{"id":46358,"date":"2016-10-19T06:30:27","date_gmt":"2016-10-18T22:30:27","guid":{"rendered":"\/\/m.iemloyee.com\/?p=46358"},"modified":"2017-03-04T23:15:13","modified_gmt":"2017-03-04T15:15:13","slug":"%e8%b5%b5%e4%b8%9c%e5%85%83nature%e5%ad%90%e5%88%8a%e7%bb%bc%e8%bf%b0%ef%bc%9a%e4%bb%8b%e5%ad%94%e6%9d%90%e6%96%99%e5%9c%a8%e8%83%bd%e9%87%8f%e8%bd%ac%e6%8d%a2%e4%b8%8e%e5%ad%98%e5%82%a8%e4%b8%ad","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=46358","title":{"rendered":"\u8d75\u4e1c\u5143Nature\u5b50\u520a\u7efc\u8ff0\uff1a\u4ecb\u5b54\u6750\u6599\u5728\u80fd\u91cf\u8f6c\u6362\u4e0e\u5b58\u50a8\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"
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1\uff09\u7814\u7a76\u80cc\u666f
\n2\uff09\u4ecb\u5b54\u6750\u6599\u7684\u76f8\u5173\u4ecb\u7ecd
\n3\uff09\u4ecb\u5b54\u6750\u6599\u5728\u80fd\u6e90\u5668\u4ef6\u4e2d\u7684\u5e94\u7528
\n4\uff09\u603b\u7ed3<\/p>\n
<\/p>\n
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1\u00a0<\/strong>\u7814\u7a76\u80cc\u666f<\/strong><\/p>\n 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\u5728\u529f\u80fd\u6750\u6599\u4e2d\uff0c\u591a\u5b54\u6750\u6599\u53c8\u662f\u8fd9\u4e00\u9886\u57df\u4e2d\u4e00\u9897\u6700\u95ea\u4eae\u7684\u661f\u661f\u3002\u6839\u636e\u56fd\u9645\u7eaf\u7cb9\u4e0e\u5e94\u7528\u5316\u5b66\u8054\u5408\u4f1a\uff08IUPAC\uff09\u7684\u5b9a\u4e49\uff0c\u591a\u5b54\u6750\u6599\u53ef\u4ee5\u5206\u4e3a\u4e09\u79cd\uff0c\u5206\u522b\u662f\uff1a\u5fae\u5b54\u6750\u6599\uff08\u5b54\u5f84<2 nm\uff09\u3001\u4ecb\u5b54\u6750\u6599\uff082 nm<\u5b54\u5f84<50 nm\uff09\u548c\u5927\u5b54\u6750\u6599\uff08\u5b54\u5f84>50 nm\uff09\u3002\u5176\u4e2d\uff0c\u81ea\u4ece20\u4e16\u7eaa90\u5e74\u4ee3\u9996\u6b21\u62a5\u9053\u4ecb\u5b54\u6750\u6599\u4ee5\u6765\uff0c\u5404\u79cd\u5404\u6837\u7684\u4ecb\u5b54\u6750\u6599\u5c42\u51fa\u4e0d\u7a77\uff0c\u800c\u5176\u4e2d\u57fa\u4e8e\u4ecb\u5b54\u6750\u6599\u7684\u5404\u9879\u79d1\u5b66\u6280\u672f\u66f4\u662f\u5448\u73b0\u4e86\u7206\u53d1\u5f0f\u589e\u957f\u3002<\/p>\n 2\u00a0<\/strong>\u4ecb\u5b54\u6750\u6599\u7684\u76f8\u5173\u4ecb\u7ecd<\/strong><\/p>\n 2.1 \u4ecb\u5b54\u6750\u6599\u7684\u6027\u8d28<\/strong><\/p>\n \u5173\u4e8e\u4ecb\u5b54\u6750\u6599\u7684\u6027\u8d28\uff0c\u4e3b\u8981\u5305\u62ec\u5177\u6709\u8d85\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u5927\u7684\u5b54\u5bb9\u3001\u53ef\u8c03\u63a7\u7684\u5b54\u5c3a\u5bf8\u548c\u5f62\u8c8c\u7279\u6027\uff0c\u540c\u65f6\u4ecb\u5b54\u6750\u6599\u7684\u5b54\u58c1\u548c\u5b54\u9053\u7ed3\u6784\u5448\u73b0\u51fa\u7eb3\u7c73\u5c3a\u5bf8\u6548\u5e94\u3002<\/p>\n 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2.2 \u4ecb\u5b54\u6750\u6599\u7684\u5236\u5907\u65b9\u6cd5<\/strong><\/p>\n \u4ecb\u5b54\u6750\u6599\u5408\u6210\u65b9\u6cd5\u5206\u7c7b\uff1a\u8f6f\u6a21\u677f\u6cd5\u3001\u786c\u6a21\u677f\u6cd5\u3001\u65e0\u6a21\u677f\u6cd5\u4ee5\u53ca\u6d89\u53ca\u5230\u5757\u4f53\u6750\u6599\u4ecb\u5b54\u7684\u5f62\u6210\u7684\u65b9\u6cd5\u3002\u4e0b\u9762\u5c06\u5206\u6761\u8fdb\u884c\u4ecb\u7ecd\uff1a<\/p>\n 1\uff09\u8f6f\u6a21\u677f\u6cd5<\/p>\n \u56fe1-a<\/strong>\uff1a<\/strong>\u8f6f\u6a21\u677f\u6cd5\u539f\u7406\u793a\u610f\u56fe<\/p>\n \u5236\u5907\u8fc7\u7a0b\uff1a\u9996\u5148\uff0c\u8868\u9762\u6d3b\u6027\u5242\u5206\u5b50\u4e0e\u524d\u9a71\u7269\u6df7\u5408\uff0c\u7ec4\u88c5\u6210\u5177\u6709\u4ecb\u5b54\u7ed3\u6784\u7684\u6df7\u5408\u6750\u6599\uff1b\u4e4b\u540e\uff0c\u53bb\u6a21\u677f\uff0c\u4ece\u800c\u5f97\u5230\u6709\u5e8f\u4ecb\u5b54\u6750\u6599\u3002<\/p>\n 2\uff09\u786c\u6a21\u677f\u6cd5<\/p>\n \u56fe1-b<\/strong>\uff1a<\/strong>\u786c\u6a21\u677f\u6cd5\u539f\u7406\u793a\u610f\u56fe<\/p>\n \u786c\u6a21\u677f\u6cd5\u7b49\u540c\u4e8e\u7eb3\u7c73\u7ea7\u7684\u94f8\u6a21\u6cd5\u3002<\/p>\n \u5236\u5907\u8fc7\u7a0b\uff1a\u9996\u5148\uff0c\u524d\u9a71\u7269\u548c\u5177\u6709\u4e00\u5b9a\u5f62\u8c8c\u7684\u6a21\u677f\u5242\u6df7\u5408\uff0c\u5f62\u6210\u590d\u5408\u7269\uff1b\u4e4b\u540e\uff0c\u53bb\u6a21\u677f\uff0c\u5f97\u5230\u7279\u5f81\u5f62\u72b6\u7684\u4ecb\u5b54\u6750\u6599\u3002<\/p>\n 3\uff09\u8f6f-\u786c\u6a21\u677f\u8054\u7528\u6cd5<\/p>\n \u56fe1-c<\/strong>\uff1a<\/strong>\u8f6f-\u786c\u6a21\u677f\u8054\u7528\u6cd5<\/p>\n \u8f6f-\u786c\u6a21\u677f\u8054\u7528\u6cd5\u53ef\u4ee5\u5236\u5907\u5c24\u5176\u9002\u7528\u4e8e\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5206\u7ea7\u591a\u5b54\u6750\u6599\u3002<\/p>\n 4\uff09\u539f\u4f4d\u6a21\u677f\u6cd5<\/p>\n \u56fe1-d\uff1a<\/strong>\u539f\u4f4d\u6a21\u677f\u6cd5\u539f\u7406\u793a\u610f\u56fe<\/p>\n 5\uff09\u65e0\u6a21\u677f\u5c01\u88c5\u6cd5<\/p>\n \u56fe1-e\uff1a<\/strong>\u65e0\u6a21\u677f\u5c01\u88c5\u6cd5<\/p>\n 6\uff09\u7f51\u683c\u6784\u5efa\u6cd5<\/p>\n \u56fe1-<\/strong>f<\/strong>\uff1a<\/strong>\u7f51\u683c\u6784\u5efa\u6cd5\u539f\u7406\u793a\u610f\u56fe\uff1b\u00a0<\/strong><\/p>\n \u88681<\/strong>\uff1a<\/strong>\u4e0d\u540c\u65b9\u6cd5\u5408\u6210\u7684\u4ecb\u5b54\u6750\u6599\u7684\u6bd4\u8f83<\/p>\n \u00a0 3 <\/strong>\u4ecb\u5b54\u6750\u6599\u5728\u80fd\u6e90\u5668\u4ef6\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n \uff08\u4e00\uff09\u592a\u9633\u80fd\u8f6c\u6362\u4e0e\u50a8\u5b58\u65b9\u9762<\/strong><\/p>\n 3.1 \u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08DSSCs\uff09\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n 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nm\u5230400 nm\u5c3a\u5ea6\u7684TiO2<\/sub>\u9897\u7c92\u4e3a\u4e3b\u4f53\u7684\u6355\u5149\u5c42\u3002\u6355\u5149\u5c42\u80fd\u591f\u589e\u957f\u5149\u5b50\u5728\u7535\u6c60\u4e2d\u7684\u901a\u9053\uff0c\u4ece\u800c\u63d0\u9ad8\u5bf9\u5149\u5b50\u7684\u5438\u6536\u3002\u76ee\u524d\u6765\u8bf4\uff0c\u4ecb\u5b54\u5355\u6676TiO2<\/sub>\u5fae\u7403\u662f\u901a\u8fc7EIAA\u6cd5\u5236\u5907\u7684\u3002\u6700\u7ec8\uff0cTiO2<\/sub>\u5bf9\u5546\u4e1a\u67d3\u6599N719\u7684\u5e94\u7528\uff0c\u53ef\u4ee5\u5bfc\u81f4PCE\u9ad8\u8fbe12.1%\uff0c\u8fd9\u4e2a\u503c\u5df2\u7ecf\u662fTiO2<\/sub>\u548cP25\u7ed3\u5408\u4f7f\u7528\u65f6\u7684\u4e24\u500d\u3002<\/p>\n \u5728DSSCs\u4e2d\uff0c\u5bf9\u7535\u6781\u4e00\u822c\u542b\u6709\u8d35\u91d1\u5c5ePt\u6765\u4f5c\u4e3a\u7535\u50ac\u5316\u5242\u50ac\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u7136\u800c\uff0cPt\u7684\u6210\u672c\u9ad8\u6602\uff0c\u9650\u5236\u4e86\u5176\u5728\u5546\u4e1a\u4e0a\u7684\u5927\u89c4\u6a21\u4f7f\u7528\u3002\u6700\u8fd1\u7814\u7a76\u8868\u660e\uff0c1.1 \u03bcm\u539a\u5ea6\u7684\u4ecb\u5b54\u78b3\u5c42\u5bf9\u7535\u6781\u80fd\u591f\u4f7f\u5f97DSSCs\u7684PCE\u9ad8\u8fbe8.18%\uff0c\u5df2\u7ecf\u975e\u5e38\u63a5\u8fd1Pt\u7535\u6781\u76848.85%\u3002\u800c\u4ece\u53e6\u4e00\u65b9\u9762\u6765\u770b\uff0c\u6070\u597d\u5c31\u662f\u4ecb\u5b54\u7ed3\u6784\u80fd\u591f\u589e\u8fdb\u5bf9\u7535\u6781\u4e2d\u50ac\u5316\u5242\u7684\u6d3b\u6027\u3002\u7c7b\u4f3c\u7684\u62a5\u9053\u5728\u8fd8\u539f\u4ecb\u5b54\u6c27\u5316\u94a8\u548c\u591a\u5b54\u5bfc\u7535\u805a\u5408\u7269\u4e5f\u6709\u51fa\u73b0\u3002\u4f46\u662f\uff0c\u66ff\u4ee3\u8d35\u91d1\u5c5ePt\u5c1d\u8bd5\u4e2d\uff0c\u6311\u6218\u4f9d\u7136\u5b58\u5728\uff0c\u90a3\u5c31\u662f\u76ee\u524d\u6765\u8bf4\u8fd8\u65e0\u6cd5\u540c\u65f6\u8fbe\u5230Pt\u6240\u5177\u6709\u7684\u5bfc\u7535\u6027\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u7136\u800c\uff0c\u5229\u7528\u4ecb\u5b54\u6750\u6599\u7684\u76f8\u4e92\u590d\u5408\uff0c\u4e5f\u6709\u4e86\u4e00\u4e9b\u660e\u663e\u7684\u7a81\u7834\u6027\u8fdb\u5c55\uff0c\u4f8b\u5982\uff0c\u5c06\u91d1\u5c5e\u5316\u5408\u7269\u548c\u4ecb\u5b54\u78b3\u8fdb\u884c\u590d\u5408\uff0c\u6b64\u79cd\u590d\u5408\u6750\u6599\u7535\u6781\u6240\u80fd\u63d0\u4f9b\u7684PCE\u7adf\u7136\u80fd\u591f\u8d85\u8fc7Pt\u7535\u6781\u3002<\/p>\n \u800c\u5bf9\u4e8e\u7535\u89e3\u8d28\u6765\u8bf4\uff0c\u4f7f\u7528\u4ecb\u5b54TiO2<\/sub>\u7535\u89e3\u8d28\uff0c\u53c8\u662f\u56e0\u4e3a\u5b83\u7684\u754c\u9762\u80fd\u591f\u51cf\u5c11\u7535\u8377\u590d\u5408\uff0c\u589e\u8fdb\u6355\u5149\u80fd\u529b\uff0c\u4ece\u800c\u4fc3\u8fdb\u67d3\u6599\u7684\u518d\u751f\u53cd\u5e94\u3002\u65f6\u81f3\u4eca\u65e5\uff0c\u6700\u9ad8\u7684PCE\u80fd\u591f\u9ad8\u8fbe13%\uff0c\u5c31\u662f\u8fd0\u7528\u4e86\u5206\u5b50\u5de5\u7a0b\u535f\u5549\u67d3\u6599\u654f\u5316\u53cc\u5c42\u4ecb\u5b54TiO2<\/sub>\u8584\u819c\u548c\u77f3\u58a8\u70ef\u7eb3\u7c73\u8584\u819c\u5206\u522b\u505a\u5de5\u4f5c\u7535\u6781\u548c\u5bf9\u7535\u6781\u7684\u7ed3\u679c\u3002\u53d7\u6b64\u9879\u5de5\u4f5c\u7684\u6fc0\u52b1\uff0c\u4ecb\u5b54TiO2<\/sub>\u5355\u6676\u548c\u8d85\u8584\u4ecb\u5b54\u77f3\u58a8\u70ef\u8584\u819c\u5fc5\u5c06\u80fd\u591f\u5728\u672a\u6765\u5c06PCE\u63d0\u9ad8\u523020%\u4ee5\u4e0a\u3002<\/p>\n \u56fe2<\/strong>\uff1a<\/strong>\uff08a\uff09\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u548c\uff08b\uff09\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u793a\u610f\u56fe<\/p>\n 3.2 \u5728\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n \u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5c06\u6709\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u65e2\u4f5c\u56fa\u6001\u5149\u5438\u6536\u6750\u6599\u53c8\u4f5c\u7a7a\u7a74\u8f6c\u79fb\u6750\u6599\u3002\u5982\u679c\u4ecb\u5b54TiO2<\/sub>\u88ab\u7528\u6765\u4f5c\u4e3a\u652f\u67b6\uff0c\u9650\u5236\u9499\u949b\u77ff\u578b\u989c\u6599\u7684\u751f\u957f\uff0c\u5c3d\u7ba1\u662f\u9ad8\u6e29\u9000\u706b\u8fc7\u7a0b\u6240\u9700\u7684\uff0c\u90a3\u4e48\u66f4\u597d\u5730\u63a7\u5236\u9499\u949b\u77ff\u7684\u5f62\u8c8c\uff0c\u5c31\u53ef\u4ee5\u5f97\u5230\u91cd\u590d\u6027\u66f4\u9ad8\u6216\u6027\u80fd\u66f4\u4f18\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u3002<\/p>\n \u65f6\u81f3\u4eca\u65e5\uff0c\u6700\u9ad8\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u8f6c\u6362\u6548\u7387\u4e3a20.1%\u3002\u4f9d\u9760\u7684\u5c31\u662f\u5c06FAPbI3<\/sub>\u6c89\u79ef\u4e8e\u4ecb\u5b54TiO2<\/sub>\u7535\u6781\u7684\u8868\u9762\u3002\u7136\u800c\uff0c\u5728\u5149\u7535\u6d41\u2014\u7535\u52bf\u66f2\u7ebf\u4e2d\u5b58\u5728\u6ede\u540e\u73af\uff0c\u8fd9\u4e0e\u5176\u4e2d\u6709\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u5185\u5728\u7684\u7a33\u5b9a\u6027\u76f8\u5173\u3002\u4e4b\u540e\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0c\u901a\u8fc7\u63ba\u6742\u80fd\u591f\u63d0\u9ad8\u7535\u5b50\u5bfc\u7535\u6027\u548c\u4ecb\u5b54TiO2<\/sub>\u7684\u6d41\u52a8\u6027\uff0c\u4ece\u800c\u51cf\u8f7b\u8fd9\u79cd\u6ede\u540e\u73af\u6548\u5e94\u3002\u5982\u5728\u4ecb\u5b54TiO2<\/sub>\u4e2d\u63baLi\uff0c\u5df2\u7ecf\u88ab\u8bc1\u5b9e\u80fd\u591f\u589e\u52a0\u7535\u5b50\u4f20\u8f93\u901f\u7387\uff0c\u4ece\u800c\u5c06PCE\u4ece17%\u63d0\u9ad8\u523019%\u3002<\/p>\n 3.3 \u592a\u9633\u80fd\u71c3\u6599\u751f\u4ea7<\/strong><\/p>\n \u6a21\u62df\u5149\u5408\u4f5c\u7528\u6355\u83b7\u5e76\u50a8\u5b58\u592a\u9633\u80fd\u662f\u5f53\u524d\u4eba\u7c7b\u89e3\u51b3\u80fd\u6e90\u5371\u673a\u7684\u4e00\u79cd\u6709\u6548\u9014\u5f84\u3002\u6c22\u6c14\u53ef\u4ee5\u7528\u5149\u7535\u5316\u5b66\u7535\u6c60\u5b9e\u73b0\u751f\u4ea7\uff0c\u800c\u8fd9\u9879\u6280\u672f\u5219\u6d89\u53ca\u5230\u4e86\u534a\u5bfc\u4f53\u548c\u6db2\u4f53\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u534a\u5bfc\u4f53\u7535\u6781\u5c06\u5149\u8f6c\u5316\u4e3a\u7535\u5b50\u548c\u7a7a\u7a74\uff0c\u5e76\u5728\u7535\u573a\u4e2d\u5206\u79bb\uff0c\u6700\u7ec8\u7528\u4e8e\u5149\u89e3\u6c34\u3002\u53e6\u4e00\u9879\u76f4\u63a5\u7684\u65b9\u5f0f\u662f\u4f7f\u7528\u7279\u5b9a\u7684\u5149\u50ac\u5316\u5242\uff0c\u5176\u4e2d\u7684\u5149\u7535\u5b50\u5728\u52a9\u50ac\u5316\u5242\u4e0b\u80fd\u591f\u76f4\u63a5\u5c06H+<\/sup>\u8fd8\u539f\u6210H2<\/sub>\u3002\u76f8\u5e94\u5730\uff0c\u5149\u751f\u7a7a\u7a74\u80fd\u591f\u76f4\u63a5\u6c27\u5316H2<\/sub>O\u4e3aO2<\/sub>\u3002\u901a\u8fc7\u592a\u9633\u80fd\u9ad8\u6548\u5149\u89e3\u6c34\u4e3a\u6709\u7528\u7684H2<\/sub>\uff0c\u5c31\u5b9e\u73b0\u4e86\u592a\u9633\u80fd\u80fd\u6e90\u7684\u9ad8\u6548\u4f7f\u7528\u3002<\/p>\n \u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0c\u4e00\u7cfb\u5217\u4ecb\u5b54\u6750\u6599\u88ab\u5e94\u7528\u4e8e\u5149\u89e3\u6c34\u8fd9\u4e00\u9886\u57df\u4e2d\u6765\u3002\u5982\u56fe3\u6240\u793a\uff1a<\/p>\n \u56fe3<\/strong>\uff1a<\/strong>\u7528\u4e8e\u751f\u4ea7\u592a\u9633\u80fd\u4ea7\u54c1\u7684\u4ecb\u5b54\u6750\u6599\u3002\uff08a\uff09\u5149\u7535\u5316\u5b66\u7535\u6c60\uff08PEC\uff09\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4e2d\u7684\u5355\u4f53\u4ecb\u5b54\u50ac\u5316\u5242\u548c\u52a9\u50ac\u5316\u5242\uff1b\uff08c\uff09\u901a\u8fc7\u4f7f\u7528\u4ecb\u5b54\u50ac\u5316\u5242\u7528\u4f5c\u6790\u6c22\u53cd\u5e94\u548c\u6790\u6c27\u53cd\u5e94\u7684\u4e00\u79cd\u7528\u4e8e\u5149\u89e3\u6c34\u7684\u5149\u4f0fPEC\u88c5\u7f6e\uff1b\uff08d\uff09\u4ecb\u5b54\u6676\u4f53\u7845\u7684TEM\u56fe\uff1b\uff08e\uff09300 W Xe\u706f\u4e0b\u4ecb\u5b54\u7845\u548c\u7845\u7eb3\u7c73\u9897\u7c92\u8fdb\u884c\u7684\u5149\u4f0f\u6790\u6c22\u53cd\u5e94\uff1b\uff08f\uff09\u6709\u5e8f\u4ecb\u5b54TiO2<\/sub>\u7684\u5149\u4f0f\u6790\u6c22\u53cd\u5e94\u4ee5\u53ca\u5728100 mW cm-2 AM 1.5G\u4e0b\u5149\u7167\u539f\u59cb\u6709\u5e8f\u4ecb\u5b54TiO2<\/sub>\u6750\u6599\uff1b\uff08g\uff09\u4ecb\u5b54CoO\u7eb3\u7c73\u9897\u7c92\u7684TEM\u56fe\uff1b\uff08h\uff09\u4ecb\u5b54CoO\u7eb3\u7c73\u9897\u7c92\u548cCoO\u5fae\u7c89\u7684\u80fd\u5e26\u4f4d\u7f6e\u793a\u610f\u56fe\uff1b\uff08i\uff09\u53cc\u87ba\u65cb\u4ecb\u5b54MoS2<\/sub>\u8584\u819c\u548c\u9ad8\u7eb5\u6a2a\u6bd4\u6838\u58f3\u578bMoO3<\/sub>-MoS2<\/sub>\u7eb3\u7c73\u7ebf\u7684\u6bd4\u8868\u9762\u79ef\u3001\u6bd4\u8868\u9762\u79ef\u4e0b\u7684\u6d3b\u6027\u70b9\u4f4d\u5bc6\u5ea6\u4ee5\u53ca\u603b\u7684\u6790\u6c22\u53cd\u5e94\u6d3b\u6027\u3002<\/p>\n \uff08\u4e8c\uff09\u4e8c\u6b21\u7535\u6c60<\/strong><\/p>\n \u4e8c\u6b21\u7535\u6c60\u5e94\u7528\u5e7f\u6cdb\uff0c\u662f\u5f53\u524d\u6700\u4e3b\u8981\u7684\u50a8\u80fd\u5668\u4ef6\u3002\u5f53\u524d\u7814\u7a76\u6700\u4e3a\u70ed\u95e8\u7684\u6709\u4e09\u79cd\uff0c\u5206\u522b\u662f\u9502\u79bb\u5b50\u7535\u6c60\u3001\u9502\u786b\u7535\u6c60\u4ee5\u53ca\u9502-\u7a7a\u6c14\u7535\u6c60\u3002<\/p>\n 3.4 \u9502\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n \u56fe4<\/strong>\uff1a<\/strong>\u4ecb\u5b54\u6750\u6599\u5728\u9502\u79bb\u5b50\u4e8c\u6b21\u7535\u6c60\u4e2d\u7684\u4f7f\u7528\u3002\uff08a\uff09\u5728\u7535\u6d41\u5bc6\u5ea66000 mA\/g\u4e0b\uff0c\u56db\u6781\u4ecb\u5b54\u03b1-MnO2<\/sub>\u3001\u53cc\u6781\u4ecb\u5b54\u03b1-MnO2<\/sub>\u4ee5\u53ca\u5757\u4f53\u03b1-MnO2<\/sub>\u7684\u653e\u7535\u5faa\u73af\u66f2\u7ebf\uff1b\uff08b\uff09\u5206\u522b\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1\u30010.2\u30010.5\u30011\u30012\u30015\u300110\u30011\u548c0.1 A g\u22121<\/sup>\u4e0b\u4ecb\u5b54\u548c\u5757\u4f53MoS2<\/sub>\u7684\u7535\u5316\u5b66\u6d4b\u8bd5\u66f2\u7ebf\uff1b\uff08c\uff09\u5d4c\u9502\u540e\u4ecb\u5b54\u7845\u6d77\u7ef5\u7684\u7ed3\u6784\u53d8\u5316\u7684\u6a21\u578b\u7ed3\u6784\u793a\u610f\u56fe\uff1b\uff08d\uff09\u4f5c\u4e3a\u4e2d\u5b54\u7845\u6d77\u7ef5\u7684\u5b54\u9699\u5ea6\u7c92\u5b50\u4e0e\u4f53\u79ef\u81a8\u80c0\u7684\u51fd\u6570\u56fe\u50cf\uff1b\uff08e\uff09\u8d28\u91cf\u8d1f\u8f7d\u301c46wt\uff05\u7684\u4ecb\u5b54\u7845\u6d77\u7ef5\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b\uff08f\uff09\u4ecb\u5b54Si\/C\u590d\u5408\u6750\u6599\u5d4c\u9502\u548c\u8131\u9502\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b\uff08g\uff09\u5728\u5faa\u73af\u901f\u73870.5 A\/g\u6761\u4ef6\u4e0b\u4ecb\u5b54Si\/C\u590d\u5408\u6750\u6599\u7684\u5145\u653e\u7535\u5faa\u73af\u66f2\u7ebf\uff1b\uff08h\uff09\u4ecb\u5b54Si\/C\u590d\u5408\u6750\u6599100\u6b21\u5faa\u73af\u540e\u7684TEM\u56fe\u3002<\/p>\n \u5f53\u524d\uff0c\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u7684\u80fd\u91cf\u5bc6\u5ea6\u7684\u8981\u6c42\u4e0e\u65e5\u4ff1\u589e\uff0c\u4ecb\u5b54\u6750\u6599\u7531\u4e8e\u5176\u5177\u6709\u4e30\u5bcc\u7684\u4ecb\u5b54\u901a\u9053\u4ee5\u53ca\u4ecb\u5b54\uff0c\u53ef\u4ee5\u6ee1\u8db3\u7535\u89e3\u8d28\u79bb\u5b50\u7684\u4ea4\u6362\uff0c\u6b64\u5916\uff0c\u5b83\u4eec\u975e\u5e38\u5927\u7684\u5b54\u4f53\u79ef\uff0c\u53ef\u4ee5\u4e3a\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u63d0\u4f9b\u7f13\u51b2\uff0c\u4ece\u800c\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8fd9\u4e9b\u4f18\u5f02\u7684\u6027\u8d28\uff0c\u4f7f\u5f97\u4ecb\u5b54\u6750\u6599\u6210\u4e3a\u4e86\u6700\u7406\u60f3\u7684\u7535\u6781\u6750\u6599\u3002\u5f53\u524d\uff0c\u6bd4\u8f83\u5e38\u7528\u7684\u9633\u6781\u4ecb\u5b54\u6750\u6599\u6709\u6709\u5e8f\u4ecb\u5b54\u7684Li1.12<\/sub>Mn1.88<\/sub>O4<\/sub>\u5c16\u6676\u77f3\u4ee5\u53ca\u5c42\u72b6LiCoO2<\/sub>\u6750\u6599\u3002\u800c\u6bd4\u8f83\u5e38\u7528\u7684\u9634\u6781\u6750\u6599\u662f\u949b\u57fa\u4ecb\u5b54\u6750\u6599\u3001\u4e2d\u7a7aCo3<\/sub>O4<\/sub>\u5fae\u7403\u3002\u7406\u8bba\u6027\u80fd\u57281.12 C\u4e0b\u53ef\u4ee5\u8fbe\u5230925 mAh\/g\uff0c\u800c\u57285.62 C\u4e0b\uff0c\u5faa\u73af\u5bff\u547d\u4e3a7000\u6b21\u3002<\/p>\n \u503c\u5f97\u4e00\u63d0\u7684\u662f\u7845\u57fa\u9633\u6781\u6750\u6599\uff0c\u6bd4\u5bb9\u91cf\u53ef\u8fbe4200 mAh\/g\uff0c\u4f46\u7531\u4e8e\u5b58\u5728\u8f83\u5927\u7684\u4f53\u79ef\u81a8\u80c0\u6548\u5e94\uff08\u7ea6300%\uff09\uff0c\u76ee\u524d\u5728\u5e94\u7528\u4e0a\u8fd8\u9700\u6539\u8fdb\u3002\u6b64\u5916\uff0c\u7531\u5c01\u88c5\u5728\u4e2d\u7a7a\u78b3\u9aa8\u67b6\u4e2d\u7684\u7845\u7eb3\u7c73\u9897\u7c92\u7ec4\u6210\u7684\u77f3\u69b4\u72b6\u7ed3\u6784\u7684Si@C\u590d\u5408\u6750\u6599\uff0c\u8868\u73b0\u51fa\u4e8699.87 %\u7684\u5e93\u4f26\u6548\u7387\u548c1270 mAh\/cm3<\/sup>\u7684\u4f53\u79ef\u6bd4\u5bb9\u91cf\u3002<\/p>\n 3.5 \u9502-\u786b\u7535\u6c60<\/strong><\/p>\n \u56fe5<\/strong>\uff1a<\/strong>\u9502\u786b\u7535\u6c60\u4e2d\u7684\u4ecb\u5b54\u78b3\u6750\u6599\u793a\u610f\u56fe\u3002\uff08a\uff09\u6709\u5e8f\u4ecb\u5b54\u78b3\uff08CMK-3\uff09\u4e0e\u786b\u9897\u7c92\u53ca\u5176\u5d4c\u9502\u548c\u8131\u9502\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09\u5c06CMK-3\/S\u590d\u5408\u6750\u6599\u7528\u805a\u5408\u7269\u5305\u88f9\uff0c\u4ece\u800c\u4f7f\u591a\u786b\u5316\u7269\u88ab\u9650\u5236\u5728\u78b3\u7b3c\u5b50\u4e2d\u7684\u539f\u7406\u793a\u610f\u56fe\u3002<\/p>\n \u4ecb\u5b54\u6750\u6599\u4e00\u4e2a\u975e\u5e38\u91cd\u8981\u7684\u5e94\u7528\u5c31\u662f\u5e94\u7528\u4e8e\u9502\u786b\u7535\u6c60\uff0c\u9502\u786b\u7535\u6c60\u6bd4\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u66f4\u9ad8\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u4ee5\u53ca\u66f4\u4f4e\u7684\u6210\u672c\uff0c\u4f7f\u5f97\u5176\u6709\u671b\u6210\u4e3a\u4e0b\u4e00\u4ee3\u50a8\u80fd\u5668\u4ef6\u3002\u4f46\u9502\u786b\u7535\u6c60\u7684\u5e94\u7528\u53d7\u5230\u5176\u81ea\u8eab\u7f3a\u9677\u7684\u9650\u5236\uff0c\u4f8b\u5982\uff0c\u7a7f\u68ad\u6548\u5e94\u7b49\u3002\u8fd9\u662f\u7531\u4e8e\u9502\u79bb\u5b50\u548cS\u5bb9\u6613\u53cd\u5e94\uff0c\u5f62\u6210Li2<\/sub>S\uff0c\u8fdb\u800c\u5f71\u54cd\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u6709\u5e8f\u4ecb\u5b54\u78b3\u6750\u6599CMK-3\u53ef\u4ee5\u7528\u4e8e\u9634\u6781\u4e2d\u786b\u7684\u8f7d\u4f53\uff0c\u4ece\u800c\u5c06\u786b\u88c5\u8fdb\u4ecb\u5b54\u78b3\u7684\u7b3c\u5b50\u91cc\uff0c\u5728\u80fd\u591f\u6ee1\u8db3\u6b63\u5e38\u7684\u7535\u5316\u5b66\u53cd\u5e94\u7684\u540c\u65f6\uff0c\u53c8\u80fd\u591f\u6291\u5236\u7a7f\u68ad\u6548\u5e94\u3002\u4f8b\u5982\uff0c\u7ecf\u8fc7\u4f18\u5316\uff0cCMK-3\/S\u7535\u6781\u7684\u653e\u7535\u5bb9\u91cf\u53ef\u4ee5\u8fbe\u52301320 mAh\/g\u3002<\/p>\n 3.6 \u9502-\u7a7a\u6c14\u7535\u6c60<\/strong><\/p>\n \u56fe6<\/strong>\uff1a<\/strong>\u4ecb\u5b54\u6750\u6599\u5728\u9502-\u7a7a\u6c14\u7535\u6c60\u4e2d\u7684\u4f7f\u7528\u3002\uff08a\uff09\u9502-\u6c27\u7535\u6c60\u4e2d\u50ac\u5316\u5242\u4e0e\u7535\u6781\u7684\u76f8\u5e94\u7ed3\u6784\u793a\u610f\u56fe\uff1b\uff08b\uff09\u4ecb\u5b54\u91d1\u7684TEM\u56fe\uff1b\uff08c\u3001d\uff09\u4ecb\u5b54\u91d1\u505a\u7535\u6781\u65f6\uff0c\u9502-\u6c27\u7535\u6c60\u7535\u6d41\u5bc6\u5ea6\u4e3a500 mA\/g\u4e0b\u7684\u5145\u653e\u7535\u5faa\u73af\u66f2\u7ebf\u3002<\/p>\n \u9502-\u7a7a\u6c14\u7535\u6c60\uff08LABs\uff09\uff0c\u76f8\u8f83\u4e8e\u5176\u4ed6\u50a8\u80fd\u5668\u4ef6\uff0c\u63d0\u4f9b\u4e86\u6700\u9ad8\u7684\u7406\u8bba\u50a8\u80fd\u5bc6\u5ea6\u3002LABs\u4e2d\u5e38\u7528\u9502\u91d1\u5c5e\u4f5c\u4e3a\u9633\u6781\uff0c\u5176\u4e2dLi+<\/sup>\u5728\u7535\u89e3\u8d28\u548c\u6c27\u9634\u6781\u4e4b\u95f4\u8fdb\u884c\u4f20\u5bfc\u3002\u5176\u4e2d\u6700\u5927\u7684\u6311\u6218\u662f\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u4e0d\u53ef\u907f\u514d\u5730\u4f1a\u53d1\u751fLi\u4e0eO2<\/sub>\u5316\u5408\u53cd\u5e94\uff0c\u4ea7\u751fLi2<\/sub>O2<\/sub>\u9897\u7c92\uff0c\u5bfc\u81f4\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u4f4e\u4e0b\u3002\u7814\u7a76\u8868\u660e\uff0c\u53ef\u4ee5\u4f7f\u7528\u4ecb\u5b54\u6750\u6599\u6765\u4fc3\u8fdb\u6790\u6c27\u53cd\u5e94\u52a8\u529b\u5b66\u4ee5\u53ca\u6c27\u9634\u6781\u53ef\u9006\u6027\u7684\u53d1\u751f\u3002\u5176\u4e2d\u7684\u4e3b\u8981\u4ee3\u8868\u662f\u5206\u7ea7\u591a\u5b54\u78b3\u6750\u6599\u3002<\/p>\n \uff08\u4e09\uff09\u7535\u5316\u5b66\u8d85\u7ea7\u7535\u5bb9\u5668<\/strong><\/p>\n \u7535\u5316\u5b66\u8d85\u7ea7\u7535\u5bb9\u5668\u5177\u6709\u6bd4\u7535\u6c60\u66f4\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u3002\u4e3b\u8981\u5206\u6210\u4e24\u7c7b\uff0c\uff081\uff09\u7535\u5316\u5b66\u53cc\u5c42\u7535\u5bb9\u5668\uff08EDLCs\uff09\uff1b\uff082\uff09\u7535\u5316\u5b66\u8d5d\u7535\u5bb9\u5668\u3002<\/p>\n \u56fe7<\/strong>\uff1a<\/strong>\u4ecb\u5b54\u6750\u6599\u5728\u7535\u5316\u5b66\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528\u3002\uff08a\uff09EDLC\u4e2d\u96c6\u6d41\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1b\uff08b\uff09\u8d5d\u7535\u5bb9\u5668\u4e2d\u96c6\u6d41\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1b\uff08c\uff09\u76f8\u5e94\u4ecb\u5b54\u6750\u6599\u7684\u500d\u7387\u66f2\u7ebf\uff1b\uff08d\uff09\u76f8\u5e94\u4ecb\u5b54\u6750\u6599\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u66f2\u7ebf\u56fe\u3002<\/p>\n 3.7 \u53cc\u7535\u5c42\u7535\u5bb9\u5668<\/strong><\/p>\n \u50a8\u80fd\u539f\u7406\u662f\u6839\u636e\u7535\u89e3\u8d28\u4e0e\u7535\u6781\u8868\u9762\u5f62\u6210\u53cc\u7535\u5c42\u754c\u9762\u4ece\u800c\u5b9e\u73b0\u50a8\u80fd\uff0c\u6240\u4ee5\uff0cEDLCs\u7684\u80fd\u91cf\u5bc6\u5ea6\u4e0e\u7535\u6781\u6240\u7528\u6750\u6599\u7684\u6bd4\u7535\u5bb9\u5448\u6b63\u76f8\u5173\u3002\u6240\u4ee5\u539f\u5219\u4e0a\uff0c\u589e\u52a0\u4ecb\u5b54\u78b3\u7535\u6781\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\u548c\u5bfc\u7535\u6027\u5c31\u80fd\u5b8c\u7f8e\u5730\u6539\u8fdbEDLCs\u7684\u6027\u80fd\u3002\u76ee\u524d\uff0c\u7ecf\u8fc7\u6539\u8fdb\u540e\uff0c\u53cc\u7535\u5c42\u6bd4\u7535\u5bb9\u80fd\u591f\u8fbe\u5230200 F\/g\uff0c\u4f46\u8fd9\u4e00\u503c\u5bf9\u4e8e\u5546\u4e1a\u5e94\u7528\u8fd8\u8fdc\u8fdc\u4e0d\u591f\u3002<\/p>\n 3.8 \u8d5d\u7535\u5bb9\u5668<\/strong><\/p>\n \u8d5d\u7535\u5bb9\u5668\u7684\u50a8\u80fd\u539f\u7406\u540c\u7535\u6c60\u7c7b\u4f3c\uff0c\u4e0e\u53d1\u751f\u7684\u6cd5\u62c9\u7b2c\u8fc7\u7a0b\u76f8\u5173\u3002\u76f8\u5bf9\u4e8eEDLCs\uff0c\u8d5d\u7535\u5bb9\u5668\u7684\u6bd4\u7535\u5bb9\u4e00\u822c\u662f\u517610\u500d\u4ee5\u4e0a\u3002\u4f46\u662f\uff0c\u5f0a\u7aef\u662f\u8d5d\u7535\u5bb9\u5668\u7684\u5faa\u73af\u5bff\u547d\u8f83\u77ed\uff0c\u500d\u7387\u7279\u6027\u8f83\u4f4e\u3002\u5728\u8fd9\u70b9\u4e0a\uff0c\u76f8\u5173\u7684\u4ecb\u5b54\u6750\u6599\u6709\u4ecb\u5b54\u78b3\u3001\u76f8\u5173\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u5982TiO2<\/sub>\u3001RhO\u3001MnO2<\/sub>\u7b49\u3002<\/p>\n \uff08\u56db\uff09\u71c3\u6599\u7535\u6c60<\/strong><\/p>\n \u805a\u5408\u7269\u7535\u89e3\u8d28\u8584\u819c\u71c3\u6599\u7535\u6c60\uff0c\u4f8b\u5982\u76f4\u63a5\u4ee5\u7532\u9187\u4e3a\u71c3\u6599\u548c\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\uff0c\u7531\u4e8e\u5176\u9ad8\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u3001\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u4ee5\u53ca\u4f4e\u7684\u64cd\u4f5c\u6e29\u5ea6\u5df2\u7ecf\u53d7\u5230\u79d1\u5b66\u754c\u7684\u6781\u5927\u7684\u5173\u6ce8\u3002\u540cLABs\u4e00\u6837\uff0c\u5178\u578b\u7684\u71c3\u6599\u7535\u6c60\u5177\u6709\u4e0e\u9633\u6781\u63d0\u4f9b\u7684\u8d28\u5b50\u548c\u7535\u5b50\u53d1\u751f\u6c27\u5316\u53cd\u5e94\u7684\u6c27\u9634\u6781\uff0c\u4ece\u800c\u4ea7\u751f\u7535\u80fd\u3002<\/p>\n \u56fe8<\/strong>\uff1a<\/strong>\u4ecb\u5b54\u6750\u6599\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002\uff08a\uff09\u5178\u578b\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28\u8584\u819c\u71c3\u6599\u7535\u6c60\u8bbe\u8ba1\u7ed3\u6784\u793a\u610f\u56fe\uff1b\uff08b\uff09\u4ecePtNi3<\/sub>\u5230Pt3<\/sub>Ni\u7eb3\u7c73\u6846\u67b6\u7684\u8f6c\u53d8\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b\uff08c\uff09\u4ee5Pt\u4e3a\u8868\u9762\u7684\u5546\u7528Pt\/C\u3001\u56fa\u6001PtNi\/C\u590d\u5408\u7eb3\u7c73\u9897\u7c92\u4ee5\u53caPt3<\/sub>Ni\/C\u7eb3\u7c73\u6846\u67b6\u7684\u6781\u5316\u7535\u6d41\u6d4b\u8bd5\u66f2\u7ebf\uff1b\uff08d\uff09\u4ee5Pt\u4e3a\u8868\u9762\u7684PtNi\/C\u7eb3\u7c73\u9897\u7c92\u3001Pt3<\/sub>Ni\/C\u7eb3\u7c73\u6846\u67b6\u4ee5\u53ca\u4ee5\u79bb\u5b50\u6d41\u5c01\u88c5\u7684Pt3<\/sub>Ni\/C\u7eb3\u7c73\u6846\u67b6\u57280.95 V\u4e0b\u4e0e\u5546\u7528Pt\/C\u50ac\u5316\u5242\u7684\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\u6bd4\u8f83\u56fe\u8868\u3002<\/p>\n 3.9 \u50ac\u5316\u5242<\/strong><\/p>\n \u71c3\u6599\u7535\u6c60\u4e2d\u53d1\u751f\u53cd\u5e94\uff0c\u9700\u8981\u50ac\u5316\u5242\u3002\u5176\u4e2d\u6700\u4e3a\u5e38\u7528\u7684\u662fPt\/C\u590d\u5408\u50ac\u5316\u5242\uff0c\u4f46\u662f\uff0c\u7531\u4e8ePt\u662f\u8d35\u91d1\u5c5e\uff0c\u6210\u672c\u9ad8\uff0c\u6240\u4ee5\u9700\u8981\u627e\u66ff\u4ee3\u3002\u4ecb\u5b54\u78b3\uff0c\u80fd\u591f\u6781\u5927\u5730\u589e\u8fdbPt\u5728\u5176\u8868\u9762\u7684\u5206\u6563\u6027\uff0c\u4ece\u800c\u964d\u4f4e\u6210\u672c\u540c\u65f6\u8fd8\u80fd\u6784\u5efa\u4e00\u79cd\u6d3b\u6027\u4e09\u76f8\u4f4d\u70b9\uff0c\u63d0\u9ad8\u50ac\u5316\u6548\u7387\u3002\u5f53\u524d\uff0cPt@\u77f3\u58a8\u590d\u5408\u6750\u6599\u53c8\u88ab\u62a5\u9053\uff0c\u8be5\u590d\u5408\u6750\u6599\u5177\u6709\u975e\u5e38\u4f18\u5f02\u7684\u50ac\u5316\u71c3\u6599\u7535\u6c60\u4e2d\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u6d3b\u6027\u3002\u5176\u4ed6\u964d\u4f4e\u6210\u672c\u7684\u65b9\u6cd5\uff0c\u8fd8\u6709\u5c06Pt\u4e0e\u8d31\u91d1\u5c5e\u590d\u5408\u5f62\u6210\u5408\u91d1\uff0c\u5982Pt3<\/sub>Ni\u3002\u8fd8\u6709\u5c31\u662f\uff0c\u76f4\u63a5\u5229\u7528C\u63ba\u6742\u4ecb\u5b54Ni\u7528\u4f5c\u52a9\u50ac\u5316\u5242\u3002\u5f53\u7136\uff0c\u4e5f\u53ef\u4ee5\u7528\u65e0\u91d1\u5c5e\u7eff\u8272\u50ac\u5316\u5242\u3002<\/p>\n 3.10 \u805a\u5408\u7269\u8584\u819c\u7535\u89e3\u8d28<\/strong><\/p>\n \u5728\u71c3\u6599\u7535\u6c60\u7814\u7a76\u4e2d\uff0c\u9664\u4e86\u50ac\u5316\u5242\u6240\u9762\u4e34\u7684\u6311\u6218\u5916\uff0c\u8fd8\u6709\u5176\u7535\u89e3\u8d28\u8584\u819c\u4e5f\u9762\u4e34\u6311\u6218\u3002\u5168\u6c1f\u78fa\u9178\u9178\u79bb\u5b50\u5982Nafion\uff0c\u56e0\u5176\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u7a33\u5b9a\u6027\u548c\u8d28\u5b50\u4f20\u5bfc\u7387\u800c\u6210\u4e3a\u57fa\u51c6\u819c\u6750\u6599\u3002\u4f46\u662f\u7531\u4e8e\u6210\u672c\u9ad8\u3001\u7532\u9187\u5bb9\u6613\u6e17\u900f\u4ee5\u53ca100\u5ea6\u4ee5\u4e0a\u5931\u6c34\u4e25\u91cd\u7b49\u95ee