{"id":46120,"date":"2016-10-12T06:30:17","date_gmt":"2016-10-11T22:30:17","guid":{"rendered":"\/\/m.iemloyee.com\/?p=46120"},"modified":"2016-10-11T23:19:23","modified_gmt":"2016-10-11T15:19:23","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81%ef%bd%9cjacs%ef%bc%9a9%e6%9c%88%e6%9d%90%e6%96%99%e5%89%8d%e6%b2%bf%e7%a7%91%e7%a0%94%e6%88%90%e6%9e%9c%e5%8d%81%e5%a4%a7%e7%b2%be%e9%80%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=46120","title":{"rendered":"\u9876\u520a\u52a8\u6001\uff5cJACS\uff1a9\u6708\u6750\u6599\u524d\u6cbf\u79d1\u7814\u6210\u679c\u5341\u5927\u7cbe\u9009"},"content":{"rendered":"

\"176<\/p>\n

\u4eca\u5929\u6750\u6599\u725b\u9080\u60a8\u4e00\u8d77\u6765\u770b\u770b\u56fd\u9645\u8457\u540d\u671f\u520aJACS 2016\u5e749\u6708\u6750\u6599\u524d\u6cbf\u79d1\u7814\u6210\u679c\u5341\u5927\u7cbe\u9009\uff1a\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66<\/strong>\u2014\u2014<\/strong>NBN\u578b\u952f\u9f7f\u72b6\u591a\u73af\u82b3\u70c3\u78b3\u6c22\u5316\u5408\u7269\u7684\u5408\u6210\u2014\u2014\u4ee51,9-Diaza-9a-boraphenalene\u4e3a\u7ed3\u6784\u57fa\u5143\uff1b\u5170\u5dde\u5927\u5b66<\/strong>\u2014\u2014<\/strong>\u5229\u7528\u624b\u6027\u57fa\u5143\u6784\u5efa\u6676\u72b6\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\uff1b\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u5316\u6240<\/strong>\u2014\u2014<\/strong>\u5355\u5206\u5b50\u7eb3\u7c73\u50ac\u5316\u4f5c\u7528\u63ed\u793a\u5355\u6676\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u5316\u80fd\uff1b\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66<\/strong>\u2014\u2014<\/strong>\u4e8c\u7ef4\u624b\u6027\u591a\u5b54\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u7684\u591a\u76f8\u4e0d\u5bf9\u79f0\u50ac\u5316\uff1b\u53a6\u95e8\u5927\u5b66\u2014\u2014<\/strong>\u901a\u8fc7\u79bb\u5b50\u914d\u5bf9\u6cd5\u4e0d\u5bf9\u79f0\u5408\u6210\u624b\u6027\u53cc\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4\u2212<\/sup>\uff1b\u5357\u5f00\u5927\u5b66<\/strong>\u2014\u2014<\/strong>Zn\uff08CF3<\/sub>SO3<\/sub>\uff092<\/sub>\u4e3a\u7535\u89e3\u8d28\u7684Zn\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u9633\u79bb\u5b50\u578b\u5c16\u6676\u77f3LiMn2<\/sub>O4<\/sub>\u8d1f\u6781\u7814\u7a76\uff1b\u5317\u4eac\u5927\u5b66<\/strong>\u2014\u2014<\/strong>\u65e0\u6c22\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\u5b9e\u73b0\u4e9a\u5fae\u7c73\u7ea7\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u9635\u5217\u7684\u9009\u62e9\u6027\u751f\u957f\uff1b\u6258\u83b1\u591a\u5927\u5b66<\/strong>&<\/strong>\u4e1c\u5357\u5927\u5b66\u2014\u2014<\/strong>\u6c1f\u4ee3\u7532\u8112\u7898\u5316\u9521\u4e0e\u7532\u57fa\u7898\u5316\u94c5\u7ed3\u5408\u6cd5\u6784\u5efa\u9ad8\u6548\u4f4e\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff1b\u4e2d\u79d1\u9662\u5317\u4eac\u7406\u5316\u6280\u672f\u7814\u7a76\u6240<\/strong>\u2014\u2014<\/strong>\u6709\u673a\u94c2\uff08II\uff09\u91d1\u5c5e\u73af\u7684\u591a\u7ea7\u81ea\u7ec4\u88c5\u53cd\u5e94\u2014\u2014\u5177\u6709\u5bfc\u901a\u8367\u5149\u6027\u7684TMV\u5408\u6210\u7269\uff1b\u590d\u65e6\u5927\u5b66<\/strong>\u2014\u2014<\/strong>\u80f6\u675f\u878d\u5408-\u805a\u96c6\u88c5\u914d\u6cd5\u5236\u5907\u7528\u4e8e\u8d85\u7075\u654f\u6c28\u6c14\u4f20\u611f\u5668\u7684\u6709\u5e8f\u4ecb\u5b54\u78b3\u6750\u6599\u3002<\/p>\n

