{"id":44310,"date":"2016-10-05T14:00:41","date_gmt":"2016-10-05T06:00:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=44310"},"modified":"2017-03-18T22:10:01","modified_gmt":"2017-03-18T14:10:01","slug":"adv-funct-mater-%e8%87%aa%e7%bb%99%e6%b0%a7%e6%b0%94%e4%bb%bf%e7%94%9f%e7%ba%b3%e7%b1%b3%e5%b9%b3%e5%8f%b0%e7%94%a8%e4%ba%8e%e9%ab%98%e7%b2%be%e5%87%86%e5%85%89%e5%8a%a8%e5%8a%9b%e6%b2%bb%e7%96%97","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=44310","title":{"rendered":"Adv. Funct. Mater. \u81ea\u7ed9\u6c27\u6c14\u4eff\u751f\u7eb3\u7c73\u5e73\u53f0\u7528\u4e8e\u9ad8\u7cbe\u51c6\u5149\u52a8\u529b\u6cbb\u7597"},"content":{"rendered":"

<\/del>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5149\u52a8\u529b\u6cbb\u7597\u662f\u4e00\u79cd\u5bf9\u6076\u6027\u80bf\u7624\u5f88\u6709\u5e0c\u671b\u7684\u6cbb\u7597\u65b9\u6cd5\uff0c\u5b83\u88ab\u7528\u4e8e\u6cbb\u7597\u76ae\u80a4\u764c\uff0c\u4e5f\u88ab\u53d1\u5c55\u4f7f\u7528\u8fd1\u7ea2\u5916\u5149\u8fdb\u884c\u6fc0\u53d1\uff0c\u4ece\u800c\u5b9e\u73b0\u6df1\u5165\u7ec4\u7ec7\u7684\u6cbb\u7597\u3002\u4f46\u7531\u4e8e\u80bf\u7624\u90e8\u4f4d\u7684\u4e4f\u6c27\u6027\uff0c\u4e0d\u5229\u4e8e\u5149\u52a8\u529b\u6cbb\u7597\u7684\u6709\u6548\u5b9e\u65bd\u3002\u6b64\u5916\uff0c\u7eb3\u7c73\u6750\u6599\u7684\u751f\u7269\u533b\u5b66\u5e94\u7528\u8fd8\u53d7\u56f0\u4e8e\u5176\u9776\u5411\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\u6b66\u6c49\u5927\u5b66\u7684\u5f20\u5148\u6b63\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u8bbe\u8ba1\u4e86\u4e00\u79cd\u6c27\u6c14\u81ea\u7ed9\u4e88\u4eff\u751f\u7ec6\u80de\u7684\u7eb3\u7c73\u590d\u5408\u6750\u6599 CAT-PS-ZIF@ Mem\uff08\u89c1[\u6ce8]<\/strong>\uff09\u3002\u7531\u4e8e\u764c\u7ec6\u80de\u819c\u7684\u540c\u6e90\u9776\u5411\u4f5c\u7528\uff0cCAT-PS-ZIF@Mem \u88ab\u9759\u8109\u6ce8\u5c04\u5230\u4f53\u5185\uff0c\u9009\u62e9\u6027\u7684\u79ef\u7d2f\u5728\u80bf\u7624\u4f4d\u7f6e\uff0c\u5e76\u88ab\u80bf\u7624\u6709\u6548\u7684\u6444\u53d6\u3002\u7ec6\u80de\u5185\u7684H2O2\u6e17\u900f\u5230\u8fd9\u4e2a\u591a\u5b54\u6750\u6599\u7684\u9aa8\u67b6\u4e2d\uff0c\u88ab\u8fc7\u6c27\u5316\u6c22\u9176CAT\u50ac\u5316\uff0c\u5728\u4e4f\u6c27\u7684\u80bf\u7624\u5904\u4ea7\u751fO2\uff0c\u4fc3\u8fdb\u5355\u7ebf\u6001\u6c27\u7684\u4ea7\u751f\uff0c\u5728\u8fd1\u7ea2\u5916\u5149\u7684\u7167\u5c04\u4e0b\u5b9e\u73b0\u5149\u52a8\u529b\u6cbb\u7597\u3002\u901a\u8fc7\u7ed3\u5408\u514d\u75ab\u548c\u7ec6\u80de\u540c\u6e90\u8bc6\u522b\uff0c\u4ee5\u53ca\u6c27\u6c14\u81ea\u7ed9\u4e88\uff0c\u5b9e\u73b0\u4e86\u9ad8\u9776\u5411\u6027\u548c\u9ad8\u6548\u7684\u5149\u52a8\u529b\u6cbb\u7597\uff0c\u5927\u5927\u51cf\u5c11\u4e86\u5bf9\u5468\u56f4\u6b63\u5e38\u7ec4\u7ec7\u7684\u4f24\u5bb3\u3002<\/p>\n

