{"id":45033,"date":"2016-10-08T06:32:36","date_gmt":"2016-10-07T22:32:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=45033"},"modified":"2017-03-04T10:39:52","modified_gmt":"2017-03-04T02:39:52","slug":"jacs%e5%b0%81%e9%9d%a2%e8%ae%ba%e6%96%87%ef%bc%9a%e4%b8%ad%e7%a7%91%e5%a4%a7%e4%bf%9e%e4%b9%a6%e5%ae%8f%e8%af%be%e9%a2%98%e7%bb%84%e6%88%90%e5%8a%9f%e5%90%88%e6%88%90%e5%85%b7%e6%9c%89%e6%98%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=45033","title":{"rendered":"JACS\u5c01\u9762\u8bba\u6587\uff1a\u4e2d\u79d1\u5927\u4fde\u4e66\u5b8f\u8bfe\u9898\u7ec4\u6210\u529f\u5408\u6210\u5177\u6709\u663e\u8457\u589e\u5f3a\u5149\u7535\u6027\u80fd\u7684\u65b0\u578b\u591a\u5f62\u4f53\u786b\u5316\u94dc\u7eb3\u7c73\u5f02\u8d28\u7ed3"},"content":{"rendered":"<p><span style=\"color: #ff0000;\"><strong>\u611f\u8c22\u4fde\u8001\u5e08\u5bf9\u672c\u6587\u7684\u6307\u5bfc\u548c\u5bf9\u6750\u6599\u4eba\u7f51\u7684\u5927\u529b\u652f\u6301\uff01<\/strong><\/span><\/p>\n<p>\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5408\u80a5\u5fae\u5c3a\u5ea6\u7269\u8d28\u79d1\u5b66\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u4fde\u4e66\u5b8f\u6559\u6388\u8bfe\u9898\u7ec4\u4e0e\u674e\u9707\u5b87\u6559\u6388\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u5728\u591a\u5f62\u4f53\u786b\u5316\u7269\u534a\u5bfc\u4f53\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u5149\u7535\u8f6c\u6362\u5e94\u7528\u65b9\u9762\u53d6\u5f97\u4e86\u65b0\u8fdb\u5c55\u3002\u7814\u7a76\u6210\u679c\u201cPrecursor Triggering Synthesis of Self-Coupled Sulfide Polymorphs with Enhanced Photoelectrochemical Properties\u201d\u4ee5\u5c01\u9762\u8bba\u6587\u53d1\u8868\u5728\u300a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\u300b(J. Am. Chem. Soc. 2016, 138(39), 12913-12919)\uff0c\u5e76\u88abJACS Spotlights\u4ee5\u201cHeteronanostructure Polymorphs with Enhanced Photoelectrochemical Properties\u201d \u9009\u4e3a\u7814\u7a76\u4eae\u70b9\u3002<\/p>\n<p>\u65b0\u9896\u7684\u7eb3\u7c73\u6676\u6750\u6599\u7684\u5408\u6210\u53ca\u5176\u5f62\u6210\u673a\u7406\u662f\u76ee\u524d\u80f6\u4f53\u6e7f\u5316\u5b66\u65b9\u6cd5\u5408\u6210\u7eb3\u7c73\u6676\u7684\u7814\u7a76\u91cd\u70b9\u3002\u786b\u5316\u94dc\uff08Cu2-xS\uff09\u662f\u4e00\u7c7b\u4f20\u7edf\u7684\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u968f\u7740x\u503c\u7684\u53d8\u5316\u5448\u73b0\u51fa\u4e0d\u540c\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u5f53x\u503c\u589e\u52a0\u65f6\uff0c\u5176\u7981\u5e26\u5bbd\u5ea6\u51cf\u5c0f\uff0c\u8868\u9762\u7b49\u79bb\u5b50\u5171\u632f\u6548\u5e94\u589e\u5f3a\uff0c\u5b9e\u73b0\u7531\u534a\u5bfc\u4f53\u5411\u91d1\u5c5e\u7684\u8f6c\u53d8\u3002\u4eba\u4eec\u5bf9\u4e8e\u5355\u4e00\u7ec4\u5206\u548c\u4e0d\u540c\u7269\u76f8\u7684Cu2-xS\u7684\u7814\u7a76\u5df2\u7ecf\u505a\u4e86\u5927\u91cf\u5de5\u4f5c\u3002\u76ee\u524d\u7eb3\u7c73\u5f02\u8d28\u7ed3\u7684\u5408\u6210\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\uff0c\u56e0\u4e3a\u5b83\u80fd\u591f\u96c6\u6210\u4e0d\u540c\u6750\u6599\u7ec4\u5206\u7684\u4f18\u52bf\u800c\u83b7\u5f97\u4f18\u4e8e\u5355\u4e00\u7ec4\u5206\u7684\u534f\u540c\u6548\u5e94\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u6709\u5173\u591a\u5f62\u4f53\u7eb3\u7c73\u5f02\u8d28\u7ed3\u7684\u7814\u7a76\u5219\u76f8\u5bf9\u8f83\u5c11\uff0c\u6240\u4ee5\u5982\u679c\u628a\u534a\u5bfc\u4f53\u6027\u7684Cu2-xS\u548c\u91d1\u5c5e\u6027\u7684CuS\u590d\u5408\u5728\u4e00\u8d77\uff0c\u6709\u671b\u8868\u73b0\u51fa\u66f4\u5947\