{"id":43039,"date":"2016-09-27T06:30:20","date_gmt":"2016-09-26T22:30:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=43039"},"modified":"2017-03-18T21:43:22","modified_gmt":"2017-03-18T13:43:22","slug":"chem-rev-%e8%b5%b5%e7%ab%8b%e4%b8%9ckanatzidis%e7%bb%bc%e8%bf%b0%ef%bc%9a%e9%ab%98%e6%80%a7%e8%83%bd%e5%9d%97%e7%8a%b6%e7%83%ad%e7%94%b5%e6%9d%90%e6%96%99%e7%9a%84%e5%90%88%e7%90%86%e8%ae%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=43039","title":{"rendered":"Chem. 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Kanatzidis<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5728<strong>Chemical Reviews<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a<strong>Rationally Designing High-Performance Bulk Thermoelectric 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-43043\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/3-42.jpg\" alt=\"\" width=\"500\" height=\"493\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/3-42.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/3-42-300x296.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3 \u6750\u6599\u63ba\u6742\u5bf9ZT\u503c\u7684\u5f71\u54cd<\/strong><\/p>\n<p>\uff08a\uff09\u901a\u8fc7\u5f62\u6210\u4ecb\u4e8eAC\u548cBC\u7684\u56fa\u6eb6\u4f53A1-xBxC\u5f71\u54cd\u80fd\u5e26\u8f90\u5408\uff1a\u968f\u7740\u63ba\u6742\u767e\u5206\u6bd4\u7684\u589e\u52a0\uff0c\u80fd\u5e26\u7ed3\u6784\u53d1\u751f\u6539\u53d8<br \/>\n\uff08b\uff09Seebeck\u7cfb\u6570<br 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cm-3\u6570\u91cf\u7ea7\u3002\u8f83\u4f4e\u63ba\u6742\u6216\u65e0\u63ba\u6742\u6750\u6599\uff0c\u7531\u4e8e\u79bb\u5b50\u6742\u8d28\u6563\u5c04\u6548\u5e94\u589e\u5f3a\uff0c\u5728\u9ad8\u63ba\u6742\u7684\u534a\u5bfc\u4f53\u4e2d\u5bc6\u96c6\u7684\u81ea\u7531\u8f7d\u6d41\u5b50\u5c06\u4f1a\u5bfc\u81f4\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u7684\u964d\u4f4e\u3002\u56e0\u6b64\u9700\u8981\u5bf9\u63ba\u6742\u8fdb\u884c\u4e00\u5b9a\u7684\u63a7\u5236\uff0c\u6765\u63d0\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\uff0c\u8fdb\u800c\u63d0\u9ad8ZT\u503c\u3002\u4e5f\u5df2\u6709\u7814\u7a76\u8868\u660e\u4e3a\u4e86\u6539\u5584\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\uff0c\u8fdb\u884c\u4e09\u7ef4\u7684\u8c03\u5236\u63ba\u6742\u53ef\u6709\u6548\u63d0\u9ad8\u4e00\u4e9b\u91cd\u8981\u7684\u70ed\u7535\u6750\u6599\u7684ZT\u503c\u3002\u53e6\u5916\uff0c\u9664\u4e86\u8c03\u5236\u63ba\u6742\uff0c\u6750\u6599\u7684\u7eb9\u7406\u7ed3\u6784\u53ef\u4f5c\u4e3a\u63d0\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u7684\u53e6\u4e00\u53ef\u884c\u9014\u5f84\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u4e00\u4e9b\u5177\u5404\u5411\u5f02\u6027\u7ed3\u6784\u7684\u6750\u6599\u6765\u8bf4\u3002\u5404\u9879\u5f02\u8d28\u7ed3\u6784\u4e2d\uff0c\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u53ef\u80fd\u53ea\u5728\u4e00\u4e9b\u7279\u5b9a\u7684\u6676\u5411\u8868\u73b0\u66f4\u9ad8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-43044\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/5-37.jpg\" alt=\"\" width=\"297\" height=\"509\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/5-37.jpg 