{"id":46457,"date":"2016-10-17T14:00:24","date_gmt":"2016-10-17T06:00:24","guid":{"rendered":"\/\/m.iemloyee.com\/?p=46457"},"modified":"2016-10-15T16:00:51","modified_gmt":"2016-10-15T08:00:51","slug":"nature%e5%ad%90%e5%88%8a%ef%bc%9a%e5%af%bc%e7%94%b5mof%e6%9d%90%e6%96%99%e7%94%a8%e4%ba%8e%e9%ab%98%e6%80%a7%e8%83%bd%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=46457","title":{"rendered":"Nature\u5b50\u520a\uff1a\u5bfc\u7535MOF\u6750\u6599\u7528\u4e8e\u9ad8\u6027\u80fd\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u5316\u5b66\u53cc\u7535\u5c42\u7535\u5bb9\u5668\uff08EDLCs\uff09\u5177\u6709\u5f88\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u4f18\u8d8a\u7684\u5faa\u73af\u5bff\u547d\uff0c\u6210\u4e3a\u91cd\u8981\u7684\u7535\u80fd\u50a8\u5b58\u6280\u672f\u4e4b\u4e00\uff0c\u5728\u95f4\u6b47\u6027\u53ef\u518d\u751f\u80fd\u6e90\u7684\u5927\u89c4\u6a21\u90e8\u7f72\u3001\u667a\u80fd\u7535\u7f51\u548c\u7535\u52a8\u6c7d\u8f66\u4e2d\u5145\u5f53\u91cd\u8981\u89d2\u8272\u3002<\/p>\n

\u7535\u5bb9\u91cf\u3001\u5145\u653e\u7535\u901f\u7387\u5206\u522b\u4e0e\u6750\u6599\u7684\u8868\u9762\u79ef\u3001\u5bfc\u7535\u6027\u6210\u6b63\u76f8\u5173\uff0c\u56e0\u6b64\uff0c\u4ee5\u6d3b\u6027\u70ad\u3001\u78b3\u7eb3\u7c73\u7ba1\u548c\u4ea4\u8054\u591a\u5b54\u77f3\u58a8\u70ef\u7b49\u4e3a\u4ee3\u8868\u7684\u591a\u5b54\u78b3\u6750\u6599\u5e38\u5e7f\u6cdb\u7528\u4e8eEDLCs\u7684\u7535\u6781\u6750\u6599\u3002<\/p>\n

\u53e6\u4e00\u7c7b\u6bd4\u8868\u9762\u79ef\u8fdc\u8d85\u6d3b\u6027\u70ad\u7684\u6750\u6599\u4e3a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u3002\u5e38\u89c4\u7684MOFs\u5177\u6709\u5f88\u9ad8\u7684\u5b54\u9699\u7387\uff0c\u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe7000 m2<\/sup>\/g\uff0c\u6709\u5e0c\u671b\u6311\u6218\u78b3\u6750\u6599\u5728EDLCs\u4e2d\u7684\u5730\u4f4d\uff0c\u7136\u800cMOFs\u7684\u5bfc\u7535\u6027\u9650\u5236\u5176\u53d1\u5c55\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662<\/strong>Mircea Dinc\u0103<\/strong>\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Nature Materials<\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201cConductive MOF electrodes for stable supercapacitors with high areal capacitance<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u7814\u7a76\u4eba\u5458\u5236\u5907\u5177\u6709\u9ad8\u5bfc\u7535\u6027\u7684Ni3<\/sub>(2,3,6,7,10,11-\u516d\u80fa\u4e09\u4e9a\u82ef)2<\/sub>\uff08Ni3<\/sub>(HITP)2<\/sub>\uff09\uff0c\u5e76\u7b2c\u4e00\u6b21\u5168\u90e8\u91c7\u7528<\/strong>\u8fd9\u79cd\u7eafMOFs\u4f5c\u4e3a\u7535\u6781\u6750\u6599\uff08\u4e0d\u6dfb\u52a0\u5bfc\u7535\u5242\u548c\u7c98\u7ed3\u5242\uff09\u7528\u4e8eEDLCs\u3002\u8be5MOFs\u57fa\u5668\u4ef6\u8868\u73b0\u51fa\u6bd4\u7edd\u5927\u90e8\u5206\u78b3\u57fa\u6750\u6599\u66f4\u9ad8\u7684\u9762\u79ef\u5bb9\u91cf\uff0c10000\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u4e8e90%\uff0c\u5ab2\u7f8e\u5546\u4e1a\u5316\u5668\u4ef6<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1<\/strong>\uff1a<\/strong>Ni3<\/sub>(HITP)2<\/sub><\/strong>\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"1\"<\/p>\n

