{"id":42638,"date":"2016-09-25T06:30:01","date_gmt":"2016-09-24T22:30:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=42638"},"modified":"2016-09-24T21:56:36","modified_gmt":"2016-09-24T13:56:36","slug":"adv-mater-%ef%bc%9a%e9%94%82-%e6%b0%a7%e7%94%b5%e6%b1%a0-%e9%98%b4%e6%9e%81%e8%a1%a8%e9%9d%a2%e8%af%b1%e5%af%bc%e5%92%8c%e6%ba%b6%e5%89%82%e5%8c%96%e4%bb%8b%e5%af%bc%e7%9a%84%e5%be%ae%e7%b1%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=42638","title":{"rendered":"Adv. Mater.\uff1a\u9502-\u6c27\u7535\u6c60\u9634\u6781\u8868\u9762\u8bf1\u5bfc\u548c\u6eb6\u5242\u5316\u4ecb\u5bfc\u7684\u5fae\u7c73\u7ea7Li2O2\u7684\u5faa\u73af\u8fc7\u7a0b"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u53ef\u5145\u7535\u7684\u8d28\u5b50\u60f0\u6027Li-O2<\/sub>\u7535\u6c60\u5177\u6709\u5f88\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8fdc\u80dc\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u6709\u5e0c\u671b\u6210\u4e3a\u6c7d\u6cb9\u7684\u66ff\u4ee3\u54c1\uff0c\u56e0\u6b64\u8fd1\u6765\u5907\u53d7\u5173\u6ce8\u3002Li-O2<\/sub>\u7535\u6c60\u53cd\u5e94\u867d\u7136\u7b80\u5355\uff0c\u4f46\u662f\u5145\u653e\u7535\u5faa\u73af\u4e2d\u4ea7\u7269Li2<\/sub>O2<\/sub>\u7684\u751f\u957f\u5206\u89e3\u8fc7\u7a0b\u5927\u5927\u5f71\u54cd\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u653e\u7535\u8fc7\u7a0b\u4e2dLi2<\/sub>O2<\/sub>\u7684\u751f\u957f\u673a\u7406\u6a21\u578b\u4e3b\u8981\u4e3a\u8868\u9762\u5438\u9644\u9014\u5f84\u548c\u6eb6\u5242\u5316\u4ecb\u5bfc\u9014\u5f84\uff1b\u800c\u5145\u7535\u8fc7\u7a0bLi2<\/sub>O2<\/sub>\u7684\u5206\u89e3\u9014\u5f84\u5374\u5f88\u5c11\u6709\u4eba\u7814\u7a76\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5927\u591a\u6570\u5bf9Li2<\/sub>O2<\/sub>\u751f\u957f\u673a\u7406\u7684\u7814\u7a76\u4ec5\u9650\u4e8e\u9996\u6b21\u5145\u7535\u8fc7\u7a0b\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/span><\/strong><\/p>\n

2016\u5e749\u670816\u65e5\uff0cAdvanced Materials\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8eLi-O2<\/sub>\u7535\u6c60\u7684\u6587\u7ae0\uff0c\u9898\u76ee\u4e3a\u201cCathode Surface-Induced, Solvation-Mediated, Micrometer-Sized Li2<\/sub>O2<\/sub> Cycling for Li\u2013O2<\/sub> Batteries\u201d\u3002\u8be5\u6587\u7ae0\u7684\u901a\u8baf\u4f5c\u8005\u662f\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u5f20\u745c\u6559\u6388<\/strong>\u3002\u8be5\u6587\u7ae0\u4e3b\u8981\u9610\u8ff0\u9634\u6781\u4e0aLi2<\/sub>O2<\/sub>\u7684\u751f\u6210\u3001\u5206\u89e3\u548c\u6f14\u53d8\u673a\u7406\u3002<\/p>\n

