{"id":42472,"date":"2016-09-25T06:30:20","date_gmt":"2016-09-24T22:30:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=42472"},"modified":"2017-03-18T21:37:12","modified_gmt":"2017-03-18T13:37:12","slug":"adv-energy-mater-%e7%bb%bc%e8%bf%b0-%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e5%9b%a2%e6%88%98%ef%bc%8c%e5%af%8c%e5%8b%92%e7%83%af%e5%9d%9a%e6%8c%ba%e8%be%85%e5%8a%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=42472","title":{"rendered":"Adv. Energy Mater. \u674e\u6c38\u822b\u7efc\u8ff0\uff1a\u592a\u9633\u80fd\u7535\u6c60\u56e2\u6218\uff0c\u5bcc\u52d2\u70ef\u575a\u633a\u8f85\u52a9"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011
\n<\/strong><\/p>\n

\u80fd\u6e90\u5371\u673a\u52a0\u91cd\uff0c\u65b0\u80fd\u6e90\u5bb6\u65cf\u80a9\u8d1f\u4f7f\u547d\u4efb\u91cd\u9053\u8fdc\uff0c\u5176\u4e2d\u7684\u592a\u9633\u80fd\u7535\u6c60\u56e2\u961f\u6218\u62a5\u6377\u6377\uff0c\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60(OSCs)\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60(pero-SCs)\u88ab\u79d1\u5b66\u754c\u8ba4\u4e3a\u662f\u6700\u5177\u524d\u666f\u7684\u5149\u4f0f\u5668\u4ef6\uff0c\u5728\u6700\u8fd1\u7684\u62a5\u9053\u4e2d\u4ed6\u4eec\u7684\u6548\u7387\u5206\u522b\u7a81\u7834\u4e8610%\u548c20% \u3002\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u5728\u4e24\u79cd\u5668\u4ef6\u4e2d\u7684\u575a\u633a\u8f85\u52a9\u529f\u4e0d\u53ef\u6ca1\uff0c\u5b83\u5206\u522b\u4f5c\u4e3aOSCs\u4e2d\u7684\u53d7\u4f53\u6750\u6599\u548cpero-SCs\u9634\u6781\u7f13\u51b2\u5c42(CBL)\u3002\u6765\u81ea\u82cf\u5dde\u5927\u5b66\u674e\u6c38\u822b\u9662\u58eb\u7684\u8bfe\u9898\u7ec4\u5bf9\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7684\u6700\u65b0\u8fdb\u5c55\u548c\u5e94\u7528\u524d\u666f\u505a\u51fa\u6c47\u603b\u3002<\/p>\n

\u9996\u5148\u7b80\u5355\u4e86\u89e3\u4e00\u4e0b\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u3002<\/p>\n

\u6709\u673a\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u6709\u673a\u5149\u654f\u5e26\u7531P\u578b\u6709\u673a\u534a\u5bfc\u4f53\u6784\u6210\u7684\u7ed9\u4f53\uff0cN\u578b\u534a\u5bfc\u4f53\u6784\u6210\u7684\u53d7\u4f53\u7ec4\u6210\u3002\u5149\u7167\u65f6\uff0c\u6709\u673a\u534a\u5bfc\u4f53\u5438\u6536\u5177\u6709\u4e00\u5b9a\u80fd\u91cf\u7684\u5149\u5b50\uff0c\u7535\u5b50\u53d1\u751f\u8dc3\u8fc1\u5f62\u6210\u675f\u7f1a\u6001\u7684\u7535\u5b50-\u7a7a\u7a74\u5bf9\uff0c\u5373\u6fc0\u5b50\u3002\u6fc0\u5b50\u6269\u6563\u81f3\u7ed9\u53d7\u4f53\u754c\u9762\uff0c\u5728\u754c\u9762\u52bf\u5792\u4f5c\u7528\u4e0b\u53d1\u751f\u5206\u79bb\uff0c\u5f62\u6210\u81ea\u7531\u79fb\u52a8\u7684\u7535\u5b50\u7a7a\u7a74\uff0c\u4f20\u8f93\u81f3\u9634\u6781\u548c\u9633\u6781\u88ab\u6536\u96c6\uff0c\u5728\u5916\u7535\u8def\u63a5\u901a\u4e0b\u4ea7\u751f\u5149\u7535\u6d41\u3002\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e0e\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7c7b\u4f3c\uff0c\u5177\u6709\u4e09\u660e\u6cbb\u7ed3\u6784\uff0c\u4e3b\u8981\u7684\u4e0d\u540c\u5728\u4e8e\u5149\u654f\u5c42\uff0c\u5b83\u662f\u6709\u673a\u65e0\u673a\u6742\u5316\u6784\u6210\u7684\u9499\u949b\u77ff\u7ed3\u6784\u3002<\/p>\n