[\u6ce8]<\/strong>Mem: \u764c\u7ec6\u80de\u819c\uff1bZIF-8\uff1a\u7c7b\u4f3c\u4e8e\u7ec6\u80de\u9aa8\u67b6\u7684\u591a\u5b54\u6cb8\u77f3\u54aa\u5511\u9aa8\u67b6\uff0c\u5e76\u5d4c\u5165\u8fc7\u6c27\u5316\u6c22\u9176CAT\u5149\u654f\u5242AlPcS4\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u57fa\u4e8e\u7eb3\u7c73\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6NMOF\u9aa8\u67b6\u7684\u7c7b\u7ec6\u80de\u7684\u4eff\u751f\u5e73\u53f0\u7528\u4e8e\u9776\u5411\u5149\u52a8\u529b\u6cbb\u7597\uff08PDT\uff09<\/strong><\/p>\n

\"\u56fe\u72471\"<\/p>\n

\uff08a\uff09CAT-PS-ZIF@Mem\u7684\u5408\u6210\u3002<\/p>\n

\uff08b\uff09\u7eb3\u7c73\u6750\u6599CAT-PS-ZIF@Mem\u901a\u8fc7\u9759\u8109\u6ce8\u5165\u540e\uff0c\u7ecf\u8840\u6db2\u5faa\u73af\u9009\u62e9\u6027\u7684\u79ef\u7d2f\u5728\u80bf\u7624\u90e8\u4f4d\u3002<\/p>\n

\uff08c\uff09\u5728\u8fd1\u7ea2\u5916\u5149\u7167\u5c04\u4e0b\uff0c\u540c\u6e90\u9776\u5411\u7684\u7eb3\u7c73\u6750\u6599CAT-PS-ZIF-Mem\u5728\u80bf\u7624\u7ec4\u7ec7\u5904\u79ef\u7d2f\u5e76\u9ad8\u6548\u5730\u5b9e\u73b0\u5149\u52a8\u529b\u6cbb\u7597\u3002<\/p>\n

\u56fe2 CAT-PS-ZIF@Mem \u6750\u6599\u7684\u8868\u5f81<\/strong><\/p>\n

\"\u56fe\u72472\"<\/p>\n

\uff08a\uff09CAT-PS-ZIF@Mem \u5f62\u8c8cSEM\u548cTEM\u56fe\u7247<\/p>\n

\uff08b\uff09CAT-PS-ZIF@Mem \u7eb3\u7c73\u7403\u7684\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c<\/p>\n

\uff08c\uff09CAT-PS-ZIF@Mem \u5728\u57f9\u517b\u57fa\u4e2d\u5b75\u80b224h\u540e\u7684SEM\u548cTEM\u56fe\u7247<\/p>\n

\uff08d\uff09CAT-PS-ZIF@Mem \u548c\u5728\u57f9\u517b\u57fa\u4e2d\u5b75\u80b2\u540e\u7684CAT-PS-ZIF@Mem \u7684XRD<\/p>\n

\uff08e\uff09Hale \u7ec6\u80de\u7ec6\u80de\u819c\uff0cCAT-PS-ZIF\uff0cCAT-PS-ZIF@Mem\u7684SDS-PAGE\u86cb\u767d\u5206\u6790<\/p>\n

\u56fe3 \u7ec6\u80de\u5185ROS\u7684\u68c0\u6d4b<\/strong><\/p>\n

\"\u56fe\u72473\"<\/p>\n

\uff08a\uff09\u7ec6\u80de\u4e0eVc\uff0cDCFH-DA\u5171\u540c\u5b75\u80b2\u540e\uff0c\u7ec6\u80de\u5185\u7684ROS\u7684\u8367\u5149\u68c0\u6d4b\u3002<\/p>\n

\uff08b\uff09\u7ec6\u80de\u548cDCFH-DA\u5171\u540c\u5b75\u80b2\u540e\uff0c\u7ec6\u80de\u5185\u7684ROS\u7684\u8367\u5149\u68c0\u6d4b<\/p>\n

\uff08c\uff09\u7ec6\u80de\u548cCAT-PS-ZIF@Mem\u548cDCFH-DA\u5171\u540c\u5b75\u80b2\u540e\uff0c\u7ec6\u80de\u5185\u7684ROS\u7684\u8367\u5149\u68c0\u6d4b<\/p>\n