\u7814\u7a76\u4eba\u5458\u4e3b\u8981\u7814\u7a76\u957f\u5faa\u73af\u8fc7\u7a0b\u4e2dLi2<\/sub>O2<\/sub>\u7684\u5f62\u8c8c\u548c\u6676\u578b\u7684\u6f14\u53d8\u673a\u7406\u3002\u4ed6\u4eec\u91c7\u7528\u57fa\u4e8eRuO2<\/sub>\u7eb3\u7c73\u9897\u7c92\u5305\u8986\u7684\u4eba\u5b57\u5f62\u56fe\u6848\u78b3\u7eb3\u7c73\u7ba1\uff08CNTs\uff09\u4f5c\u4e3a\u9ad8\u7a33\u5b9a\u9634\u6781\uff0c\u9610\u8ff0Li-O2<\/sub>\u7535\u6c60\u653e\u7535\u4ea7\u7269Li2<\/sub>O2<\/sub>\u7684\u589e\u5f3a\u6eb6\u5242\u5316\u4ecb\u5bfc\u751f\u957f\/\u5206\u89e3\u8fc7\u7a0b\u3002\u7814\u7a76\u8868\u660eRuO2<\/sub>\/CNT\u9634\u6781\u8868\u73b0\u51fa\u5bf9\u8d85\u6c27\u5316\u7269\uff08LiO2<\/sub>\u6216 O2\u00af\uff09\u6291\u5236\u7684\u8868\u9762\u7ed3\u5408\u80fd\uff0c\u56e0\u6b64\u4fc3\u8fdbLiO2<\/sub>\u7684\u751f\u6210\uff0c \u6613\u4e8e\u6269\u6563\u81f3\u6eb6\u6db2\u4e2d\u5e76\u5feb\u901f\u5f62\u6210\/\u5206\u89e3\u5fae\u7c73\u7ea7\u82b1\u72b6Li2<\/sub>O2<\/sub>\u7c07\uff0c\u8fd9\u79cd\u82b1\u72b6\u5f62\u8c8c\u4ece\u672a\u6709\u4eba\u62a5\u9053\u8fc7\u3002\u5e76\u4e14\u53d1\u73b0\u8fd9\u79cd\u9ad8\u6548\u751f\u957f\/\u5206\u89e3\u673a\u7406\u5728\u957f\u5faa\u73af\u65f6\u5177\u6709\u53ef\u6301\u7eed\u6027\u3002\u56e0\u6b64\uff0c\u5f97\u5230\u8d85\u9ad8\u6bd4\u5bb9\u91cf\u3001\u5f88\u4f4e\u8fc7\u7535\u4f4d\u548c\u957f\u5faa\u73af\u5bff\u547d\u7684Li-O2<\/sub>\u7535\u6c60\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe<\/strong>1<\/strong>\uff1a\u7eaf<\/strong>CNT<\/strong>\u548c<\/strong>RuO2<\/sub>\/CNT<\/strong>\u7684\u793a\u610f\u56fe\u53ca\u8868\u5f81<\/strong><\/p>\n

\"1\"<\/p>\n

(a) RuO2<\/sub>\/CNT\u8bbe\u8ba1\u548c\u5236\u5907\u7684\u793a\u610f\u56fe\u3002<\/p>\n

(b) \u7eafCNT\u7684TEM\u56fe\u3002<\/p>\n

(c) RuO2<\/sub>\/CNT\u7684TEM\u56fe\uff0cCNT\u7684\u8868\u9762\u5747\u5300\u5305\u89861.5 nm\u7684RuO2<\/sub>\u9897\u7c92\u3002<\/p>\n

(d-f) \u5206\u522b\u4e3aRuO2<\/sub>\/CNT\u7684Ru 3p\u3001C 1s\u3001O 1s\u7684XPS\u56fe\u8c31\u3002\u542b\u6c27\u5b98\u80fd\u56e2\u5cf0\u7684\u6d88\u5931\u8bf4\u660eRuO2<\/sub>\u7684\u5305\u8986\u663e\u8457\u964d\u4f4e\u4e86CNT\u8868\u9762\u4e0a\u7f3a\u9677\u3002<\/p>\n

(g) \u7eafCNT\u548cRuO2<\/sub>\/CNT\u7684\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u3002\u7eafCNT\u8868\u9762\u5927\u91cf\u542b\u6c27\u5b98\u80fd\u56e2\u9020\u6210\u7684\u5c0f\u5b54\uff083 nm\uff09\u5728RuO2<\/sub>\/CNT\u8868\u9762\u6d88\u5931\u3002<\/p>\n

