9\u5927\u5bb6\u5206\u4eab\u7684\u662fGarret M. Miyake\u8bfe\u9898\u7ec42016\u5e74\u53d1\u8868\u5728Science\u4e0a\u7684\u4e00\u9879\u5de5\u4f5c[5]\uff0c\u8be5\u5de5\u4f5c\u9488\u5bf9\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u6c61\u67d3\u6709\u673a\u805a\u5408\u53cd\u5e94\u4ea7\u7269\u7684\u95ee\u9898\uff0c\u53d1\u5c55\u4e86\u4e00\u7cfb\u5217\u6709\u673a\u50ac\u5316\u5242(\u56fe4B)\uff0c\u5b9e\u73b0\u4e86\u53ef\u89c1\u5149\u4e0b\u9ad8\u6548\u50ac\u5316\u805a\u5408\u7269\u5408\u6210(\u56fe4A)\uff0c\u8fd9\u79cd\u6709\u673a\u50ac\u5316\u539f\u5b50\u8f6c\u79fb\u81ea\u7531\u57fa\u805a\u5408\u53cd\u5e94(O-ATRP)\u7684\u673a\u7406\u5982\u56fe4C\u6240\u793a\u3002<\/p>\n

\"4\"\u56fe4 (a) \u53ef\u89c1\u5149\u50ac\u5316MMA\u5355\u4f53\u805a\u5408\uff1b(b) \u50ac\u5316\u5242\u7ed3\u6784\uff1b(c) \u805a\u5408\u53cd\u5e94\u673a\u7406[5]<\/p>\n

\u5149\u50ac\u5316\u6709\u673a\u53cd\u5e94\u8bf4\u5230\u5e95\u662f\u5149\u5316\u5b66(\u50ac\u5316)\u53cd\u5e94\uff0c\u5982\u4f55\u4ece\u50ac\u5316\u5242\u7ed3\u6784\u548c\u50ac\u5316\u673a\u7406\u7684\u89d2\u5ea6\u51fa\u53d1\u8bbe\u8ba1\u3001\u5408\u6210\u5177\u6709\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u5e76\u7528\u4e8e\u5b9e\u9645\u7684\u50ac\u5316\u53cd\u5e94\u662f\u6838\u5fc3\u95ee\u9898\uff0c\u901a\u8fc7\u6709\u673a\u5149\u50ac\u5316\u53cd\u5e94\u5c06\u592a\u9633\u80fd(\u5c24\u5176\u662f\u53ef\u89c1\u5149)\u8f6c\u53d8\u6210\u5316\u5b66\u80fd\u5bf9\u80fd\u6e90\u5229\u7528\u548c\u5316\u5b66\u54c1\u7684\u751f\u4ea7\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5bf9\u5149\u50ac\u5316\u6709\u673a\u53cd\u5e94\u611f\u5174\u8da3\u7684\u8bfb\u8005\u53ef\u4ee5\u9605\u8bfb\u4ee5\u4e0b\u6587\u732e\uff1a\uff08\u89c1\u201c\u63a8\u8350\u6587\u732e\u201d[17]-[18]<\/span>\uff09<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/span><\/p>\n

[1] Guan M, Xiao C, Zhang J, et al. Vacancy associates promoting solar-driven photocatalytic activity of ultrathin bismuth oxychloride nanosheets[J]. Journal of the American Chemical Society, 2013, 135(28): 10411-10417.
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\u63a8\u8350\u6587\u732e<\/strong><\/span><\/p>\n

[1] Zuo F, Wang L, Wu T, et al. Self-doped Ti3+ enhanced photocatalyst for hydrogen production under visible light[J]. Journal of the American Chemical Society, 2010, 132(34): 11856-11857.<\/p>\n

[2] Li L, Yan J, Wang T, et al. Sub-10 nm rutile titanium dioxide nanoparticles for efficient visible-light-driven photocatalytic hydrogen production[J]. Nature communications, 2015, 6.<\/p>\n

[3]\u00a0Wang S, Pan L, Song J J, et al. Titanium-defected undoped anatase TiO2 with p-type conductivity, room-temperature ferromagnetism, and remarkable photocatalytic performance[J]. Journal of the American Chemical Society, 2015, 137(8): 2975-2983.<\/p>\n

[4]\u00a0Wu Q, Huang F, Zhao M, et al. Ultra-small yellow defective TiO 2 nanoparticles for co-catalyst free photocatalytic hydrogen production[J]. Nano Energy, 2016, 24: 63-71.<\/p>\n

[5]\u00a0Marschall R. Semiconductor composites: strategies for enhancing charge carrier separation to improve photocatalytic activity[J]. Advanced Functional Materials, 2014, 24(17): 2421-2440.<\/p>\n

[6]\u00a0Zhou P, Yu J, Jaroniec M. All\u2010Solid\u2010State Z\u2010Scheme Photocatalytic Systems[J]. Advanced Materials, 2014, 26(29): 4920-4935.<\/p>\n

[7 ]Li H, Zhou Y, Tu W, et al. State\u2010of\u2010the\u2010art progress in diverse Heterostructured photocatalysts toward promoting photocatalytic performance[J]. Advanced Functional Materials, 2015, 25(7): 998-1013.<\/p>\n

[8]\u00a0Xiao F X, Miao J, Tao H B, et al. One\u2010Dimensional Hybrid Nanostructures for Heterogeneous Photocatalysis and Photoelectrocatalysis[J]. Small, 2015, 11(18): 2115-2131.<\/p>\n

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[18]\u00a0Schultz D M, Yoon T P. Solar synthesis: prospects in visible light photocatalysis[J]. Science, 2014, 343(6174): 1239176.<\/p>\n

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