u7279\u7684\u6027\u8d28\u3002<\/p>\n<p>\u4e3a\u4e86\u5b9e\u73b0\u8fd9\u4e00\u76ee\u6807\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u5c55\u4e86\u80f6\u4f53\u6e7f\u5316\u5b66\u201c\u524d\u9a71\u7269\u8bf1\u5bfc\u201d\u65b9\u6cd5\u6210\u529f\u5236\u5907\u4e86\u4e00\u79cd\u72ec\u7279\u7684\u591a\u5f62\u4f53\u5f02\u8d28\u7ed3Cu1.94S-CuS\uff0c\u5373\u628a\u4e00\u7ef4\u534a\u5bfc\u4f53\u6027\u7684Cu1.94S\u548c\u4e8c\u7ef4\u91d1\u5c5e\u6027\u7684CuS\u590d\u5408\u5728\u4e00\u8d77\uff0c\u4ee5\u5f62\u6210\u7279\u6b8a\u7684\u201c\u81ea\u76f8\u4e92\u4f5c\u7528\u201d\u754c\u9762\u3002\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u524d\u9a71\u7269Mn(S2CNEt2)2\u8d77\u5230\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u5b83\u53ef\u8bf1\u5bfc\u548c\u63a7\u5236Cu1.94S\u81f3CuS\u7684\u76f8\u53d8\u8fc7\u7a0b\uff0c\u4f7f\u5f62\u6210\u7684Cu1.94S-CuS\u7eb3\u7c73\u5f02\u8d28\u7ed3\u53ef\u4ee5\u7a33\u5b9a\u5b58\u5728\u3002\u8fd9\u79cd\u72ec\u7279\u7684Cu1.94S-CuS\u7eb3\u7c73\u5f02\u8d28\u7ed3\u53ef\u6709\u6548\u5438\u6536\u592a\u9633\u5149\u7684\u53ef\u89c1\u548c\u8fd1\u7ea2\u5916\u533a\u57df\u3002\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u8fd9\u79cd\u7279\u6b8a\u7684\u754c\u9762\u53ef\u4ee5\u6784\u7b51\u7c7b\u4f3c\u4e8e\u201c\u91d1\u5c5e-\u534a\u5bfc\u4f53\u201d\u754c\u9762\u7ed3\u6784\u4ece\u800c\u5bfc\u81f4\u5f62\u6210\u7c7b\u4f3c\u4e8etype-II\u5f02\u8d28\u7ed3\u6784\u7c7b\u578b\uff0c\u4fc3\u8fdb\u4e86\u4f53\u7cfb\u4e2d\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u5206\u79bb\uff0c\u663e\u8457\u63d0\u5347\u4e86\u5176\u5149\u7535\u8f6c\u6362\u6027\u80fd\u3002<\/p>\n<p>\u8fd9\u79cd\u57fa\u4e8e\u524d\u9a71\u7269\u8bf1\u5bfc\u5408\u6210\u786b\u5316\u7269\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684\u65b9\u6cd5\uff0c\u6709\u52a9\u4e8e\u4eba\u4eec\u7cbe\u786e\u63a7\u5236\u7eb3\u7c73\u6750\u6599\u7684\u7ed3\u6784\u548c\u6df1\u5165\u7406\u89e3\u5176\u5f62\u6210\u673a\u7406\u3002\u540c\u65f6\uff0c\u8fd9\u79cd\u65e0\u8d35\u91d1\u5c5e\u53c2\u4e0e\u7684\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684\u5408\u6210\u7b56\u7565\u4e5f\u4e3a\u63d0\u5347\u548c\u4f18\u5316\u4f20\u7edf\u534a\u5bfc\u4f53\u7684\u5149\u7535\u8f6c\u6362\u6027\u80fd\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n<p><a href=\"\/\/m.iemloyee.com\/45033.html\/1-609\" rel=\"attachment wp-att-45035\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-45035\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/1-3.jpg\" alt=\"1\" width=\"451\" height=\"600\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/1-3.jpg 451w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/1-3-226x300.jpg 226w\" sizes=\"(max-width: 451px) 100vw, 451px\" \/><\/a><\/p>\n<p><strong>\u56fe1\u3001Cu1.94S-CuS\u5f02\u8d28\u7ed3\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/45033.html\/2-502\" rel=\"attachment wp-att-45036\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-45036\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/2-1.jpg\" alt=\"2\" width=\"600\" height=\"273\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/2-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/2-1-300x137.