297w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/5-37-175x300.jpg 175w\" sizes=\"(max-width: 297px) 100vw, 297px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4 \u6bd4\u8f83\u4e0d\u540c\u63ba\u6742\u65b9\u5f0f\u5bf9\u6750\u6599\u6027\u80fd\u7684\u5f71\u54cd<\/strong><\/p>\n<p>\uff08a\uff09\uff08b\uff09\uff08c\uff09\u5206\u522b\u8868\u793a\u65e0\u63ba\u6742\u3001\u8c03\u5236\u63ba\u6742\u548c\u5747\u5300\u63ba\u6742\u4e09\u79cd\u4e0d\u540c\u6a21\u5f0f\u7684\u63ba\u6742\u539f\u7406\u56fe<br \/>\n\uff08d\uff09\uff08e\uff09\u5206\u522b\u8868\u793an\u578b\u548cp\u578b\u63ba\u6742<br \/>\n\uff08f\uff09\u6bd4\u8f83p\u578b\u63ba\u6742\u7684SiGe\u5408\u91d1\u548cp\u578b\u63ba\u6742\u7684BiCuSeO\u5728\u5747\u5300\u63ba\u6742\u548c\u8c03\u5236\u63ba\u6742\u4e24\u79cd\u4e0d\u540c\u6a21\u5f0f\u4e0b\u7684\u6750\u6599\u7684\u529f\u7387\u7cfb\u6570<\/p>\n<p><strong>3\uff09\u964d\u4f4e\u6676\u683c\u70ed\u5bfc\u7387<\/strong><\/p>\n<p>\u56fa\u4f53\u4e2d\uff0c\u539f\u5b50\u95f4\u5728\u4ece\u4e0d\u5e73\u8861\u4f4d\u7f6e\u53d1\u751f\u79fb\u4f4d\u65f6\u4ea7\u751f\u7684\u76f8\u4e92\u4f5c\u7528\u4f1a\u5bfc\u81f4\u4e00\u7cfb\u5217\u5177\u591a\u79cd\u6ce2\u957f\u7684\u632f\u52a8\u6ce2\uff0c\u79f0\u4e3a\u58f0\u5b50\u3002\u58f0\u5b50\u662f\u4e00\u4e2a\u70ed\u8f7d\u4f53\uff0c\u80fd\u5728\u6676\u683c\u95f4\u4f20\u8f93\uff0c\u662f\u6676\u683c\u70ed\u5bfc\u7387\u03balat\u7684\u4e00\u90e8\u5206\u3002\u800c\u8981\u63d0\u9ad8\u6750\u6599\u7684ZT\u503c\uff0c\u5219\u9700\u8981\u964d\u4f4e\u03balat\u4ee5\u589e\u52a0\u989d\u5916\u7684\u70ed\u963b\u3002\u8fd9\u4e3b\u8981\u901a\u8fc7\u5bf9\u58f0\u5b50\u6ce2\u7684\u6563\u5c04\u6765\u5b9e\u73b0\uff0c\u539f\u5b50\u7f6e\u6362\u548c\u7eb3\u7c73\u5c3a\u5ea6\u4e0a\u7b2c\u4e8c\u76f8\u6210\u6838\u4e0e\u751f\u957f\u5e26\u6765\u7684\u539f\u5b50\u70b9\u7f3a\u9677\u3001\u5fae\u7c73\u6216\u4e9a\u5fae\u7c73\u7ea7\u7684\u7ed3\u6784\u7f3a\u9677\u90fd\u6709\u52a9\u4e8e\u6563\u5c04\u58f0\u5b50\u6ce2\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-43045\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/6-26.jpg\" alt=\"\" width=\"491\" height=\"500\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/6-26.jpg 491w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/6-26-295x300.jpg 295w\" sizes=\"(max-width: 491px) 100vw, 491px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5 \u4e0d\u540c\u7684\u70b9\u7f3a\u9677\u5bf9\u964d\u4f4e\u6750\u6599\u6676\u683c\u70ed\u5bfc\u7387\u7684\u7a0b\u5ea6<\/strong><\/p>\n<p>\uff08a\uff09\uff08b\uff09\uff08c\uff09\u5206\u522b\u4e3a\u5355\u4e2a\u539f\u5b50\u63ba\u6742\u3001\u5341\u5b57\u578b\u66ff\u6362\u548c\u6676\u683c\u7a7a\u4f4d\u5f62\u6210\u7684\u70b9\u7f3a\u9677\u793a\u56fe<br \/>\n\uff08d\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0b\uff0c\u5177\u4e0d\u540c\u70b9\u7f3a\u9677\u7684SnTe\u7684\u70ed\u5bfc\u7387\u66f2\u7ebf\u56fe<\/p>\n<p><strong>\u56db\u3001\u7535\u5b50\u548c\u58f0\u5b50\u4f20\u8f93\u7684\u89e3\u8026<\/strong><\/p>\n<p>\u5757\u4f53\u6750\u6599\u4e2d\uff0c\u7eb3\u7c73\u7ed3\u6784\u6539\u53d8\u53ef\u80fd\u4f1a\u663e\u8457\u964d\u4f4e\u6750\u6599\u7684\u70ed\u5bfc\u7387\uff0c\u4f46\u540c\u65f6\u7531\u4e8e\u6750\u6599\u8868\u9762\u7ed3\u6676\u9519\u914d\u6216\u7535\u5b50\u5e26\u672a\u91cd\u5408\u5f15\u8d77\u7684\u989d\u5916\u80fd\u91cf\u52bf\u5792\uff0c\u540c\u6837\u4e5f\u4f1a\u589e\u52a0\u7535\u8377\u8f7d\u6d41\u5b50\u7684\u6563\u5c04\u3002\u8fd9\u5bf9\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u548c\u529f\u7387\u7cfb\u6570\u6765\u8bf4\u90fd\u662f\u6781\u4e3a\u4e0d\u5229\u7684\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u8981\u907f\u514d\u7eb3\u7c73\u7ed3\u6784\u7684\u70ed\u7535\u6750\u6599\u8fc1\u79fb\u7387\u7684\u635f\u5931\uff0c\u5747\u5300\u7684\u754c\u9762\u548c\u80fd\u91cf\u91cd\u5408\u7684\u7535\u5b50\u5e26\u662f\u975e\u5e38\u5fc5\u8981\u7684\u3002\u5e76\u4e14\u5728\u67d0\u79cd\u7a0b\u5ea6\u4e0a\uff0c\u8fd9\u79cd\u72b6\u6001\u4f1a\u5b9e\u73b0\u7535\u5b50\u4e0e\u58f0\u5b50\u4f20\u8f93\u7684\u89e3\u8026\u3002\u5b9e\u73b0\u89e3\u8026\u7684\u65b9\u6cd5\u6709\u5e94\u53d8\u8fde\u7eed\u7eb3\u7c73\u7ed3\u6784\u5316\u3001\u57fa\u5e95\/\u6c89\u79ef\u7269\u4ef7\u5e26\u6392\u5217\u3001\u7ec4\u5206\u5408\u91d1\u5316\u7eb3\u7c73\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-43046\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/10-7.jpg\" alt=\"\" width=\"400\" height=\"500\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/10-7.jpg 400w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/10-7-240x300.jpg 240w\" sizes=\"(max-width: 400px) 100vw, 400px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6 \u7535\u5b50\u4e0e\u58f0\u5b50\u4f20\u8f93\u89e3\u8026\u793a\u610f\u56fe<\/strong><\/p>\n<p>\uff08a\uff09\u7eb3\u7c73\u7ed3\u6784\u5757\u4f53\u6750\u6599\u4e2d\u7535\u5b50\u4e0e\u58f0\u5b50\u89e3\u8026\u56fe\u793a\uff0c\u58f0\u5b50\uff08\u84dd\u8272\u7bad\u5934\uff09\u901a\u8fc7\u7eb3\u7c73\u6c89\u79ef\u7269\u800c\u5f3a\u70c8\u6563\u5c04\uff0c\u800c\u7535\u5b50\uff08\u7ea2\u8272\u7bad\u5934\uff09\u5219\u5728\u754c\u9762\u95f4\u81ea\u7531\u7a7f\u884c<br \/>\n\uff08b\uff09\u58f0\u5b50\u5728\u901a\u8fc7\u4e09\u79cd\u53ef\u80fd\u7684\u754c\u9762\uff08\u8fde\u7eed\u3001\u534a\u8fde\u7eed\uff0c\u4e0d\u8fde\u7eed\uff09\u548c\u57fa\u5e95\u95f4\u4ea7\u751f\u7684\u6563\u5c04\u56fe\u793a<br \/>\n\uff08c\uff09\u5c11\u91cfSrTe\u7eb3\u7c73\u6c89\u79ef\u7269\u5d4c\u5165PbTe\u57fa\u5e95\u4e2d\uff0c\u6750\u6599\u7684\u9ad8\u5206\u8fa8\u7387TEM\u76f8\u886c\u56fe\u50cf<br \/>\n\uff08d\uff09\u9644\u7740\u5728\u8fb9\u754c\u4e0a\u7684\u7eb3\u7c73\u6c89\u79ef\u7269\u7684\u7535\u955c\u653e\u5927\u56fe<br \/>\n\uff08e\uff09\u7ffb\u8f6c\u9996\u4e2a\u6c89\u79ef\u7269\u7684\u5085\u91cc\u53f6\u53d8\u5316\u56fe\u50cf\uff0c\u8868\u660e\u5728\u6676\u754c\u7f3a\u5931\u4f4d\u79fb<br \/>\n\uff08f\uff09\u56db\u4e2a\u7eb3\u7c73\u6c89\u79ef\u7269\u7684\u526a\u5207\u5e94\u53d8\u56fe<\/p>\n<p><strong>\u4e94\u3001\u672c\u5f81\u56fa\u6709\u4f4e\u70ed\u5bfc\u7387\u7684\u65b0\u578b\u70ed\u7535\u6750\u6599<\/strong><\/p>\n<p>\u672c\u5f81\u56fa\u6709\u4f4e\u70ed\u5bfc\u7387\u7684\u6750\u6599\u53ef\u514d\u53bb\u4e00\u7cfb\u5217\u4e3a\u964d\u4f4e\u70ed\u5bfc\u7387\u7684\u65b9\u6cd5\uff0c\u4ece\u800c\u76f4\u63a5\u5236\u5907\u51fa\u9ad8\u6027\u80fd\u7684\u70ed\u7535\u6750\u6599\u3002\u8fd9\u7c7b\u6750\u6599\u7684\u4f4e\u70ed\u5bfc\u7387\u6027\u8d28\u4e3b\u8981\u6e90\u4e8e\u4e0d\u8c10\u548c\u6216\u662f\u5404\u5411\u5f02\u6027\u7684\u7c98\u7ed3\u3001\u6676\u683c\u632f\u52a8\u3001\u79bb\u5b50\u8fc1\u79fb\u5f15\u8d77\u7684\u539f\u5b50\u65e0\u5e8f\u3001\u94dc\u79bb\u5b50\u6db2\u72b6\u7684\u8fc1\u79fb\u65b9\u5f0f\u3001\u5927\u5206\u5b50\u91cd\u91cf\u3001\u590d\u6742\u7684\u6676\u4f53\u7ed3\u6784\u53ca\u5b64\u5bf9\u7535\u5b50\u7b49\u3002\u76ee\u524d\uff0c\u6700\u5177\u53d1\u5c55\u524d\u666f\u4e14\u5177\u4f4e\u70ed\u5bfc\u7387\u7684\u65b0\u578b\u70ed\u7535\u6750\u6599\u4e3b\u8981\u6709\u5c42\u72b6SnSe\u3001BiCuSeO\u3001\u534a\u8d6b\u65af\u52d2\uff08half-Heusler\uff09MgAgSb\u3001\u94dc\u786b\u5c5e\u5316\u5408\u7269\u3001\u590d\u6742\u7684\u94cb\u786b\u5c5e\u5316\u5408\u7269\u3001\u5177\u5b64\u5bf9\u7535\u5b50\u7684\u786b\u5c5e\u5316\u5408\u7269\u548c\u9edd\u94dc\u77ff\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-43047\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/13-3.jpg\" alt=\"\" width=\"500\" height=\"264\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/13-3.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/13-3-300x158.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7 SnSe\u6676\u4f53\u7ed3\u6784\u53ca\u5176ZT\u503c<\/strong><\/p>\n<p>\uff08a\uff09\u4eceb\u8f74\u5bf9SnSe\u6676\u4f53\u7ed3\u6784\u7684\u900f\u89c6\u56fe\uff1aSn\u539f\u5b50\uff08\u7070\u8272\uff09\uff1bSe\u539f\u5b50\uff08\u7ea2\u8272\uff09<br \/>\n\uff08b\uff09SnSe\u5355\u6676\u4e0d\u540c\u8f74\u5411\u548c\u591a\u6676SnSe\u5fae\u7403\u5728\u5f84\u5411\u548c\u8f74\u5411\u4e0a\uff0c\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8ZT\u503c\u7684\u53d8\u5316\u66f2\u7ebf<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-43048\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/17-2.jpg\" alt=\"\" width=\"500\" height=\"262\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/17-2.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/09\/17-2-300x157.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe8 BiCuSeO\u7684\u6676\u4f53\u7ed3\u6784\u53caZT\u503c<\/strong><\/p>\n<p>\uff08a\uff09\u4ecea\u8f74\u900f\u89c6\u5f97\u5230\u7684\u6676\u4f53\u7ed3\u6784\u56fe\uff1aCu\u539f\u5b50\uff08\u9ec4\u8272\uff09\u3001Se\u539f\u5b50\uff08\u7ea2\u8272\uff09\u3001B\u539f\u5b50\uff08\u7c89\u7ea2\u8272\uff09\u3001O\u539f\u5b50\uff08\u84dd\u8272\uff09\u3002<br \/>\n\uff08b\uff09\u4e0d\u540c\u70ed\u7535\u6750\u6599\uff1aCsBi4Te6, Bi\u2212Sb\u2212Te, AgPbmSbTem+2 (LAST), Mg2SiSn, PbTe\u2212SrTe\u2212Na, \u65b9\u94b4\u77ff, BiCuSeO, half-Heusler, SiGe, and 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\/>\n<strong>\uff081\uff09\u901a\u8fc7\u8c03\u63a7\u80fd\u5e26\u7ed3\u6784\u53ca\u5fae\u89c2\u7ed3\u6784\uff0c\u4f18\u5316\u5df2\u77e5\u6750\u6599\u3002<\/strong><br 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