\u5728\u8fc7\u53bb\u51e0\u5e74\u4e2d\uff0c\u5728\u63d0\u9ad8\u4e24\u79cd\u7535\u6c60\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u4e0a\u53d6\u5f97\u7684\u5de8\u5927\u8fdb\u5c55\uff0c\u4e3b\u8981\u662f\u901a\u8fc7\u4f18\u5316\u5149\u654f\u5316\u5c42\u548c\u7535\u6781\u7f13\u51b2\u5c42\u7684\u6750\u6599\u53d6\u5f97\u7684\u3002\u5c31\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u6765\u8bf4\uff0c\u8bbe\u8ba1\u548c\u5408\u6210\u4e00\u79cd\u65b0\u7684\u5171\u8f6d\u5c42\u7ed9\u4f53\u6750\u6599\uff0c\u4f7f\u5176\u5177\u6709\u5bbd\u7684\u5438\u6536\u8c31\uff0c\u4f4e\u5e26\u9699\uff0c\u4f4e\u7684\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\uff08LUMO\uff09\u548c\u9ad8\u7684\u7a7a\u7a74\u8fc1\u79fb\u7387\uff0c\u5c06\u4f1a\u8fdb\u4e00\u6b65\u63d0\u9ad8\u6548\u7387\u3002<\/p>\n

1.\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u53d7\u4f53<\/strong><\/p>\n

C60\u5177\u6709\u5f88\u9ad8\u7684\u7535\u5bfc\u6027\uff0c\u7531\u4e8e\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u6eb6\u89e3\u5ea6\u7684\u4f4e\uff0c\u963b\u788d\u4e86\u5b83\u5728\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002\u7406\u60f3\u7684\u53d7\u4f53\u6750\u6599\u5e94\u5728\u6709\u673a\u7269\u4e2d\u5177\u6709\u8f83\u597d\u6eb6\u89e3\u6027\uff0c\u800c\u4e14\u6709\u5408\u9002\u7684\u80fd\u7ea7\uff0c\u4e0e\u7ed9\u4f53\u6750\u6599\u76f8\u914d\u5408\u3002\u6240\u4ee5\u666e\u904d\u7684\u505a\u6cd5\u662f\u5728\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4e0a\u60ac\u6302\u5b98\u80fd\u56e2\u63d0\u9ad8\u6eb6\u89e3\u5ea6\u548cLUMO,\u4ee5\u8fbe\u5230\u5f00\u8def\u7535\u538b\u6700\u5927\u5316\u7684\u76ee\u7684\u3002\u8fd9\u91cc\u4e2d\u6211\u4eec\u5c06\u63d0\u5230\u4e00\u4e9b\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u53d7\u4f53\uff0c\u4ee5\u53ca\u4ed6\u4eec\u7684\u7406\u5316\u3001\u5149\u7535\u6027\u8d28\u3002<\/p>\n

1.1\u00a0PCMB\u548cPCMB-like\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269<\/strong><\/p>\n

\u5728C60\u7684\u57fa\u7840\u4e0a\u4eba\u4eec\u9996\u5148\u5b9a\u5411\u6539\u9020\u51faPCMB\uff0c\u8fd9\u79cd\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u88ab\u8ba4\u4e3a\u5728\u6709\u673a\u7269\u4e2d\u5177\u6709\u66f4\u597d\u7684\u6eb6\u89e3\u6027\u548c\u70ed\u7a33\u5b9a\u6027\uff0cLUMO\u548cHOMO\u7684\u5dee\u503c\uff08\u5dee\u503c\u8d8a\u5c0f\u5219\u66f4\u5bb9\u6613\u53d1\u751f\u7535\u5b50\u8dc3\u8fc1\u4ece\u800c\u4ea7\u751f\u66f4\u591a\u6fc0\u5b50\uff09\u4e3a2.02eV. \u800cPC70BM\u7684\u5149\u8c31\u5438\u6536\u8303\u56f4\u66f4\u5e7f\uff0cLUMO\u4e0eHOMO\u5dee\u503c\u4e3a1.96eV. \u5728\u63d0\u5347LUMO\u4e0a\u5b66\u8005\u4eec\u505a\u4e86\u5927\u91cf\u5de5\u4f5c\uff0c\u4e0d\u540c\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4f5c\u4e3a\u53d7\u4f53\u4e0e\u76f8\u5e94\u7ed9\u4f53\u76f8\u914d\u5408\u6240\u5236\u6210\u5668\u4ef6\u7684\u5404\u9879\u6570\u636e\u6d4b\u8bd5\u7ed3\u679c\u5982\u88681.\u6240\u793a\uff1a<\/p>\n

\u88681.PCBM\u548cPCBM-like\u53d7\u4f53\u7684\u5149\u7535\u6027\u80fd<\/strong>
\n\"\u88681\"<\/p>\n

