{"id":39012,"date":"2016-09-19T06:30:45","date_gmt":"2016-09-18T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=39012"},"modified":"2016-09-18T12:45:06","modified_gmt":"2016-09-18T04:45:06","slug":"jacs%e5%88%b7%e5%9e%8b%e9%ab%98%e5%88%86%e5%ad%90%e7%a6%bb%e5%ad%90%e8%83%b6%e4%bd%93%e5%af%b9co2%e7%94%b5%e5%82%ac%e5%8c%96%e8%bf%98%e5%8e%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=39012","title":{"rendered":"JACS\uff1a\u5237\u578b\u9ad8\u5206\u5b50\u79bb\u5b50\u80f6\u4f53\u5bf9CO2\u7535\u50ac\u5316\u8fd8\u539f"},"content":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/span><\/strong><\/p>\n

\u52a0\u5dde\u7406\u5de5\u5927\u5b66Robert H. Grubbs Harry\u548c B. Gray\u7b49\u4eba\u5229\u7528\u7269\u7406\u4ea4\u8054\u7684\u9ad8\u5206\u5b50\u7f51\u683c\u6291\u5236\u5206\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5236\u5907\u4e86\u65e0\u56fa\u6001\u8d1f\u8f7d\u7684\u5747\u76f8\u5c0f\u5206\u5b50\u50ac\u5316\u5242\uff0c\u907f\u514d\u50ac\u5316\u5242\u5728\u56fa\u6001\u8d1f\u8f7d\u4e0a\u91cd\u65b0\u5206\u5e03\u548c\u8fde\u63a5\u3002\u6eb6\u89e3\u5728\u4e3b\u8981\u57fa\u8d28\u4e2d\u7684\u7535\u6d3b\u6027\u5c0f\u5206\u5b50\u5177\u6709\u9ad8\u79bb\u5b50\u5bfc\u901a\u6027\u5185\u5c42\u4ecb\u8d28\u7684\u6781\u6027\u3002\u50ac\u5316\u5242\u91cc\u7684Re(bpy)(CO)3<\/sub>Cl\u80fd\u591f\u4e0e\u8fd8\u539fCO2\u7684\u50ac\u5316\u5242\u76f8\u5339\u914d\uff0c\u4fdd\u8bc1\u50ac\u5316\u5242\u5177\u6709\u5b8f\u89c2\u56fa\u6001\u6027\u8d28\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/span><\/strong><\/p>\n

\u56fe\u4e00\u3001\u542b\u6709\u4e0d\u540c\u57fa\u8d28\u7684\u79bb\u5b50\u80f6\u4f53\u7684\u4f0f\u5b89\u5faa\u73af\u66f2\u7ebf<\/strong><\/p>\n

\"1\"<\/p>\n

\u7a7a\u767d\u79bb\u5b50\u80f6\u4f53\u7684\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff08\u9ed1\u8272\uff09\uff0c\u542b\u670914.3 mM\u4e8c\u8302\u94c1\uff08Fc\uff09\u7684\u79bb\u5b50\u80f6\u4f53\uff08\u7eff\u8272\uff09\uff0c\u542b\u670914.3 mM Fc\u548c15.3 mM CoCp2+<\/sup>\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff08\u84dd\u8272\uff09\u3002<\/p>\n

\u56fe\u4e8c\u3001\u79bb\u5b50\u80f6\u4f53\u91ccFc+\/0<\/sup>\u7684\u7535\u5316\u5b66\u6d3b\u6027\u8868\u5f81<\/strong><\/p>\n

\"2\"<\/p>\n

Fc+\/0<\/sup>\u5728\u79bb\u5b50\u6eb6\u80f6\u7535\u89e3\u8d28\u91cc\u9762\u7684\u626b\u63cf\u901f\u7387\u76f8\u5173\u6027\uff0814.3 mM Fc\uff09<\/p>\n

\u56fe\u4e09\u3001Re(bpy)(CO)3<\/sub>Cl\u548cFc\u4e24\u79cd\u7269\u8d28\u5bf9\u79bb\u5b50\u80f6\u4f53\u7684\u7535\u5316\u5b66\u6d3b\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n

\"3\"<\/p>\n

\u542b14.3 mM Re(bpy)(CO)3<\/sub>Cl\u548c5 mM Fc\u7684\u79bb\u5b50\u6eb6\u80f6\u7535\u89e3\u8d28\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\u50cf\u3002\u7535\u538b\u76f8\u5bf9\u4e8e\u534a\u53cd\u5e94Fc+\/0<\/sup>\u53d1\u751f\u4e86\u79fb\u52a8\u3002<\/p>\n