1\u3001\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\uff1aNBN<\/strong>\u578b\u952f\u9f7f\u72b6\u591a\u73af\u82b3\u70c3\u78b3\u6c22\u5316\u5408\u7269\u7684\u5408\u6210\uff1a\u4ee51,9-Diaza-9a-boraphenalene<\/strong>\u4e3a\u7ed3\u6784\u57fa\u5143<\/strong><\/p>\n

\"01\"<\/p>\n

\u56fe1 <\/strong>NBN\u578b\u952f\u9f7f\u72b6\u591a\u73af\u82b3\u70c3\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\u8fd1\u671f\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u7684\u5f20\u5e06\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u51af\u65b0\u4eae\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u4ee5\u4e00\u79cd\u63ba\u6742\u4e86\u4e24\u4e2a\u6c2e\u539f\u5b50\u548c\u4e00\u4e2a\u787c\u539f\u5b50\u7684\u952f\u9f7f\u72b6\u591a\u73af\u82b3\u70c3\u4e3a\u57fa\u7840\uff0c\u5408\u6210\u4e86\u591a\u79cd\u65b0\u578b\u952f\u9f7f\u72b6\u591a\u73af\u82b3\u70c3\uff08\u4e09\u79cdNBN-DBP\u548c\u4e00\u79cdNBN-DBHZ\uff09\u3002\u8be5\u9879\u7814\u7a76\u6210\u679c\u80fd\u591f\u5e94\u7528\u4e8e\u83b7\u5f97\u03c0\u952e\u5171\u8f6d\u7684NBN\u578b\u4e8c\u82ef\u4e03\u5d4c\u6bb5\u805a\u5408\u7269\uff08NBN-DBHZ\uff09\uff0c\u6b64\u5916\uff0c\u8fd8\u80fd\u6210\u4e3a\u5408\u6210NBN\u578b\u63ba\u6742\u7684\u952f\u9f7f\u72b6\u77f3\u58a8\u70ef\u7eb3\u7c73\u5e26\u7684\u6709\u6548\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSynthesis of NBN-Type Zigzag-Edged Polycyclic Aromatic Hydrocarbons: 1,9-Diaza-9a-boraphenalene as a Structural Motif<\/a> \uff08J. Am. Chem. Soc., 2016, \u00a0<\/strong>DOI: 10.1021\/jacs.6b04445\uff09<\/p>\n

2\u3001\u5170\u5dde\u5927\u5b66\uff1a\u5229\u7528\u624b\u6027\u57fa\u5143\u6784\u5efa\u6676\u72b6\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs<\/strong>\uff09<\/strong><\/p>\n

\"02\"<\/p>\n

\u56fe2 <\/strong>\u624b\u6027\u57fa\u5143\u6784\u5efa\u6676\u72b6\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u7684\u539f\u7406\u793a\u610f\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u5170\u5dde\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u7684\u738b\u4e3a\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u4e01\u4e09\u5143\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u624b\u6027\u57fa\u5143\u76f4\u63a5\u5408\u6210\u624b\u6027\u529f\u80fd\u5316COFs\u6750\u6599\u7684\u65b9\u6cd5\u3002\u5176\u4e2d\u7684\u6838\u5fc3\u8bbe\u8ba1\u662f\u4f7f\u7528\u5177\u6709\u521a\u6027\u7684\u652f\u67b64,4′-(1H-\u82ef\u5e76[d]\u54aa\u5511-4,7-\u4e8c\u57fa)\u4e8c\u82ef\u80fa\u7528\u4e8e\u652f\u6491\u5404\u79cd\u624b\u6027\u57fa\u56e2\u3002\u8fdb\u4e00\u6b65\u7684\u5b9e\u9a8c\u8868\u660e\u8fd9\u4e9b\u624b\u6027COFs\u6750\u6599\u5177\u6709\u7ed3\u6784\u7a33\u5b9a\u6027\u5e76\u4e14\u5728\u5f02\u8d28\u6709\u673a\u50ac\u5316\u65b9\u9762\u8868\u73b0\u51fa\u9ad8\u5ea6\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8be5\u9879\u7814\u7a76\u6210\u679c\u4e3a\u529f\u80fd\u5316COFs\u6750\u6599\u7684\u5efa\u6784\u63d0\u4f9b\u4e86\u65b0\u7684\u7814\u7a76\u9014\u5f84\uff0c\u5e76\u8d4b\u4e88\u5176\u9ad8\u5ea6\u6709\u7528\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aConstructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b07516\uff09<\/p>\n