\u9898\u800c\u5236\u7ea6\u4e86\u5b83\u7684\u4f7f\u7528\u3002\u9ad8\u4ea4\u8054\u805a\u82ef\u4e59\u70ef\u548c\u805a\u4e59\u70ef\u6c27\u5316\u7269\u80fd\u591f\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\u3002\u6b64\u5916\uff0c\u8d28\u5b50\u4f20\u5bfc\u7684\u4ecb\u5b54\u6750\u6599\uff0c\u4f8b\u5982\u78f7\u94a8\u9178\u529f\u80fd\u5316\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u4e5f\u8868\u73b0\u51fa\u4ee3\u66ff\u8be5\u79cd\u8584\u819c\u5e94\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u7684\u80fd\u529b\u3002\u5e76\u4e14\uff0c\u7a33\u5b9a\u6027\u66f4\u597d\uff0c\u6548\u7387\u66f4\u9ad8\u3002<\/p>\n 4 <\/strong>\u603b\u7ed3<\/strong><\/p>\n \u4e3a\u4e86\u5b9e\u73b0\u5546\u4e1a\u4e0a\u53ef\u4f9d\u8d56\u7684\u80fd\u6e90\u5668\u4ef6\uff0c\u4ecb\u5b54\u6750\u6599\u7684\u6027\u80fd\u5fc5\u987b\u80fd\u591f\u5b9e\u73b0\u6548\u76ca\u5927\u4e8e\u6210\u672c\u3002\u65f6\u81f3\u4eca\u65e5\uff0c\u57fa\u4e8e\u4ecb\u5b54TiO2<\/sub>\u7684\u7535\u6781\u6750\u6599\uff0c\u5206\u522b\u5728DSSCs\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e0a\u5df2\u7ecf\u8868\u73b0\u51fa\u4e86\u9ad8\u8fbe13%\u548c20.1%\u7684PCE\u3002\u5728\u592a\u9633\u80fd\u71c3\u6599\u4ea7\u54c1\u4e0a\uff0c\u4ecb\u5b54CoO\u7eb3\u7c73\u7c92\u5b50\u5448\u73b0\u51fa5%\u7684STH\u6548\u7387\uff0c\u540c\u65f6\uff0cRh\u7535\u50ac\u5316\u5242\u4e32\u8054\u7684\u5149\u7535\u7535\u6781\u8868\u73b0\u51fa\u6700\u9ad8\u4e3a14%\u7684STH\u6548\u7387\u3002\u5728LIBs\u9886\u57df\uff0c\u4ecb\u5b54Si@C\u590d\u5408\u7535\u6781\u6750\u6599\u5448\u73b0\u51fa3.67 mAh\/cm2<\/sup>\u7684\u53ef\u9006\u9762\u5bb9\u91cf\u3002\u5728Li-S\u7535\u6c60\u9886\u57df\uff0c\u5206\u7ea7\u591a\u5b54\u78b3\u7535\u6781\uff0c\u6bd4\u5bb9\u91cf\u53ef\u8fbe1382 mAh\/g\uff0c1000\u6b21\u5faa\u73af\u540e\uff0c\u5e73\u5747\u6bcf\u6b21\u5faa\u73af\u7684\u5bb9\u91cf\u8870\u51cf\u4ec5\u4e3a0.039%\u3002\u5728LABs\u9886\u57df\uff0c\u4ecb\u5b54\u91d1\u9634\u6781\u6750\u6599\u5b9e\u73b0\u4e86Li-O2<\/sub>\u7535\u6c60\u4e2d\u7684\u6700\u9ad8\u53ef\u9006\u7387\uff0c100\u6b21\u5faa\u73af\u540e\u8fd8\u670995%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\uff0c\u4ecb\u5b54\u78b3\u63ba\u6742\u7684Ni\u7535\u6781\u6750\u6599\uff0c\u6bd4\u7535\u5bb9\u9ad8\u8fbe790 F\/g\uff0c\u8fdc\u9ad8\u4e8e\u5546\u4e1a\u4e0a\u6d3b\u6027\u70ad\u7535\u6781\u7684165 F\/g\u3002\u71c3\u6599\u7535\u6c60\u65b9\u9762\uff0c\u4ecb\u5b54Pt\u5305\u88f9\u7684Pt3<\/sub>Ni\u7eb3\u7c73\u6846\u67b6\u7684\u7535\u6d41\u5bc6\u5ea6\u80fd\u8fbe\u52305.7 A\/mg \u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u8fdc\u9ad8\u4e8e\u7f8e\u56fd\u80fd\u6e90\u90e8\u8bbe\u7f6e\u76842017\u5e74\u76ee\u68070.44 A\/mg\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n \u5728\u8be5\u7bc7\u7efc\u8ff0\u4e4b\u4e2d\uff0c\u4f5c\u8005\u7cfb\u7edf\u5730\u603b\u7ed3\u4e86\u4ecb\u5b54\u6750\u6599\u5728\u80fd\u91cf\u8f6c\u6362\u548c\u50a8\u5b58\u4e2d\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u3002\u901a\u8fc7\u5bf9\u4ecb\u5b54\u6750\u6599\u5728\u5236\u5907\u65b9\u6cd5\u3001\u5e94\u7528\u9014\u5f84\u7684\u8be6\u5c3d\u4ecb\u7ecd\uff0c\u4e3a\u672a\u6765\u80fd\u91cf\u8f6c\u6362\u4e0e\u80fd\u91cf\u50a8\u5b58\u9886\u57df\u4e2d\u4ecb\u5b54\u6750\u6599\u53ef\u80fd\u53d1\u6325\u7684\u4f5c\u7528\u8fdb\u884c\u4e86\u9610\u8ff0\uff0c\u4e3a\u4eca\u540e\u4eba\u4eec\u5728\u65b0\u80fd\u6e90\u9886\u57df\u4e86\u89e3\u548c\u8fd0\u7528\u4ecb\u5b54\u6750\u6599\u63d0\u4f9b\u8f83\u4e3a\u5b8c\u5907\u7684\u8d44\u6599\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1aMesoporous materials for energy conversion and storage devices<\/a> \uff08Nat. Rev. Mater., 2016,\u00a0DOI<\/strong>:10.1038\/natrevmats.2016.23\uff09\uff08\u6587\u732e\u5168\u6587PDF\u5df2\u6709\u7f51\u53cb\u4e0a\u4f20\u81f3\u6750\u6599\u4eba\u8bba\u575b<\/a>\u548c\u6750\u6599\u4eba\u8d44\u6e90\u5171\u4eab\u4ea4\u6d41\u7fa4 425218085\uff09<\/p>\n<\/p>\n
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