\u8868\u4e2d\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u53d7\u4f53\u7684\u5206\u5b50\u7ed3\u6784\u5982\u4e0b\u56fe\u6240\u793a\uff1a<\/p>\n

\"1\"<\/p>\n

\u56fe1. \u51e0\u79cd\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7684\u5206\u5b50\u7ed3\u6784\u56fe<\/strong><\/p>\n

a)C60\u6539\u9020\u540e\u7684 PCBM\u548cPC70BM\u6539\u8fdb\uff0c\u5177\u6709\u66f4\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548cLUMO.<\/p>\n

b) bisPCBM\u548ctrisPCBM\u90fd\u662fPCBM\u7684\u539f\u4ea7\u7269\uff0c\u7ecf\u8fc7\u52a0\u5de5\u4fee\u9970\u540e\u5f62\u6210\u5177\u6709\u7279\u5b9a\u6027\u8d28\u7684\u4ea7\u7269\uff0c\u5982bisPC70BM<\/p>\n

c) F1-F5\u5177\u6709\u66f4\u957f\u7684\u7532\u57fa\u94fe\uff0c\u5bf9\u7d2b\u5916\u5149\u7684\u5438\u6536\u9020\u6210\u5f71\u54cd<\/p>\n

d) \u4e2d\u95f4\u70f7\u57fa\u94fe\u4fee\u9970C60\u53ef\u4ee5\u4f7f\u5f97\u5149\u8c31\u5438\u6536\u6548\u679c\u964d\u4f4e\uff0c\u4f46\u662f\u5f53P3HT\u4f5c\u4e3a\u7ed9\u4f53\u65f6\uff0c\u7535\u5b50\u8fc1\u79fb\u901f\u7387\u5c06\u5927\u5927\u63d0\u9ad8<\/p>\n

e) F15-F17\u662f\u53d6\u4ee3\u82ef\u57fa\u56e2\u7684\u884d\u751f\u7269\uff0c\u5f53P3HT\u4f5c\u4e3a\u7ed9\u4f53\u65f6\u8868\u73b0\u51fa\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027<\/p>\n

1.2 ICBA\u548cICBA-like\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269<\/strong><\/p>\n

\u4ee5\u7535\u5b50\u5bcc\u96c6\u7684\u831a\u4f5c\u4e3a\u53d6\u4ee3\u57fa\uff0c\u6784\u6210\u5bcc\u52d2\u70ef\u884d\u751f\u7269ICBA\uff0c\u4f7f\u5f97LUMO \u80fd\u7ea7\u76f8\u6bd4PCBM\u63d0\u9ad8\u4e860.17eV\uff0c\u592a\u9633\u80fd\u7535\u6c60\u7684\u5f00\u8def\u7535\u538b\u968f\u4e4b\u5f97\u5230\u63d0\u9ad8\uff0c\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0cP3HT:ICBA\u7684\u7ed9\u53d7\u4f53\u7ec4\u5408\u8981\u6bd4P3HT:PCBM\u5728\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u4e0a\u9ad8\u51fa5.44%\uff0c\u5f00\u8def\u7535\u538b\u9ad8\u51fa0.26V.\u5171\u53d7\u4f53\u7ec4\u5408\u548c\u6548\u7387\u89c1\u88682\uff1a<\/p>\n

\u88682.PCBM\u548cPCBM-like\u53d7\u4f53\u7684\u5149\u7535\u6027\u80fd<\/strong><\/p>\n

\"\u88682\"<\/p>\n

\u8868\u4e2d\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u53d7\u4f53\u7684\u5206\u5b50\u7ed3\u6784\u5982\u4e0b\u56fe\u6240\u793a\uff1a<\/p>\n

\"2\"<\/p>\n

\u56fe2. ICBA (bisPCBM\u7684\u4e00\u79cd\u884d\u751f\u7269)\u548cICBA-like\u7684\u5206\u5b50\u7ed3\u6784\u5f0f<\/strong><\/p>\n

a) \u65b0\u578b\u5bcc\u52d2\u70ef\u884d\u751f\u7269ICBA\uff0c\u53ef\u4ee5\u63d0\u9ad8\u6700\u4f4e\u4e3a\u5360\u636e\u5206\u5b50\u8f68\u9053\uff0c\u4ece\u800c\u63d0\u9ad8\u5668\u4ef6\u8f6c\u5316\u6548\u7387<\/p>\n

b) F19:\u57fa\u4e8eC60\u7684\u5bf9\u4e8c\u6c22\u8418\u7684\u53cc\u52a0\u6210\u5bcc\u52d2\u70ef\u884d\u751f\u7269\uff1bF20:C70\u5bf9\u4e8c\u6c22\u8418\u7684\u53cc\u52a0\u6210\u5bcc\u52d2\u70ef\u884d\u751f\u7269\uff0c\u5747\u5177\u6709\u63d0\u9ad8\u6700\u4f4e\u4e3a\u5360\u636e\u5206\u5b50\u8f68\u9053\u4ee5\u63d0\u9ad8\u5149\u7535\u8f6c\u5316\u6548\u7387<\/p>\n

