{"id":44500,"date":"2016-10-07T06:30:43","date_gmt":"2016-10-06T22:30:43","guid":{"rendered":"\/\/m.iemloyee.com\/?p=44500"},"modified":"2016-10-07T20:08:58","modified_gmt":"2016-10-07T12:08:58","slug":"energy-environ-sci-%e4%b8%80%e7%a7%8d%e7%94%a8%e4%bd%9c%e6%9e%90%e6%b0%a7%e5%8f%8d%e5%ba%94%e5%92%8c%e6%b0%b4%e8%a3%82%e8%a7%a3%e7%9a%84%e5%8d%95%e7%89%87%e6%97%a0%e9%87%91%e5%b1%9e%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=44500","title":{"rendered":"Energy Environ. Sci. \u7528\u4f5c\u6790\u6c27\u53cd\u5e94\u548c\u6c34\u88c2\u89e3\u7684\u5355\u7247\u65e0\u91d1\u5c5e\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5728\u4e0d\u540c\u7684\u80fd\u91cf\u50a8\u5b58\u548c\u80fd\u91cf\u8f6c\u6362\u4f53\u7cfb\u4e2d\uff0c\u6790\u6c27\u53cd\u5e94\u5728\u7535\u50ac\u5316\u88c2\u89e3\u6c34\u4e2d\u662f\u4e00\u4e2a\u975e\u5e38\u91cd\u8981\u7684\u534a\u53cd\u5e94\u3002\u7136\u800c\uff0c\u5728\u6b63\u6781\u4e2d\u7531\u4e8e\u6162\u7684\u52a8\u529b\u5b66\u5e38\u6570\u800c\u5e26\u6765\u7684\u6790\u6c27\u53cd\u5e94\u7684\u8fc7\u7535\u52bf\u7684\u635f\u5931\uff0c\u8fd9\u5c31\u8981\u6c42\u5408\u9002\u7684\u7535\u50ac\u5316\u5242\u6765\u964d\u4f4e\u8fd9\u4e2a\u635f\u5931\u5982\u5728\u8d1f\u6781\u6790\u6c22\u53cd\u5e94\u8981\u6c42\u5916\u52a0\u7535\u538b\u3002\u7531\u4e8e\u50ac\u5316\u5242\u7684\u6d3b\u6027\u5c42\u5bb9\u6613\u8131\u843d\uff0c\u4e14\u50ac\u5316\u5242\u6240\u5728\u7684\u4f4d\u7f6e\u6709\u5927\u91cf\u7684\u6c27\u6c14\u6790\u51fa\uff0c\u8fd9\u5bfc\u81f4\u50ac\u5316\u5242\u7684\u6548\u7387\u548c\u5bff\u547d\u964d\u4f4e\u3002\u56e0\u6b64\uff0c\u7535\u50ac\u5316\u5242\u7684\u6301\u4e45\u8010\u7528\u6027\u5e94\u8be5\u901a\u8fc7\u53d1\u5c55\u65e0\u91d1\u5c5e\u81ea\u7ed9\u7684\u7535\u50ac\u5316\u5242\u800c\u5f97\u5230\u63d0\u9ad8\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u5c71\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5b66\u5de5\u7a0b\u5b66\u9662\u7684\u7ae5\u53f6\u7fd4\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u5408\u6210\u4e86\u4e00\u79cd\u4e09\u7ef4\u5355\u7247\u65e0\u91d1\u5c5e\u7684N\u63ba\u6742\u591a\u5b54\u70ad\u5e03\u7684\u7535\u50ac\u5316\u5242\uff0c\u7531\u4e8e\u8868\u9762\u79ef\u7684\u589e\u52a0\u4ee5\u53ca\u63baN\u4f5c\u7528\u7684\u7ed3\u679c\uff0c\u81ea\u7ed9\u578b\u50ac\u5316\u5242\u80fd\u591f\u6709\u6548\u7684\u50ac\u5316\u6790\u6c27\u53cd\u5e94\uff0c\u4e5f\u7b2c\u4e00\u6b21\u4ee5\u76f8\u5f53\u4f4e\u7684\u8fc7\u7535\u52bf\u88ab\u7528\u4f5c\u9633\u6781\u7528\u5728\u78b1\u6027\u7535\u89e3\u69fd\u4e2d\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u65b9\u6848\uff1a\u5408\u6210\u539f\u7406\u56fe\u00a0<\/strong><\/p>\n