\u56fe<\/strong>2<\/strong>\uff1a<\/strong>Li-O2<\/sub><\/strong>\u7535\u6c60\u653e\u7535\u6027\u80fd\u53ca\u4ea7\u7269\u5f62\u8c8c<\/strong><\/p>\n

\"2\"<\/p>\n

(a-c) \u7eafCNT\u9634\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200 mA\/g\uff0c\u622a\u6b62\u5bb9\u91cf\u5206\u522b\u4e3a500\u30011000\u30012000 mAh\/g\u6761\u4ef6\u4e0b\u653e\u7535\u540e\u7684FESEM\u56fe\u3002<\/p>\n

(d-f) RuO2<\/sub>\/CNT\u9634\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200 mA\/g\uff0c\u622a\u6b62\u5bb9\u91cf\u5206\u522b\u4e3a500\u30011000\u30012000 mAh\/g\u6761\u4ef6\u4e0b\u653e\u7535\u540e\u7684FESEM\u56fe\uff0c\u63d2\u56fe\u5206\u522b\u662f\u5bf9\u5e94\u7684\u653e\u5927FESEM\u56fe\u3002<\/p>\n

(g) Li-O2<\/sub>\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200 mA\/g\uff0c\u622a\u6b62\u5bb9\u91cf\u4e3a2000 mAh\/g\u6761\u4ef6\u4e0b\u7684\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

(h) \u4e24\u79cd\u9634\u6781\u5bf9\u5e94\u7684PXRD\u56fe\uff0c\u5c3d\u7ba1\u653e\u7535\u4ea7\u7269\u5f62\u8c8c\u4e0d\u540c\uff0cPXRD\u4e0a\u7684\u5cf0\u5747\u4e3aLi2<\/sub>O2<\/sub>\u3002<\/p>\n

(i) \u4e24\u79cd\u9634\u6781\u7ec4\u88c5\u7684Li-O2<\/sub>\u7535\u6c60\u5728100 mA\/g\u548c2 A\/g\u4e0b\u653e\u7535\u7684\u500d\u7387\u5bb9\u91cf\u3002\u00b2<\/p>\n

\u56fe<\/strong>3<\/strong>\uff1a<\/strong>Li2<\/sub>O2<\/sub><\/strong>\u7684\u751f\u957f\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n

\"3\"<\/p>\n

(a) Li2<\/sub>O2<\/sub>\u7684\u751f\u957f\u673a\u7406\u793a\u610f\u56fe\u663e\u793a\uff0c\u5f53\u9634\u6781\u8868\u9762LiO2<\/sub>*\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u5927\u4e8e\u6eb6\u89e3\u7269\u65f6\u4e3a\u8868\u9762\u5438\u9644\u9014\u5f84\uff0c\u800c\u5f53\u6eb6\u89e3\u7269\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u5c0f\u4e8e\u8868\u9762\u7684LiO2<\/sub>*\u65f6\u4e3a\u6eb6\u5242\u5316\u4ecb\u5bfc\u9014\u5f84\u3002<\/p>\n

(b) Li-O2<\/sub>\u7535\u6c60\u7684\u7eafCNT\u548cRuO2<\/sub>\/CNT\u9634\u6781\u7684LSVs\u6d4b\u8bd5\u57280.05 mV\/s\u4e0b\u8fdb\u884c\u3002CNT\u9634\u6781\u5728\u7ea62.5 V\u51fa\u73b0\u5355\u5cf0\uff0c\u800cRuO2<\/sub>\/CNT\u9634\u6781\u8fd8\u5728\u7ea62.22 V\u51fa\u73b0\u7b2c\u4e8c\u4e2a\u5cf0\u3002\u7b2c\u4e00\u4e2a\u5cf0\u662fLi2<\/sub>O2<\/sub>\u7684\u751f\u957f\u6765\u81ea\u8868\u9762\u5438\u9644\u9014\u5f84\uff0c\u7b2c\u4e8c\u4e2a\u5cf0\u5219\u662f\u6765\u81ea\u6eb6\u5242\u5316\u4ecb\u5bfc\u9014\u5f84\u3002<\/p>\n