c) F21-F24:\u57fa\u4e8eC60 \u7684\u5bf9\u4e8c\u82ef\u57fa\u7532\u70f7\u7684\u53cc\u52a0\u6210\u5bcc\u52d2\u70ef\u884d\u751f\u7269\uff0c\u540c\u6837\u63d0\u9ad8LUMO\u4ee5\u63d0\u5347\u80fd\u91cf\u8f6c\u5316\u6548\u7387<\/p>\n

d) F31:\u56e0\u4f53\u79ef\u5e9e\u5927\u9650\u5236\u4e86\u7535\u5b50\u7684\u6d41\u52a8\uff1bF32\uff1a\u7528\u8f83\u5c0f\u7684\u7532\u57fa\u53d6\u4ee3\u831a\u4ee5\u63d0\u9ad8\u7535\u5b50\u6d41\u52a8\u6027<\/p>\n

e) F33-F35:\u66f4\u597d\u7684\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242<\/p>\n

1.3\u5176\u4ed6\u5bcc\u52d2\u70ef\u884d\u751f\u7269<\/strong><\/p>\n

\u9664\u4e86\u4e0a\u8ff0\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u5916\uff0c\u8fd8\u6709\u4f5c\u4e3a\u6709\u673a\u592a\u9633\u80fd\u53d7\u4f53\u7684\u884d\u751f\u7269\u5c55\u793a\u5728\u88683\u4e2d\uff0c\u5bf9\u5e94\u7684\u5206\u5b50\u7ed3\u6784\u5f0f\u89c1\u56fe3.<\/p>\n

\u88683.\u5176\u4ed6\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7684\u5149\u7535\u6027\u80fd<\/strong><\/p>\n

\"\u88683\"<\/p>\n

\u8868\u4e2d\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u53d7\u4f53\u7684\u5206\u5b50\u7ed3\u6784\u5982\u4e0b\u56fe\u6240\u793a\uff1a<\/p>\n

\"3_\u770b\u56fe\u738b\"<\/p>\n

\u56fe3.\u5176\u4ed6\u4f5c\u4e3a\u53d7\u4f53\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7684\u5316\u5b66\u7ed3\u6784\u5f0f<\/strong><\/p>\n

2.\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4f5c\u4e3a\u9634\u6781\u7f13\u51b2\u5c42\uff08CBL\uff09<\/strong><\/p>\n

\u9634\u6781\u7f13\u51b2\u5c42\u9700\u6ee1\u8db3\u5982\u4e0b\u51e0\u4e2a\u6761\u4ef6\uff0c\u624d\u80fd\u8fbe\u5230\u63d0\u9ad8\u6709\u673a\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u7684\u76ee\u6807\uff1a<\/p>\n

    \n
  1. \u5bfc\u7535\u6027\u80fd\u597d\u4e14\u8868\u9762\u80fd\u4f4e<\/li>\n
  2. \u5728\u9634\u6781\u548c\u6d3b\u6027\u5c42\u4e4b\u95f4\u6709\u8f83\u4f4e\u7684\u80fd\u91cf\u5c4f\u969c<\/li>\n
  3. \u9ad8\u7684\u7535\u5b50\u9009\u62e9\u6027<\/li>\n
  4. \u53ef\u4ee5\u4e0e\u6d3b\u6027\u5c42\u826f\u597d\u56fa\u5b9a\uff0c\u5e76\u80fd\u963b\u6b62\u6d3b\u6027\u5c42\u548c\u9634\u6781\u7535\u6781\u95f4\u7684\u5316\u5b66\u53cd\u5e94<\/li>\n
  5. \u517c\u5bb9\u6027\u826f\u597d<\/li>\n<\/ol>\n

    \u4ee5\u524d\u5927\u91cf\u7684\u5de5\u4f5c\u6295\u5165\u5728\u7814\u7a76\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3aCBL\u6750\u6599\u4e0a\uff0c\u7531\u4e8e\u6709\u673a\u7269\u5177\u6709\u6eb6\u6db2\u517c\u5bb9\u6027\u597d\u548c\u539f\u6750\u6599\u4e30\u5bcc\u7684\u7279\u70b9\u5438\u5f15\u4e86\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5c24\u5176\u662f\u5929\u7136n\u578b\u534a\u5bfc\u4f53\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u5177\u6709\u80fd\u91cf\u5c4f\u969c\u4f4e\u3001\u6536\u96c6\u7535\u5b50\u80fd\u529b\u5f3a\u7684\u7279\u70b9\uff0c\u548c\u5176\u4ed6\u529f\u80fd\u5982\u81ea\u7ec4\u88c5\u529f\u80fd\uff0c\u4e00\u8d77\u5e94\u7528\u5728CBL\u4e2d\uff0c\u53d6\u5f97\u4e86\u826f\u597d\u7684\u6548\u679c\u3002<\/p>\n