(a) Ni3<\/sub>(HITP)2<\/sub>\u7684\u5206\u5b50\u7ed3\u6784\u3002<\/p>\n

(b) \u7406\u60f3\u7684Ni3<\/sub>(HITP)2<\/sub>\u7a7a\u95f4\u586b\u5145\u56fe\u663e\u793a\u4e86\u7ec6\u5b54\u3001\u7535\u89e3\u8d28Et4<\/sub>N+<\/sup>\u548cBF4<\/sub>–<\/sup>\u3001\u4e59\u8148\u6eb6\u5242\u5206\u5b50\u7684\u76f8\u5bf9\u5927\u5c0f\u3002\u7eff\u8272\u3001\u7eff\u9ec4\u8272\u3001\u84dd\u8272\u3001\u7070\u8272\u3001\u68d5\u8272\u548c\u767d\u8272\u5c0f\u7403\u5206\u522b\u4ee3\u8868Ni\u3001F\u3001N\u3001C\u3001B\u548cH\u539f\u5b50\u3002<\/p>\n

\u56fe<\/strong>2<\/strong>\uff1a<\/strong> Ni3<\/sub>(HITP)2<\/sub><\/strong>\u7c89<\/strong>\u672b\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/strong><\/p>\n

\"2\"<\/p>\n

\u5728\u9759\u6b62\u5f00\u8def\u7535\u4f4d0.02 V\u5f00\u59cb\u4ee5\u626b\u901f10 mV\/s\u5206\u522b\u4ece\u6b63\u5411\u548c\u8d1f\u5411\u63d0\u9ad8\u7535\u4f4d\u9650\u5236\u3002\u624b\u52a8\u538b\u7247\u5c06Ni3<\/sub>(HITP)2<\/sub>\u7c89\u672b\u538b\u8fdb\u94c2\u7f51\u83b7\u5f97~5 mg\/cm2<\/sup>\u7684\u5de5\u4f5c\u7535\u6781\u3002<\/p>\n

\u56fe<\/strong>3<\/strong>\uff1a\u7ec4\u88c5\u6210\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u4e14\u7535\u538b\u63d0\u9ad8\u81f3<\/strong>1 V<\/strong>\u65f6<\/strong>Ni3<\/sub>(HITP)2<\/sub><\/strong>\u7535\u6781\u7684\u6027\u80fd<\/strong><\/p>\n

\"3\"<\/p>\n

(a) \u626b\u901f10 mV\/s\u4e0b\uff0c\u9010\u6e10\u63d0\u9ad8\u7535\u6c60\u7535\u538b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002\u57281 V\u5de6\u53f3CV\u66f2\u7ebf\u7684\u77e9\u5f62\u6027\u53d1\u751f\u8f7b\u5fae\u504f\u5dee\u5f52\u56e0\u4e8e\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u3002<\/p>\n

(b) \u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5\u30011.0\u30012.0 A\/g\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

(c) Nyquist\u56fe\u663e\u793a62 kHz-10 mHz\u8303\u56f4\u5185\u865a\u90e8\u5bf9\u5b9e\u90e8\u7684\u963b\u6297\u3002\u63d2\u56fe\u662f\u9ad8\u9891\u533a\u7684\u653e\u5927\u56fe\uff0862 kHz-1 Hz\uff09\u3002<\/p>\n

(d) \u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a2 A\/g\u4e0b\u5faa\u73af10000\u6b21\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n