\"\u539f\u7406\u56fe\"<\/p>\n

\u65b9\u68481.\u5355\u72473D NiD-PCC(3D self-supporting metal-free monolithic\u00a0porous carbon cloth doped with N-heteroatom)\u7684\u5408\u6210\u539f\u7406\u793a\u610f\u56fe<\/p>\n

\u56fe<\/strong>1.<\/strong>\u5408\u6210\u6837\u54c1\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"1\"<\/p>\n

(a)BCC\u7684SEM\u56fe\uff1b<\/p>\n

(b)\u3001(c)NiD-PCC\u7684SEM\u56fe\uff1b<\/p>\n

(d) TCC\u7684SEM\u56fe\uff1b<\/p>\n

(e) NiD-PCC\u7684TEM\u56fe,\u5185\u90e8\u63d2\u56fe\u4e3aNiD-PCC\u7684\u6807\u5b9a\u7684\u4eae\u9ec4\u8272\u6807\u8bb0\u533a\u57df\u7684\u5265\u843d\u90e8\u5206\u7684HRTEM\u56fe;<\/p>\n

(f)\u5de6\u56fe\u4e2d\u9ec4\u8272\u533a\u57df\u7684\u653e\u5927\u7684TEM\u56fe\u3002<\/p>\n

\u56fe<\/strong>2.<\/strong>\u6837\u54c1\u7684\u7ec4\u6210\u548c\u7ed3\u6784<\/strong><\/p>\n

\"2\"<\/strong>(a)N\u7684\u7b49\u6e29\u5438\u9644\u66f2\u7ebf\uff1b<\/p>\n

(b)\u5b54\u5f84\u5927\u5c0f\u5206\u5e03\uff1b<\/p>\n

(c)BCC\u548cNiD-PCC\u6837\u54c1\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n

(d)BCC,NiC\u548cNiD-PCC\u6837\u54c1\u7684Ni\u76842p\u8f68\u9053\u7684XPS\u56fe\uff1b<\/p>\n

(e)\u9876\u90e8\uff1aBCC\u548cNiD-PCC\u6837\u54c1\u7684\u6b63\u5e38\u7684C\u76841s\u8f68\u9053\u7684XPS\u56fe\uff1b\u5e95\u90e8\uff1aNiD-PCC\u6837\u54c1\u7684C\u76841s\u8f68\u9053\u7684\u5149\u8c31\uff1b<\/p>\n

(f)BCC\u548cNiD-PCC\u6837\u54c1\u7684N\u76841s\u8f68\u9053\u7684XPS\u56fe\u8c31\u3002<\/p>\n

\u56fe<\/strong>3.<\/strong>\u50ac\u5316\u5242\u5728\u6790\u6c27\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6d3b\u6027<\/strong><\/p>\n

\"3\"<\/strong><\/p>\n

(a)\u626b\u63cf\u901f\u7387\u4e3a10mV\/s\u65f6\u57281M NaOH\u6eb6\u6db2\u4e2d\u7684LSV\u66f2\u7ebf\u70b9\uff1b<\/p>\n

(b)\u5854\u83f2\u5c14\u66f2\u7ebf\u70b9\uff1b<\/p>\n

(c)\u50ac\u5316\u5242\u7684EIS\u66f2\u7ebf\u70b9\uff0c\u5185\u90e8\u63d2\u56fe\u4e3aNiC\u548cNiD-PCC\u50ac\u5316\u5242\u7684\u653e\u5927\u56fe\uff1b<\/p>\n