    3.1\u6b63\u4ea4\u6eb6\u5242\u5904\u7406\u7684\u9634\u6781\u7f13\u51b2\u5c42<\/strong><\/p>\n

    \u5f02\u8d28\u7ed3\uff08BHJ\uff09\u5c42\u901a\u8fc7\u6b63\u4ea4\u6eb6\u5242\u5236\u5907\u9187\u6eb6\u6027\u7684\u5bcc\u52d2\u70ef\u8868\u9762\u6d3b\u6027\u6750\u6599\uff0c\u53ef\u4ee5\u4f5c\u4e3aOSCs\u7684CBL.\u5b83\u53ef\u4ee5\u53d6\u4ee3\u5bb9\u6613\u4e0e\u6c34\u548c\u7a7a\u6c14\u53d1\u751f\u53cd\u5e94\u7684Ga\uff0c\u8fd8\u53ef\u4ee5\u7701\u53bb\u771f\u7a7a\u70ed\u84b8\u53d1\u7684\u6b65\u9aa4\u3002\u4e00\u65b9\u9762\u5bcc\u52d2\u70ef\u8868\u9762\u6d3b\u6027\u6750\u6599\u53ef\u4ee5\u901a\u8fc7\u9152\u7cbe\u6eb6\u6db2\u5236\u5f97\uff0c\u6240\u4ee5\u5728\u5236\u5907CBL\u7684\u6709\u673a\u6eb6\u6db2\u6b65\u9aa4\u4e2d\u4e0d\u4f1a\u53d1\u751f\u6027\u80fd\u4e0a\u7684\u9000\u5316\uff0c\u53e6\u4e00\u65b9\u9762\u5bcc\u52d2\u70ef\u8868\u9762\u7684\u4eb2\u6c34\u57fa\u56e2\u6709\u52a9\u4e8e\u706b\u661f\u5c42\u548c\u91d1\u5c5e\u9634\u6781\u80fd\u7ea7\u4e0a\u7684\u5bf9\u9f50\u3002<\/p>\n

    \u88684.\u6b63\u4ea4\u6eb6\u5242\u5904\u7406CBL\u7684\u5668\u4ef6\u5149\u7535\u6548\u7387<\/strong><\/p>\n

    <\/p>\n

    a)CBL\u7684\u80fd\u7ea7<\/p>\n

    b)\u4fee\u9970\u540e\u9634\u6781\u7684\u529f\u51fd\u6570<\/p>\n

    \"4\"<\/p>\n

    \u56fe4.\u6b63\u4ea4\u6eb6\u5242\u5904\u7406\u540e\u7684\u77f3\u58a8\u70ef\u884d\u751f\u7269\u7684\u7ed3\u6784\u5f0f<\/strong><\/p>\n

    \u8be5\u7c7b\u578b\u77f3\u58a8\u70ef\u884d\u751f\u7269\u4f5c\u4e3a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u9634\u6781\u7f13\u51b2\u5c42\u53ef\u4ee5\u63d0\u9ad8\u5f00\u8def\u7535\u538b\u3001\u77ed\u8def\u7535\u6d41\u548c\u586b\u5145\u56e0\u5b50\uff0c\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u63d0\u5347\u52307.92% .<\/p>\n

    2.2\u6c2e\u63ba\u6742\u7684\u9634\u6781\u7f13\u51b2\u5c42<\/strong><\/p>\n

    \u4e3a\u4e86\u83b7\u5f97\u66f4\u597d\u6027\u80fd\uff0c\u6709\u673aCBL\u539a\u5ea6\u4fdd\u6301\u57285-10nm\uff0c\u4f46\u5374\u4e0d\u80fd\u63d0\u4f9b\u6709\u6548\u7684\u6b27\u59c6\u63a5\u89e6\uff0c\u4e0d\u5229\u4e8e\u7535\u5b50\u7684\u53d6\u51fa\u548c\u8fd0\u8f93\uff0c\u4e0d\u5229\u4e8e\u5927\u9762\u79ef\u7684\u5236\u5907\u3002\u4f46\u63ba\u6742\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u5177\u6709\u9ad8\u7535\u5bfc\u6027\uff0c\u6d3b\u6027\u5c42\u548c\u9634\u6781\u95f4\u7684\u6b27\u59c6\u63a5\u89e6\u6548\u679c\u4e5f\u5f88\u597d\u3002<\/p>\n

    \"5\"<\/p>\n

    \u56fe5.\u6c2e\u63ba\u6742\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269<\/strong><\/p>\n

