{"id":43675,"date":"2016-10-01T06:30:30","date_gmt":"2016-09-30T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=43675"},"modified":"2017-03-18T21:13:29","modified_gmt":"2017-03-18T13:13:29","slug":"jacs%ef%bc%9a%e6%89%8b%e6%80%a72d%e5%a4%9a%e5%ad%94%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%ef%bc%88cofs%ef%bc%89%e7%9a%84%e5%a4%9a%e7%9b%b8%e4%b8%8d%e5%af%b9%e7%a7%b0%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=43675","title":{"rendered":"JACS\uff1a\u624b\u60272D\u591a\u5b54\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u7684\u591a\u76f8\u4e0d\u5bf9\u79f0\u50ac\u5316"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011<\/strong><\/p>\n

\u5317\u4eac\u65f6\u95f49\u670813\u53f7\uff0cJACS\u5b98\u7f51\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u591a\u76f8\u4e0d\u5bf9\u79f0\u50ac\u5316\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201cHomochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis\u201d\u3002\u8bba\u6587\u901a\u8baf\u4f5c\u8005<\/strong>\u4e3a\u6765\u81ea\u4e0a\u6d77\u4ea4\u5927\u7684\u5218\u71d5\u548c\u5d14\u52c7\u6559\u6388<\/strong>\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u4e0a\u6d77\u4ea4\u5927\u7684\u5218\u71d5\u548c\u5d14\u52c7\u6559\u6388<\/strong>\u4f7f\u7528\u5bf9\u6620\u5f02\u6784\u4f53\u4e8c\u7532\u9187\u548c4,4\u2032-\u4e8c\u80fa\u4ea4\u8054\u5242\uff0c\u6210\u529f\u7684\u5408\u6210\u4e86\u5177\u6709\u624b\u6027\u529f\u80fd\u5d4c\u5165\u5230\u6846\u67b6\u4e2d\u76842D COFs\u3002\u7ecf\u8fc7\u8868\u5f81\u53d1\u73b0\uff0c\u6240\u5408\u6210\u7684CCOFs\u5177\u6709\u53cc\u91cd\u7684\u4e92\u7a7f\u7f51\u683c\u578b\u7f51\u7edc\u3002\u901a\u8fc7\u5bf9\u5e26\u6709Ti(O`Pr)4\u7684\u4e8c\u7532\u9187\u5355\u5143\u7684\u624b\u6027\u4e8c\u7f9f\u57fa\u7ec4\u8fdb\u884c\u540e\u6539\u6027\uff0c\u6750\u6599\u6210\u4e3a\u5177\u6709\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684\u4e8c\u4e59\u57fa\u950c\u5bf9\u919b\u7684\u4e0d\u5bf9\u79f0\u52a0\u6210\u7684\u975e\u5747\u76f8\u50ac\u5316\u5242\u3002<\/p>\n

\u8be5\u7814\u7a76\u5c06\u4f1a\u4e3a\u521b\u9020\u65b0\u578b\u591a\u5b54\u6750\u6599\u62d3\u5bbd\u6750\u6599\u8bbe\u8ba1\u4e0e\u5de5\u7a0b\u7684\u8303\u56f4\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\uff1aCCOFs\u7684\u5408\u6210\u8fc7\u7a0b<\/strong><\/p>\n

\"1\"<\/p>\n

CCOF-1\u548c CCOF-2\u901a\u8fc7\u6eb6\u5242\u70ed\u53cd\u5e94\u6cd5\u5408\u6210\uff0c\u5bf9\u6620\u5f02\u6784\u4f53TTA\u6216TTPA (0.25 mmol) \u548c 4\uff0c4\u2032-DADPM (0.5 mmol)\u57281\uff0c4-\u4e8c\u6c27\u516d\u73af(6 mL)\u548c\u6c34\u4e59\u9178(1.5 mL)\u4e2d\uff0c\u572810\u2103\u4e0b\u53cd\u5e943\u5929\uff0c\u6700\u7ec8\u83b7\u5f97\u7684\u7070\u8272\u5fae\u6676\u9897\u7c92\u7684\u4ea7\u91cf\u8fbe70%\u3002<\/p>\n

\u56fe2\uff1a\uff08a\uff09CCOF-1\u548c\uff08b\uff09CCOF-2\u7684PXRD\u56fe<\/strong><\/p>\n