(c) \u6700\u4f18\u7ed3\u6784\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\u4ee5\u53ca\u5728C-O-C\u5b98\u80fd\u56e2\u5185\u53cc\u7f3a\u9677CNT\u4e0a \u548cLiO2<\/sub>\u5bf9\u5e94\u7684\u7ed3\u5408\u80fd\u3002<\/p>\n

(d) \u6700\u4f18\u7ed3\u6784\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\u4ee5\u53ca\u5728RuO2<\/sub>\u5305\u8986RuO2<\/sub>\/CNT\u4e0a \u548cLiO2<\/sub>\u5bf9\u5e94\u7684\u7ed3\u5408\u80fd\u3002\u4e0eCNT\u8868\u9762\u4e0a\u7684\u8fd8\u539f\u7269\u76f8\u6bd4\u7ed3\u5408\u80fd\u66f4\u5c0f\u8bf4\u660e\u201c\u5931\u91cd\u201d\u7269\u66f4\u6613\u8131\u79bbRuO2<\/sub>\/CNT\u8868\u9762\u8fdb\u5165\u7535\u89e3\u6db2\u3002<\/p>\n

\u989c\u8272\u6807\u8bb0\uff1a\u78b3\uff08\u7070\uff09\uff0c\u6c27\uff08\u7ea2\uff09\uff0c\u948c\uff08\u6df1\u7eff\uff09\uff0c\u9502\uff08\u7c89\u7ea2\uff09\uff0c \u548cLiO2<\/sub>\u7684\u6c27\uff08\u84dd\u8272\uff09<\/p>\n

\u56fe<\/strong>4<\/strong>\uff1a<\/strong>Li2<\/sub>O2<\/sub><\/strong>\u5145\u653e\u7535\u5faa\u73af\u4e2d\u7684\u751f\u957f<\/strong>\/<\/strong>\u5206\u89e3<\/strong><\/p>\n

\"4\"<\/p>\n

(a-c) RuO2<\/sub>\/CNT\u9634\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200 mA\/g\uff0c\u622a\u6b62\u5bb9\u91cf\u5206\u522b\u4e3a500\u30011000\u30012000 mAh\/g\u6761\u4ef6\u4e0b\u518d\u5145\u7535\u540e\u7684FESEM\u56fe\u3002\u82b1\u72b6Li2<\/sub>O2<\/sub>\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u9010\u6e10\u5206\u89e3\u3002<\/p>\n

(d-e) \u5bf9\u6bd4\u539f\u59cb\u7684RuO2<\/sub>\/CNT\u9634\u6781\u548c\u9650\u5b9a\u5bb9\u91cf\u4e3a2000 mAh\/g\u4e0b\u5145\u7535\u548c\u653e\u7535\u540e\u7684\u9634\u6781\u7684XRD\u56fe\u548c\u7ea2\u5916\u5149\u8c31\u3002\u540c\u65f6\u4e5f\u5bf9\u6bd4Li2<\/sub>O2<\/sub>\u7684\u6807\u51c6\u56fe\u8c31\u3002<\/p>\n

(f) Li-O2<\/sub>\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200 mA\/g\uff0c\u622a\u6b62\u5bb9\u91cf\u4e3a2000 mAh\/g\u6761\u4ef6\u4e0b\u7684\u518d\u5145\u7535\u66f2\u7ebf\u3002<\/p>\n

(g) Li2<\/sub>O2<\/sub>\u6c27\u5316\u673a\u7406\u793a\u610f\u56fe\u5c55\u793a\u4e86LiO2<\/sub>\u5438\u9644\u81f3\u9634\u6781\u8868\u9762\u7684\u4e24\u7535\u5b50\u8f6c\u79fb\u9014\u5f84\u548cLiO2<\/sub>(sol)\u6eb6\u4e8e\u7535\u89e3\u6db2\u7684\u5355\u7535\u5b50\u8f6c\u79fb\u9014\u5f84\u3002<\/p>\n