    \u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u884d\u751f\u7269\u4f5c\u4e3a\u9634\u6781\u7f13\u51b2\u5c42\uff0c\u4f1a\u5728\u6d3b\u6027\u5c42\u548c\u9634\u6781\u4e4b\u95f4\u5f62\u6210\u7c7b\u4f3c\u6b27\u59c6\u63a5\u89e6\uff0c\u53ef\u4ee5\u63d0\u9ad8\u7535\u5bfc\u6027<\/p>\n

    \u88685.\u6c2e\u63ba\u6742CBL\u5236\u6210\u5668\u4ef6\u7684\u5149\u7535\u6027\u80fd<\/strong><\/p>\n

    <\/p>\n

    a)CBL\u7684\u80fd\u7ea7<\/p>\n

    b)\u4fee\u9970\u540e\u9634\u6781\u7684\u529f\u51fd\u6570<\/p>\n

    3.3\u81ea\u7ec4\u88c5\u7684\u9634\u6781\u7f13\u51b2\u5c42<\/strong><\/p>\n

    \u5236\u9020\u9634\u6781\u7f13\u51b2\u5c42\u7684\u6b65\u9aa4\u4e2d\u6709\u5e72\u71e5\u7684\u771f\u7a7a\u84b8\u53d1\u548c\u6e7f\u6da6\u7684\u65cb\u6d82\uff0c\u4f7f\u5236\u9020\u592a\u9633\u80fd\u7535\u6c60\u7684\u6b65\u9aa4\u53d8\u5f97\u590d\u6742\uff0c\u81ea\u7ec4\u88c5\u7684\u65b9\u6cd5\u5e94\u8fd0\u800c\u751f\u3002<\/p>\n

    \u88686.\u81ea\u7ec4\u88c5CBL\u5728OSCs\u4e2d\u7684\u5149\u7535\u6027\u80fd<\/strong><\/p>\n

    <\/p>\n

    a)CBL\u7684\u80fd\u7ea7<\/p>\n

    b)\u4fee\u9970\u540e\u9634\u6781\u7684\u529f\u51fd\u6570<\/p>\n

    \"6_\u770b\u56fe\u738b\"<\/p>\n

    \u56fe6.\u81ea\u7ec4\u88c5\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u548c\u4ed6\u4eec\u5728\u5668\u4ef6\u4e2d\u7684\u56fe\u89e3<\/strong><\/p>\n

    2.4\u4fee\u9970\u540e\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3a\u9634\u6781\u7f13\u51b2\u5c42<\/strong><\/p>\n

    \u53d1\u5c55\u5177\u6709\u9ad8\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u548c\u7a33\u5b9a\u6027\u826f\u597d\u7684OSCs\u548cpero-SCs\u81f3\u4eca\u4ecd\u7136\u662f\u4e00\u95e8\u5177\u6709\u6311\u6218\u6027\u7684\u96be\u9898\u3002\u672a\u5c01\u88c5\u7684OSCs\u548cp-i-n\u578bpero-SCs\u5728\u7a7a\u6c14\u4e2d\u4f1a\u8fc5\u901f\u9000\u5316\uff0c\u53cd\u5411\u7684OSCs\u548cn-i-p\u578bpero-SCs\uff0c\u4f7f\u7528\u91d1\u6216\u94f6\u4f5c\u4e3a\u9634\u6781\u7f13\u51b2\u5c42\uff0c\u5728\u91d1\u5c5e\u6c27\u5316\u7269\u548cITO\u4e4b\u95f4\u63d2\u5165\u65e0\u673a\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3a\u7f13\u51b2\u5c42\uff08\u56fe7\uff09\u5c06\u4f1a\u63d0\u9ad8\u7a33\u5b9a\u6027\uff0c\u4f46\u662f\u8f6c\u5316\u6548\u7387\u53c8\u4f1a\u964d\u4f4e\u3002\u4f7f\u7528\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4fee\u9970\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u5c06\u4f1a\u53d6\u5f97\u4e0d\u9519\u7684\u6548\u679c\u3002<\/p>\n

    \u88687.\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4fee\u9970CBL\u5c42\u7684\u540e\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387<\/strong><\/p>\n