\u56fe\u56db\u3001\u5927\u6c14\u538b\u4e0b\uff0cRe(bpy)(CO)3<\/sub>Cl\u548cFc\u4e24\u79cd\u7269\u8d28\u5bf9\u79bb\u5b50\u80f6\u4f53\u7684\u7535\u5316\u5b66\u6d3b\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n

\"fig4\"<\/p>\n

\u542b14.3 mM Fc\uff0c\u57281 atm\u4e0b\u79bb\u5b50\u6eb6\u80f6\u7535\u89e3\u8d28\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff08\u9ed1\u8272\uff09\uff0c\u542b5 mM Fc\u548c10 mM Re(bpy)(CO)3<\/sub>Cl \u79bb\u5b50\u6eb6\u80f6\u7535\u89e3\u8d28\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff08\u84dd\u8272\uff09\uff0c\u542b7.1 mM Fc\u548c14.3 mM Re(bpy)(CO)3<\/sub>Cl\u79bb\u5b50\u6eb6\u80f6\u7535\u89e3\u8d28\u57281 atm\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff08\u7eff\u8272\uff09\u3002<\/p>\n

\u56fe\u4e94\u3001\u542b\u6709Re(bpy)(CO)3<\/sub>Cl\u548cFc\u4e24\u79cd\u7269\u8d28\u7684\u79bb\u5b50\u80f6\u4f53\u7684\u63a7\u5236\u7535\u52bf\u7814\u7a76<\/strong><\/p>\n

\"5\"<\/p>\n

\u00a0\u542b7.1 mM Fc\u548c14.3 mM Re(bpy)(CO)3<\/sub>Cl\u79bb\u5b50\u6eb6\u80f6\u7535\u89e3\u8d28\u57281 atm\u4e0b\u7684\u63a7\u5236\u7535\u52bf\u7535\u89e3\u66f2\u7ebf\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/span><\/p>\n

\u5747\u76f8\u6eb6\u6db2\u6001\u50ac\u5316\u5242\u548c\u591a\u76f8\u56fa\u6001\u50ac\u5316\u5242\u7684\u76f8\u7ed3\u5408\u5b9e\u73b0\u4e86\u5305\u542b\u4e86\u5177\u6709\u6db2\u6001\u52a8\u529b\u5b66\u7684\u7535\u5316\u5b66\u54cd\u5e94\u5c0f\u5206\u5b50\u7684\u56fa\u5316\u4f5c\u7528\uff0c\u8fd9\u79cd\u65b0\u6750\u6599\u5177\u6709\u901a\u5e38\u5747\u76f8\u6eb6\u6db2\u624d\u5177\u6709\u7535\u50ac\u5316\u8fd8\u539fCO2<\/sub>\u7279\u6027\uff0c\u4e0e\u901a\u5e38\u7684\u975e\u6db2\u6001\u7535\u89e3\u8d28\u76f8\u6bd4\uff0cCO2<\/sub>\u8fd8\u539f\u7535\u4f4d\u80fd\u591f\u660e\u663e\u5730\u964d\u4f4e\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Electrocatalysis of CO<\/span>2 <\/span>Reduction in Brush Polymer Ion Gels<\/span> <\/a>\uff08JACS\uff0c2016\uff0cDOI : <\/span>10.1021\/jacs.6b08795<\/span>\u00a0\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4\u4e1c\u6d77\u6728\u5b50\u674e\u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c \u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"\u65b0\u80fd\u6e90\u524d\u7ebf\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u52a0\u5dde\u7406\u5de5\u5927\u5b66Robert H. Grubbs Harry\u548c B. Gray\u7b49\u4eba\u5229\u7528\u7269\u7406\u4ea4\u8054\u7684\u9ad8\u5206\u5b50\u7f51\u683c\u6291\u5236\u5206\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5236\u5907\u4e86\u65e0\u56fa\u6001\u8d1f\u8f7d\u7684\u5747…<\/p>\n","protected":false},"author":1225,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[42],"class_list":["post-39012","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/39012"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1225"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=39012"}],"version-history":[{"count":12,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/39012\/revisions"}],"predecessor-version":[{"id":41726,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/39012\/revisions\/41726"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=39012"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=39012"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=39012"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}