{"id":44254,"date":"2016-10-08T06:30:44","date_gmt":"2016-10-07T22:30:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=44254"},"modified":"2016-10-07T15:35:12","modified_gmt":"2016-10-07T07:35:12","slug":"adv-energy-mater-%e7%bb%99%e4%bd%93%e5%8d%95%e5%85%83%e7%9a%84%e4%b8%80%e5%af%b9%e4%b8%80%e8%81%94%e7%b3%bb%e8%83%bd%e5%90%a6%e6%8f%90%e9%ab%98pscs%e7%9a%84%e6%80%a7%e8%83%bd%ef%bc%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=44254","title":{"rendered":"Adv. Energy Mater. \u7ed9\u4f53\u5355\u5143\u7684\u4e00\u5bf9\u4e00\u8054\u7cfb\u80fd\u5426\u63d0\u9ad8PSCs\u7684\u6027\u80fd\uff1f"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7ecf\u8fc7\u8bb8\u591a\u5e74\u7684\u53d1\u5c55\uff0c\u7845\u57fa\u592a\u9633\u80fd\u7535\u6c60\u5df2\u7ecf\u5f88\u96be\u53d6\u5f97\u7a81\u7834\u6027\u8fdb\u5c55\uff0c\u76f8\u6bd4\u4e4b\u4e0b\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u6210\u672c\u4f4e\u3001\u8d28\u91cf\u8f7b\u548c\u673a\u68b0\u6027\u80fd\u597d\u7b49\u7279\u70b9\uff0c\u5f02\u8d28\u7ed3\u7684\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u5df2\u7ecf\u7a81\u783411%\uff0c\u53d1\u5c55\u524d\u666f\u5e7f\u9614\u3002\u8bbe\u8ba1\u5e76\u5408\u6210\u65b0\u9896\u7684\u7ed3\u6784\u5bf9\u8fdb\u4e00\u6b65\u53d1\u5c55\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u6765\u8bf4\u81f3\u5173\u91cd\u8981\u3002\u6765\u81ea\u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u90ed\u65ed\u5c97\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u6700\u8fd1\u5728Adv. Mater.\u4e0a\u53d1\u8868\u4ed6\u4eec\u5728\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u8bbe\u8ba1\u4e0a\u7684\u8fdb\u5c55\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u65b0\u9896\u7684\u7ed3\u6784\u8981\u5177\u6709\u5408\u9002\u7684\u51e0\u4f55\u5f62\u6001\u3001\u826f\u597d\u7684\u5149\u7535\u6027\u8d28\u548c\u589e\u6eb6\u7684\u7279\u70b9\u3002\u5728\u6709\u673a\u8584\u819c\u573a\u6548\u5e94\u6676\u4f53\u7ba1(OTFT)\u9886\u57df,nTs\u5177\u6709\u8f83\u597d\u7684\u6d41\u52a8\u6027\u88ab\u5e7f\u6cdb\u7528\u4e8e\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ed9\u4f53\u90e8\u5206\uff0c\u4e5f\u6b63\u662f\u7531\u4e8enTs\u7684\u8d21\u732e\uff0c\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u586b\u5145\u56e0\u5b50\u83b7\u5f97\u4e86>75%\u7684\u6c34\u5e73\u3002<\/p>\n

\u5145\u5206\u5229\u7528\u70f7\u57fa\u5316\u6a21\u5f0f\u548c\u567b\u5429\u7684\u6570\u91cf\u53ef\u4ee5\u5f97\u5230\u6027\u80fd\u4e0a\u7684\u63d0\u5347\uff0c\u5728\u4e0d\u540c\u7684nTs\u4e2d\uff0c\u4e09\u567b\u5429(3T)\u548c\u56db\u567b\u5429(4T)\u5177\u6709\u5e7f\u9614\u524d\u666f\u3002\u90ed\u6559\u6388\u8bfe\u9898\u7ec4\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u7684\u7ed9\u4f53\u5355\u5143<\/strong>\uff0c\u5177\u6709\u4e00\u5bf9\u4e00\u8054\u7cfb\u76843-\u70f7\u6c27\u57fa-3\uff07-\u70f7\u57fa-2\uff0c2\uff07-\u8054\u567b\u5429(TRTOR)\u7ed3\u6784\uff0cTRTOR\u5177\u6709\u4e24\u4e2a\u53ef\u6eb6\u6027\u957f\u94fe\uff0c\u5177\u6709\u9ad8\u5ea6\u5171\u9762\u6027\u4ee5\u4f7f\u5f97S-O\u5206\u5b50\u7684\u63a5\u89e6\uff0c\u6700\u7ec8\u4f7f\u589e\u6eb6\u80fd\u529b\u5f97\u5230\u63d0\u5347\u3002\u5728\u63d0\u5347\u5149\u8c31\u5438\u6536\u3001\u964d\u4f4e\u80fd\u5e26\u9699\u548c\u4f18\u5316\u7ed3\u6676\u5ea6\u7b49\u6027\u80fd\u4e0a\u5747\u6709\u6240\u6539\u5584\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1.\u5408\u6210TRTOR\u9ad8\u5206\u5b50\u5171\u805a\u7269\u7684\u6d41\u7a0b\u56fe<\/strong><\/p>\n