\"2\"<\/p>\n

\u9ed1\u8272\u7ebf\u4e3a\u539f\u56fe\uff1b\u7ea2\u8272\u7ebf\u4e3a\u7cbe\u4fee\u56fe\uff1b\u84dd\u8272\u7ebf\u4e3a\u8ba1\u7b97\u5256\u9762\uff1b\u7eff\u8272\u7ebf\u8868\u793a\u5b9e\u9a8c\u548c\u7cbe\u4feePXRD\u7684\u533a\u522b\uff1b\uff08a\uff09\u63d2\u5165\u56fe\u4e3aCCOF-1\u7684\u5e76\u884c\u7684\u53cc\u91cd\u6e17\u900f\u5c42\uff1b\uff08b\uff09\u63d2\u5165\u56fe\u4e2d\uff0c\u5de6\u4fa7\u4e3a\uff08110\uff09\u548c\uff08001\uff09\u9762\u7684\u56fe\u8c31\uff0c\u53f3\u4fa7\u4e3aCCOF-2\u7684AB\u5806\u79ef\u5c42\u3002<\/p>\n

\u56fe3\uff1aCCOF-1\u548cCCOF-2\u7684\u7a7a\u95f4\u586b\u5145\u6a21\u578b<\/strong><\/p>\n

\"3\"<\/p>\n

\u56fe\uff08a\uff09\uff08b\uff09\u4e3aCCOF-1\u6cbf\u7740\uff08a\uff0cc\uff09c\u8f74\u65b9\u5411\u7684\u7a7a\u95f4\u586b\u5145\u6a21\u578b\uff1b\u56fe\uff08c\uff09\uff08d\uff09\u4e3aCCOF-2\u6cbf\u7740\uff08b\uff0cd\uff09b\u8f74\u65b9\u5411\u7684\u7a7a\u95f4\u586b\u5145\u6a21\u578b\u3002<\/p>\n

\u56fe4\uff1aN2\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\u548c\u5b54\u5f84\u5206\u5e03\u5256\u9762<\/strong><\/p>\n

\"4\"<\/p>\n

\u56fe\uff08a\uff09\uff08c\uff09\u5206\u522b\u4e3aCCOF-1\u548cCCOF-2\u572877K\u4e0b\u7684N2\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\uff1b\u56fe\uff08b\uff09\uff08d\uff09\u5206\u522b\u4e3aCCOF-1\u548cCCOF-2\u7684\u5b54\u5f84\u5206\u5e03\u5256\u9762\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u4e0a\u6d77\u4ea4\u5927\u7684\u5218\u71d5\u548c\u5d14\u52c7\u6559\u6388\u6210\u529f\u5408\u6210\u4e86CCOFs\u3002\u901a\u8fc7\u5404\u79cd\u8868\u5f81\u6280\u672f\u53d1\u73b0\uff0cTi(O`Pr)4\u4f5c\u7528\u4e8e\u6750\u6599\u540e\uff0c\u50ac\u5316\u5242\u5bf9\u82b3\u9999\u919b\u7684\u4e0d\u5bf9\u79f0\u52a0\u6210\u7684\u6548\u7387\u63d0\u9ad8\u3002\u50ac\u5316\u5242\u53ef\u4ee5\u56de\u6536\u548c\u91cd\u590d\u4f7f\u7528\u800c\u4e0d\u635f\u5931\u4efb\u4f55\u5177\u6709\u7684\u50ac\u5316\u6d3b\u6027\u7684\u6210\u5206\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u8bc1\u660e\u4e86\u5b83\u662f\u53ef\u4ee5\u8bbe\u8ba1\u5e76\u5408\u6210\u5177\u6709\u6c38\u4e45\u7684\u5b54\u9699\u7684CCOFs\uff0c\u4e5f\u8868\u660e\u6709\u671b\u901a\u8fc7\u6a21\u5757\u5316\u7684\u5408\u6210\u65b9\u6cd5\u521b\u9020\u51fa\u66f4\u591a\u79cd\u7c7b\u7684COF\u6750\u6599\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis <\/a>(JACS, 2016, DOI: 10.1021\/jacs.6b07714)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8MOF\u7ec4\u6731\u6653\u79c0\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0eMOF\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3MOF\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8bed\u3011 \u5317\u4eac\u65f6\u95f49\u670813\u53f7\uff0cJACS\u5b98\u7f51\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u591a\u76f8\u4e0d\u5bf9\u79f0\u50ac\u5316\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201cHomochiral 2D Porous Coval…<\/p>\n","protected":false},"author":1056,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1388],"class_list":["post-43675","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-cuiyong"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/43675"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1056"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=43675"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/43675\/revisions"}],"predecessor-version":[{"id":43892,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/43675\/revisions\/43892"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=43675"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=43675"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=43675"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}