(d)NiD-PCC\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10mA cm-2<\/sup>\u65f6\u95f4\u4e3a28h\u65f6\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff0c\u5185\u90e8\u63d2\u56fe\u4e3a\u8fbe\u5230600\u4e2a\u5faa\u73af\u65f6\u7684CV\u7a33\u5b9a\u6027\uff1b<\/p>\n

(e) NiD-PCC\u7535\u50ac\u5316\u5242\u5728\u8fdb\u884c28h\u7a33\u5b9a\u6027\u6d4b\u8bd5\u4e4b\u524d\u7684LSV\u66f2\u7ebf\u70b9\uff1b<\/p>\n

(f) NiD-PCC\u7535\u50ac\u5316\u5242\u5728\u8fdb\u884c28h\u7a33\u5b9a\u6027\u6d4b\u8bd5\u4e4b\u540e\u7684Nyquist\u66f2\u7ebf\u70b9\uff1b<\/p>\n

(e)\u4e2d\u5185\u90e8\u63d2\u56fe\u4e3aNiD-PCC\u7535\u50ac\u5316\u5242\u5728\u8fdb\u884c28h\u7a33\u5b9a\u6027\u6d4b\u8bd5\u4e4b\u540e\u7684SEM\u56fe\u3002<\/p>\n

\u56fe<\/strong>4.<\/strong>\u7cfb\u5217\u6837\u54c1\u78b1\u6027\u7535\u89e3\u69fd\u7684\u6c34\u5b8c\u5168\u88c2\u89e3\u7684\u6d3b\u6027<\/strong><\/p>\n

\"4\"<\/strong><\/p>\n

BCC\/\/BCC\u3001NiC\/\/NiC\u548cNiC\/\/NiD-PCC\u78b1\u6027\u7535\u89e3\u69fd\u7684\u6c34\u5b8c\u5168\u88c2\u89e3\u7684\u6d3b\u6027\u3002<\/p>\n

(a) \u626b\u63cf\u901f\u7387\u4e3a10mV\/s\u65f6\u57281M NaOH\u6eb6\u6db2\u4e2d\u7684LSV\u66f2\u7ebf\u70b9\uff1b<\/p>\n

(b)\u7167\u7247\u663e\u793a\u4e86\u5728NiC\/\/NiD-PCC\u7535\u89e3\u69fd\u7535\u6781\u4e0a\u6709\u6c22\u6c14\u548c\u6c27\u6c14\u6c14\u6ce1\u4ea7\u751f\uff1b<\/p>\n

(c) BCC\/\/BCC\u3001NiC\/\/NiC\u548cNiC\/\/NiD-PCC\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10mA cm-2<\/sup>\u65f6\u95f4\u4e3a28h\u65f6\u7684\u8ba1\u65f6\u7535\u52bf\u6d4b\u91cf\u56fe\u3002<\/p>\n

\u56fe<\/strong>5.<\/strong>\u6837\u54c1\u7684\u7535\u5316\u5b66\u6790\u6c27\u7279\u6027<\/strong><\/p>\n

\"5\"<\/strong>\u00a0NiO\u5305\u8986BCC\u548cNiD-PCC\u7535\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6790\u6c27\u7279\u6027\u3002<\/p>\n

(a)NiD-PCC\/NiO\u7535\u50ac\u5316\u5242\u7684SEM\u56fe\uff1b<\/p>\n

(b)BCC\/NiO\u548cNiD-PCC\/NiO\u7535\u50ac\u5316\u5242\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a20mA cm-2<\/sup>\u57281M KOH\u6eb6\u6db2\u4e2d\u7684LSV\u66f2\u7ebf\u70b9\u3002<\/p>\n