3\u3001\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u5316\u6240\uff1a\u5355\u5206\u5b50\u7eb3\u7c73\u50ac\u5316\u4f5c\u7528\u63ed\u793a\u5355\u6676\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u5316\u80fd<\/strong><\/p>\n

\"03\"<\/p>\n

\u56fe3 <\/strong>\u4e24\u5e8f\u50ac\u5316\uff08\u5373\uff0c\u4ea7\u7269\u5f62\u6210\u548c\u89e3\u6784\uff09\u8fc7\u7a0b\u793a\u610f\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u636e\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u7684\u5f90\u7ef4\u6797\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\uff0c\u901a\u8fc7\u76d1\u6d4b\u5355\u4f53\u91d1\u7eb3\u7c73\u50ac\u5316\u5242\u5728\u8367\u5149\u53cd\u5e94\u4e2d\u5bf9\u6e29\u5ea6\u7684\u4f9d\u8d56\u6027\uff0c\u4ed6\u4eec\u4ece\u57fa\u4e8e\u5355\u4f53\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u4e24\u5e8f\u50ac\u5316\uff08\u5373\uff0c\u4ea7\u7269\u5f62\u6210\u548c\u89e3\u6784\uff09\u7684\u6301\u7eed\u6b65\u9aa4\u4e2d\u83b7\u5f97\u4e86\u6d3b\u5316\u80fd\u4fe1\u606f\u3002\u6d3b\u5316\u80fd\u5728\u591a\u4e2a\u5355\u4f53\u7eb3\u7c73\u50ac\u5316\u5242\u4e2d\u7684\u5177\u6709\u5e7f\u6cdb\u5206\u5e03\u7684\u7279\u70b9\uff0c\u8868\u660e\u5355\u4f53\u7eb3\u7c73\u50ac\u5316\u5242\u95f4\u5b58\u5728\u5de8\u5927\u7684\u9759\u6001\u5f02\u8d28\u6027\u3002\u5728\u5355\u9897\u7c92\u6c34\u5e73\u4e0a\uff0c\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u8865\u507f\u6548\u5e94\u548c\u7b49\u52a8\u5173\u7cfb\u4e5f\u80fd\u591f\u88ab\u89c2\u5bdf\u5230\u3002\u8be5\u9879\u7814\u7a76\u6210\u679c\u4e3a\u5176\u4ed6\u7684\u529f\u80fd\u5316\u5355\u5206\u5b50\u7eb3\u7c73\u50ac\u5316\u53cd\u5e94\u548c\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u4e00\u4e9b\u91cd\u8981\u7684\u7406\u89e3\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSingle-Molecule Nanocatalysis Reveals Catalytic Activation Energy of Single Nanocatalysts<\/a> \uff08J. Am. Chem. Soc., 2016,\u00a0DOI: 10.1021\/jacs.6b05600\uff09<\/p>\n

4\u3001\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\uff1a\u4e8c\u7ef4\u624b\u6027\u591a\u5b54\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs<\/strong>\uff09\u7684\u591a\u76f8\u4e0d\u5bf9\u79f0\u50ac\u5316<\/strong><\/p>\n