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>(a) \u626b\u63cf\u7535\u955c\u7167\u7247\uff1b(b) \u4f4e\u500d\u7387\u900f\u5c04\u7535\u955c\u7167\u7247\uff1b(c) \u9ad8\u500d\u7387\u900f\u5c04\u7535\u955c\u7167\u7247\u548c\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1b(d) \u9ad8\u5206\u8fa8\u7535\u955c\u900f\u5c04\u7167\u7247\uff1b(e) \u5143\u7d20\u9762\u5206\u5e03\u7167\u7247\u3002<\/p>\n<p><strong>\u56fe2\u3001Cu1.94S\u548cCuS\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/45033.html\/3-450\" rel=\"attachment wp-att-45037\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-45037\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/3-1.jpg\" alt=\"3\" width=\"600\" height=\"285\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/3-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/3-1-300x143.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>(a) Cu1.94S\u5143\u7d20\u9762\u5206\u5e03\u7167\u7247\u548c\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1b(b) CuS\u5143\u7d20\u9762\u5206\u5e03\u7167\u7247\u548c\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u56fe3\u3001\u542bMn\u524d\u9a71\u7269\u8bf1\u5bfcCu1.94S\u3001Cu1.94S-CuS\u548cCuS\u7684\u5f62\u6210\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/45033.html\/4-390\" rel=\"attachment wp-att-45038\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-45038\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/4-1.jpg\" alt=\"4\" width=\"650\" height=\"219\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/4-1.jpg 650w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/4-1-300x101.jpg 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/a><\/p>\n<p><strong>\u56fe4\u3001Cu1.94S\u3001Cu1.94S-CuS\u548cCuS\u7684\u6027\u8d28\u8868\u5f81<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/45033.html\/5-331\" rel=\"attachment wp-att-45039\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-45039\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/5-1.jpg\" alt=\"5\" width=\"600\" height=\"477\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/5-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/5-1-300x239.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>(a,b) Cu1.94S\u3001Cu1.94S-CuS\u548cCuS\u7684\u5149\u7535\u5b50\u80fd\u8c31\u8868\u5f81\uff1b<br \/>\n(c,d) Cu1.94S\u3001Cu1.94S-CuS\u548cCuS\u7684\u7d2b\u5916-\u53ef\u89c1-\u8fd1\u7ea2\u5916\u5438\u6536\u548c\u5149\u54cd\u5e94\u6027\u80fd\u8868\u5f81\u3002<\/p>\n<p><strong>\u56fe5\u3001Cu1.94S-CuS\u754c\u9762\u7684\u7406\u8bba\u8ba1\u7b97\u6a21\u578b<\/strong><\/p>\n<p><a href=\"\/\/m.iemloyee.com\/45033.html\/6-260\" rel=\"attachment wp-att-45034\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-45034\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/6-1.jpg\" alt=\"6\" width=\"600\" height=\"609\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/6-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/10\/6-1-296x300.jpg 296w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>(a) Cu1.94S(100)\u548cCuS(100)\u754c\u9762\u5904\u7684\u6001\u5bc6\u5ea6\u8ba1\u7b97\u7ed3\u679c\uff1b<br \/>\n(b) Cu1.94S(100)\u548cCuS(100)\u754c\u9762\u5904\u7684\u7535\u5b50\u7a7a\u7a74\u5206\u5e03\u6a21\u578b\uff1b<br \/>\n(c) Cu1.94S(100)\u548cCuS(100)\u754c\u9762\u5904\u7684\u80fd\u5e26\u63a5\u89e6\u548c\u7535\u5b50\u8f6c\u79fb\u6a21\u578b\u3002<\/p>\n<p><strong>\u8bba\u6587\u94fe\u63a5\uff1a<br \/>\n<\/strong>Shi-Kui Han\u2020, Chao Gu\u2020, Songtao Zhao\u2020, Sen Xu, Ming Gong, Zhenyu Li*, Shu-Hong Yu*, <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b06609\" target=\"_blank\">Precursor Triggering Synthesis of Self-Coupled Copper Sulfide Polymorphs with Enhanced Photoelectrochemical Properties<\/a>, J. Am. Chem. 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