{"id":40152,"date":"2016-09-13T14:00:12","date_gmt":"2016-09-13T06:00:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=40152"},"modified":"2016-10-10T08:56:10","modified_gmt":"2016-10-10T00:56:10","slug":"angew-chem-int-ed-%e4%b8%ad%e7%a7%91%e5%a4%a7%e5%b0%86%e9%95%8d%e7%9a%84%e6%b0%a2%e6%b0%a7%e5%8c%96%e7%89%a9%e7%94%a8%e4%ba%8e%e7%87%83%e6%96%99%e7%94%b5%e6%b1%a0%e5%82%ac%e5%8c%96%e5%b0%bf","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=40152","title":{"rendered":"Angew. Chem. Int. Ed. \u4e2d\u79d1\u5927\u5c06\u954d\u7684\u6c22\u6c27\u5316\u7269\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u50ac\u5316\u5c3f\u7d20\u6c27\u5316"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u5728\u5168\u7403\u53d8\u6696\u548c\u5316\u77f3\u71c3\u6599\u65e5\u6e10\u67af\u7aed\u7684\u63a8\u52a8\u4e0b\uff0c\u53d1\u5c55\u4e00\u79cd\u53ef\u518d\u751f\u7684\u80fd\u6e90\u4ea7\u54c1\u548c\u50a8\u5b58\u6280\u672f\u53d8\u5f97\u8d8a\u6765\u8d8a\u91cd\u8981\u3002\u57fa\u4e8e\u8fd9\u4e9b\u4e8b\u5b9e\uff0c\u4e00\u4e9b\u7814\u7a76\u4eba\u5458\u7740\u529b\u4e8e\u5f00\u53d1\u76f4\u63a5\u5c3f\u7d20\u71c3\u6599\u7535\u6c60\uff0c\u8fd9\u79cd\u7535\u6c60\u4e0d\u4ec5\u610f\u5473\u7740\u662f\u4e00\u79cd\u6709\u6f5c\u529b\u7684\u53ef\u518d\u751f\u80fd\u6e90\uff0c\u800c\u4e14\u8fd8\u80fd\u5c06\u5bcc\u542b\u5c3f\u7d20\u7684\u6c61\u6c34\u52a0\u4ee5\u5229\u7528\uff0c\u7f13\u89e3\u6c34\u7684\u6c61\u67d3\u3002<\/p>\n \u76f8\u5bf9\u4e8e\u9634\u6781\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\u6765\u8bf4\uff0c\u9633\u6781\u7684\u5c3f\u7d20\u6c27\u5316\u53cd\u5e94\u901f\u7387\u6162\u7684\u591a\u3002\u56e0\u6b64\u9ad8\u6027\u80fd\u7684\u5c3f\u7d20\u6c27\u5316\u50ac\u5316\u5242\u5e94\u8be5\u6709\u66f4\u4f4e\u7684\u8fc7\u7535\u4f4d\u6765\u9a71\u52a8\u8fd9\u79cd\u7f13\u6162\u7684\u53cd\u5e94\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5434\u957f\u5f81\u6559\u6388<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u5c06NiCl2<\/sub>\u00b76H2<\/sub>O\u7c89\u672b\u901a\u8fc7\u56de\u6d41\u7684\u65b9\u6cd5\u5f97\u5230\u03b2-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\uff0c\u518d\u8fdb\u4e00\u6b65\u786b\u5316\u5904\u7406\u5f97\u5230\u9ad8\u6027\u80fd\u4e14\u6709\u91d1\u5c5e\u6027\u8d28\u7684Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u3002<\/p>\n \u7814\u53d1\u56e2\u961f\u57fa\u4e8e\u03b2-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u7684\u7406\u8bba\u7814\u7a76\uff0c\u901a\u8fc7\u8bbe\u8ba1\u7535\u5b50\u7ed3\u6784\u7814\u53d1\u51fa\u5177\u6709\u91d1\u5c5e\u6027\u8d28\u7684Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\uff0c\u7b2c\u4e00\u6b21\u63d0\u51fa\u8fc7\u6e21\u91d1\u5c5e\u7684\u6c22\u6c27\u5316\u7269\u6709\u91d1\u5c5e\u7ed3\u6784\u3002\u5176\u8868\u9762\u6210\u529f\u7ed3\u5408\u786b\u540e\uff0c\u8868\u73b0\u51fa\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u66f4\u597d\u7684\u6da6\u6e7f\u6027\u4ee5\u53ca\u9ad8\u6548\u7684\u7535\u5b50\u8f6c\u79fb\u6027\u80fd\u3002\u6b64\u95f4\u7684\u534f\u540c\u6548\u5e94\u4fc3\u4f7f\u5c3f\u7d20\u6c27\u5316\u53cd\u5e94\u6027\u80fd\u5f97\u5230\u5f88\u5927\u7a0b\u5ea6\u7684\u63d0\u9ad8\u3002\u4ece\u800c\u4f7f\u5f97\u6709\u91d1\u5c5e\u6027\u8d28\u7684\u7eb3\u7c73\u7247\u8868\u73b0\u51fa\u5f88\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u66f4\u4f4e\u7684\u8d77\u59cb\u7535\u4f4d\u4ee5\u53ca\u66f4\u5f3a\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n \u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n \u56fe<\/strong>1<\/strong>\uff0c\u786b\u4e0e<\/strong>Ni(OH)2<\/sub><\/strong>\u7ed3\u5408\u5f62\u6210\u7c7b\u91d1\u5c5e\u7684<\/strong>Ni(OH)2<\/sub><\/strong>\u7eb3\u7c73\u7247\u793a\u610f\u56fe<\/strong><\/p>\n (a),\u7c7b\u91d1\u5c5e\u7684 Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u4fa7\u89c6\u56fe\u3002<\/p>\n (b), H2<\/sub>S\u548cNi(OH)2<\/sub>\u7eb3\u7c73\u7247\u53cd\u5e94\u793a\u610f\u56fe\u3002<\/p>\n (c),\u786b\u7ed3\u5408\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u5206\u6790\u3002<\/p>\n \u56fe<\/strong>2<\/strong>\uff0c\u7ed3\u5408\u786b\u540e\u7684<\/strong>Ni(OH)2<\/sub><\/strong>\u7ed3\u6784\u56fe\u8c31<\/strong><\/p>\n (a), \u954dK<\/em>\u8fb9\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u80fd\u8c31\u76f8\u5e94\u7684\u632f\u52a8\u51fd\u6570\u3002<\/p>\n (b),\u76f8\u5e94\u7684\u5085\u91cc\u53f6\u53d8\u6362\uff0ck<\/em>\u4e3a\u6ce2\u77e2\uff0c\u03c7<\/em> (k<\/em>)\u4e3a\u5149\u7535\u5b50\u6ce2\u6570\u7684\u632f\u52a8\u51fd\u6570\u3002\u63d2\u56fe\u4e3a\u5085\u91cc\u53f6\u53d8\u6362\u653e\u5927\u89c6\u56fe\u3002<\/p>\n (c)\u4e09\u79cdNi(OH)2<\/sub>\u4e2d1<\/sup>H\u7684\u56fa\u4f53\u6838\u78c1\u5171\u632f\u5149\u8c31\u3002<\/p>\n \u56fe<\/strong>3<\/strong>\uff0c\u7ed3\u5408\u786b\u7684<\/strong>M-Ni(OH)2<\/sub><\/strong>\u7eb3\u7c73\u7247<\/strong>\u7535\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n (a), M-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u548cP-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u4e2dNi \u7684K<\/em>\u8fb9X\u5c04\u7ebf\u8fd1\u8fb9\u5438\u6536\u7ed3\u6784\u3002<\/p>\n (b), M-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u548cP-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u7684\u72b6\u6001\u5bc6\u5ea6(\u5782\u76f4\u7684\u84dd\u6761\u8868\u793a\u786b\u7ed3\u5408\u540e\u5e26\u9699\u964d\u4f4e)\u3002<\/p>\n (c), M-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u7684\u7535\u963b\u7387\u4e0e\u6e29\u5ea6\u6b63\u76f8\u5173\u3002<\/p>\n (d), M-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u7684\u8f7d\u6d41\u5b50\u6d53\u5ea6\u548c\u970d\u5c14\u7cfb\u6570\u3002<\/p>\n \u56fe<\/strong>4<\/strong>\uff0c<\/strong>M-Ni(OH)2<\/sub><\/strong>\u7eb3\u7c73\u7247\u7684\u5c3f\u7d20\u6c27\u5316\u50ac\u5316\u6027\u80fd<\/strong><\/p>\n (a), M-Ni(OH)2<\/sub>\u7684\u6781\u5316\u66f2\u7ebf\uff0c\u63d2\u56fe\u5c55\u793a\u7684\u662f\u8d77\u59cb\u7535\u4f4d\u3002<\/p>\n (b), M-Ni(OH)2<\/sub>\u548cP-Ni(OH)2<\/sub>\u6781\u5316\u66f2\u7ebf\u7684\u5bf9\u6bd4\u3002<\/p>\n (c), M-Ni(OH)2<\/sub>\u548cP-Ni(OH)2<\/sub>\u5728\u8ba1\u65f6\u7535\u6d41\u6d4b\u8bd5\u4e2d\u7684\u54cd\u5e94\u3002<\/p>\n (d),\u4e0d\u540c\u7535\u50ac\u5316\u5242\u76f8\u5e94\u7684\u6700\u5927\u7535\u6d41\u5bc6\u5ea6\u5bf9\u6bd4\u3002<\/p>\n \u56fe<\/strong>5<\/strong>\uff0c<\/strong>CO2<\/sub><\/strong>\u4ece\u7535\u50ac\u5316\u5242\u8868\u9762\u8131\u9644\u7684\u52a8\u529b\u5b66\u793a\u610f\u56fe<\/strong><\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u5177\u6709\u91d1\u5c5e\u6027\u8d28\u7684\u7eb3\u7c73\u7247\u5728\u5ba4\u6e29\u4e0b\u5c55\u73b0\u51fa\u9ad8\u8fbe3.19\u00d71000\u00a0S\u00b7m-1<\/sup>\u7684\u8d85\u9ad8\u5bfc\u7535\u7387\uff0c\u63d0\u4f9b\u4e86\u66f4\u591a\u6709\u6548\u7684\u7535\u5b50\u8f6c\u79fb\u3002\u7eb3\u7c73\u7247\u4e2d\u954d\u7684\u5316\u5b66\u72b6\u6001\u4fc3\u4f7f\u4e86CO2<\/sub>\u7684\u8131\u9644\u4e14\u968f\u4e4b\u66b4\u9732\u51fa\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u8fdb\u800c\u52a0\u5feb\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u8be5\u7814\u7a76\u4e3a\u954d\u57fa\u6750\u6599\u7684\u7535\u50ac\u5316\u6027\u80fd\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Metallic Nickel Hydroxide Nanosheets Give Superior Electrocatalytic Oxidation of Urea for Fuel Cells\u00a0<\/a>(Angew. Chem. Int. Ed., 2016, DOI:10.1002\/anie.201606313)<\/p>\n<\/strong><\/p>\n
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