\"04\"<\/p>\n

\u56fe4 <\/strong>\u5408\u6210\u8fc7\u7a0b\u539f\u7406\u53ca\u6240\u5f97COFs\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u7684\u5d14\u52c7\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5218\u71d5\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u4f7f\u7528\u5bf9\u6620\u5f02\u6784\u4f53\u4e8c\u7532\u9187\u548c4,4\u2032-\u4e8c\u80fa\u4ea4\u8054\u5242\uff0c\u6210\u529f\u5408\u6210\u4e86\u5177\u6709\u624b\u6027\u529f\u80fd\u7684\u4e8c\u7ef4\u5d4c\u6bb5\u5f0f\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u3002\u7ecf\u7ed3\u6784\u8868\u5f81\u548c\u8ba1\u7b97\u673a\u6a21\u62df\u540e\u53d1\u73b0\uff0c\u8be5\u79cdCCOF\u6750\u6599\u5177\u6709\u53cc\u91cd\u7684\u4e92\u7a7f\u578b\u7f51\u683c\u3002\u901a\u8fc7\u5bf9\u5e26\u6709Ti(O`Pr)4\u7684\u4e8c\u7532\u9187\u5355\u5143\u7684\u624b\u6027\u4e8c\u7f9f\u57fa\u7ec4\u8fdb\u884c\u540e\u6539\u6027\uff0c\u6750\u6599\u6210\u4e3a\u5177\u6709\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684\u4e8c\u4e59\u57fa\u950c\u5bf9\u919b\u7684\u4e0d\u5bf9\u79f0\u52a0\u6210\u7684\u975e\u5747\u76f8\u50ac\u5316\u5242\u3002\u8be5\u7814\u7a76\u5c06\u4f1a\u4e3a\u521b\u9020\u65b0\u578b\u591a\u5b54\u6750\u6599\u62d3\u5bbd\u6750\u6599\u8bbe\u8ba1\u4e0e\u5de5\u7a0b\u7684\u8303\u56f4\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHomochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis<\/a> \uff08J. Am. Chem. Soc., 2016, \u00a0<\/strong>DOI: 10.1021\/jacs.6b07714\uff09<\/p>\n

5\u3001\u53a6\u95e8\u5927\u5b66\uff1a\u901a\u8fc7\u79bb\u5b50\u914d\u5bf9\u6cd5\u4e0d\u5bf9\u79f0\u5408\u6210\u624b\u6027\u53cc\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4\u2212<\/sup> <\/strong><\/p>\n

\"05\"<\/p>\n

\u56fe5 <\/strong>BCNC\u548cBCDC\u7684\u7ed3\u6784\u5dee\u5f02\u793a\u610f\u56fe\u4e0e\u76f8\u5e94\u5706\u4e8c\u8272\u8c31\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u7684\u90d1\u5357\u5cf0\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548cBoon K. Teo\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5408\u4f5c\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u79bb\u5b50\u914d\u5bf9\u6cd5\u9996\u6b21\u4e0d\u5bf9\u79f0\u5408\u6210\u4e86\u624b\u6027\u53cc\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4\u2212<\/sup>\uff0c\u8d28\u8c31\u6d4b\u8bd5\u663e\u793a\u5728\u9634\u9633\u79bb\u5b50\u56e2\u7c07\u4e4b\u95f4\u5177\u6709\u76f8\u5bf9\u8f83\u5f3a\u7684\u79bb\u5b50\u914d\u5bf9\u76f8\u4e92\u4f5c\u7528\u3002\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u8868\u660e\uff0c\u5149\u5b66\u6d3b\u6027\u7684\u65cb\u5149\u5bf9\u6620\u4f53[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4\u2212<\/sup>\u7684\u76f4\u63a5\u4e0d\u5bf9\u79f0\u5408\u6210\u662f\u901a\u8fc7\u4f7f\u7528\u56e2\u7c07\u4e2d\u9002\u5f53\u7684\u624b\u6027\u94f5\u9633\u79bb\u5b50\uff08\u4f8b\u5982\uff0cN-benzylcinchoninium\u548cN-benzylcinchonidinium\uff09\u5b9e\u73b0\u7684\u3002\u8fd9\u9879\u4ee5\u79bb\u5b50\u914d\u5bf9\u4f7f\u5bf9\u6620\u4f53\u5206\u79bb\u548c\u4f7f\u7528\u4e86\u624b\u6027\u6297\u8861\u65b9\u5f0f\u5b9e\u73b0\u76f4\u63a5\u4e0d\u5bf9\u79f0\u5408\u6210\u7684\u7b80\u6d01\u65b9\u6848\uff0c\u53ef\u80fd\u4f1a\u6210\u4e3a\u5236\u5907\u624b\u6027\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u4e00\u822c\u6027\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAsymmetric Synthesis of Chiral Bimetallic [Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4\u2212<\/sup> Nanoclusters via Ion Pairing<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b08100\uff09<\/p>\n