\"1\"1\uff0cPd2(dba)3, P(o-tolyl)3\u572803\u5f53\u91cfPd\u50ac\u5316\uff0c\u5728\u5fae\u6ce2\u653e\u5c04\u4e0b\u5408\u6210\u3002<\/p>\n

2\uff0c\u5fae\u6ce2\u653e\u5c042-\u567b\u5429\uff0c2-\u6eb4\u567b\u5429\u7ee7\u7eed\u5fae\u6ce2\u653e\u5c04\uff0c\u7ea2\u7ebf\u6807\u793a\u5206\u5b50\u5185S-O\u65e0\u5171\u4ef7\u952e\u63a5\u89e6<\/p>\n

\u56fe2.\u5149\u8c31\u5438\u6536\u548c\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u6d4b\u8bd5\u56fe<\/strong><\/p>\n

\"2\"<\/p>\n

a)1 \u00d7 10\u22125<\/sup> m \u7684o-DCB\u6eb6\u6db2\u548c1 mg mL\u22121<\/sup>\u7684o-DCB\u6eb6\u6db2\u65cb\u6d82\u6210\u8584\u819c\u540e\u7684\u5149\u8c31\u5438\u6536\u66f2\u7ebf<\/p>\n

b)\u805a\u5408\u7269\u8584\u819c\u5728\u6c30\u5316\u7532\u70f7\u6eb6\u6db2\u4e2d\uff0c50 mV s\u22121<\/sup>\u6761\u4ef6\u4e0b\u6d4b\u8bd5\u800c\u5f97\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n

\u56fe3.\u592a\u9633\u80fd\u7535\u6c60\u7efc\u5408\u6027\u80fd\u6d4b\u8bd5\u56fe<\/strong><\/p>\n

\"3\"<\/p>\n

a)\u53cd\u5411\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u3002\u63d2\u56fe\u662f\u754c\u9762\u5c42\u6750\u6599PFN\u548cPEIE\u7684\u5206\u5b50\u7ed3\u6784\u5f0f<\/p>\n

b)\u5f00\u8def\u6761\u4ef6\u4e0b\u7ec4\u6210\u7535\u6c60\u7684\u80fd\u7ea7\u56fe<\/p>\n

c)\u5927\u6c14\u8d28\u91cf1.5AM\uff0c\u5149\u901a\u91cf100mW cm-2<\/sup>\u6761\u4ef6\u4e0b\uff0c\u5145\u5206\u5229\u7528P1-P3\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684J-V\u66f2\u7ebf<\/p>\n

d)\u5bf9\u5e94\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u91cf\u5b50\u6548\u7387\u6d4b\u8bd5\u56fe<\/p>\n

\u56fe4.P1-P3\u7ed3\u6784\u548c\u5f02\u8d28\u7ed3\u80fd\u5e26\u7684\u63a0\u89d2\u884d\u5c04\u56fe<\/strong><\/p>\n

\"4\"<\/p>\n

a-i)TRTOR\u805a\u5408\u7269\u7684\u5e73\u9762\u884d\u5c04\u56fe<\/p>\n

j-i)\u6676\u4f53\u7684\u4fa7\u9762\u5256\u89c6\u56fe<\/p>\n

\u56fe5.\u6709\u65e0\u6dfb\u52a0\u5242OTD\u7684\u5bf9\u6bd4\u56fe<\/strong><\/p>\n

\"5\"<\/p>\n

a,c)\u5206\u522b\u4e3a\u5728\u5236\u4f5c\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u65f6\u6ca1\u6709\u6dfb\u52a0\u5242OTD\u7684\u60c5\u51b5<\/p>\n

b,d)\u4e3a\u5728\u540c\u7b49\u6761\u4ef6\u4e0b\u52a0\u5165\u6dfb\u52a0\u5242OTD\u7684\u60c5\u51b5<\/p>\n