    <\/p>\n

    a)CBL\u7684\u80fd\u7ea7<\/p>\n

    b)\u4fee\u9970\u540e\u9634\u6781\u7684\u529f\u51fd\u6570<\/p>\n

    \"7_\u770b\u56fe\u738b\"<\/p>\n

    \u56fe7.\u542b\u6709\u9634\u6781\u7f13\u51b2\u5c42\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ed3\u6784<\/strong><\/p>\n

    a) PyC60\u5c42\u53d6\u4ee3ZnO\u4f5c\u4e3a\u9634\u6781\u7f13\u51b2\u5c42<\/p>\n

    b) \u4f4d\u4e8eZnO\u4e4b\u4e0a\u7684\u81ea\u7ec4\u88c5\u5355\u5c42\u77f3\u58a8\u70ef\u884d\u751f\u7269<\/p>\n

    c) \u4f4d\u4e8eTiO2\u4e4b\u4e0a\u7684\u81ea\u7ec4\u88c5\u5355\u5c42\u77f3\u58a8\u70ef\u884d\u751f\u7269<\/p>\n

    d) \u4e0e\u6d3b\u6027\u5c42\u6df7\u5408\u7684\u8d2f\u7a7f\u578b\u6df7\u5408\u5c42<\/p>\n

    \"8_\u770b\u56fe\u738b\"<\/p>\n

    \u56fe8.\u4f7f\u7528\u81ea\u7ec4\u88c5\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4fee\u9970\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u9634\u6781\u7f13\u51b2\u5c42\u7684\u5206\u5b50\u7ed3\u6784<\/strong><\/p>\n

    \u88ab\u81ea\u7ec4\u88c5\u7684\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4fee\u9970\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u5c42\uff0c\u5728\u4e8e\u6d3b\u6027\u5c42\u63a5\u89e6\u65f6\u5bfc\u7535\u6027\u4f1a\u589e\u52a0\uff0c\u968f\u4e4b\u7535\u6c60\u6548\u7387\u5f97\u5230\u63d0\u9ad8<\/p>\n

    \u3010\u603b\u7ed3\u3011
    \n<\/strong><\/p>\n

    \u5bcc\u52d2\u70ef\u884d\u751f\u7269\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6709\u673a\u4e2a\u6709\u673a\u65e0\u673a\u6742\u5316\u7684\u5149\u7535\u6280\u672f\u9886\u57df\uff0c\u672c\u6587\u603b\u7ed3\u4e86\u5728\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u53d7\u4f53\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u9634\u6781\u7f13\u51b2\u5c42\u65b9\u9762\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u8fd9\u4e24\u79cd\u7535\u6c60\u9762\u4e34\u7684\u6311\u6218\u4e3b\u8981\u6709\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u548c\u7a33\u5b9a\u6027\u7684\u63d0\u5347\u3002\u53d1\u5c55\u65b0\u578b\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u4f5c\u4e3a\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u53d7\u4f53\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u6700\u4f4e\u672a\u5360\u636e\u5206\u5b50\u8f68\u9053\uff0c\u901a\u8fc7\u7ed3\u6784\u4fee\u9970\uff0c\u662f\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u80fd\u591f\u6ee1\u8db3\u6fc0\u5b50\u6269\u6563\u957f\u5ea6\u7684\u9700\u6c42\uff0c\u8fd8\u6709\u5728\u7406\u5316\u6027\u8d28\u65b9\u9762\u8fdb\u4e00\u6b65\u7684\u7406\u89e3\uff0c\u662f\u63d0\u9ad8\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u7684\u5fc5\u7531\u4e4b\u8def\u3002<\/p>\n