\u56fe<\/strong>4<\/strong>\uff1a<\/strong> \u5bf9\u6bd4\u4e0d\u540c<\/strong>EDLC<\/strong>\u6750\u6599\u7684\u9762\u79ef\u6bd4\u5bb9\u91cf<\/strong><\/p>\n

\"4\"<\/p>\n

\u5f52\u4e00\u5316\u76f8\u5bf9\u6bd4\u8868\u9762\u79ef\u7684\u4e0d\u540c\u6750\u6599\u7684\u9762\u79ef\u6bd4\u5bb9\u91cf\u5bf9\u6bd4\u3002<\/p>\n

\u56fe<\/strong>5<\/strong>\uff1a<\/strong> Ni3<\/sub>(HITP)2<\/sub><\/strong>\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u5728<\/strong>1.5 V<\/strong>\u6df1\u5faa\u73af\u524d\u540e\u7684\u5bb9\u91cf\u635f\u5931\u3002<\/strong><\/p>\n

\"5\"<\/p>\n

(a) 0-1.5 V\u6d4b\u8bd5\u7684CV\u66f2\u7ebf\uff0c\u663e\u793a\u6cd5\u62c9\u7b2c\u8fc7\u7a0b\u6709\u660e\u663e\u7684\u635f\u5931\u3002<\/p>\n

(b) 0-1.0 V\u6d4b\u8bd5\u7684CV\u66f2\u7ebf\uff0c\u663e\u793a\u4ec5\u6709\u53cc\u7535\u5c42\u7535\u5bb9\u7684\u635f\u5931\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

Mircea Dinc\u0103\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u5de5\u4f5c\u8868\u660e\u5bfc\u7535\u591a\u5b54MOF Ni3<\/sub>(HITP)2<\/sub>\u662f\u5f88\u6709\u5e0c\u671b\u7684EDLCs\u6d3b\u6027\u6750\u6599\u3002\u91c7\u7528\u7eafNi3<\/sub>(HITP)2<\/sub>\u7ec4\u88c5\u7684\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u8fbe\u5230\u975e\u5e38\u9ad8\u7684\u9762\u79ef\u6bd4\u5bb9\u91cf\uff08~18 uF\/cm2<\/sup>\uff09\u548c\u975e\u5e38\u4f4e\u7684\u7b49\u6548\u4e32\u8054\u7535\u963b\u3002\u8fd9\u662f\u7b2c\u4e00\u4e2a\u57fa\u4e8e\u975e\u78b3\u6750\u6599\u7684EDLCs\uff0c\u8fd9\u9879\u5de5\u4f5c\u786e\u7acb\u5bfc\u7535MOF\u6210\u4e3aEDLCs\u7684\u65b0\u6210\u5458\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aConductive MOF electrodes for stable supercapacitors with high areal capacitance<\/a> (Nat. Mater., 2016, DOI: 10.1038\/NMAT4766 )<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 \u849c\u5934 \u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d,\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"2016-09-2016-08-\u65b0\u80fd\u6e90\u524d\u7ebf-2-300x300\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u5316\u5b66\u53cc\u7535\u5c42\u7535\u5bb9\u5668\uff08EDLCs\uff09\u5177\u6709\u5f88\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u4f18\u8d8a\u7684\u5faa\u73af\u5bff\u547d\uff0c\u6210\u4e3a\u91cd\u8981\u7684\u7535\u80fd\u50a8\u5b58\u6280\u672f\u4e4b\u4e00\uff0c\u5728\u95f4\u6b47\u6027\u53ef\u518d\u751f\u80fd\u6e90\u7684\u5927\u89c4\u6a21\u90e8\u7f72\u3001\u667a\u80fd\u7535\u7f51\u548c\u7535\u52a8\u6c7d\u8f66\u4e2d\u5145…<\/p>\n","protected":false},"author":1206,"featured_media":46627,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[293,18,386],"class_list":["post-46457","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-nature","tag-xinnengyuan","tag-superccapacitor"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/46457"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1206"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=46457"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/46457\/revisions"}],"predecessor-version":[{"id":46893,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/46457\/revisions\/46893"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/46627"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=46457"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=46457"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=46457"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}