\u3010\u5c55\u671b\u3011<\/strong><\/p>\n

\u8fd9\u79cd\u65b9\u6cd5\u5728\u53d1\u5c55\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u4e0a\u4e3a\u81ea\u7ed9\u578b\u6750\u6599\u548c\u6709\u6548\u7684\u57fa\u5e95\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u601d\u8def\uff0c\u8fd9\u4e0d\u4ec5\u4f53\u73b0\u5728\u7535\u50ac\u5316\u5242\u4e0a\uff0c\u4e5f\u4f53\u73b0\u5728\u5176\u4ed6\u80fd\u91cf\u50a8\u5b58\u548c\u8f6c\u6362\u7cfb\u7edf\u4e2d\u3002<\/p>\n

\u7ae5\u53f6\u7fd4\u6559\u6388\u7b80\u4ecb\uff1a<\/strong>\u7ae5\u53f6\u7fd4\uff0c\u7537\uff0c\u4e2d\u5c71\u5927\u5b66\u5316\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u4e2d\u56fd\u5316\u5b66\u4f1a\u7406\u4e8b\uff0c\u4e2d\u56fd\u7535\u5316\u5b66\u4f1a\u6750\u6599\u7535\u5316\u5b66\u5206\u4f1a\u59d4\u5458\uff0c\u5e7f\u4e1c\u7701\u7a00\u571f\u534f\u4f1a\u7406\u4e8b\uff0c\u88ab\u8bc4\u4e3a\u4e2d\u5c71\u5927\u5b66\u6559\u5b66\u540d\u5e08\uff0c\u5e7f\u4e1c\u7701\u5357\u7ca4\u6559\u575b\u65b0\u79c0\uff0c\u56fd\u5bb6\u7406\u79d1\u57fa\u5730\u5efa\u8bbe\u5b9e\u65bd\u5148\u8fdb\u5de5\u4f5c\u8005\u7b49\uff0c\u76ee\u524d\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u7eb3\u7c73\u6750\u6599\u7684\u7535\u5316\u5b66\u5408\u6210\u53ca\u5176\u6027\u80fd\u8868\u5f81\uff0c\u4e3b\u8981\u5305\u62ec\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u534a\u5bfc\u4f53\u6750\u6599\u3001\u9ad8\u71b5\u5408\u91d1\u3001\u5149\u50ac\u5316\u548c\u7535\u50ac\u5316\u6750\u6599\u3001\u5149\u7535\u6750\u6599\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/strong>A monolithic metal-free electrocatalyst for oxygen evolution reaction and overall water<\/a><\/p>\n

splitting<\/a>\u00a0\u00a0(Energy Environ.Sci.\uff0c2016\uff0cDOI:10.1039\/c6ee01930g)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4YenHo\u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d,\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"\u65b0\u80fd\u6e90\u5fae\u4fe1\u4e8c\u7ef4\u7801\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5728\u4e0d\u540c\u7684\u80fd\u91cf\u50a8\u5b58\u548c\u80fd\u91cf\u8f6c\u6362\u4f53\u7cfb\u4e2d\uff0c\u6790\u6c27\u53cd\u5e94\u5728\u7535\u50ac\u5316\u88c2\u89e3\u6c34\u4e2d\u662f\u4e00\u4e2a\u975e\u5e38\u91cd\u8981\u7684\u534a\u53cd\u5e94\u3002\u7136\u800c\uff0c\u5728\u6b63\u6781\u4e2d\u7531\u4e8e\u6162\u7684\u52a8\u529b\u5b66\u5e38\u6570\u800c\u5e26\u6765\u7684\u6790\u6c27\u53cd\u5e94\u7684\u8fc7\u7535\u52bf\u7684\u635f\u5931\uff0c\u8fd9\u5c31…<\/p>\n","protected":false},"author":1405,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,18],"class_list":["post-44500","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-catalyst","tag-xinnengyuan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/44500"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1405"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=44500"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/44500\/revisions"}],"predecessor-version":[{"id":45420,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/44500\/revisions\/45420"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=44500"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=44500"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=44500"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}