6\u3001\u5357\u5f00\u5927\u5b66\uff1a Zn<\/strong>\uff08CF3<\/sub>SO3<\/sub><\/strong>\uff092<\/sub><\/strong>\u4e3a\u7535\u89e3\u8d28\u7684Zn<\/strong>\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u9633\u79bb\u5b50\u578b\u5c16\u6676\u77f3LiMn2<\/sub>O4<\/sub><\/strong>\u8d1f\u6781\u7814\u7a76<\/strong><\/p>\n

\"06\"<\/p>\n

\u56fe6<\/strong> Zn\u79bb\u5b50\u7535\u6c60\u4e2d\u5728ZnMnO\u5c16\u6676\u77f3\u8d1f\u6781\u4e2d\u7684\u5145\u653e\u7535\u539f\u7406\u793a\u610f\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u636e\u5357\u5f00\u5927\u5b66\u5316\u5b66\u7cfb\u7684\u7a0b\u65b9\u76ca\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\uff0c\u4ed6\u4eec\u6210\u529f\u8bc1\u660e\u4e86\u9633\u79bb\u5b50\u578b\u7f3a\u9677ZnMn2<\/sub>O4<\/sub>\u5c16\u6676\u77f3\u80fd\u591f\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u8d1f\u6781\u6750\u6599\u7528\u4e8e\u6c34\u6eb6\u6027Zn\u79bb\u5b50\u4e8c\u6b21\u7535\u6c60\u4e4b\u4e2d\u3002\u5728\u4ee5Zn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u4e3a\u7535\u89e3\u8d28\u7684\u60c5\u51b5\u4e0b\uff0c\u6240\u5f97ZMO\/C\u542b\u6709\u975e\u5e38\u4e30\u5bcc\u7684\u7a7a\u4f4d\u9633\u79bb\u5b50\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a50 mA\/g\u4e0b\u5448\u73b0\u51fa\u9ad8\u8fbe150 mAh\/g\u80fd\u91cf\u5bc6\u5ea6\u3002\u8be5\u9879\u7814\u7a76\u540c\u65f6\u8868\u660e\uff0c\u4ece\u4e8c\u5143\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u8f6c\u53d8\u4e3a\u590d\u5408\u5c16\u6676\u77f3\u6c27\u5316\u7269\u4ee5\u53ca\u7535\u89e3\u8d28\u76d0\u7684\u4f7f\u7528\u5305\u62ec\u7b28\u91cd\u7684\u9634\u79bb\u5b50\uff08\u5982CF3<\/sub>SO3<\/sub>–<\/sup>\uff09\uff0c\u4e5f\u8bb8\u80fd\u591f\u4e3a\u53d1\u5c55\u9ad8\u5b89\u5168\u6027\u3001\u4f4e\u6210\u672c\u548c\u73af\u4fdd\u578b\u7684\u6c34\u6eb6\u6027Zn\u79bb\u5b50\u4e8c\u6b21\u7535\u6c60\u6253\u5f00\u4e00\u4e2a\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCation-Deficient Spinel ZnMn2<\/sub>O4<\/sub> Cathode in Zn(CF3<\/sub>SO3<\/sub>)2<\/sub> Electrolyte for Rechargeable Aqueous Zn-Ion Battery<\/a> \uff08J. Am. Chem. Soc., 2016, \u00a0DOI: 10.1021\/jacs.6b05958\uff09<\/p>\n

7\u3001\u5317\u4eac\u5927\u5b66\uff1a\u65e0\u6c22\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\u5b9e\u73b0\u4e9a\u5fae\u7c73\u7ea7\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u9635\u5217\u7684\u9009\u62e9\u6027\u751f\u957f<\/strong><\/p>\n