\uff08d\uff09\u7ec6\u80de\u548cCAT-PS-ZIF@Mem \u548cDCFH-DA\u5171\u540c\u5b75\u80b2\u540e\uff0c\u7ec6\u80de\u5185\u7684ROS\u7684\u8367\u5149\u68c0\u6d4b<\/p>\n

(A1)-(D1)\u4e3aDCF\u7684\u8367\u5149\uff08\u7eff\u8272\uff09,\u53cd\u6620\u7ec6\u80de\u5185\u7684ROS\uff1b(A2)-(D2)\u4e3a\u660e\u573a\uff1b(A3)-(D3)\u9ed8\u7f6e\u7684\u56fe\u7247\u3002<\/p>\n

\u56fe4 CAT-PS-ZIF@Mem\u5728\u4e0d\u540c\u7ec6\u80de\u5185\u7684\u6444\u53d6\u5bf9\u6bd4<\/strong><\/p>\n

\"\u56fe\u72474\"<\/p>\n

\uff08a\uff09Hela\u7ec6\u80de\u5185\u5bf9CAT-PS-ZIF@Mem\u7684\u6444\u53d6<\/p>\n

\uff08b\uff09COS7\u7ec6\u80de\u5185\u5bf9CAT-PS-ZIF@Mem\u7684\u6444\u53d6\u3002A1\uff0cB1\u4e3a\u67d3\u6599Hoechst33342\u7684\u84dd\u8272\u8367\u5149\uff1bA2,B2\u4e3aAlPcS4\u7684\u7ea2\u8272\u8367\u5149\uff1bA3,B3\u4e3a\u660e\u573a\uff1bA4,B4\u4e3a\u9ed8\u7f6e\u56fe\u7247\u3002
\n\uff08c\uff09 Hela\uff08green\uff09\u7ec6\u80de\u548cCOS7(orange)\u7ec6\u80de\u5185\u7684CAT-PS-ZIF@Mem<\/p>\n

\uff08d\uff09\u6d41\u5f0f\u7ec6\u80de\u4eea\u5bf9\u5e94\u7684MFI \u503c\u5206\u6790<\/p>\n

\u56fe5 \u5de8\u566c\u7ec6\u80de\u5bf9CAT-PS-ZIF@Mem\u548cCAT-PS-ZIF\u7684\u7ec6\u80de\u5185\u6444\u53d6<\/strong><\/p>\n

\"\u56fe\u72475\"<\/p>\n

(A)\u5de8\u566c\u7ec6\u80de\u5bf9CAT-PS-ZIF@Mem \u7ec6\u80de\u5185\u6444\u53d6\u60c5\u51b5\u7684\u6210\u50cf<\/p>\n

(B)\u5de8\u566c\u7ec6\u80de\u5bf9 CAT-PS-ZIF\u7684\u7ec6\u80de\u5185\u6444\u53d6\u60c5\u51b5\u7684\u6210\u50cf\u3002A1\uff0cB1\u4e3a\u67d3\u6599Hoechst33342\u7684\u84dd\u8272\u8367\u5149\uff1bA2,B2\u4e3aAlPcS4\u7684\u7ea2\u8272\u8367\u5149\uff1bA3,B3\u4e3a\u660e\u573a\uff1bA4,B4\u4e3a\u9ed8\u7f6e\u56fe\u7247\u3002<\/p>\n

(C)\u88ab\u5de8\u566c\u7ec6\u80de\u6444\u53d6\u7684CAT-PS-ZIF@Mem \uff08\u84dd\u8272\uff09\u7ec6\u80de\u548cCAT-PS-ZIF\uff08\u6a58\u8272\uff09\u6ca1\u6709\u505a\u4efb\u4f55\u5904\u7406\u7684\u7ec6\u80de (\u7ea2\u8272) \u63a7\u5236\u7ec4<\/p>\n

(D)\u6d41\u5f0f\u7ec6\u80de\u4eea\u5bf9\u5e94\u7684MFI \u503c\u5206\u6790<\/p>\n

\u56fe6 \u6cbb\u7597\u540e\u5bf9\u7ec6\u80de\u51cb\u4ea1\u7684\u89c2\u5bdf<\/strong><\/p>\n

\"\u56fe\u72476\"<\/p>\n

\uff08a\uff09\u53ea\u5bf9\u7ec6\u80de\u8fdb\u884c\u5149\u8f90\u7167\uff0c\u89c2\u5bdf\u7ec6\u80de\u7684\u51cb\u4ea1\u72b6\u6001\u3002<\/p>\n