\u7ed3\u679c\u8868\u660e\u5728\u5236\u5907\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u65f6\uff0c\u6dfb\u52a0OTD\u53ef\u4ee5\u63d0\u5347\u80fd\u91cf\u8f6c\u6362\u6548\u7387<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4ee5\u5f80\u4e3b\u8981\u56e02T\u30013T\u548c4T\u9650\u5236\u7684\u805a\u5408\u7269\u534a\u5bfc\u4f53\u7ed9\u4f53\u5355\u5143\uff0c\u5728\u90ed\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u7814\u7a76\u4e2d\u5f97\u5230\u6539\u8fdb\uff0c\u4ed6\u4eec\u8bbe\u8ba1\u4e86\u4e00\u5bf9\u4e00\u8054\u7cfb\u7684\u7ed9\u4f53\u5355\u5143\uff0cPCE\u8fbe\u52309.76%\u5e26\u9699\u964d\u4f4e\u52301.50eV\u4ee5\u4e0b\uff0c\u8fd9\u79cd\u65b0\u578b\u7ed3\u6784\u4e3a\u4eca\u540ePSCs\u7684\u7ed9\u4f53\u7ed3\u6784\u63d0\u4f9b\u4e86\u66f4\u591a\u9009\u62e9\uff0c\u7814\u7a76\u8fd8\u8868\u660e\u5206\u5b50\u5185S-O\u975e\u5171\u4ef7\u952e\u63a5\u89e6\u5c06\u4f1a\u4e3a\u805a\u5408\u7269\u7684\u6027\u80fd\u63d0\u5347\u5230\u66f4\u9ad8\u6c34\u5e73\u3002<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u90ed\u65ed\u5c97<\/strong>\uff1a\u8fd1\u4e94\u5e74\u6765\uff0c\u53d1\u8868\u9ad8\u6c34\u5e73\u8bba\u6587\u8fd130\u7bc7\uff0c \u4e00\u4f5c\u548c\u901a\u8baf\u4f5c\u8005\u8bba\u658720\u4f59\u7bc7\uff0c \u5176\u4e2dChem. Rev. (\u5f71\u54cd\u56e0\u5b50: 46.568) \u4e00\u4f5c\u517c\u901a\u8baf1\u7bc7\uff0c Nature Photonics (\u5f71\u54cd\u56e0\u5b50: 32.386) \u4e00\u4f5c1\u7bc7\uff0cJACS (\u5f71\u54cd\u56e0\u5b50: 12.113) \u4e00\u4f5c\u548c\u901a\u8baf6\u7bc7\uff0cAdv. Mater. (\u5f71\u54cd\u56e0\u5b50: 17.493) \u4e00\u4f5c1\u7bc7\u3002\u591a\u7bc7\u8bba\u6587\u5728\u5c01\u9762\u53d1\u8868\uff0c\u5e76\u88ab\u56fd\u5185\u5916\u5a92\u4f53\u5e7f\u6cdb\u62a5\u9053\uff0c\u8bba\u6587\u5f15\u75281900\u4f59\u6b21\uff0c\u5355\u7bc7\u5f15\u7528100\u6b21\u4ee5\u4e0a\u8bba\u65879\u7bc7\uff0c\u7533\u8bf7\u56fd\u9645\u53d1\u660e\u4e13\u52293\u9879\uff0c\u6388\u67431\u9879\uff0c\u6210\u679c\u8f6c\u53161\u9879\u3002\u53d7\u5305\u62ecChem. Rev.\u5728\u5185\u7684\u591a\u5bb6\u6742\u5fd7\u548c\u51fa\u7248\u793e\u7ea6\u7a3f\u64b0\u5199\u7efc\u8ff0\u548c\u4e13\u8457, \u5728\u56fd\u5185\u5916\u8457\u540d\u4f1a\u8bae\u548c\u7814\u7a76\u673a\u6784\u4f5c\u9080\u8bf7\u62a5\u544a20\u4f59\u6b21, \u5728\u7814\u9879\u76ee\u7ecf\u8d39\u8fd12000\u4e07\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5:<\/strong>Head-to-Head Linkage Containing Bithiophene-Based\u00a0Polymeric Semiconductors for Highly Efficient Polymer\u00a0Solar Cells<\/a>\uff08Adv. Mater. 2016, DOI: 10.1002\/adma.201603112\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u5c0f\u7ec4 YueZhou<\/strong> \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\"2016-09-2016-08-\u65b0\u80fd\u6e90\u524d\u7ebf-2-300x300\"<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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