(h) Li-O2<\/sub>\u7535\u6c60\u4e2d\u653e\u7535\u540e\u7684CNT\u9634\u6781\u548cRuO2<\/sub>\/CNT\u9634\u6781\u57280.1 mV\/s\u4e0b\u7684CV\u56fe\u3002<\/p>\n

\u56fe<\/strong>5. <\/strong>\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4ea7\u7269\u7684\u5f62\u8c8c\u548c\u7ed3\u6676\u5ea6<\/strong><\/p>\n

\"5\"<\/p>\n

(a) Li-O2<\/sub>\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200\u548c500 mA\/g\uff0c\u9650\u5236\u5bb9\u91cf\u4e3a1000 mAh\/g\u6761\u4ef6\u4e0b\u7684\u653e\u7535\u7ec8\u6b62\u7535\u538b\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n

(b-d) CNT\u9634\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200 mA\/g\uff0c\u622a\u6b62\u5bb9\u91cf\u4e3a2000 mAh\/g\u6761\u4ef6\u4e0b\u7b2c1\u30015\u300120\u6b21\u7684FESEM\u56fe\u3002<\/p>\n

(e-g) RuO2<\/sub>\/CNT\u9634\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a200 mA\/g\uff0c\u622a\u6b62\u5bb9\u91cf\u4e3a2000 mAh\/g\u6761\u4ef6\u4e0b\u7b2c1\u30015\u300120\u6b21\u7684FESEM\u56fe\u3002\u63d2\u56fe\u662f\u5bf9\u5e94\u7684\u653e\u5927FESEM\u56fe\u3002<\/p>\n

(h-i) RuO2<\/sub>\/CNT\u9634\u6781\u548c\u7eafCNT\u9634\u6781\u4e0a\u5728\u6807\u660e\u7684\u5faa\u73af\u6b21\u6570\u653e\u7535\u540e\u7684\u653e\u7535\u4ea7\u7269\u7684PXRD\u56fe\u3002\u540c\u65f6\u4e5f\u7ed9\u51faLi2<\/sub>O2<\/sub>\u7684\u6807\u51c6\u56fe\u8c31\u3002<\/p>\n

\u56fe<\/strong>6.Li-O2<\/sub><\/strong>\u7535\u6c60\u5145\u653e\u7535\u5faa\u73af\u8fc7\u7a0b\u7684\u526f\u53cd\u5e94\u4ea7\u7269<\/strong><\/p>\n

\"6\"<\/p>\n

(a-b) \u7b2c1\u6b21\u548c\u7b2c20\u6b21\u653e\u7535\u540e\u7eafCNT\u548cRuO2<\/sub>\/CNT\u9634\u6781\u7684FTIR\u5149\u8c31\u3002\u540c\u65f6\u5c55\u793aLi2<\/sub>O2<\/sub>\u3001Li2<\/sub>CO3<\/sub>\u3001HCO2<\/sub>Li\u548cCH3<\/sub>CO2<\/sub>Li\u7684\u56fe\u8c31\u4ee5\u5bf9\u6bd4\u3002\u53ef\u4ee5\u770b\u51fa\uff0c\u7eafCNT\u9634\u6781\u591a\u6b21\u5faa\u73af\u540e\u6709\u660e\u663e\u7684\u526f\u53cd\u5e94\u53d1\u751f\u3002<\/p>\n

(c-d) \u7b2c1\u6b21\u548c\u7b2c20\u6b21\u653e\u7535\u540e\u7eafCNT\u548cRuO2<\/sub>\/CNT\u9634\u6781\u76841<\/sup>H NMR\u5149\u8c31\u3002\u540c\u65f6\u5c55\u793aTEGDME\uff08\u56db\u7518\u9187\u4e8c\u7532\u919a\uff09\u3001HCO2<\/sub>Li\u548cCH3<\/sub>CO2<\/sub>Li\u7684\u56fe\u8c31\u4ee5\u5bf9\u6bd4\u3002\u540c\u6837\u8bc1\u660e\u591a\u6b21\u5faa\u73af\u540eRuO2<\/sub>\/CNT\u9634\u6781\u4e0a\u7684\u7535\u89e3\u6db2\u5206\u89e3\u4ea7\u7269\u66f4\u5c11\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u5f20\u745c\u6559\u6388\u91c7\u7528\u9ad8\u7a33\u5b9a\u7684RuO2<\/sub>\/CNT\u9634\u6781\u5f97\u5230\u9ad8\u6027\u80fd\u7684Li-O2<\/sub>\u7535\u6c60\uff0c\u5e76\u63d0\u51fa\u4e00\u79cd\u65b0\u7684\u5faa\u73af\u8fc7\u7a0b\u4e2dLi2<\/sub>O2<\/sub>\u7684\u751f\u957f\u3001\u5206\u89e3\u3001\u6f14\u53d8\u673a\u7406\u3002\u8fd9\u9879\u5de5\u4f5c\u5c06\u6fc0\u52b1\u66f4\u591a\u7684\u4eba\u6295\u5165Li-O2<\/sub>\u7535\u6c60\u7684\u7535\u5316\u5b66\u673a\u7406\u7814\u7a76\u3002<\/p>\n