    \u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong>\uff1a<\/p>\n

    \u674e\u6c38\u822b\uff1a<\/strong>\u9ad8\u5206\u5b50\u5316\u5b66\u5bb6\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u30021948\u5e748\u670810\u65e5\u51fa\u751f\u4e8e\u91cd\u5e86\u5e02\uff0c\u7c4d\u8d2f\u6cb3\u5357\u7762\u53bf\u30021982\u5e74\u5728\u534e\u4e1c\u7406\u5de5\u5927\u5b66\uff08\u539f\u534e\u4e1c\u5316\u5de5\u5b66\u9662\uff09\u5316\u5de5\u7cfb\u83b7\u7855\u58eb\u5b66\u4f4d\uff0c1986\u5e74\u5728\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\u83b7\u535a\u58eb\u5b66\u4f4d\u3002\u957f\u671f\u4ece\u4e8b\u5149\u7535\u529f\u80fd\u9ad8\u5206\u5b50\u9886\u57df\u7684\u7814\u7a76\u5de5\u4f5c\uff0c\u5728\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u5171\u8f6d\u805a\u5408\u7269\u7ed9\u4f53\u548c\u5bcc\u52d2\u70ef\u53d7\u4f53\u5149\u4f0f\u6750\u6599\u4ee5\u53ca\u7535\u6781\u754c\u9762\u4fee\u9970\u5c42\u6750\u6599\u3001\u5bfc\u7535\u805a\u5408\u7269\u7535\u5316\u5b66\u7b49\u65b9\u9762\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u6210\u679c\u3002\u63d0\u51fa\u4e86\u901a\u8fc7\u5171\u8f6d\u652f\u94fe\u6765\u62d3\u5c55\u805a\u5408\u7269\u5171\u8f6d\u7a0b\u5ea6\uff0c\u4ece\u800c\u62d3\u5bbd\u5176\u5438\u6536\u5149\u8c31\u7684\u5206\u5b50\u8bbe\u8ba1\u601d\u60f3\uff1b\u63d0\u51fa\u901a\u8fc7\u4f7f\u7528\u5bcc\u7535\u5b50\u7684\u831a\u53cc\u52a0\u6210\u6765\u63d0\u9ad8C60\u7684LUMO\u80fd\u7ea7\u7684\u601d\u60f3\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u831a\u53cc\u52a0\u6210\u5bcc\u52d2\u70ef\u884d\u751f\u7269\uff08ICBA\uff09\u65b0\u578b\u53d7\u4f53\u5149\u4f0f\u6750\u6599\uff0c\u4f7f\u7528ICBA\u53d7\u4f53\u521b\u9020\u4e86\u57fa\u4e8eP3HT\u5149\u4f0f\u5668\u4ef6\u6548\u7387\u7684\u65b0\u8bb0\u5f55\uff1b\u5728\u5421\u54af\u7535\u5316\u5b66\u805a\u5408\u53cd\u5e94\u673a\u7406\u548c\u805a\u5408\u53cd\u5e94\u52a8\u529b\u5b66\u3001\u5bfc\u7535\u805a\u5421\u54af\u7684\u4e24\u79cd\u6c27\u5316\u63ba\u6742\u7ed3\u6784\u548c\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u673a\u7406\u3001\u65e0\u673a\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u7684\u6eb6\u6db2\u6cd5\u5236\u5907\u53ca\u5176\u5728\u6709\u673a\/\u65e0\u673a\u6742\u5316\u5149\u7535\u5b50\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u7b49\u65b9\u9762\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u6210\u679c\u3002<\/p>\n

    \u674e\u8000\u6587\uff1a<\/strong>\u82cf\u5dde\u5927\u5b66\u6750\u6599\u4e0e\u5316\u5b66\u5316\u5de5\u5b66\u90e8\uff0c\u526f\u6559\u6388\u3001\u7855\u58eb\u751f\u5bfc\u5e08\u3002\u957f\u671f\u4ece\u4e8b\u6709\u673a\u3001\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6750\u6599\u5408\u6210\u53ca\u5668\u4ef6\u5236\u5907\u76f8\u5173\u7814\u7a76\uff0c\u7279\u522b\u662f\u529f\u80fd\u6027\u5bcc\u52d2\u70ef\u5408\u6210\u53ca\u67d4\u6027\u592a\u9633\u80fd\u7535\u6c60\u5236\u5907\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u6210\u679c\u3002\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\uff0c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9752\u5e74\u9879\u76ee\uff0c\u6c5f\u82cf\u7701\u9752\u5e74\u57fa\u91d1\uff0c\u6559\u80b2\u90e8\u535a\u58eb\u70b9\u65b0\u6559\u5e08\u57fa\u91d1\u7b49\u591a\u9879\u57fa\u91d1\u3002\u5e76\u4e0e\u591a\u5bb6\u4f01\u4e1a\u5f00\u5c55\u826f\u597d\u7684\u5408\u4f5c\u7814\u7a76\u3002<\/p>\n

    \u6587\u732e\u94fe\u63a5<\/strong>\uff1aFullerene Derivatives for the Applications as Acceptor and Cathode Buffer Layer Materials for Organic and Perovskite Solar Cells<\/a>(Adv. Energy Mater.\uff0c2016\uff0cDOI: 10.1002\/aenm.201601251)<\/p>\n

    \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4\u00a0YueZhou<\/strong> \u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d,\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"\u65b0\u80fd\u6e90\u524d\u7ebf\"<\/p>\n","protected":false},"excerpt":{"rendered":"

    \u3010\u5f15\u8a00\u3011 \u80fd\u6e90\u5371\u673a\u52a0\u91cd\uff0c\u65b0\u80fd\u6e90\u5bb6\u65cf\u80a9\u8d1f\u4f7f\u547d\u4efb\u91cd\u9053\u8fdc\uff0c\u5176\u4e2d\u7684\u592a\u9633\u80fd\u7535\u6c60\u56e2\u961f\u6218\u62a5\u6377\u6377\uff0c\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60(OSCs)\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60(pero-SCs)\u88ab\u79d1\u5b66\u754c\u8ba4\u4e3a\u662f…<\/p>\n","protected":false},"author":1203,"featured_media":43253,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[78,18,1404],"class_list":["post-42472","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-photovoltaic","tag-xinnengyuan","tag-liyongfang"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/42472"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1203"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=42472"}],"version-history":[{"count":22,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/42472\/revisions"}],"predecessor-version":[{"id":43250,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/42472\/revisions\/43250"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/43253"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=42472"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=42472"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=42472"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}