\uff08b\uff09\u4ec5\u5bf9\u7ec6\u80de\u4e0eCAT-PS-ZIF@Mem\u5171\u540c\u5b75\u80b2\uff0c\u89c2\u5bdf\u7ec6\u80de\u7684\u51cb\u4ea1\u72b6\u6001\u3002<\/p>\n

\uff08c\uff09\u4ec5\u5bf9\u7ec6\u80de\u4e0ePS-ZIF@Mem\u5171\u540c\u5b75\u80b2\uff0c\u89c2\u5bdf\u7ec6\u80de\u7684\u51cb\u4ea1\u72b6\u6001\u3002<\/p>\n

\uff08d\uff09\u5bf9\u7ec6\u80de\u4e0ePS-ZIF@Mem\u5171\u540c\u5b75\u80b2\u5e76\u8fdb\u884c\u5149\u8f90\u7167\uff0c\u89c2\u5bdf\u7ec6\u80de\u7684\u51cb\u4ea1\u72b6\u6001\u3002<\/p>\n

\uff08e\uff09\u5bf9\u7ec6\u80de\u4e0eCAT-PS-ZIF@Mem\u5171\u540c\u5b75\u80b2\u5e76\u8fdb\u884c\u5149\u8f90\u7167\uff0c\u89c2\u5bdf\u7ec6\u80de\u7684\u51cb\u4ea1\u72b6\u6001\u3002\uff08A1\uff09-(E1) \u8054\u819c\u86cb\u767dV\u6807\u8bb0\u7684FITC\u67d3\u8272\uff0c\u8868\u5f81\u51cb\u4ea1\u7ec6\u80de\u3002\uff08A2\uff09-\uff08E2\uff09\u660e\u573a\uff1b\uff08A3\uff09-\uff08E3\uff09\u9ed8\u7f6e<\/p>\n

\u56fe7 \u7ec6\u80de\u51cb\u4ea1\u65f6\u671f\u5206\u5e03\u5bf9\u6bd4<\/strong><\/p>\n

\"\u56fe\u72477\"<\/p>\n

\uff08a\uff09\u5728\u4e0d\u540c\u7684\u6cbb\u7597\u4e0b\uff0cHela\u7ec6\u80de\u51cb\u4ea1\u72b6\u51b5\u7684\u6d41\u5f0f\u5206\u6790<\/p>\n

\uff08b\uff09\u65e9\u671f\u51cb\u4ea1\u7ec6\u80de\u7684\u767e\u5206\u6bd4\u5206\u6790<\/p>\n

\uff08c\uff09\u665a\u671f\u51cb\u4ea1\u7ec6\u80de\u7684\u767e\u5206\u6bd4\u5206\u6790<\/p>\n

\uff08d\uff09\u6cbb\u7597\u540e\u6b7b\u4ea1\u7ec6\u80de\u7684\u767e\u5206\u6bd4<\/p>\n

\u56fe8 CAT-PS-ZIF\u548cCAT-PS-ZIF@Mem\u7684\u7ec6\u80de\u6bd2\u6027<\/strong><\/p>\n

\"\u56fe\u72478\"<\/p>\n

\uff08a\uff09Hela\u7ec6\u80de\uff0c\u4e0eCAT-PS-ZIF\u5b75\u80b2\u3002\u9ed1\u8272\u4e3a\u6ca1\u6709\u5149\u7167\uff0c\u7070\u8272\u4e3a\u5149\u7167<\/p>\n

\uff08b\uff09COS7\u7ec6\u80de\uff0c\u4e0eCAT-PS-ZIF\u5b75\u80b2\u3002\u9ed1\u8272\u4e3a\u6ca1\u6709\u5149\u7167\uff0c\u7070\u8272\u4e3a\u5149\u7167<\/p>\n

\uff08c\uff09Hela\u7ec6\u80de\uff0c\u4e0eCAT-PS-ZIF@Mem\u5b75\u80b2\u3002\u9ed1\u8272\u4e3a\u6ca1\u6709\u5149\u7167\uff0c\u7070\u8272\u4e3a\u5149\u7167<\/p>\n

\uff08d\uff09COS7\u7ec6\u80de\uff0c\u4e0eCAT-PS-ZIF@Mem\u5b75\u80b2\u3002\u9ed1\u8272\u4e3a\u6ca1\u6709\u5149\u7167\uff0c\u7070\u8272\u4e3a\u5149\u7167<\/p>\n

\u56fe9 \u5c0f\u9f20\u4e0d\u540c\u4f4d\u7f6e\u7684\u80bf\u7624\u7ec4\u7ec7\u7684\u5c55\u793a<\/strong><\/p>\n