\"07\"<\/p>\n

\u56fe7 <\/strong>\u65e0\u6c22CVD\u6cd5\u5b9e\u73b0SWNT\u9009\u62e9\u6027\u751f\u957f\u7684\u539f\u7406\u793a\u610f\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u7684\u5f20\u9526\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u795e\u5947\u7684\u9009\u62e9\u6027\u751f\u957f\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08SWNT\uff09\u9635\u5217\u7684\u65b9\u6cd5\uff0c\u5f97\u5230\u7684\u9635\u5217\u5728\u77f3\u82f1\u8868\u9762\u7684\u5bc6\u5ea6\u4e3a0.3\u20140.5 tubes\/\u03bc<\/em>m\uff0c\u7ea684%\u7684\u76f4\u5f84\u57280.75\u20140.95 nm\u4e4b\u95f4\u3002\u8fdb\u4e00\u6b65\u7684\u5b9e\u9a8c\u548c\u5206\u6790\u8868\u660e\u5c0f\u5c3a\u5bf8\u7684Mo\u50ac\u5316\u5242\u9009\u62e9\u6027\u6210\u6838\u53ef\u4ee5\u901a\u8fc7\u5728\u65e0\u6c22CVD\u4e2d\u4f7f\u7528\u4f4e\u7684\u78b3\u6e90\u4f9b\u7ed9\u901f\u7387\u77ed\u65f6\u95f4\u5185\u7684\u751f\u957f\u6765\u5b9e\u73b0\u3002\u66f4\u8fdb\u4e00\u6b65\u6765\u8bf4\uff0c\u8fd9\u79cd\u65b9\u6cd5\u53ef\u4ee5\u4e3a\u5c0f\u5c3a\u5bf8SWNT\u9635\u5217\u4ee5\u7a84\u5316\u7684\u624b\u6027\u5206\u5e03\u7684\u9009\u62e9\u6027\u751f\u957f\u7528\u4e8e\u84dd\u5b9d\u77f3\u4e0a\u3002\u8fd9\u9879\u6210\u679c\u4e3aSWNTs\u7684\u9009\u62e9\u6027\u751f\u957f\u673a\u7406\u63d0\u4f9b\u4e86\u66f4\u591a\u6709\u4ef7\u503c\u7684\u601d\u8def\uff0c\u540c\u65f6\u4e5f\u53ef\u4ee5\u53d1\u5c55\u4e3a\u4e00\u79cd\u4e00\u822c\u6027\u7684\u5408\u6210\u5176\u4ed6\u7ed3\u6784\u53ef\u63a7\u7684\u4e00\u7ef4\u7eb3\u7c73\u6750\u6599\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSelective Growth of Subnanometer Diameter Single-Walled Carbon Nanotube Arrays in Hydrogen-Free CVD<\/a> \uff08J. Am. Chem. Soc., 2016, \u00a0<\/strong>DOI: 10.1021\/jacs.6b06477\uff09<\/p>\n

8\u3001\u6258\u83b1\u591a\u5927\u5b66&\u4e1c\u5357\u5927\u5b66\uff1a\u6c1f\u4ee3\u7532\u8112\u7898\u5316\u9521\u4e0e\u7532\u57fa\u7898\u5316\u94c5\u7ed3\u5408\u6cd5\u6784\u5efa\u9ad8\u6548\u4f4e\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n

\"08\"<\/p>\n

\u56fe8 <\/strong>\u8be5\u79cd\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7eb5\u5411SEM\u56fe\u548cJ\u2014V<\/em>\u66f2\u7ebf\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u6258\u83b1\u591a\u5927\u5b66\u7684Yanfa Yan\uff08\u901a\u8baf\u4f5c\u8005\uff09\u3001Dewei Zhao\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u4e1c\u5357\u5927\u5b66\u7684\u718a\u4ec1\u6839\uff08\u901a\u8baf\u4f5c\u8005\uff09\u62a5\u9053\uff0c\u4ed6\u4eec\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u7684FASnI3<\/sub>\u548cMAPbI3<\/sub>\u7ed3\u5408\u578b\u524d\u9a71\u4f53\u3002\u8be5\u79cd\u524d\u9a71\u4f53\u53ef\u4ee5\u7528\u4e8e\u5236\u5907\u9ad8\u8d28\u91cf\u7684\u6df7\u5408\u578bPb\u2014Sn\u4f4e\u5e26\u9699\u9499\u949b\u77ff\u8584\u819c\uff0c\u5e76\u80fd\u591f\u7528\u4e8e\u6784\u5efa\u9ad8\u6548\u4f4e\u5e26\u9699\u6df7\u5408\u578bSn\u2014Pb\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u3002\u5176\u4e2d\uff0c\u6027\u80fd\u6700\u597d\u7684\u7535\u6c60\u7684\u5e26\u9699\u53ea\u6709\u7ea61.2 eV\uff0c\u5e76\u5b9e\u73b0\u4e86\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff0915%\uff0c\u8fdc\u9ad8\u4e8e\u4e4b\u524d\u62a5\u9053\u7684\u7c7b\u4f3c\u5e26\u9699\u5bbd\u5ea6\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u3002\u8fd9\u5c31\u4e3a\u4f4e\u5e26\u9699\u3001\u9ad8\u8f6c\u6362\u6548\u7387\u4ee5\u53ca\u9ad8\u53ef\u91cd\u590d\u6027\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aFabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide<\/a> \uff08J. Am. Chem. Soc., 2016, \u00a0DOI: 10.1021\/jacs.6b08337\uff09<\/p>\n