\u5f20\u745c\u6559\u6388\u7b80\u4ecb\uff1a<\/strong><\/p>\n

\u5f20\u745c\uff0c1978\u5e74\u751f\uff0c\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u5316\u5b66\u4e0e\u73af\u5883\u5b66\u9662\u7814\u7a76\u5458\u3002<\/strong>\u4e3b\u8981\u4ece\u4e8b\u65e0\u673a\u65b0\u80fd\u6e90\u6750\u6599\u7684\u5236\u5907\u548c\u7279\u6027\u7814\u7a76\u3002\u8fd1\u5e74\u6765\uff0c\u6709\u5173\u7814\u7a76\u6210\u679c\u5171\u5728\u56fd\u5185\u5916\u91cd\u8981\u671f\u520a\uff08\u5982\uff1a Nature Energy, Energy Environ. Sci., Adv. Energy Mater., Adv. Funct. Mater., Nano Energy, Chem. Soc. Rev.\uff09\u7b49\u4e0a\u53d1\u886830\u4f59\u7bc7SCI\u6536\u5f55\u8bba\u6587\u30022012\u5e743\u6708\u56de\u56fd\uff0c\u5e76\u4e8e2012\u5e7412\u6708\u987a\u5229\u901a\u8fc7\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u5353\u8d8a\u767e\u4eba\u526f\u6559\u6388\u8bc4\u9009\uff0c2013\u5e742\u6708\u6b63\u5f0f\u5c31\u804c\u4e8e\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u5316\u5b66\u4e0e\u73af\u5883\u5b66\u9662\uff0c2015\u5e74\u83b7\u6279\u7814\u7a76\u5458\u53ca\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u76ee\u524d\u627f\u62c5\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9752\u5e74\u9879\u76ee\u4e00\u9879\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\u4e00\u9879\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u4e00\u9879\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Cathode Surface-Induced, Solvation-Mediated, Micrometer-Sized Li2<\/sub>O2<\/sub> Cycling for Li\u2013O2<\/sub> Batteries\u00a0<\/a>\u00a0\uff08 Adv. Mater., 2016, DOI: 10.1002\/adma.201603454\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 \u849c\u5934 \u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d,\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"\u65b0\u80fd\u6e90\u524d\u7ebf\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u53ef\u5145\u7535\u7684\u8d28\u5b50\u60f0\u6027Li-O2\u7535\u6c60\u5177\u6709\u5f88\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8fdc\u80dc\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u6709\u5e0c\u671b\u6210\u4e3a\u6c7d\u6cb9\u7684\u66ff\u4ee3\u54c1\uff0c\u56e0\u6b64\u8fd1\u6765\u5907\u53d7\u5173\u6ce8\u3002Li-O2\u7535\u6c60\u53cd\u5e94\u867d\u7136\u7b80\u5355\uff0c\u4f46\u662f\u5145\u653e\u7535\u5faa…<\/p>\n","protected":false},"author":1206,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[18,129],"class_list":["post-42638","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-xinnengyuan","tag-battery"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/42638"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1206"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=42638"}],"version-history":[{"count":10,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/42638\/revisions"}],"predecessor-version":[{"id":42927,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/42638\/revisions\/42927"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=42638"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=42638"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=42638"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}