\"\u56fe\u72479\"<\/p>\n

\uff08a\uff09\u5bf9\u79cd\u7624\u5c0f\u9f20\u4ec5\u6ce8\u5c04PBS\u7f13\u51b2\u6db2<\/p>\n

\uff08b\uff09\u9759\u8109\u6ce8\u5c04PS-ZIF@Mem<\/p>\n

\uff08c\uff09\u9759\u8109\u6ce8\u5c04CAT-PS-ZIF@Mem\u3002\u00a0A1-C1\u4e3a\u67d3\u6599DAPI\u7684\u7ea2\u8272\uff1bA2-C2\u4e3aHIF-1\u03b1\u6297\u4f53(\u68c0\u6d4b\u4f4e\u6c27)\u7684\u514d\u75ab\u8367\u5149\u67d3\u8272\uff1bA3-C3\u4e3a\u9ed8\u7f6e\u56fe\u7247\u3002<\/p>\n

\u56fe10 \u5b9e\u9a8c\u9f20\u9759\u8109\u6ce8\u5c04\u540e\uff0c\u751f\u7269\u6d3b\u4f53\u6210\u50cf\u53ca\u5668\u5b98\u7684\u4f53\u5916\u6210\u50cf<\/strong><\/p>\n

\"\u56fe\u724710\"<\/p>\n

\uff08a\uff09\u9759\u8109\u6ce8\u5c04CAT-PS-ZIF@Mem\uff0c\u968f\u7740\u5b75\u80b2\u65f6\u95f4\uff0c\u6d3b\u4f53\u6210\u50cf\u7684\u53d8\u5316\u3002 A1\u4e3a\u5b75\u80b20h,A2\u4e3a\u5b75\u80b21h,A3\u5b75\u80b24h\uff0cA4\u5b75\u80b26h\uff0cA5\u5b75\u80b28h\uff0cA6\u5b75\u80b224h\uff0cA7\u5b75\u80b248h\uff0cA8\u5b75\u80b272h\u3002A9\u4e3a\u4e3a\u5b75\u80b272h\u540e\u8865\u5145\u6ce8\u5c04\u836f\u7269\uff0c\u5bf9\u5404\u4e2a\u5668\u5b98\u8fdb\u884c\u4f53\u5916\u6210\u50cf\u3002<\/p>\n

\uff08b\uff09\u9759\u8109\u6ce8\u5c04CAT-PS-ZIF,B1\u4e3a\u5b75\u80b20h,B2\u4e3a\u5b75\u80b21h,B3\u5b75\u80b24h\uff0cB4\u5b75\u80b26h\uff0cB5\u5b75\u80b28h\uff0cB6\u5b75\u80b224h\uff0cB7\u5b75\u80b248h\uff0cB8\u5b75\u80b272h\uff0cB9\u4e3a\u5b75\u80b272h\u540e\u8865\u5145\u6ce8\u5c04\u836f\u7269\uff0c\u5bf9\u5404\u4e2a\u5668\u5b98\u8fdb\u884c\u4f53\u5916\u6210\u50cf\u3002<\/p>\n

\uff08c\uff09\u836f\u7269\u6ce8\u5c0472h\u540e\uff0c\u5b9e\u9a8c\u9f20\u5404\u5668\u5b98\u5bf9\u5e94\u7684MFI\u503c\u3002<\/p>\n

\uff08d\uff09\u8840\u6db2\u4e2dCAT-PS-ZIF@Mem\u548cCAT-PS-ZIF\u7684\u6d53\u5ea6\u968f\u7740\u5faa\u73af\u65f6\u95f4\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe11 \u5728\u6d3b\u4f53\u4e2d\u9759\u8109\u6ce8\u5c04\u6297\u764c\u7814\u7a76<\/strong><\/p>\n

\"\u56fe\u724711\"<\/p>\n

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\uff08e\uff09\u901a\u8fc7\u514d\u75ab\u5370\u8ff9\u6cd5\uff0c\u5bf9\u80bf\u7624\u4e2dCaspase-3\u548cBcl-2\u86cb\u767d\u8868\u8fbe\u7684\u5206\u6790<\/p>\n

\uff08f\uff09Caspase-3\u548cBcl-2\u86cb\u767d\u8868\u8fbe\u5b9a\u91cf\u5206\u6790<\/p>\n

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\u3010\u5c0f\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>An O2\u00a0Self-Sufficient Biomimetic Nanoplatform for Highly Specific and Efficient Photodynamic Therapy<\/a>\uff08Adv. Fuct. Mater.,2016,DOI: 10.1002\/adfm.201603212\uff09<\/p>\n

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