9\u3001\u4e2d\u79d1\u9662\u5317\u4eac\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\uff1a\u6709\u673a\u94c2\uff08II<\/strong>\uff09\u91d1\u5c5e\u73af\u7684\u591a\u7ea7\u81ea\u7ec4\u88c5\u53cd\u5e94\u2014\u2014\u5177\u6709\u5bfc\u901a\u8367\u5149\u6027\u7684TMV<\/strong>\u5408\u6210\u7269<\/strong><\/p>\n

\"09\"<\/p>\n

\u56fe9 <\/strong>\u68d2\u72b6\u70df\u8349\u82b1\u53f6\u75c5\u6bd2TMV\u4e0e\u6709\u673a\u94c2\uff08\u2161\uff09\u91d1\u5c5e\u73af\u4f5c\u7528\u793a\u610f\u56fe<\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5317\u4eac\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u7684\u725b\u5fe0\u4f1f\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u7f8e\u56fd\u72b9\u4ed6\u5927\u5b66\u7684Peter J. Stang\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5408\u4f5c\u62a5\u9053\u4e86\u4ed6\u4eec\u7684\u6700\u65b0\u6210\u679c\u3002\u4ed6\u4eec\u9996\u6b21\u63cf\u8ff0\u4e86\u68d2\u72b6\u70df\u8349\u82b1\u53f6\u75c5\u6bd2TMV\u4e0e\u79bb\u6563\u56db\u82ef\u4e59\u70ef\uff08TPE\uff09\u6709\u673a\u94c2\uff08\u2161\uff09\u91d1\u5c5e\u73af\u901a\u8fc7\u9759\u7535\u4f5c\u7528\u8fdb\u884c\u591a\u7ea7\u81ea\u7ec4\u88c5\u7684\u673a\u5236\u3002\u8fd9\u79cd\u75c5\u6bd2\u53ef\u4ee5\u901a\u8fc7\u4e0e\u4e00\u4e2a\u6b63\u7535\u8377\u5206\u5b50\u201c\u80f6\u201d\u4e4b\u95f4\u7684\u591a\u91cd\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u7ec4\u88c5\u6210\u4e09\u7ef4\u5fae\u7c73\u5c3a\u5bf8\u7684\u8d85\u7ed3\u6784\uff0c\u5373\u4e00\u4e2a\u56db\u82ef\u4e59\u70ef\uff08TPE\uff09\u57fa\u7684\u79bb\u6563\u6709\u673a\u94c2(II)\u91d1\u5c5e\u73af\u9519\u5408\u7269\uff08TPE-Pt-MC\uff09\u3002\u8be5\u9879\u7814\u7a76\u6210\u679c\u5728\u52a8\u6001\u5149\u5b66\u6750\u6599\u6216\u751f\u7269\u586b\u6599\u7684\u7814\u7a76\u4e2d\u5177\u6709\u975e\u5e38\u5ba2\u89c2\u7684\u5438\u5f15\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHierarchical Self-Assembly of Responsive Organoplatinum(II) Metallacycle\u2013TMV Complexes with Turn-On Fluorescence<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b07402\uff09
\n
\n10\u3001\u590d\u65e6\u5927\u5b66\uff1a\u80f6\u675f\u878d\u5408-<\/strong>\u805a\u96c6\u88c5\u914d\u6cd5\u5236\u5907\u7528\u4e8e\u8d85\u7075\u654f\u6c28\u6c14\u4f20\u611f\u5668\u7684\u6709\u5e8f\u4ecb\u5b54\u78b3\u6750\u6599<\/strong><\/p>\n

\"10\"<\/p>\n

\u56fe10 <\/strong>OMCs\u7684\u5f62\u8c8c\u4ee5\u53ca\u7528\u4e8e\u4f20\u611f\u5668\u65f6\u7684\u6027\u80fd\u6d4b\u8bd5\u7ed3\u679c<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aA Micelle Fusion\u2013Aggregation Assembly Approach to Mesoporous Carbon Materials with Rich Active Sites for Ultrasensitive Ammonia Sensing<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b07355\uff09<\/p>\n

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